JP2006008659A - シート状化粧料 - Google Patents
シート状化粧料 Download PDFInfo
- Publication number
- JP2006008659A JP2006008659A JP2005052431A JP2005052431A JP2006008659A JP 2006008659 A JP2006008659 A JP 2006008659A JP 2005052431 A JP2005052431 A JP 2005052431A JP 2005052431 A JP2005052431 A JP 2005052431A JP 2006008659 A JP2006008659 A JP 2006008659A
- Authority
- JP
- Japan
- Prior art keywords
- sheet
- meth
- component
- resin powder
- acrylate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000002537 cosmetic Substances 0.000 title claims abstract description 37
- 239000000843 powder Substances 0.000 claims abstract description 46
- -1 acrylate ester Chemical class 0.000 claims abstract description 43
- 239000006185 dispersion Substances 0.000 claims abstract description 39
- 229920005989 resin Polymers 0.000 claims abstract description 34
- 239000011347 resin Substances 0.000 claims abstract description 34
- 239000000178 monomer Substances 0.000 claims description 37
- 239000002245 particle Substances 0.000 claims description 34
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 16
- 229920001296 polysiloxane Polymers 0.000 claims description 16
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 13
- 239000000463 material Substances 0.000 claims description 7
- 238000006386 neutralization reaction Methods 0.000 claims description 7
- 229920000642 polymer Polymers 0.000 claims description 6
- 239000003795 chemical substances by application Substances 0.000 claims description 5
- 239000002270 dispersing agent Substances 0.000 claims description 4
- 125000005396 acrylic acid ester group Chemical group 0.000 claims description 2
- 125000005397 methacrylic acid ester group Chemical group 0.000 claims description 2
- 230000006835 compression Effects 0.000 abstract description 3
- 238000007906 compression Methods 0.000 abstract description 3
- 239000004615 ingredient Substances 0.000 abstract description 2
- 206010013786 Dry skin Diseases 0.000 abstract 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 37
- 238000004519 manufacturing process Methods 0.000 description 15
- 239000003921 oil Substances 0.000 description 14
- 235000019198 oils Nutrition 0.000 description 14
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 12
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 12
- 229920001577 copolymer Polymers 0.000 description 11
- 238000006116 polymerization reaction Methods 0.000 description 11
- 125000000217 alkyl group Chemical group 0.000 description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 10
- 239000002585 base Substances 0.000 description 9
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 9
- 235000019441 ethanol Nutrition 0.000 description 9
- 239000000203 mixture Substances 0.000 description 9
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
- 125000004432 carbon atom Chemical group C* 0.000 description 8
- 238000000034 method Methods 0.000 description 8
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 7
- 150000003839 salts Chemical group 0.000 description 7
- 238000003756 stirring Methods 0.000 description 7
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 6
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 6
- 239000004698 Polyethylene Substances 0.000 description 6
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 6
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 6
- 125000003342 alkenyl group Chemical group 0.000 description 6
- 229920000573 polyethylene Polymers 0.000 description 6
- 238000005507 spraying Methods 0.000 description 6
- 239000000758 substrate Substances 0.000 description 6
- YIVJZNGAASQVEM-UHFFFAOYSA-N Lauroyl peroxide Chemical compound CCCCCCCCCCCC(=O)OOC(=O)CCCCCCCCCCC YIVJZNGAASQVEM-UHFFFAOYSA-N 0.000 description 5
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 5
- 238000005470 impregnation Methods 0.000 description 5
- 239000007788 liquid Substances 0.000 description 5
- 239000004745 nonwoven fabric Substances 0.000 description 5
- LYCAIKOWRPUZTN-NMQOAUCRSA-N 1,2-dideuteriooxyethane Chemical compound [2H]OCCO[2H] LYCAIKOWRPUZTN-NMQOAUCRSA-N 0.000 description 4
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 4
- DBCAQXHNJOFNGC-UHFFFAOYSA-N 4-bromo-1,1,1-trifluorobutane Chemical compound FC(F)(F)CCCBr DBCAQXHNJOFNGC-UHFFFAOYSA-N 0.000 description 4
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 4
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 4
- 239000007900 aqueous suspension Substances 0.000 description 4
- STVZJERGLQHEKB-UHFFFAOYSA-N ethylene glycol dimethacrylate Substances CC(=C)C(=O)OCCOC(=O)C(C)=C STVZJERGLQHEKB-UHFFFAOYSA-N 0.000 description 4
- 229910052757 nitrogen Inorganic materials 0.000 description 4
- 239000004094 surface-active agent Substances 0.000 description 4
- XDOFQFKRPWOURC-UHFFFAOYSA-N 16-methylheptadecanoic acid Chemical compound CC(C)CCCCCCCCCCCCCCC(O)=O XDOFQFKRPWOURC-UHFFFAOYSA-N 0.000 description 3
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 229920002125 Sokalan® Polymers 0.000 description 3
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 3
- 125000002947 alkylene group Chemical group 0.000 description 3
- 230000001166 anti-perspirative effect Effects 0.000 description 3
- 239000003213 antiperspirant Substances 0.000 description 3
- 235000019437 butane-1,3-diol Nutrition 0.000 description 3
- 150000001768 cations Chemical class 0.000 description 3
- 125000004122 cyclic group Chemical group 0.000 description 3
- 235000014113 dietary fatty acids Nutrition 0.000 description 3
- 239000004205 dimethyl polysiloxane Substances 0.000 description 3
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 3
- GMSCBRSQMRDRCD-UHFFFAOYSA-N dodecyl 2-methylprop-2-enoate Chemical compound CCCCCCCCCCCCOC(=O)C(C)=C GMSCBRSQMRDRCD-UHFFFAOYSA-N 0.000 description 3
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 3
- 239000000194 fatty acid Substances 0.000 description 3
- 229930195729 fatty acid Natural products 0.000 description 3
- 150000004665 fatty acids Chemical class 0.000 description 3
- 239000003205 fragrance Substances 0.000 description 3
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 3
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 3
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 3
- 229920000728 polyester Polymers 0.000 description 3
- 239000003505 polymerization initiator Substances 0.000 description 3
- 229920001451 polypropylene glycol Polymers 0.000 description 3
- 239000008213 purified water Substances 0.000 description 3
- 210000002374 sebum Anatomy 0.000 description 3
- 229910052708 sodium Inorganic materials 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 3
- 210000004243 sweat Anatomy 0.000 description 3
- BJDAUCLANVMIOB-UHFFFAOYSA-N (3-decanoyloxy-2,2-dimethylpropyl) decanoate Chemical compound CCCCCCCCCC(=O)OCC(C)(C)COC(=O)CCCCCCCCC BJDAUCLANVMIOB-UHFFFAOYSA-N 0.000 description 2
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 2
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 2
- 229940058015 1,3-butylene glycol Drugs 0.000 description 2
- SPSPIUSUWPLVKD-UHFFFAOYSA-N 2,3-dibutyl-6-methylphenol Chemical compound CCCCC1=CC=C(C)C(O)=C1CCCC SPSPIUSUWPLVKD-UHFFFAOYSA-N 0.000 description 2
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 2
- TXBCBTDQIULDIA-UHFFFAOYSA-N 2-[[3-hydroxy-2,2-bis(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propane-1,3-diol Chemical class OCC(CO)(CO)COCC(CO)(CO)CO TXBCBTDQIULDIA-UHFFFAOYSA-N 0.000 description 2
- MACVUTCNLULHLQ-UHFFFAOYSA-N 2-[methyl(octadecanoyl)amino]ethanesulfonic acid;sodium Chemical compound [Na].CCCCCCCCCCCCCCCCCC(=O)N(C)CCS(O)(=O)=O MACVUTCNLULHLQ-UHFFFAOYSA-N 0.000 description 2
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 2
- RDFQSFOGKVZWKF-UHFFFAOYSA-N 3-hydroxy-2,2-dimethylpropanoic acid Chemical class OCC(C)(C)C(O)=O RDFQSFOGKVZWKF-UHFFFAOYSA-N 0.000 description 2
- HIQIXEFWDLTDED-UHFFFAOYSA-N 4-hydroxy-1-piperidin-4-ylpyrrolidin-2-one Chemical compound O=C1CC(O)CN1C1CCNCC1 HIQIXEFWDLTDED-UHFFFAOYSA-N 0.000 description 2
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 2
- 239000004342 Benzoyl peroxide Substances 0.000 description 2
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 2
- 229920000742 Cotton Polymers 0.000 description 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- 239000004166 Lanolin Substances 0.000 description 2
- 239000004909 Moisturizer Substances 0.000 description 2
- 239000005642 Oleic acid Substances 0.000 description 2
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 2
- 239000004743 Polypropylene Substances 0.000 description 2
- 229920000297 Rayon Polymers 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 2
- 239000012736 aqueous medium Substances 0.000 description 2
- 125000003710 aryl alkyl group Chemical group 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- 239000003899 bactericide agent Substances 0.000 description 2
- 235000019400 benzoyl peroxide Nutrition 0.000 description 2
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 2
- 235000010354 butylated hydroxytoluene Nutrition 0.000 description 2
- 239000004359 castor oil Substances 0.000 description 2
- 235000019438 castor oil Nutrition 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000012669 compression test Methods 0.000 description 2
- 239000003431 cross linking reagent Substances 0.000 description 2
- 125000000753 cycloalkyl group Chemical group 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000010696 ester oil Substances 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 235000011187 glycerol Nutrition 0.000 description 2
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 2
- 125000005842 heteroatom Chemical group 0.000 description 2
- XXMIOPMDWAUFGU-UHFFFAOYSA-N hexane-1,6-diol Chemical compound OCCCCCCO XXMIOPMDWAUFGU-UHFFFAOYSA-N 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 150000007529 inorganic bases Chemical class 0.000 description 2
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 2
- XUGNVMKQXJXZCD-UHFFFAOYSA-N isopropyl palmitate Chemical compound CCCCCCCCCCCCCCCC(=O)OC(C)C XUGNVMKQXJXZCD-UHFFFAOYSA-N 0.000 description 2
- 229940039717 lanolin Drugs 0.000 description 2
- 235000019388 lanolin Nutrition 0.000 description 2
- 238000000691 measurement method Methods 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 230000001333 moisturizer Effects 0.000 description 2
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 2
- 229940117969 neopentyl glycol Drugs 0.000 description 2
- 125000004433 nitrogen atom Chemical group N* 0.000 description 2
- 239000002304 perfume Substances 0.000 description 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 2
- 229920001155 polypropylene Polymers 0.000 description 2
- 239000002964 rayon Substances 0.000 description 2
- 238000010992 reflux Methods 0.000 description 2
- 229920002545 silicone oil Polymers 0.000 description 2
- 229910000029 sodium carbonate Inorganic materials 0.000 description 2
- PRAKJMSDJKAYCZ-UHFFFAOYSA-N squalane Chemical compound CC(C)CCCC(C)CCCC(C)CCCCC(C)CCCC(C)CCCC(C)C PRAKJMSDJKAYCZ-UHFFFAOYSA-N 0.000 description 2
- 238000010557 suspension polymerization reaction Methods 0.000 description 2
- XOAAWQZATWQOTB-UHFFFAOYSA-N taurine Chemical class NCCS(O)(=O)=O XOAAWQZATWQOTB-UHFFFAOYSA-N 0.000 description 2
- 229920005992 thermoplastic resin Polymers 0.000 description 2
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 2
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 2
- 239000002759 woven fabric Substances 0.000 description 2
- JNYAEWCLZODPBN-JGWLITMVSA-N (2r,3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol Chemical compound OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O JNYAEWCLZODPBN-JGWLITMVSA-N 0.000 description 1
- ALSTYHKOOCGGFT-KTKRTIGZSA-N (9Z)-octadecen-1-ol Chemical compound CCCCCCCC\C=C/CCCCCCCCO ALSTYHKOOCGGFT-KTKRTIGZSA-N 0.000 description 1
- QMMJWQMCMRUYTG-UHFFFAOYSA-N 1,2,4,5-tetrachloro-3-(trifluoromethyl)benzene Chemical compound FC(F)(F)C1=C(Cl)C(Cl)=CC(Cl)=C1Cl QMMJWQMCMRUYTG-UHFFFAOYSA-N 0.000 description 1
- QLLUAUADIMPKIH-UHFFFAOYSA-N 1,2-bis(ethenyl)naphthalene Chemical compound C1=CC=CC2=C(C=C)C(C=C)=CC=C21 QLLUAUADIMPKIH-UHFFFAOYSA-N 0.000 description 1
- JNAYPSWVMNJOPQ-UHFFFAOYSA-N 2,3-bis(16-methylheptadecanoyloxy)propyl 16-methylheptadecanoate Chemical compound CC(C)CCCCCCCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCCCCCCCC(C)C)COC(=O)CCCCCCCCCCCCCCC(C)C JNAYPSWVMNJOPQ-UHFFFAOYSA-N 0.000 description 1
- XFOQWQKDSMIPHT-UHFFFAOYSA-N 2,3-dichloro-6-(trifluoromethyl)pyridine Chemical compound FC(F)(F)C1=CC=C(Cl)C(Cl)=N1 XFOQWQKDSMIPHT-UHFFFAOYSA-N 0.000 description 1
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 1
- WYGWHHGCAGTUCH-UHFFFAOYSA-N 2-[(2-cyano-4-methylpentan-2-yl)diazenyl]-2,4-dimethylpentanenitrile Chemical compound CC(C)CC(C)(C#N)N=NC(C)(C#N)CC(C)C WYGWHHGCAGTUCH-UHFFFAOYSA-N 0.000 description 1
- OWTQQPNDSWCHOV-UHFFFAOYSA-N 2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-(2-hydroxyethoxy)ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethanol Chemical compound OCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCO OWTQQPNDSWCHOV-UHFFFAOYSA-N 0.000 description 1
- VXZBYIWNGKSFOJ-UHFFFAOYSA-N 2-[4-[5-(2,3-dihydro-1H-inden-2-ylamino)pyrazin-2-yl]pyrazol-1-yl]-1-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)ethanone Chemical compound C1C(CC2=CC=CC=C12)NC=1N=CC(=NC=1)C=1C=NN(C=1)CC(=O)N1CC2=C(CC1)NN=N2 VXZBYIWNGKSFOJ-UHFFFAOYSA-N 0.000 description 1
- LTQRFSDXNWHXKQ-UHFFFAOYSA-N 2-[methyl(octadecanoyl)amino]ethanesulfonic acid Chemical compound CCCCCCCCCCCCCCCCCC(=O)N(C)CCS(O)(=O)=O LTQRFSDXNWHXKQ-UHFFFAOYSA-N 0.000 description 1
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- SFAAOBGYWOUHLU-UHFFFAOYSA-N 2-ethylhexyl hexadecanoate Chemical compound CCCCCCCCCCCCCCCC(=O)OCC(CC)CCCC SFAAOBGYWOUHLU-UHFFFAOYSA-N 0.000 description 1
- WFUGQJXVXHBTEM-UHFFFAOYSA-N 2-hydroperoxy-2-(2-hydroperoxybutan-2-ylperoxy)butane Chemical compound CCC(C)(OO)OOC(C)(CC)OO WFUGQJXVXHBTEM-UHFFFAOYSA-N 0.000 description 1
- MUHFRORXWCGZGE-KTKRTIGZSA-N 2-hydroxyethyl (z)-octadec-9-enoate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCCO MUHFRORXWCGZGE-KTKRTIGZSA-N 0.000 description 1
- GECRRQVLQHRVNH-MRCUWXFGSA-N 2-octyldodecyl (z)-octadec-9-enoate Chemical compound CCCCCCCCCCC(CCCCCCCC)COC(=O)CCCCCCC\C=C/CCCCCCCC GECRRQVLQHRVNH-MRCUWXFGSA-N 0.000 description 1
- BGRXBNZMPMGLQI-UHFFFAOYSA-N 2-octyldodecyl tetradecanoate Chemical compound CCCCCCCCCCCCCC(=O)OCC(CCCCCCCC)CCCCCCCCCC BGRXBNZMPMGLQI-UHFFFAOYSA-N 0.000 description 1
- FRIBMENBGGCKPD-UHFFFAOYSA-N 3-(2,3-dimethoxyphenyl)prop-2-enal Chemical compound COC1=CC=CC(C=CC=O)=C1OC FRIBMENBGGCKPD-UHFFFAOYSA-N 0.000 description 1
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 1
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- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
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Landscapes
- Cosmetics (AREA)
Abstract
【解決手段】 (a)圧縮強度が0.7〜10kgf/mm2である架橋(メタ)アクリル酸エステル系樹脂粉体及び(b)油剤を含有する水性分散液を、シート状基材に含浸させてなるシート状化粧料。
【選択図】 なし
Description
(a)圧縮強度が0.7〜10kgf/mm2である架橋(メタ)アクリル酸エステル系樹脂粉体
(b)油剤
本発明はまた、更に必要により、水性分散液が、(c)成分として高分子分散剤、(d)成分としてポリ(N−アシルアルキレンイミン)変性シリコーンを含有するシート状化粧料を提供する。
本発明の(a)成分の樹脂粉体は、十分なさらさら感及びなめらかさを得る観点から、圧縮強度が0.7〜10kgf/mm2であり、特に2〜8kgf/mm2が好ましい。
樹脂粒子の圧縮強度は、樹脂粒子を構成する単量体と架橋剤の種類と配合量を制御することにより、適宜調節することができる。
なお、本明細書において、「(メタ)アクリル」とは、アクリル及びメタクリルの両方を含む概念である。
[式中、R1は置換基を有していてもよい炭素数5〜30のアルキル基又はアルケニル基、R2は水素原子又はメチル基、Mは水素原子又はカチオンを示す。]
一般式(I)において、R1としては、炭素数6〜24のアルキル基又はアルケニル基が好ましい。具体例としては、ヘキシル、オクチル、ノニル、デシル、ウンデシル、ドデシル、テトラデシル、ヘキサデシル、オクタデシル、エイコシル、ドコシル、テトラコシル、デセニル、ドデセニル、テトラデセニル、ヘキサデセニル、オクタデセニル、エイコセニル等が挙げられる。また、アルキル基又はアルケニル基の置換基としては、水酸基、カルボキシル基、エステル基、エーテル基、アミド基等が挙げられる。
重合温度や重合時間は特に限定されるものではないが、重合温度は40〜100℃、重合時間は1〜15時間が好ましい。
本発明の(b)成分として用いられる油剤としては、シリコーン油、炭化水素類、エステル油、脂肪族アルコール類、エーテル油、分岐脂肪酸類等が挙げられる。
本発明の(c)成分として用いられる高分子分散剤は、水溶性であって、水性媒体中での成分(a)及び成分(b)の分散性向上に寄与する高分子化合物である。例えば、カルボキシビニルポリマー、アルキル変性カルボキシビニルポリマー、(メタ)アクリル酸又はその塩・(メタ)アクリル酸アルキル共重合体、(メタ)アクリル酸又はその塩・(メタ)アクリル酸アルキル・(メタ)アクリル酸ポリオキシエチレンアルキルエーテル共重合体等が挙げられる。これらの高分子化合物は、カルボン酸基を適当な塩基で部分的に中和することにより、好適な増粘性や分散性を発揮する。用いられる塩基は、水酸化ナトリウム、水酸化カリウム、炭酸ナトリウム、アンモニア等の無機塩基、トリエタノールアミン、アミノメチルプロパノール、ジイソプロパノールアミン等のアルカノールアミン類等である。
本発明の(d)成分として用いられるポリ(N−アシルアルキレンイミン)変性シリコーンとしては、オルガノポリシロキサンセグメントの末端又は鎖中のケイ素原子の少なくとも1個に、ヘテロ原子を含むアルキレン基を介して、下記一般式(II)
で表される繰り返し単位からなるポリ(N−アシルアルキレンイミン)のセグメントが結合してなるものが挙げられる。
本発明のシート状化粧料は、上記(a)成分及び(b)成分、更に必要により(c)成分、(d)成分等を含有する水性分散液をシート状基材に含浸させることにより得ることができる。
ビーカーにラウリルメタクリレート82g、メタクリル酸3g、エチレングリコールジメタクリレート15g、ラウロイルパーオキサイド2gを仕込み混合攪拌して溶解させた。ここにN−ステアロイル−N−メチルタウリンナトリウム(SMT)を0.75g溶解させたイオン交換水400gを加え、ホモミキサーで粒径が2.2μmになるまで分散させた。
製造例1において、重合した粒子の分散液に1N NaOH3.9gを滴下して中和を行った以外は、製造例1と同様にして樹脂粉体Aの中和品を得た。この樹脂粉体Aの中和品は、カルボキシル基の中和度が11.2%であった。
ビーカーにブチルアクリレート82g、メタクリル酸3g、エチレングリコールジメタクリレート15g、ラウロイルパーオキサイド2gを仕込み混合撹拌して溶解させた。ここにN−ステアロイル−N−メチルタウリンナトリウム(SMT)を0.75g溶解させたイオン交換水400gを加え、ホモミキサーで粒径3.5μmになるまで分散させた。
製造例3において、重合した粒子の分散液に1N NaOH3.9gを滴下して中和を行った以外は、製造例3と同様にして樹脂粉体Bの中和品を得た。この樹脂粉体Bの中和品は、カルボキシル基の中和度が11.2%であった。
ビーカーにラウリルメタクリレート85g、エチレングリコールジメタクリレート15g、ラウロイルパーオキサイド2gを仕込み混合攪拌して溶解させた。ここにN−ステアロイル−N−メチルタウリンナトリウム(SMT)を0.75g溶解させた。イオン交換水400gを加え、ホモミキサーで粒径が2.4μmになるまで分散させた。
ビーカーにラウリルメタクリレート82g、メタクリル酸3g、エチレングリコールジメタクリレート15g、ラウロイルパーオキサイド2gを仕込み混合攪拌して溶解させた。ここにドデシル硫酸ナトリウム(SDS)を0.75g溶解させたイオン交換水400gを加え、ホモミキサーで粒径が2.5μmになるまで分散させた。
樹脂粉体を(株)堀場製作所レーザー回折散乱式粒度分布測定装置(型番:LA920)にて、相対屈折率が1.10(樹脂粉体の屈折率を1.46、水の屈折率を1.33とする)の条件にて、粒径を測定した際のメジアン径を平均粒径とした。
樹脂粒子を、(株)島津製作所製微小圧縮試験機MCT-M200にて、29mgf/sの一定負荷速度で1gfの荷重まで圧縮試験を行い、粒子径の10%変形時の荷重と粒子径とから下記式によって算出した。10点の試料について測定を行い、その平均値をもって圧縮強度とした。
硫酸ジエチル3.77g(0.0244モル)と2−エチル−2−オキサゾリン48.4g(0.488モル)を脱水したクロロホルム107gに溶解し、窒素雰囲気下5時間加熱還流し、ポリ(N−プロピオニルエチレンイミン)の末端未反応ポリマー(分子量2000)を合成した。ここに、側鎖1級アミノプロピル変性ジメチルシロキサン(分子量110000,アミン当量9840)400g(アミノ基にして0.0407モル)の50%酢酸エチル溶液を一括して加え、13時間加熱還流した。反応混合物を減圧濃縮し、ポリジメチルシロキサンにN−プロピオニルエチレンイミン鎖の付いたグラフト共重合体(分子量137000)が得られた。得られた共重合体は淡黄色ゴム状固体(収量444g,収率98%)であった。
表2に示す組成の水性分散液5gを、2gのパルプシート(坪量60g/m2)上にスプレーで噴霧することにより含浸させてシート状化粧料を調製した。水性分散液の含浸率は250質量%である。
・さらさら感
スコア4…さらさらする
スコア3…ややさらさらする
スコア2…余りさらさらしない
スコア1…さらさらしない
・かさつきの少なさ
スコア4…かさつかない
スコア3…余りかさつかない
スコア2…ややかさつく
スコア1…かさつく
・さらさら感の持続性(塗布1時間後)
スコア4…さらさら感が持続する
スコア3…さらさら感がやや持続する
スコア2…さらさら感が余り持続しない
スコア1…さらさら感が持続しない
<判定基準>
平均スコア3.5〜4.0…◎
平均スコア2.5〜3.4…○
平均スコア1.5〜2.4…△
平均スコア1.0〜1.4…×
下記組成の水性分散液2gを、2gの80%レーヨン/20%ポリエチレン不織布(坪量50g/m2)上にスプレーで噴霧することにより含浸させてシート状化粧料を調製した。水性分散液の含浸率は100質量%である。得られたシート状化粧料は、さらさらし、かさつかず、また塗布1時間後もさらさら感が持続していた。
樹脂粉体B 5.00%
ミリスチン酸イソプロピル 2.00
ジメチルシリコーン(10cs) 0.50
KF−6015*1 0.05
ポリオキシエチレン硬化ヒマシ油*2 0.15
PEMULEN TR-1*3 0.10
トリエタノールアミン 0.10
香料 0.10
エタノール 15.00
精製水 77.00
合計 100.00
*1:ポリオキシエチレン・メチルポリシロキサン共重合体 信越化学社製
*2:エマノーンCH−40 花王社製
*3:アクリル酸・メタクリル酸アルキル共重合体 Noveon INC.製。
下記組成の水性分散液4gを、1.5gの90%パルプ/10%ポリエチレン不織布(坪量50g/m2)上にスプレーで噴霧することにより含浸させてシート状化粧料を調製した。水性分散液の含浸率は267質量%である。得られたシート状化粧料は、さらさらし、かさつかず、また塗布1時間後もさらさら感が持続していた。
樹脂粉体Bの中和品 6.00%
パルミチン酸イソプロピル 2.00
オレイン酸 0.10
キハダエキス 0.50
カーボポールETD2020*1 0.15
トリエタノールアミン 0.15
ジブチルヒドロキシトルエン 0.02
香料 0.08
エタノール 50.00
精製水 41.00
合計 100.00
*1:アクリル酸・メタクリル酸アルキル共重合体 Noveon INC.製。
下記組成の水性分散液5gを、2gの85%パルプ/15%ポリエチレン不織布(坪量50g/m2)上にスプレーで噴霧することにより含浸させてシート状化粧料を調製した。水性分散液の含浸率は250質量%である。得られたシート状化粧料は、さらさらし、かさつかず、また塗布1時間後もさらさら感が持続していた。
樹脂粉体Bの中和品 5.00%
ジカプリン酸ネオペンチルグリコール 0.50
モノステアリン酸ポリオキシエチレン(EO=20)ソルビタン 0.15
PEG400 0.50
PEMULEN TR-1*1 0.15
炭酸ナトリウム 0.02
香料 0.06
ジブチルヒドロキシトルエン 0.02
エタノール 25.00
精製水 68.60
合計 100.00
*1:アクリル酸・メタクリル酸アルキル共重合体 Noveon INC.製
Claims (6)
- 下記(a)成分及び(b)成分を含有する水性分散液を、シート状基材に含浸させてなるシート状化粧料。
(a)圧縮強度が0.7〜10kgf/mm2である架橋(メタ)アクリル酸エステル系樹脂粉体
(b)油剤 - 架橋(メタ)アクリル酸エステル系樹脂粉体が、アクリル酸エステル及びメタクリル酸エステルから選ばれる少なくとも1種の単量体とカルボキシル基を有する単量体とを含む単量体成分を共重合してなる請求項1記載のシート状化粧料。
- 樹脂粉体中のカルボキシル基の中和度が1〜30%である請求項2記載のシート状化粧料。
- (a)成分の樹脂粉体の平均粒径が1〜10μmである、請求項1〜3いずれかに記載のシート状化粧料。
- 水性分散液が、更に(c)成分として、高分子分散剤を含有する請求項1〜4いずれかに記載のシート状化粧料。
- 水性分散液が、更に(d)成分として、ポリ(N−アシルアルキレンイミン)変性シリコーンを含有する請求項1〜5いずれかに記載のシート状化粧料。
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JP2005052431A JP3889426B2 (ja) | 2004-05-28 | 2005-02-28 | シート状化粧料 |
AU2005202290A AU2005202290B2 (en) | 2004-05-28 | 2005-05-26 | Cosmetic preparation |
US11/137,493 US8142768B2 (en) | 2004-05-28 | 2005-05-26 | Cosmetic preparation |
TW094117205A TW200607526A (en) | 2004-05-28 | 2005-05-26 | Sheet cosmetic |
CN200510073068.3A CN1781475B (zh) | 2004-05-28 | 2005-05-27 | 化妆品 |
DE602005018722T DE602005018722D1 (de) | 2004-05-28 | 2005-05-27 | Kosmetische Zusammensetzung enthaltend einen pulverförmigen vernetzten (Meth)Acrylsäureester |
EP05011459.4A EP1634564B2 (en) | 2004-05-28 | 2005-05-27 | Cosmetic preparation comprising a crosslinked (meth)acrylic acid ester resin powder |
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