JP2005513064A - フルオロホルム(hfc−23)の処理 - Google Patents
フルオロホルム(hfc−23)の処理 Download PDFInfo
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- JP2005513064A JP2005513064A JP2003552693A JP2003552693A JP2005513064A JP 2005513064 A JP2005513064 A JP 2005513064A JP 2003552693 A JP2003552693 A JP 2003552693A JP 2003552693 A JP2003552693 A JP 2003552693A JP 2005513064 A JP2005513064 A JP 2005513064A
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- Prior art keywords
- fluoroform
- hfc
- hcfc
- reaction
- temperature
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- XPDWGBQVDMORPB-UHFFFAOYSA-N Fluoroform Chemical compound FC(F)F XPDWGBQVDMORPB-UHFFFAOYSA-N 0.000 title claims abstract description 180
- VOPWNXZWBYDODV-UHFFFAOYSA-N Chlorodifluoromethane Chemical compound FC(F)Cl VOPWNXZWBYDODV-UHFFFAOYSA-N 0.000 claims abstract description 55
- 238000000034 method Methods 0.000 claims abstract description 27
- HCDGVLDPFQMKDK-UHFFFAOYSA-N hexafluoropropylene Chemical group FC(F)=C(F)C(F)(F)F HCDGVLDPFQMKDK-UHFFFAOYSA-N 0.000 claims abstract description 25
- 239000000203 mixture Substances 0.000 claims abstract description 13
- 238000006243 chemical reaction Methods 0.000 claims description 68
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims description 16
- 238000004519 manufacturing process Methods 0.000 claims description 16
- 239000010931 gold Substances 0.000 claims description 15
- 229910052737 gold Inorganic materials 0.000 claims description 15
- DAFIBNSJXIGBQB-UHFFFAOYSA-N perfluoroisobutene Chemical group FC(F)=C(C(F)(F)F)C(F)(F)F DAFIBNSJXIGBQB-UHFFFAOYSA-N 0.000 claims description 13
- 239000002184 metal Substances 0.000 claims description 8
- 229910052751 metal Inorganic materials 0.000 claims description 8
- BOUGCJDAQLKBQH-UHFFFAOYSA-N 1-chloro-1,2,2,2-tetrafluoroethane Chemical compound FC(Cl)C(F)(F)F BOUGCJDAQLKBQH-UHFFFAOYSA-N 0.000 claims description 7
- JQZFYIGAYWLRCC-UHFFFAOYSA-N 1-chloro-1,1,2,2-tetrafluoroethane Chemical compound FC(F)C(F)(F)Cl JQZFYIGAYWLRCC-UHFFFAOYSA-N 0.000 claims description 6
- 150000001875 compounds Chemical class 0.000 claims description 6
- 238000000354 decomposition reaction Methods 0.000 claims description 3
- GTLACDSXYULKMZ-UHFFFAOYSA-N pentafluoroethane Chemical compound FC(F)C(F)(F)F GTLACDSXYULKMZ-UHFFFAOYSA-N 0.000 claims description 3
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical group [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 2
- UKACHOXRXFQJFN-UHFFFAOYSA-N heptafluoropropane Chemical compound FC(F)C(F)(F)C(F)(F)F UKACHOXRXFQJFN-UHFFFAOYSA-N 0.000 claims description 2
- 238000012856 packing Methods 0.000 claims description 2
- 239000011541 reaction mixture Substances 0.000 claims 7
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims 1
- 239000005977 Ethylene Substances 0.000 claims 1
- 239000000945 filler Substances 0.000 claims 1
- 238000000197 pyrolysis Methods 0.000 abstract description 25
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 abstract description 22
- 229920006395 saturated elastomer Polymers 0.000 abstract description 4
- 239000000047 product Substances 0.000 description 20
- 239000007789 gas Substances 0.000 description 16
- YFMFNYKEUDLDTL-UHFFFAOYSA-N 1,1,1,2,3,3,3-heptafluoropropane Chemical compound FC(F)(F)C(F)C(F)(F)F YFMFNYKEUDLDTL-UHFFFAOYSA-N 0.000 description 15
- 239000006227 byproduct Substances 0.000 description 13
- 239000000463 material Substances 0.000 description 11
- 239000000376 reactant Substances 0.000 description 10
- 238000005979 thermal decomposition reaction Methods 0.000 description 9
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 8
- 229910000990 Ni alloy Inorganic materials 0.000 description 6
- 239000007795 chemical reaction product Substances 0.000 description 5
- 238000010438 heat treatment Methods 0.000 description 5
- 229910001026 inconel Inorganic materials 0.000 description 5
- 239000010453 quartz Substances 0.000 description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 5
- 238000001816 cooling Methods 0.000 description 4
- 230000007423 decrease Effects 0.000 description 3
- 229910052759 nickel Inorganic materials 0.000 description 3
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- 125000004429 atom Chemical group 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000000571 coke Substances 0.000 description 2
- 229910000856 hastalloy Inorganic materials 0.000 description 2
- 229910000040 hydrogen fluoride Inorganic materials 0.000 description 2
- 239000011261 inert gas Substances 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 238000010791 quenching Methods 0.000 description 2
- 238000007086 side reaction Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000012546 transfer Methods 0.000 description 2
- JGZVUTYDEVUNMK-UHFFFAOYSA-N 5-carboxy-2',7'-dichlorofluorescein Chemical compound C12=CC(Cl)=C(O)C=C2OC2=CC(O)=C(Cl)C=C2C21OC(=O)C1=CC(C(=O)O)=CC=C21 JGZVUTYDEVUNMK-UHFFFAOYSA-N 0.000 description 1
- 239000004604 Blowing Agent Substances 0.000 description 1
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 1
- 239000004341 Octafluorocyclobutane Substances 0.000 description 1
- 229920001774 Perfluoroether Polymers 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 239000003575 carbonaceous material Substances 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 229960001701 chloroform Drugs 0.000 description 1
- 238000004587 chromatography analysis Methods 0.000 description 1
- 238000004939 coking Methods 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 238000003682 fluorination reaction Methods 0.000 description 1
- 125000001153 fluoro group Chemical group F* 0.000 description 1
- NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical compound FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 description 1
- 239000001307 helium Substances 0.000 description 1
- 229910052734 helium Inorganic materials 0.000 description 1
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 1
- 229910000039 hydrogen halide Inorganic materials 0.000 description 1
- 239000012433 hydrogen halide Substances 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 239000000543 intermediate Substances 0.000 description 1
- 239000013067 intermediate product Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- BCCOBQSFUDVTJQ-UHFFFAOYSA-N octafluorocyclobutane Chemical compound FC1(F)C(F)(F)C(F)(F)C1(F)F BCCOBQSFUDVTJQ-UHFFFAOYSA-N 0.000 description 1
- 235000019407 octafluorocyclobutane Nutrition 0.000 description 1
- UJMWVICAENGCRF-UHFFFAOYSA-N oxygen difluoride Chemical compound FOF UJMWVICAENGCRF-UHFFFAOYSA-N 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 230000000171 quenching effect Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 239000003507 refrigerant Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- TXEYQDLBPFQVAA-UHFFFAOYSA-N tetrafluoromethane Chemical compound FC(F)(F)F TXEYQDLBPFQVAA-UHFFFAOYSA-N 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/26—Preparation of halogenated hydrocarbons by reactions involving an increase in the number of carbon atoms in the skeleton
- C07C17/263—Preparation of halogenated hydrocarbons by reactions involving an increase in the number of carbon atoms in the skeleton by condensation reactions
- C07C17/269—Preparation of halogenated hydrocarbons by reactions involving an increase in the number of carbon atoms in the skeleton by condensation reactions of only halogenated hydrocarbons
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
Description
775℃の運転制御設定温度、600℃の予備加熱設定温度を保持した反応器に、HFC−23を、標準の温度および圧力換算で800、400、200および100cc/分(sccm)の流量で供給する。400、200および100sccmの運転流量で、HFC−23のTFEへの転化率は、それぞれ約0.2、0.4、および0.6%である。微量のHFP、HFC−125およびHFC−227eaが観測される。gcの検出限界は約1000ppmである。
結論:HFC−23が単味で775℃の反応器に供給されるとき、>99モル%のHFC−23が未反応であり、わずかに起きている反応の中で、唯一TFEが測定可能な量で生成される。他の微量に生成されている副生物の量は、全体の0.2モル%未満であった。
850℃の運転制御設定温度、600℃の予備加熱設定温度を保持した反応器に、HFC−23を、400、200および100sccmの流量で供給する。HFC−23のTFEへの転化率は、それぞれ0.9、2.0、および3.0%である。HFC−23の流量が200および100sccmのときには、0.2および0.6%のHFPが観測される。HFC−23の運転流量が100sccmで、0.15%のHFC−125が得られ、これはTFEおよびHFC−125の合計の5%未満に相当する。パーフルオロイソブチレン(0.08%)もまた、この低流量条件下でGC/MSによって同定される。
結論:850℃の運転制御設定温度であってさえも、HFC−23が単味で反応器に供給されるときは、転化率は僅か約1から5モル%であり、生成物の95%はTFEとHFPである。HFC−125の生成は生成物中の<5%であり、HFC−227eaは1%未満である。
制御設定温度が775℃と850℃の間、600℃の予備加熱温度で運転する反応器に、HFC−23とHCFC−22の等モル流を表1に示す流量で供給する。反応の主生成物および出発物質であるHCFC−22とHFC−23の合計未反応量を表1に示す。これらの実施例における接触時間は約1秒である。
これらの実施例では、反応器制御温度とともに、HFC−23:HCFC−22の比も変化させる。予備加熱設定温度は600℃である。表2は結果の要約であり、得られた反応生成物を示す。これらの実施例における接触時間は約0.5秒である。
これらの実施例は、パーフルオロ化した2mmのガンマアルミナ球を充填した、金で内張りした石英製TGA(熱重量分析計)タイプの流通式反応器(金箔で内張りした直径1インチ(2.54cm)の石英管)で行う。供給される反応物質は別々に予備加熱し、HFC−23は600℃に、HCFC−22は400℃に予備加熱する。HCFC−22:HFC−23の比を変化させ、全流量および管壁温度も変化させる。これらの実施例における接触時間は、0.5秒未満である。結果を示す表3には、反応生成物を記す。残りは実質的に未反応のHCFC−22およびHFC−23である。
Claims (14)
- フルオロホルムを処理する方法であって、前記フルオロホルムとクロロジフルオロメタンの反応混合物を、約625〜800℃の範囲の温度、約2秒未満の接触時間で共熱分解し、その結果、テトラフルオロエチレン(TFE)、ヘキサフルオロプロピレン(HFP)、ペンタフルオロエタン(CF3CHF2)およびヘプタフルオロプロパン(CF3CHFCF3)からなる群より選択される少なくとも3つの化合物を含む生成混合物を得ることによって、前記フルオロホルムを消費することを特徴とする方法。
- 表面が金属からなる反応ゾーンを通して前記反応混合物を供給することによって行われることを特徴とする請求項1に記載の方法。
- 前記金属は、金であることを特徴とする請求項2に記載の方法。
- 前記TFEおよびHFPの生成に対し生成されるCF3CHF2およびCF3CHFCF3の割合を最大にするために、前記フルオロホルム対前記クロロジフルオロメタンのモル比を、少なくとも約5:1から約2:1とすることを特徴とする請求項1に記載の方法。
- 前記CF3CHF2およびCF3CHFCF3の生成に対し生成されるTFEおよびHFPの割合を最大にするために、前記フルオロホルム対前記クロロジフルオロメタンのモル比を、約1:1以下とすることを特徴とする請求項1に記載の方法。
- パーフルオロイソブチレンの生成量が、前記化合物の全重量を基準として約5%未満であることを特徴とする請求項1に記載の方法。
- パーフルオロイソブチレンの生成量が、前記化合物の全重量を基準として約2%未満であることを特徴とする請求項3に記載の方法。
- 生成混合物はフルオロホルムを含み、前記フルオロホルムを生成混合物から分離し、得られたフルオロホルムを前記反応混合物に加えることを特徴とする請求項1に記載の方法。
- 生成混合物は、HCFC−124、HCFC−124aおよびc318を含み、前記HCFC−124、HCFC−124aおよびc318を生成混合物から分離し、得られたHCFC−124、HCFC−124aおよびc318を前記反応混合物に加えることを特徴とする請求項1に記載の方法。
- さらに、前記フルオロホルムおよび前記クロロジフルオロメタンを、一緒に、かつ、約500〜600℃の予備加熱温度で、前記反応混合物に供給することを特徴とする請求項1に記載の方法。
- さらに、前記フルオロホルムおよび前記クロロジフルオロメタンを、それぞれ約500〜600℃および約300〜450℃の予備加熱温度で、前記反応混合物に供給することを特徴とする請求項1に記載の方法。
- さらに、前記フルオロホルムおよび前記クロロジフルオロメタンを、それぞれ、少なくとも約850℃であるが前記フルオロホルムの分解温度よりも低い温度および約300〜550℃の予備加熱温度で、前記反応混合物に供給することを特徴とする請求項1に記載の方法。
- 前記反応ゾーンは充填物を含むことを特徴とする請求項2に記載の方法。
- 前記充填物は、パーフルオロ化ガンマアルミナであることを特徴とする請求項13に記載の方法。
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US34164001P | 2001-12-18 | 2001-12-18 | |
PCT/US2002/040332 WO2003051802A1 (en) | 2001-12-18 | 2002-12-18 | Disposal of fluoroform (hfc-23) |
Publications (3)
Publication Number | Publication Date |
---|---|
JP2005513064A true JP2005513064A (ja) | 2005-05-12 |
JP2005513064A5 JP2005513064A5 (ja) | 2006-02-02 |
JP4425636B2 JP4425636B2 (ja) | 2010-03-03 |
Family
ID=23338414
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2003552693A Expired - Lifetime JP4425636B2 (ja) | 2001-12-18 | 2002-12-18 | フルオロホルム(hfc−23)の処理 |
Country Status (6)
Country | Link |
---|---|
US (1) | US6806396B2 (ja) |
EP (1) | EP1463698B1 (ja) |
JP (1) | JP4425636B2 (ja) |
CN (1) | CN100343209C (ja) |
DE (1) | DE60239357D1 (ja) |
WO (1) | WO2003051802A1 (ja) |
Cited By (13)
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JP2008544958A (ja) * | 2005-05-12 | 2008-12-11 | ハネウェル・インターナショナル・インコーポレーテッド | フッ化有機化合物の製造方法 |
JP2009514934A (ja) * | 2005-11-08 | 2009-04-09 | ソルヴェイ(ソシエテ アノニム) | グリセロールの塩素化によるジクロロプロパノールの製造方法 |
JP2009514955A (ja) * | 2005-11-03 | 2009-04-09 | ハネウェル・インターナショナル・インコーポレーテッド | フッ素化有機化合物の製造方法 |
US8378130B2 (en) | 2007-06-12 | 2013-02-19 | Solvay (Societe Anonyme) | Product containing epichlorohydrin, its preparation and its use in various applications |
US8389777B2 (en) | 2005-05-20 | 2013-03-05 | Solvay (Société Anonyme) | Continuous method for making chlorhydrines |
US8420871B2 (en) | 2005-05-20 | 2013-04-16 | Solvay (Societe Anonyme) | Process for producing an organic compound |
US8471074B2 (en) | 2007-03-14 | 2013-06-25 | Solvay (Societe Anonyme) | Process for the manufacture of dichloropropanol |
US8507643B2 (en) | 2008-04-03 | 2013-08-13 | Solvay S.A. | Composition comprising glycerol, process for obtaining same and use thereof in the manufacture of dichloropropanol |
US8536381B2 (en) | 2008-09-12 | 2013-09-17 | Solvay Sa | Process for purifying hydrogen chloride |
US8715568B2 (en) | 2007-10-02 | 2014-05-06 | Solvay Sa | Use of compositions containing silicon for improving the corrosion resistance of vessels |
US8795536B2 (en) | 2008-01-31 | 2014-08-05 | Solvay (Societe Anonyme) | Process for degrading organic substances in an aqueous composition |
US9309209B2 (en) | 2010-09-30 | 2016-04-12 | Solvay Sa | Derivative of epichlorohydrin of natural origin |
US9663427B2 (en) | 2003-11-20 | 2017-05-30 | Solvay (Société Anonyme) | Process for producing epichlorohydrin |
Families Citing this family (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8034989B2 (en) * | 2005-08-26 | 2011-10-11 | Knupp Stephen L | Energy generation process |
CN100424057C (zh) * | 2006-12-22 | 2008-10-08 | 山东东岳化工有限公司 | 三氟甲烷的回收方法 |
US20100032617A1 (en) * | 2007-02-20 | 2010-02-11 | Solvay (Societe Anonyme) | Process for manufacturing epichlorohydrin |
FR2918058A1 (fr) * | 2007-06-28 | 2009-01-02 | Solvay | Produit a base de glycerol, procede pour sa purification et son utilisation dans la fabrication de dichloropropanol |
CN103467239B (zh) * | 2013-09-13 | 2016-03-30 | 常熟三爱富中昊化工新材料有限公司 | 一种三氟甲烷裂解制备二氟一氯甲烷的工艺方法 |
CA2987113A1 (en) * | 2015-06-04 | 2016-12-08 | Arkema Inc. | Method for producing fluorinated olefins |
CN112973685B (zh) * | 2019-12-13 | 2022-06-28 | 浙江省化工研究院有限公司 | 一种hfc-23资源化利用中减少催化剂积碳的方法 |
CN112979410B (zh) | 2019-12-13 | 2022-06-28 | 浙江省化工研究院有限公司 | 一种hfc-23资源化利用中提高催化剂稳定性的方法 |
CN112679311A (zh) * | 2020-12-26 | 2021-04-20 | 江苏梅兰化工有限公司 | 一种从f22精馏残液中回收f21及f22的方法 |
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US3009966A (en) * | 1960-02-08 | 1961-11-21 | Pennsalt Chemicals Corp | Production of fluorinated compounds |
US3202720A (en) * | 1961-12-28 | 1965-08-24 | Pennsalt Chemicals Corp | Manufacture of saturated perfluorocarbons by the catalytic pyrolysis of fluoroform |
NL302391A (ja) | 1962-12-22 | |||
WO1995024369A1 (en) * | 1994-03-11 | 1995-09-14 | E.I. Du Pont De Nemours And Company | Process for converting chlorodifluoromethane and/or dichlorodifluoromethane |
FR2731701B1 (fr) | 1995-03-17 | 1997-04-30 | Atochem Elf Sa | Procede de fabrication de fluoroalcanes |
FR2764883B1 (fr) * | 1997-06-18 | 1999-07-16 | Atochem Elf Sa | Procede de fabrication d'hydrofluoroalcanes |
-
2002
- 2002-12-16 US US10/320,143 patent/US6806396B2/en not_active Expired - Lifetime
- 2002-12-18 CN CNB028252845A patent/CN100343209C/zh not_active Expired - Lifetime
- 2002-12-18 JP JP2003552693A patent/JP4425636B2/ja not_active Expired - Lifetime
- 2002-12-18 WO PCT/US2002/040332 patent/WO2003051802A1/en active Application Filing
- 2002-12-18 DE DE60239357T patent/DE60239357D1/de not_active Expired - Lifetime
- 2002-12-18 EP EP02794280A patent/EP1463698B1/en not_active Expired - Lifetime
Cited By (15)
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US9663427B2 (en) | 2003-11-20 | 2017-05-30 | Solvay (Société Anonyme) | Process for producing epichlorohydrin |
JP2008544958A (ja) * | 2005-05-12 | 2008-12-11 | ハネウェル・インターナショナル・インコーポレーテッド | フッ化有機化合物の製造方法 |
US8591766B2 (en) | 2005-05-20 | 2013-11-26 | Solvay (Societe Anonyme) | Continuous process for preparing chlorohydrins |
US8389777B2 (en) | 2005-05-20 | 2013-03-05 | Solvay (Société Anonyme) | Continuous method for making chlorhydrines |
US8420871B2 (en) | 2005-05-20 | 2013-04-16 | Solvay (Societe Anonyme) | Process for producing an organic compound |
JP2009514955A (ja) * | 2005-11-03 | 2009-04-09 | ハネウェル・インターナショナル・インコーポレーテッド | フッ素化有機化合物の製造方法 |
JP2009514934A (ja) * | 2005-11-08 | 2009-04-09 | ソルヴェイ(ソシエテ アノニム) | グリセロールの塩素化によるジクロロプロパノールの製造方法 |
US8471074B2 (en) | 2007-03-14 | 2013-06-25 | Solvay (Societe Anonyme) | Process for the manufacture of dichloropropanol |
US8378130B2 (en) | 2007-06-12 | 2013-02-19 | Solvay (Societe Anonyme) | Product containing epichlorohydrin, its preparation and its use in various applications |
US8399692B2 (en) | 2007-06-12 | 2013-03-19 | Solvay (Societe Anonyme) | Epichlorohydrin, manufacturing process and use |
US8715568B2 (en) | 2007-10-02 | 2014-05-06 | Solvay Sa | Use of compositions containing silicon for improving the corrosion resistance of vessels |
US8795536B2 (en) | 2008-01-31 | 2014-08-05 | Solvay (Societe Anonyme) | Process for degrading organic substances in an aqueous composition |
US8507643B2 (en) | 2008-04-03 | 2013-08-13 | Solvay S.A. | Composition comprising glycerol, process for obtaining same and use thereof in the manufacture of dichloropropanol |
US8536381B2 (en) | 2008-09-12 | 2013-09-17 | Solvay Sa | Process for purifying hydrogen chloride |
US9309209B2 (en) | 2010-09-30 | 2016-04-12 | Solvay Sa | Derivative of epichlorohydrin of natural origin |
Also Published As
Publication number | Publication date |
---|---|
EP1463698B1 (en) | 2011-03-02 |
EP1463698A1 (en) | 2004-10-06 |
JP4425636B2 (ja) | 2010-03-03 |
US6806396B2 (en) | 2004-10-19 |
DE60239357D1 (de) | 2011-04-14 |
CN100343209C (zh) | 2007-10-17 |
WO2003051802A1 (en) | 2003-06-26 |
US20030166981A1 (en) | 2003-09-04 |
CN1604886A (zh) | 2005-04-06 |
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