JP2005505701A5 - - Google Patents
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- Publication number
- JP2005505701A5 JP2005505701A5 JP2003534675A JP2003534675A JP2005505701A5 JP 2005505701 A5 JP2005505701 A5 JP 2005505701A5 JP 2003534675 A JP2003534675 A JP 2003534675A JP 2003534675 A JP2003534675 A JP 2003534675A JP 2005505701 A5 JP2005505701 A5 JP 2005505701A5
- Authority
- JP
- Japan
- Prior art keywords
- fluorinated
- isocyanate groups
- dispersion
- carbon atoms
- water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000006185 dispersion Substances 0.000 claims description 35
- 125000004432 carbon atom Chemical group C* 0.000 claims description 14
- 239000003093 cationic surfactant Substances 0.000 claims description 13
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 claims description 13
- 239000002736 nonionic surfactant Substances 0.000 claims description 13
- 239000005056 polyisocyanate Substances 0.000 claims description 13
- 229920001228 polyisocyanate Polymers 0.000 claims description 13
- 239000000758 substrate Substances 0.000 claims description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 10
- 150000001875 compounds Chemical class 0.000 claims description 9
- 125000000524 functional group Chemical group 0.000 claims description 9
- 238000000034 method Methods 0.000 claims description 9
- 125000001153 fluoro group Chemical group F* 0.000 claims description 8
- 229920000642 polymer Polymers 0.000 claims description 7
- 150000003673 urethanes Chemical class 0.000 claims description 7
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 6
- 239000004202 carbamide Substances 0.000 claims description 6
- 125000002091 cationic group Chemical group 0.000 claims description 6
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 6
- 238000004043 dyeing Methods 0.000 claims description 4
- 239000000980 acid dye Substances 0.000 claims description 3
- SJEYSFABYSGQBG-UHFFFAOYSA-M Patent blue Chemical compound [Na+].C1=CC(N(CC)CC)=CC=C1C(C=1C(=CC(=CC=1)S([O-])(=O)=O)S([O-])(=O)=O)=C1C=CC(=[N+](CC)CC)C=C1 SJEYSFABYSGQBG-UHFFFAOYSA-M 0.000 claims 1
- 230000002378 acidificating effect Effects 0.000 claims 1
- 239000000975 dye Substances 0.000 claims 1
- 150000003839 salts Chemical class 0.000 description 16
- -1 amine salt Chemical class 0.000 description 11
- 235000014113 dietary fatty acids Nutrition 0.000 description 9
- 229930195729 fatty acid Natural products 0.000 description 9
- 239000000194 fatty acid Substances 0.000 description 9
- 150000004665 fatty acids Chemical class 0.000 description 9
- 125000000217 alkyl group Chemical group 0.000 description 7
- 150000001412 amines Chemical class 0.000 description 6
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 5
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- 229920001400 block copolymer Polymers 0.000 description 3
- 150000002148 esters Chemical class 0.000 description 3
- 150000002191 fatty alcohols Chemical class 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 229920001451 polypropylene glycol Polymers 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 150000005846 sugar alcohols Polymers 0.000 description 3
- 239000013638 trimer Substances 0.000 description 3
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 2
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 2
- BAVYZALUXZFZLV-UHFFFAOYSA-N Methylamine Chemical compound NC BAVYZALUXZFZLV-UHFFFAOYSA-N 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 229910052731 fluorine Inorganic materials 0.000 description 2
- 239000011737 fluorine Substances 0.000 description 2
- 239000012948 isocyanate Substances 0.000 description 2
- 150000002513 isocyanates Chemical class 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 125000005010 perfluoroalkyl group Chemical group 0.000 description 2
- UCCKNBUJGRFXTA-UHFFFAOYSA-N 2,4-diisocyanato-1,1,2,4-tetramethylcyclohexane Chemical compound CC1(C)CCC(C)(N=C=O)CC1(C)N=C=O UCCKNBUJGRFXTA-UHFFFAOYSA-N 0.000 description 1
- 244000198134 Agave sisalana Species 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 240000000491 Corchorus aestuans Species 0.000 description 1
- 235000011777 Corchorus aestuans Nutrition 0.000 description 1
- 235000010862 Corchorus capsularis Nutrition 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 241000219146 Gossypium Species 0.000 description 1
- 239000005057 Hexamethylene diisocyanate Substances 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 125000005211 alkyl trimethyl ammonium group Chemical group 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical group [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 239000007859 condensation product Substances 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 125000001183 hydrocarbyl group Chemical group 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 125000000962 organic group Chemical group 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 229920002215 polytrimethylene terephthalate Polymers 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US09/973,101 US6790905B2 (en) | 2001-10-09 | 2001-10-09 | Highly repellent carpet protectants |
| PCT/US2002/033398 WO2003031715A1 (en) | 2001-10-09 | 2002-10-09 | Highly repellent carpet protectants |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2005505701A JP2005505701A (ja) | 2005-02-24 |
| JP2005505701A5 true JP2005505701A5 (enExample) | 2006-01-05 |
| JP4383171B2 JP4383171B2 (ja) | 2009-12-16 |
Family
ID=25520499
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2003534675A Expired - Fee Related JP4383171B2 (ja) | 2001-10-09 | 2002-10-09 | 高撥水撥油性カーペット保護剤 |
Country Status (9)
| Country | Link |
|---|---|
| US (2) | US6790905B2 (enExample) |
| EP (1) | EP1434913B1 (enExample) |
| JP (1) | JP4383171B2 (enExample) |
| KR (1) | KR100904831B1 (enExample) |
| CN (1) | CN1289564C (enExample) |
| AU (1) | AU2002343541B2 (enExample) |
| CA (1) | CA2463557C (enExample) |
| DE (1) | DE60208918T2 (enExample) |
| WO (1) | WO2003031715A1 (enExample) |
Families Citing this family (39)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6334960B1 (en) * | 1999-03-11 | 2002-01-01 | Board Of Regents, The University Of Texas System | Step and flash imprint lithography |
| US20040112862A1 (en) * | 2002-12-12 | 2004-06-17 | Molecular Imprints, Inc. | Planarization composition and method of patterning a substrate using the same |
| US7365103B2 (en) * | 2002-12-12 | 2008-04-29 | Board Of Regents, The University Of Texas System | Compositions for dark-field polymerization and method of using the same for imprint lithography processes |
| US7122079B2 (en) | 2004-02-27 | 2006-10-17 | Molecular Imprints, Inc. | Composition for an etching mask comprising a silicon-containing material |
| US7396475B2 (en) | 2003-04-25 | 2008-07-08 | Molecular Imprints, Inc. | Method of forming stepped structures employing imprint lithography |
| US20050160934A1 (en) * | 2004-01-23 | 2005-07-28 | Molecular Imprints, Inc. | Materials and methods for imprint lithography |
| US7157036B2 (en) | 2003-06-17 | 2007-01-02 | Molecular Imprints, Inc | Method to reduce adhesion between a conformable region and a pattern of a mold |
| US7307118B2 (en) * | 2004-11-24 | 2007-12-11 | Molecular Imprints, Inc. | Composition to reduce adhesion between a conformable region and a mold |
| US20060108710A1 (en) * | 2004-11-24 | 2006-05-25 | Molecular Imprints, Inc. | Method to reduce adhesion between a conformable region and a mold |
| US20050015886A1 (en) | 2003-07-24 | 2005-01-27 | Shaw Industries Group, Inc. | Methods of treating and cleaning fibers, carpet yarns and carpets |
| US8238696B2 (en) * | 2003-08-21 | 2012-08-07 | Microsoft Corporation | Systems and methods for the implementation of a digital images schema for organizing units of information manageable by a hardware/software interface system |
| US7122482B2 (en) * | 2003-10-27 | 2006-10-17 | Molecular Imprints, Inc. | Methods for fabricating patterned features utilizing imprint lithography |
| US8076386B2 (en) | 2004-02-23 | 2011-12-13 | Molecular Imprints, Inc. | Materials for imprint lithography |
| US7906180B2 (en) | 2004-02-27 | 2011-03-15 | Molecular Imprints, Inc. | Composition for an etching mask comprising a silicon-containing material |
| US7939131B2 (en) | 2004-08-16 | 2011-05-10 | Molecular Imprints, Inc. | Method to provide a layer with uniform etch characteristics |
| US7282550B2 (en) * | 2004-08-16 | 2007-10-16 | Molecular Imprints, Inc. | Composition to provide a layer with uniform etch characteristics |
| US20060062922A1 (en) | 2004-09-23 | 2006-03-23 | Molecular Imprints, Inc. | Polymerization technique to attenuate oxygen inhibition of solidification of liquids and composition therefor |
| US20060081557A1 (en) * | 2004-10-18 | 2006-04-20 | Molecular Imprints, Inc. | Low-k dielectric functional imprinting materials |
| US7292326B2 (en) | 2004-11-30 | 2007-11-06 | Molecular Imprints, Inc. | Interferometric analysis for the manufacture of nano-scale devices |
| CN101111367A (zh) * | 2004-12-16 | 2008-01-23 | 美利肯公司 | 纺织品表面遮盖物及其制造方法 |
| US7785374B2 (en) | 2005-01-24 | 2010-08-31 | Columbia Insurance Co. | Methods and compositions for imparting stain resistance to nylon materials |
| US8557351B2 (en) * | 2005-07-22 | 2013-10-15 | Molecular Imprints, Inc. | Method for adhering materials together |
| US8808808B2 (en) | 2005-07-22 | 2014-08-19 | Molecular Imprints, Inc. | Method for imprint lithography utilizing an adhesion primer layer |
| US7759407B2 (en) | 2005-07-22 | 2010-07-20 | Molecular Imprints, Inc. | Composition for adhering materials together |
| EP1917285A1 (en) * | 2005-08-05 | 2008-05-07 | 3M Innovative Properties Company | Repellent materials |
| US8142703B2 (en) * | 2005-10-05 | 2012-03-27 | Molecular Imprints, Inc. | Imprint lithography method |
| US20070136953A1 (en) * | 2005-12-20 | 2007-06-21 | Materniak Joyce M | Stability for coapplication |
| US7494511B2 (en) * | 2006-05-08 | 2009-02-24 | E.I. Du Pont De Nemours And Company | Hydrophilic stain release agents |
| US20080287020A1 (en) * | 2007-05-18 | 2008-11-20 | Rudat Martin A | Method and composition for treating fibrous substrates |
| US7754092B2 (en) * | 2007-10-31 | 2010-07-13 | E.I. Du Pont De Nemours And Company | Soil resist additive |
| US20100063197A1 (en) * | 2008-09-05 | 2010-03-11 | Collier Robert B | Compositions and methods for imparting water and oil repellency to fibers and articles thereof |
| US20100109195A1 (en) | 2008-11-05 | 2010-05-06 | Molecular Imprints, Inc. | Release agent partition control in imprint lithography |
| AU2009314186B2 (en) * | 2008-11-14 | 2014-09-18 | The Chemours Company Fc, Llc. | Fluoropolymer compositions and treated substrates |
| US8357621B2 (en) * | 2009-06-29 | 2013-01-22 | E.I. Du Pont De Nemours And Company | Soil resist method |
| US7901589B2 (en) * | 2009-06-29 | 2011-03-08 | E.I. Du Pont De Nemours And Company | Propanediol soil resist compositions |
| CN105793487B (zh) * | 2014-01-24 | 2017-11-07 | 日华化学株式会社 | 拨水剂组合物、拨水性纤维制品及拨水性纤维制品的制造方法 |
| US10138594B2 (en) * | 2014-09-26 | 2018-11-27 | The Chemours Company Fc, Llc | Partially fluorinated urethane based coatings |
| KR20180059884A (ko) * | 2015-10-02 | 2018-06-05 | 더 케무어스 컴퍼니 에프씨, 엘엘씨 | 표면 효과 코팅에서의 소수성 화합물 증량제 |
| KR20220038381A (ko) * | 2019-07-18 | 2022-03-28 | 에보니크 오퍼레이션즈 게엠베하 | 수성 폴리우레탄 분산액 중에서의 폴리올 에테르 및 양이온성 다가전해질의 조합된 용도 |
Family Cites Families (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3468697A (en) | 1966-03-02 | 1969-09-23 | Colgate Palmolive Co | Method of treating textile articles which are usually laundered |
| JPS5933315A (ja) | 1982-08-20 | 1984-02-23 | Asahi Glass Co Ltd | 防汚加工剤の製造方法 |
| US4668726A (en) | 1984-03-30 | 1987-05-26 | Minnesota Mining And Manufacturing Company | Cationic and non-ionic fluorochemicals and fibrous substrates treated therewith |
| US4566981A (en) | 1984-03-30 | 1986-01-28 | Minnesota Mining And Manufacturing Company | Fluorochemicals and fibrous substrates treated therewith: compositions of cationic and non-ionic fluorochemicals |
| US4958039A (en) | 1984-08-24 | 1990-09-18 | E. I. Du Pont De Nemours And Company | Modified fluorocarbonylimino biurets |
| US4595518A (en) | 1985-07-10 | 1986-06-17 | E. I. Du Pont De Nemours And Company | Coating fibrous substrates with fluoropolymer amphoteric polymer and surfactants |
| DE3607773C2 (de) | 1986-03-08 | 1995-06-22 | Cassella Ag | Fluoralkylliganden enthaltende Polyurethane, Verfahren zu ihrer Herstellung und ihre Zubereitungen und ihre Verwendung |
| US5410073A (en) | 1989-12-29 | 1995-04-25 | E. I. Du Pont De Nemours And Company | Manufacture of polyfluoro nitrogen containing organic compounds |
| US5414111A (en) | 1989-12-29 | 1995-05-09 | E. I. Du Pont De Nemours And Company | Polyfluoro nitrogen-containing organic compounds |
| US5411766A (en) | 1989-12-29 | 1995-05-02 | E. I. Du Pont De Nemours And Company | Substrates treated with polyfluoro nitrogen containing organic compounds |
| US5153046A (en) | 1990-05-24 | 1992-10-06 | E. I. Du Pont De Nemours And Company | Fluorochemical composition for imparting antisoiling protection and lubricity to textile fibers |
| US5276175A (en) | 1991-04-02 | 1994-01-04 | Minnesota Mining And Manufacturing Company | Isocyanate derivatives comprising flourochemical oligomers |
| US5725789A (en) | 1995-03-31 | 1998-03-10 | Minnesota Mining And Manufacturing Company | Aqueous oil and water repellent compositions |
| US5714082A (en) | 1995-06-02 | 1998-02-03 | Minnesota Mining And Manufacturing Company | Aqueous anti-soiling composition |
| US5672651A (en) | 1995-10-20 | 1997-09-30 | Minnesota Mining And Manufacturing Company | Durable repellent fluorochemical compositions |
| US5847134A (en) | 1996-01-11 | 1998-12-08 | E. I. Du Pont De Nemours And Company | Fluorocarbon-containing isocyanate derivatives and soil-resist agents |
| EP0898588B1 (en) | 1996-05-17 | 2001-06-27 | Minnesota Mining And Manufacturing Company | Fluorochemical polyurethanes, providing good laundry air-dry performance |
| GB2315783B (en) | 1996-07-27 | 2000-08-23 | Reckitt & Colman Inc | Cleaning composition imparting water and oil repellency |
| BR9701287A (pt) | 1997-03-14 | 1998-11-10 | Unilever Nv | Composição de tratamento de tecidos na lavagem e processo para tratar tecidos para proporcionar aos mesmos propriedades de repelência à sujeira |
| GB9705682D0 (en) | 1997-03-19 | 1997-05-07 | Unilever Plc | Cleaning composition comprising fluoro-surfactants |
| WO2001010922A1 (en) | 1999-08-10 | 2001-02-15 | E.I. Du Pont De Nemours And Company | Fluorochemical oil and water repellents |
-
2001
- 2001-10-09 US US09/973,101 patent/US6790905B2/en not_active Expired - Lifetime
-
2002
- 2002-10-09 CA CA2463557A patent/CA2463557C/en not_active Expired - Fee Related
- 2002-10-09 JP JP2003534675A patent/JP4383171B2/ja not_active Expired - Fee Related
- 2002-10-09 EP EP02780488A patent/EP1434913B1/en not_active Expired - Lifetime
- 2002-10-09 WO PCT/US2002/033398 patent/WO2003031715A1/en not_active Ceased
- 2002-10-09 KR KR1020047004629A patent/KR100904831B1/ko not_active Expired - Fee Related
- 2002-10-09 AU AU2002343541A patent/AU2002343541B2/en not_active Ceased
- 2002-10-09 DE DE2002608918 patent/DE60208918T2/de not_active Expired - Lifetime
- 2002-10-09 CN CNB028200055A patent/CN1289564C/zh not_active Expired - Fee Related
-
2004
- 2004-08-06 US US10/913,914 patent/US7592064B2/en not_active Expired - Fee Related
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