JP2005513172A5 - - Google Patents
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- Publication number
- JP2005513172A5 JP2005513172A5 JP2003514025A JP2003514025A JP2005513172A5 JP 2005513172 A5 JP2005513172 A5 JP 2005513172A5 JP 2003514025 A JP2003514025 A JP 2003514025A JP 2003514025 A JP2003514025 A JP 2003514025A JP 2005513172 A5 JP2005513172 A5 JP 2005513172A5
- Authority
- JP
- Japan
- Prior art keywords
- linear
- initiator
- molar ratio
- diene elastomer
- range
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229920003244 diene elastomer Polymers 0.000 claims 30
- 239000003795 chemical substances by application Substances 0.000 claims 24
- 239000003999 initiator Substances 0.000 claims 23
- 239000003054 catalyst Substances 0.000 claims 20
- 150000001993 dienes Chemical class 0.000 claims 15
- 238000004519 manufacturing process Methods 0.000 claims 14
- 229910052751 metal Inorganic materials 0.000 claims 14
- 239000002184 metal Substances 0.000 claims 14
- 150000003839 salts Chemical class 0.000 claims 14
- 239000000178 monomer Substances 0.000 claims 9
- -1 vinyl aromatic compound Chemical class 0.000 claims 9
- 229920001971 elastomer Polymers 0.000 claims 8
- 239000000806 elastomer Substances 0.000 claims 8
- 125000001931 aliphatic group Chemical group 0.000 claims 7
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims 6
- 239000004215 Carbon black (E152) Substances 0.000 claims 5
- 125000005842 heteroatom Chemical group 0.000 claims 5
- 229930195733 hydrocarbon Natural products 0.000 claims 5
- 125000001979 organolithium group Chemical group 0.000 claims 5
- 239000002904 solvent Substances 0.000 claims 5
- 238000010539 anionic addition polymerization reaction Methods 0.000 claims 4
- 238000006243 chemical reaction Methods 0.000 claims 4
- 238000000034 method Methods 0.000 claims 4
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 claims 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims 2
- KWYHDKDOAIKMQN-UHFFFAOYSA-N N,N,N',N'-tetramethylethylenediamine Chemical group CN(C)CCN(C)C KWYHDKDOAIKMQN-UHFFFAOYSA-N 0.000 claims 2
- 125000002723 alicyclic group Chemical group 0.000 claims 2
- 229910052783 alkali metal Inorganic materials 0.000 claims 2
- 125000004432 carbon atom Chemical group C* 0.000 claims 2
- 229920001577 copolymer Polymers 0.000 claims 2
- 150000004985 diamines Chemical class 0.000 claims 2
- 238000006116 polymerization reaction Methods 0.000 claims 2
- 159000000000 sodium salts Chemical group 0.000 claims 2
- 229920002554 vinyl polymer Polymers 0.000 claims 2
- 150000001450 anions Chemical class 0.000 claims 1
- 239000006085 branching agent Substances 0.000 claims 1
- 239000007822 coupling agent Substances 0.000 claims 1
- 229920001519 homopolymer Polymers 0.000 claims 1
- 229920002587 poly(1,3-butadiene) polymer Polymers 0.000 claims 1
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR0110287 | 2001-07-16 | ||
| PCT/EP2002/007866 WO2003008470A1 (fr) | 2001-07-16 | 2002-07-16 | Elastomeres dieniques a unites vinyliques cycliques et procedes d'obtention |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2005513172A JP2005513172A (ja) | 2005-05-12 |
| JP2005513172A5 true JP2005513172A5 (https=) | 2006-01-05 |
| JP4391228B2 JP4391228B2 (ja) | 2009-12-24 |
Family
ID=8866156
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2003514025A Expired - Lifetime JP4391228B2 (ja) | 2001-07-16 | 2002-07-16 | 環状ビニル単位を持つジエンエラストマー及びその製造方法 |
Country Status (5)
| Country | Link |
|---|---|
| US (2) | US7470760B2 (https=) |
| EP (1) | EP1423442B1 (https=) |
| JP (1) | JP4391228B2 (https=) |
| CN (2) | CN100509879C (https=) |
| WO (1) | WO2003008470A1 (https=) |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100509879C (zh) * | 2001-07-16 | 2009-07-08 | 米其林技术公司 | 含有环乙烯基单元的二烯高弹体及其制备工艺 |
| JP4741457B2 (ja) * | 2003-01-20 | 2011-08-03 | ソシエテ ド テクノロジー ミシュラン | タイヤトレッドのためのゴム組成物及びその調製方法 |
| JP4716756B2 (ja) * | 2005-03-03 | 2011-07-06 | 旭化成ケミカルズ株式会社 | ランダム共重合体の製造方法 |
| CN103459431B (zh) | 2011-05-27 | 2015-01-21 | 旭化成化学株式会社 | 氢化共轭二烯系共聚物的制造方法 |
| SG11201600094YA (en) * | 2013-07-17 | 2016-02-26 | Asahi Kasei Chemicals Corp | Method for producing polymer |
| EP3023439B1 (en) * | 2013-07-17 | 2018-02-07 | Asahi Kasei Kabushiki Kaisha | Method for producing polymer |
| CN116253819A (zh) * | 2016-04-20 | 2023-06-13 | 雅宝公司 | 用于氢介导的盐型氢化物引发的阴离子链转移聚合的方法和催化剂 |
| BR112019000021B1 (pt) | 2016-09-09 | 2023-03-28 | Dynasol Elastómeros, S.A. De C.V | Sistemas modificadores polares para copolimerização em bloco com alto conteúdo de vinila, copolímero em bloco, e seu processo de produção |
| CN109485791B (zh) * | 2017-09-13 | 2021-10-19 | 中国石油化工股份有限公司 | 线形丁苯共聚物及其制备方法和组合物以及芳族乙烯基树脂及其制备方法 |
| TWI774882B (zh) | 2017-11-22 | 2022-08-21 | 日商可樂麗股份有限公司 | 嵌段共聚物或其氫化物 |
| US11542355B2 (en) | 2018-10-18 | 2023-01-03 | Dynasol Elastómeros, S.A. De C.V. | Polar modifier systems for high vinyl block copolymerization |
| CN113825793B (zh) * | 2019-05-22 | 2023-06-09 | 株式会社可乐丽 | 二烯系橡胶和橡胶组合物 |
| EP4148075A4 (en) * | 2020-05-21 | 2023-11-08 | China Petroleum & Chemical Corporation | LIQUID BUTYLBENZENE POLYMER, PRODUCTION PROCESS THEREOF AND APPLICATION THEREOF, AS WELL AS COMPOSITION, POLYMER COATING, ADHESIVE AND CROSSLINKING AGENT |
Family Cites Families (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3294768A (en) | 1963-11-14 | 1966-12-27 | Phillips Petroleum Co | Preparation of conjugated diene polymers |
| US3301840A (en) * | 1964-09-17 | 1967-01-31 | Phillips Petroleum Co | Preparation of polymers of conjugated dienes using organolithium/polar compound catalyst systems |
| US3801554A (en) * | 1972-02-28 | 1974-04-02 | Phillips Petroleum Co | Lithium alkenoxides as modifiers in organolithium initiated polymerization |
| US3966691A (en) * | 1973-07-12 | 1976-06-29 | The Firestone Tire & Rubber Company | Polymerization of conjugated dienes with starved lithium, potassium or sodium catalyst |
| GB2020670A (en) * | 1978-05-09 | 1979-11-21 | Polymer Investments Nv | Liquid polymer and liquid copolymers of Butadiene and the preparation thereof. |
| DE2905763A1 (de) * | 1979-02-15 | 1980-08-28 | Bayer Ag | Katalysator, dessen herstellung und verwendung bei der herstellung von telomeren polybutadien homo- oder copolymerisaten |
| JPS57117508A (en) * | 1981-01-14 | 1982-07-22 | Asahi Chem Ind Co Ltd | Preparation of conjugated diene polymer |
| JPS5996112A (ja) * | 1982-11-26 | 1984-06-02 | Toyo Soda Mfg Co Ltd | 高純度イソプレン重合体環化物の製造方法 |
| JPS6071616A (ja) * | 1983-09-29 | 1985-04-23 | Japan Synthetic Rubber Co Ltd | ホトレジスト用共役ジエン系重合体環化物の製造方法 |
| JPS60206804A (ja) * | 1984-03-30 | 1985-10-18 | Japan Synthetic Rubber Co Ltd | 共役ジエン系重合体環化物の製法 |
| DE3707434A1 (de) * | 1986-05-31 | 1987-12-03 | Huels Chemische Werke Ag | Polyisoprene mit einem hohen anteil von 1,2- und 3,4-struktureinheiten, verfahren zu ihrer herstellung und ihre verwendung |
| US4696986A (en) | 1986-08-12 | 1987-09-29 | The Goodyear Tire & Rubber Company | Modifier for lithium catalysts |
| JPH0637530B2 (ja) * | 1987-06-24 | 1994-05-18 | 日本ゼオン株式会社 | 新規な光学材料 |
| DE3724870A1 (de) | 1987-07-28 | 1989-02-09 | Huels Chemische Werke Ag | Verfahren zur herstellung von polymerisaten auf basis von konjugierten dienen und ggf. monovinylaromatischen verbindungen |
| US4969986A (en) * | 1988-09-28 | 1990-11-13 | The Dow Chemical Company | Controlled potential electrolysis apparatus |
| US5231153A (en) * | 1992-04-06 | 1993-07-27 | The Goodyear Tire & Rubber Company | Anionic polymerization of conjugated dienes modified with alkyltetrahydrofurfuryl ethers |
| JP3319639B2 (ja) * | 1992-12-24 | 2002-09-03 | 株式会社ブリヂストン | 共役ジエン系重合体の製造方法、スチレン−ブタジエン系重合体及びそのゴム組成物 |
| US5534592A (en) | 1995-09-22 | 1996-07-09 | The Goodyear Tire & Rubber Company | High performance blend for tire treads |
| US5677402A (en) | 1995-09-22 | 1997-10-14 | The Goodyear Tire & Rubber Company | Process for preparing 3,4-polyisoprene rubber |
| EP0798339B1 (en) | 1996-03-29 | 2002-06-05 | Bridgestone Corporation | Styrene-butadiene copolymer and rubber composition comprising the copolymer |
| US6140434A (en) | 1999-01-08 | 2000-10-31 | The Goodyear Tire & Rubber Company | Synthesis of high vinyl rubber |
| FR2808025A1 (fr) | 2000-04-25 | 2001-10-26 | Michelin Soc Tech | Procede de preparation par voie anionique d'un elastomere dienique ramifie |
| CN100509879C (zh) * | 2001-07-16 | 2009-07-08 | 米其林技术公司 | 含有环乙烯基单元的二烯高弹体及其制备工艺 |
-
2002
- 2002-07-16 CN CNB028142837A patent/CN100509879C/zh not_active Expired - Lifetime
- 2002-07-16 CN CN2009101183263A patent/CN101503486B/zh not_active Expired - Lifetime
- 2002-07-16 JP JP2003514025A patent/JP4391228B2/ja not_active Expired - Lifetime
- 2002-07-16 WO PCT/EP2002/007866 patent/WO2003008470A1/fr not_active Ceased
- 2002-07-16 EP EP02774485A patent/EP1423442B1/fr not_active Expired - Lifetime
-
2004
- 2004-01-14 US US10/756,386 patent/US7470760B2/en not_active Expired - Lifetime
-
2008
- 2008-11-20 US US12/292,524 patent/US7763696B2/en not_active Expired - Lifetime
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