JP2005281327A - 難燃剤マスターバッチ樹脂組成物を用いたポリスチレン系樹脂の成形方法、および、その成形方法によって得られる成形品 - Google Patents
難燃剤マスターバッチ樹脂組成物を用いたポリスチレン系樹脂の成形方法、および、その成形方法によって得られる成形品 Download PDFInfo
- Publication number
- JP2005281327A JP2005281327A JP2004074543A JP2004074543A JP2005281327A JP 2005281327 A JP2005281327 A JP 2005281327A JP 2004074543 A JP2004074543 A JP 2004074543A JP 2004074543 A JP2004074543 A JP 2004074543A JP 2005281327 A JP2005281327 A JP 2005281327A
- Authority
- JP
- Japan
- Prior art keywords
- flame retardant
- polystyrene
- resin composition
- resin
- molding method
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title claims abstract description 203
- 239000003063 flame retardant Substances 0.000 title claims abstract description 160
- 239000004594 Masterbatch (MB) Substances 0.000 title claims abstract description 84
- 229920005990 polystyrene resin Polymers 0.000 title claims abstract description 82
- 239000011342 resin composition Substances 0.000 title claims abstract description 80
- 238000000465 moulding Methods 0.000 title claims abstract description 44
- 238000000034 method Methods 0.000 title claims abstract description 35
- 229920002223 polystyrene Polymers 0.000 claims abstract description 35
- 239000004793 Polystyrene Substances 0.000 claims abstract description 29
- 229920005989 resin Polymers 0.000 claims abstract description 29
- 239000011347 resin Substances 0.000 claims abstract description 29
- 239000000155 melt Substances 0.000 claims abstract description 14
- 238000002156 mixing Methods 0.000 claims description 14
- 238000010438 heat treatment Methods 0.000 abstract description 6
- 239000013585 weight reducing agent Substances 0.000 abstract description 6
- 230000002542 deteriorative effect Effects 0.000 abstract description 2
- 238000012360 testing method Methods 0.000 description 14
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 13
- 229920005669 high impact polystyrene Polymers 0.000 description 10
- 239000004797 high-impact polystyrene Substances 0.000 description 10
- 238000012545 processing Methods 0.000 description 8
- 239000000203 mixture Substances 0.000 description 7
- 230000007547 defect Effects 0.000 description 6
- 239000012760 heat stabilizer Substances 0.000 description 6
- 238000001746 injection moulding Methods 0.000 description 6
- 239000004014 plasticizer Substances 0.000 description 6
- 239000000654 additive Substances 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 5
- 238000001125 extrusion Methods 0.000 description 5
- -1 phosphorus compound Chemical class 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical compound O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 description 4
- 239000000945 filler Substances 0.000 description 4
- 230000000704 physical effect Effects 0.000 description 4
- 238000007493 shaping process Methods 0.000 description 4
- 229920003048 styrene butadiene rubber Polymers 0.000 description 4
- 238000002411 thermogravimetry Methods 0.000 description 4
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 3
- 238000002485 combustion reaction Methods 0.000 description 3
- 230000007423 decrease Effects 0.000 description 3
- 239000006185 dispersion Substances 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 239000004033 plastic Substances 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 229910052709 silver Inorganic materials 0.000 description 3
- 239000004332 silver Substances 0.000 description 3
- 239000003381 stabilizer Substances 0.000 description 3
- 230000004580 weight loss Effects 0.000 description 3
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 2
- 239000005977 Ethylene Substances 0.000 description 2
- 239000004605 External Lubricant Substances 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 229910052787 antimony Inorganic materials 0.000 description 2
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 2
- 229910000410 antimony oxide Inorganic materials 0.000 description 2
- 239000003963 antioxidant agent Substances 0.000 description 2
- 230000003078 antioxidant effect Effects 0.000 description 2
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 2
- 229910052794 bromium Inorganic materials 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 238000005520 cutting process Methods 0.000 description 2
- 230000003247 decreasing effect Effects 0.000 description 2
- 239000002270 dispersing agent Substances 0.000 description 2
- 238000010101 extrusion blow moulding Methods 0.000 description 2
- 229910052736 halogen Inorganic materials 0.000 description 2
- 150000002367 halogens Chemical class 0.000 description 2
- 229920001519 homopolymer Polymers 0.000 description 2
- AMWRITDGCCNYAT-UHFFFAOYSA-L hydroxy(oxo)manganese;manganese Chemical compound [Mn].O[Mn]=O.O[Mn]=O AMWRITDGCCNYAT-UHFFFAOYSA-L 0.000 description 2
- 238000004898 kneading Methods 0.000 description 2
- 239000000314 lubricant Substances 0.000 description 2
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 2
- 239000000395 magnesium oxide Substances 0.000 description 2
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 229910044991 metal oxide Inorganic materials 0.000 description 2
- 150000004706 metal oxides Chemical class 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 239000002667 nucleating agent Substances 0.000 description 2
- VTRUBDSFZJNXHI-UHFFFAOYSA-N oxoantimony Chemical compound [Sb]=O VTRUBDSFZJNXHI-UHFFFAOYSA-N 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- XQKQZOLAVMIQHZ-UHFFFAOYSA-N 1,1-dibromo-3-(3,3-dibromopropoxy)propane Chemical compound BrC(Br)CCOCCC(Br)Br XQKQZOLAVMIQHZ-UHFFFAOYSA-N 0.000 description 1
- LLVVSBBXENOOQY-UHFFFAOYSA-N 1,2,3,4,5-pentabromobenzene Chemical compound BrC1=CC(Br)=C(Br)C(Br)=C1Br LLVVSBBXENOOQY-UHFFFAOYSA-N 0.000 description 1
- VEORPZCZECFIRK-UHFFFAOYSA-N 3,3',5,5'-tetrabromobisphenol A Chemical compound C=1C(Br)=C(O)C(Br)=CC=1C(C)(C)C1=CC(Br)=C(O)C(Br)=C1 VEORPZCZECFIRK-UHFFFAOYSA-N 0.000 description 1
- DXIJHCSGLOHNES-UHFFFAOYSA-N 3,3-dimethylbut-1-enylbenzene Chemical compound CC(C)(C)C=CC1=CC=CC=C1 DXIJHCSGLOHNES-UHFFFAOYSA-N 0.000 description 1
- DYIZJUDNMOIZQO-UHFFFAOYSA-N 4,5,6,7-tetrabromo-2-[2-(4,5,6,7-tetrabromo-1,3-dioxoisoindol-2-yl)ethyl]isoindole-1,3-dione Chemical compound O=C1C(C(=C(Br)C(Br)=C2Br)Br)=C2C(=O)N1CCN1C(=O)C2=C(Br)C(Br)=C(Br)C(Br)=C2C1=O DYIZJUDNMOIZQO-UHFFFAOYSA-N 0.000 description 1
- JLBJTVDPSNHSKJ-UHFFFAOYSA-N 4-Methylstyrene Chemical compound CC1=CC=C(C=C)C=C1 JLBJTVDPSNHSKJ-UHFFFAOYSA-N 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 description 1
- 239000005751 Copper oxide Substances 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- 229920001890 Novodur Polymers 0.000 description 1
- 239000005062 Polybutadiene Substances 0.000 description 1
- 241001237745 Salamis Species 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 description 1
- 229910021536 Zeolite Inorganic materials 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 150000001463 antimony compounds Chemical class 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 229910052728 basic metal Inorganic materials 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- 229910052797 bismuth Inorganic materials 0.000 description 1
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 1
- 229910000416 bismuth oxide Inorganic materials 0.000 description 1
- 229920001400 block copolymer Polymers 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 150000007942 carboxylates Chemical class 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 229910000423 chromium oxide Inorganic materials 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 229910000428 cobalt oxide Inorganic materials 0.000 description 1
- IVMYJDGYRUAWML-UHFFFAOYSA-N cobalt(ii) oxide Chemical compound [Co]=O IVMYJDGYRUAWML-UHFFFAOYSA-N 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 229910000431 copper oxide Inorganic materials 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- UQLDLKMNUJERMK-UHFFFAOYSA-L di(octadecanoyloxy)lead Chemical compound [Pb+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O UQLDLKMNUJERMK-UHFFFAOYSA-L 0.000 description 1
- GDVKFRBCXAPAQJ-UHFFFAOYSA-A dialuminum;hexamagnesium;carbonate;hexadecahydroxide Chemical compound [OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Al+3].[Al+3].[O-]C([O-])=O GDVKFRBCXAPAQJ-UHFFFAOYSA-A 0.000 description 1
- TYIXMATWDRGMPF-UHFFFAOYSA-N dibismuth;oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Bi+3].[Bi+3] TYIXMATWDRGMPF-UHFFFAOYSA-N 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- JHXRVOAOESLJHL-UHFFFAOYSA-N ethene;1,2,3,4,5-pentabromobenzene Chemical compound C=C.BrC1=CC(Br)=C(Br)C(Br)=C1Br.BrC1=CC(Br)=C(Br)C(Br)=C1Br JHXRVOAOESLJHL-UHFFFAOYSA-N 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000005469 granulation Methods 0.000 description 1
- 230000003179 granulation Effects 0.000 description 1
- 150000002366 halogen compounds Chemical class 0.000 description 1
- 229960001545 hydrotalcite Drugs 0.000 description 1
- 229910001701 hydrotalcite Inorganic materials 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 238000010102 injection blow moulding Methods 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- OCWMFVJKFWXKNZ-UHFFFAOYSA-L lead(2+);oxygen(2-);sulfate Chemical compound [O-2].[O-2].[O-2].[Pb+2].[Pb+2].[Pb+2].[Pb+2].[O-]S([O-])(=O)=O OCWMFVJKFWXKNZ-UHFFFAOYSA-L 0.000 description 1
- 229940057995 liquid paraffin Drugs 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 229910000476 molybdenum oxide Inorganic materials 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 229910000480 nickel oxide Inorganic materials 0.000 description 1
- QGLKJKCYBOYXKC-UHFFFAOYSA-N nonaoxidotritungsten Chemical compound O=[W]1(=O)O[W](=O)(=O)O[W](=O)(=O)O1 QGLKJKCYBOYXKC-UHFFFAOYSA-N 0.000 description 1
- SSDSCDGVMJFTEQ-UHFFFAOYSA-N octadecyl 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 SSDSCDGVMJFTEQ-UHFFFAOYSA-N 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- PQQKPALAQIIWST-UHFFFAOYSA-N oxomolybdenum Chemical compound [Mo]=O PQQKPALAQIIWST-UHFFFAOYSA-N 0.000 description 1
- GNRSAWUEBMWBQH-UHFFFAOYSA-N oxonickel Chemical compound [Ni]=O GNRSAWUEBMWBQH-UHFFFAOYSA-N 0.000 description 1
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- XKJCHHZQLQNZHY-UHFFFAOYSA-N phthalimide Chemical compound C1=CC=C2C(=O)NC(=O)C2=C1 XKJCHHZQLQNZHY-UHFFFAOYSA-N 0.000 description 1
- 229920002857 polybutadiene Polymers 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 229920005604 random copolymer Polymers 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 235000015175 salami Nutrition 0.000 description 1
- 230000002000 scavenging effect Effects 0.000 description 1
- 229920000468 styrene butadiene styrene block copolymer Polymers 0.000 description 1
- 150000003440 styrenes Chemical class 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 238000005979 thermal decomposition reaction Methods 0.000 description 1
- 239000003017 thermal stabilizer Substances 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- 239000011135 tin Substances 0.000 description 1
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 1
- 229910001887 tin oxide Inorganic materials 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- 229910001930 tungsten oxide Inorganic materials 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 1
- 229910001928 zirconium oxide Inorganic materials 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2004074543A JP2005281327A (ja) | 2004-03-03 | 2004-03-16 | 難燃剤マスターバッチ樹脂組成物を用いたポリスチレン系樹脂の成形方法、および、その成形方法によって得られる成形品 |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2004059072 | 2004-03-03 | ||
| JP2004074543A JP2005281327A (ja) | 2004-03-03 | 2004-03-16 | 難燃剤マスターバッチ樹脂組成物を用いたポリスチレン系樹脂の成形方法、および、その成形方法によって得られる成形品 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2005281327A true JP2005281327A (ja) | 2005-10-13 |
| JP2005281327A5 JP2005281327A5 (enExample) | 2007-04-26 |
Family
ID=35180082
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2004074543A Pending JP2005281327A (ja) | 2004-03-03 | 2004-03-16 | 難燃剤マスターバッチ樹脂組成物を用いたポリスチレン系樹脂の成形方法、および、その成形方法によって得られる成形品 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2005281327A (enExample) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2009256502A (ja) * | 2008-04-18 | 2009-11-05 | Dic Corp | スチレン系樹脂組成物 |
| JP2011529112A (ja) * | 2008-07-22 | 2011-12-01 | ブロミン・コンパウンズ・リミテツド | スチレン含有ポリマーの難燃組成物 |
| WO2013057841A1 (ja) * | 2011-10-21 | 2013-04-25 | 東洋スチレン株式会社 | 難燃剤マスターバッチ及びそれを使用したスチレン系難燃性樹脂組成物の製造方法 |
| WO2017018505A1 (ja) * | 2015-07-29 | 2017-02-02 | 東洋スチレン株式会社 | 難燃剤マスターバッチ及びその製造方法 |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH03227370A (ja) * | 1990-01-31 | 1991-10-08 | Dainippon Ink & Chem Inc | 難燃剤マスターバッチ |
| JPH04145132A (ja) * | 1990-10-05 | 1992-05-19 | Nippon Kararingu Kk | 難燃マスターバッチ |
| JPH08109269A (ja) * | 1994-10-11 | 1996-04-30 | Asahi Chem Ind Co Ltd | 難燃マスターバッチ及びその製造方法 |
| JPH09301905A (ja) * | 1996-03-13 | 1997-11-25 | Tosoh Corp | 臭素化ｐ−クミルフェノール及びその誘導体、それらの製造方法、並びにそれらを配合してなる難燃性樹脂組成物 |
| JPH107856A (ja) * | 1996-06-26 | 1998-01-13 | Denki Kagaku Kogyo Kk | 樹脂組成物と樹脂成形体 |
| JPH107855A (ja) * | 1996-06-26 | 1998-01-13 | Denki Kagaku Kogyo Kk | 樹脂組成物と樹脂成形体 |
| JPH1143511A (ja) * | 1997-07-30 | 1999-02-16 | Tosoh Corp | 臭素化スチレンオリゴマー、その製造方法、及びそれを配合してなる難燃性樹脂組成物 |
-
2004
- 2004-03-16 JP JP2004074543A patent/JP2005281327A/ja active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH03227370A (ja) * | 1990-01-31 | 1991-10-08 | Dainippon Ink & Chem Inc | 難燃剤マスターバッチ |
| JPH04145132A (ja) * | 1990-10-05 | 1992-05-19 | Nippon Kararingu Kk | 難燃マスターバッチ |
| JPH08109269A (ja) * | 1994-10-11 | 1996-04-30 | Asahi Chem Ind Co Ltd | 難燃マスターバッチ及びその製造方法 |
| JPH09301905A (ja) * | 1996-03-13 | 1997-11-25 | Tosoh Corp | 臭素化ｐ−クミルフェノール及びその誘導体、それらの製造方法、並びにそれらを配合してなる難燃性樹脂組成物 |
| JPH107856A (ja) * | 1996-06-26 | 1998-01-13 | Denki Kagaku Kogyo Kk | 樹脂組成物と樹脂成形体 |
| JPH107855A (ja) * | 1996-06-26 | 1998-01-13 | Denki Kagaku Kogyo Kk | 樹脂組成物と樹脂成形体 |
| JPH1143511A (ja) * | 1997-07-30 | 1999-02-16 | Tosoh Corp | 臭素化スチレンオリゴマー、その製造方法、及びそれを配合してなる難燃性樹脂組成物 |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2009256502A (ja) * | 2008-04-18 | 2009-11-05 | Dic Corp | スチレン系樹脂組成物 |
| JP2011529112A (ja) * | 2008-07-22 | 2011-12-01 | ブロミン・コンパウンズ・リミテツド | スチレン含有ポリマーの難燃組成物 |
| WO2013057841A1 (ja) * | 2011-10-21 | 2013-04-25 | 東洋スチレン株式会社 | 難燃剤マスターバッチ及びそれを使用したスチレン系難燃性樹脂組成物の製造方法 |
| CN103890083A (zh) * | 2011-10-21 | 2014-06-25 | 东洋苯乙烯股份有限公司 | 阻燃剂母料及使用了该母料的苯乙烯系阻燃性树脂组合物的制造方法 |
| JPWO2013057841A1 (ja) * | 2011-10-21 | 2015-04-02 | 東洋スチレン株式会社 | 難燃剤マスターバッチ及びそれを使用したスチレン系難燃性樹脂組成物の製造方法 |
| CN103890083B (zh) * | 2011-10-21 | 2016-03-16 | 东洋苯乙烯股份有限公司 | 阻燃剂母料及使用了该母料的苯乙烯系阻燃性树脂组合物的制造方法 |
| WO2017018505A1 (ja) * | 2015-07-29 | 2017-02-02 | 東洋スチレン株式会社 | 難燃剤マスターバッチ及びその製造方法 |
| JPWO2017018505A1 (ja) * | 2015-07-29 | 2018-05-17 | 東洋スチレン株式会社 | 難燃剤マスターバッチ及びその製造方法 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP5196630B2 (ja) | ポリフェニレンエーテル系樹脂組成物の製造方法 | |
| US5194482A (en) | Flame retardant resin composition containing styrenic polymers | |
| JPH05247292A (ja) | スチレン系樹脂組成物 | |
| KR101040447B1 (ko) | 충격강도와 광택성이 우수한 난연수지 조성물 | |
| JPS63113036A (ja) | 発泡体製造用ポリフェニレンエーテル樹脂組成物 | |
| EP3301135B1 (en) | Flame-retardant resin composition and flame-retardant resin molded article | |
| WO2019235378A1 (ja) | スチレン系難燃樹脂組成物の製造方法 | |
| JP5872577B2 (ja) | 難燃剤マスターバッチ及びそれを使用したスチレン系難燃性樹脂組成物の製造方法 | |
| JP5388882B2 (ja) | 樹脂組成物及びこれを用いた成形体 | |
| JP2005281327A (ja) | 難燃剤マスターバッチ樹脂組成物を用いたポリスチレン系樹脂の成形方法、および、その成形方法によって得られる成形品 | |
| JP2005139431A (ja) | マスターバッチを用いたポリスチレン系樹脂の成形方法、および、その成形方法によって得られる成形品 | |
| US5486543A (en) | Formed thermoplastic resin article and production process thereof | |
| KR102145797B1 (ko) | 열가소성 난연 수지 조성물, 이의 제조방법 및 이를 포함하여 제조된 사출 성형품 | |
| JP2008195883A (ja) | 樹脂組成物の製造方法 | |
| JPH07216100A (ja) | 難燃樹脂材料製造用ペレット、及び難燃樹脂材料の製造方法 | |
| JPH11302480A (ja) | スチレン系樹脂組成物 | |
| JPH11292981A (ja) | 熱可塑性樹脂混練物及びその製造方法 | |
| JP2005145988A (ja) | 難燃性スチレン系樹脂組成物 | |
| JPH107855A (ja) | 樹脂組成物と樹脂成形体 | |
| JP2018087261A (ja) | 再生ポリスチレン樹脂組成物およびその製造方法 | |
| JP3388854B2 (ja) | 難燃性樹脂組成物 | |
| JP2017101191A (ja) | 粉体物の混合方法および樹脂組成物の製造方法 | |
| CN118725450B (zh) | 一种聚丙烯组合物及其制备方法和应用 | |
| JP2002256143A (ja) | 導電性ポリフェニレンエーテル樹脂組成物及びその成形品 | |
| JPH11256002A (ja) | ゴム変成スチレン系樹脂組成物 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A521 | Written amendment |
Effective date: 20070313 Free format text: JAPANESE INTERMEDIATE CODE: A523 |
|
| A621 | Written request for application examination |
Effective date: 20070313 Free format text: JAPANESE INTERMEDIATE CODE: A621 |
|
| A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20100506 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20100526 |
|
| A02 | Decision of refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A02 Effective date: 20100929 |