JP2005272557A - アクリル系共重合体の製造法 - Google Patents
アクリル系共重合体の製造法 Download PDFInfo
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- JP2005272557A JP2005272557A JP2004086082A JP2004086082A JP2005272557A JP 2005272557 A JP2005272557 A JP 2005272557A JP 2004086082 A JP2004086082 A JP 2004086082A JP 2004086082 A JP2004086082 A JP 2004086082A JP 2005272557 A JP2005272557 A JP 2005272557A
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- Prior art keywords
- weight
- meth
- acrylate
- acrylic copolymer
- acrylamide
- Prior art date
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- 229920006243 acrylic copolymer Polymers 0.000 title claims abstract description 14
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 36
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims abstract description 28
- 239000000178 monomer Substances 0.000 claims abstract description 24
- 239000000203 mixture Substances 0.000 claims abstract description 20
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 claims abstract description 14
- 229920001451 polypropylene glycol Polymers 0.000 claims abstract description 14
- 239000003093 cationic surfactant Substances 0.000 claims abstract description 8
- 238000004945 emulsification Methods 0.000 claims abstract description 8
- 238000007720 emulsion polymerization reaction Methods 0.000 claims abstract description 7
- 150000001875 compounds Chemical class 0.000 claims abstract description 6
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims abstract description 5
- 125000002947 alkylene group Chemical group 0.000 claims abstract description 3
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims abstract description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims abstract description 3
- 239000002736 nonionic surfactant Substances 0.000 claims description 7
- 239000005871 repellent Substances 0.000 claims description 6
- 125000004432 carbon atom Chemical group C* 0.000 claims description 5
- 230000001804 emulsifying effect Effects 0.000 claims description 5
- 230000002940 repellent Effects 0.000 claims description 5
- 238000000034 method Methods 0.000 claims description 4
- 239000004480 active ingredient Substances 0.000 claims description 3
- 239000000084 colloidal system Substances 0.000 claims description 2
- 239000003505 polymerization initiator Substances 0.000 claims 1
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- 238000006116 polymerization reaction Methods 0.000 abstract description 8
- 239000003995 emulsifying agent Substances 0.000 abstract description 4
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- 230000015572 biosynthetic process Effects 0.000 abstract description 2
- 229910052799 carbon Inorganic materials 0.000 description 27
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- 239000004744 fabric Substances 0.000 description 11
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- -1 2-hydroxy-3-chloropropyl Chemical group 0.000 description 10
- 229920000742 Cotton Polymers 0.000 description 9
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- 238000006243 chemical reaction Methods 0.000 description 7
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- 238000003860 storage Methods 0.000 description 6
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical group N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 5
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- 230000000052 comparative effect Effects 0.000 description 5
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- 229910001873 dinitrogen Inorganic materials 0.000 description 5
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- 239000002244 precipitate Substances 0.000 description 5
- 239000000047 product Substances 0.000 description 5
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- CNCOEDDPFOAUMB-UHFFFAOYSA-N N-Methylolacrylamide Chemical compound OCNC(=O)C=C CNCOEDDPFOAUMB-UHFFFAOYSA-N 0.000 description 4
- VBIIFPGSPJYLRR-UHFFFAOYSA-M Stearyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)C VBIIFPGSPJYLRR-UHFFFAOYSA-M 0.000 description 4
- REZZEXDLIUJMMS-UHFFFAOYSA-M dimethyldioctadecylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)CCCCCCCCCCCCCCCCCC REZZEXDLIUJMMS-UHFFFAOYSA-M 0.000 description 4
- 238000010556 emulsion polymerization method Methods 0.000 description 4
- DCAYPVUWAIABOU-UHFFFAOYSA-N hexadecane Chemical compound CCCCCCCCCCCCCCCC DCAYPVUWAIABOU-UHFFFAOYSA-N 0.000 description 4
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- NCRMXFQFOJIFQW-UHFFFAOYSA-N 1-octyl-2-(2-octylphenoxy)benzene Chemical compound CCCCCCCCC1=CC=CC=C1OC1=CC=CC=C1CCCCCCCC NCRMXFQFOJIFQW-UHFFFAOYSA-N 0.000 description 3
- REEBWSYYNPPSKV-UHFFFAOYSA-N 3-[(4-formylphenoxy)methyl]thiophene-2-carbonitrile Chemical compound C1=CC(C=O)=CC=C1OCC1=C(C#N)SC=C1 REEBWSYYNPPSKV-UHFFFAOYSA-N 0.000 description 3
- JTHZUSWLNCPZLX-UHFFFAOYSA-N 6-fluoro-3-methyl-2h-indazole Chemical compound FC1=CC=C2C(C)=NNC2=C1 JTHZUSWLNCPZLX-UHFFFAOYSA-N 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 3
- LXEKPEMOWBOYRF-UHFFFAOYSA-N [2-[(1-azaniumyl-1-imino-2-methylpropan-2-yl)diazenyl]-2-methylpropanimidoyl]azanium;dichloride Chemical compound Cl.Cl.NC(=N)C(C)(C)N=NC(C)(C)C(N)=N LXEKPEMOWBOYRF-UHFFFAOYSA-N 0.000 description 3
- 239000004664 distearyldimethylammonium chloride (DHTDMAC) Substances 0.000 description 3
- WNAHIZMDSQCWRP-UHFFFAOYSA-N dodecane-1-thiol Chemical compound CCCCCCCCCCCCS WNAHIZMDSQCWRP-UHFFFAOYSA-N 0.000 description 3
- 229920002313 fluoropolymer Polymers 0.000 description 3
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- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
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- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
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- IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 description 2
- 239000004952 Polyamide Substances 0.000 description 2
- 239000002202 Polyethylene glycol Substances 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 239000012736 aqueous medium Substances 0.000 description 2
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 2
- 238000001723 curing Methods 0.000 description 2
- DIOQZVSQGTUSAI-UHFFFAOYSA-N decane Chemical compound CCCCCCCCCC DIOQZVSQGTUSAI-UHFFFAOYSA-N 0.000 description 2
- 125000004386 diacrylate group Chemical group 0.000 description 2
- 238000010790 dilution Methods 0.000 description 2
- 239000012895 dilution Substances 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- XXMIOPMDWAUFGU-UHFFFAOYSA-N hexane-1,6-diol Chemical compound OCCCCCCO XXMIOPMDWAUFGU-UHFFFAOYSA-N 0.000 description 2
- 230000001771 impaired effect Effects 0.000 description 2
- 239000003999 initiator Substances 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 2
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 2
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 2
- 229920002647 polyamide Polymers 0.000 description 2
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 2
- 150000003839 salts Chemical group 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- BGHCVCJVXZWKCC-UHFFFAOYSA-N tetradecane Chemical compound CCCCCCCCCCCCCC BGHCVCJVXZWKCC-UHFFFAOYSA-N 0.000 description 2
- YGKOYVNJPRSSRX-UHFFFAOYSA-M (4-dodecylphenyl)methyl-trimethylazanium;chloride Chemical compound [Cl-].CCCCCCCCCCCCC1=CC=C(C[N+](C)(C)C)C=C1 YGKOYVNJPRSSRX-UHFFFAOYSA-M 0.000 description 1
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- MJYFYGVCLHNRKB-UHFFFAOYSA-N 1,1,2-trifluoroethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OC(F)(F)CF MJYFYGVCLHNRKB-UHFFFAOYSA-N 0.000 description 1
- BQCIDUSAKPWEOX-UHFFFAOYSA-N 1,1-Difluoroethene Chemical compound FC(F)=C BQCIDUSAKPWEOX-UHFFFAOYSA-N 0.000 description 1
- ALVZNPYWJMLXKV-UHFFFAOYSA-N 1,9-Nonanediol Chemical compound OCCCCCCCCCO ALVZNPYWJMLXKV-UHFFFAOYSA-N 0.000 description 1
- DNJRKFKAFWSXSE-UHFFFAOYSA-N 1-chloro-2-ethenoxyethane Chemical compound ClCCOC=C DNJRKFKAFWSXSE-UHFFFAOYSA-N 0.000 description 1
- IGGDKDTUCAWDAN-UHFFFAOYSA-N 1-vinylnaphthalene Chemical compound C1=CC=C2C(C=C)=CC=CC2=C1 IGGDKDTUCAWDAN-UHFFFAOYSA-N 0.000 description 1
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 1
- LCZVSXRMYJUNFX-UHFFFAOYSA-N 2-[2-(2-hydroxypropoxy)propoxy]propan-1-ol Chemical compound CC(O)COC(C)COC(C)CO LCZVSXRMYJUNFX-UHFFFAOYSA-N 0.000 description 1
- VUIWJRYTWUGOOF-UHFFFAOYSA-N 2-ethenoxyethanol Chemical compound OCCOC=C VUIWJRYTWUGOOF-UHFFFAOYSA-N 0.000 description 1
- DRMHKEHXDVIKKG-UHFFFAOYSA-N 2-ethylhexyl 2-methylprop-2-enoate;prop-2-enoic acid Chemical compound OC(=O)C=C.CCCCC(CC)COC(=O)C(C)=C DRMHKEHXDVIKKG-UHFFFAOYSA-N 0.000 description 1
- ABMULKFGWTYIIK-UHFFFAOYSA-N 2-hexylphenol Chemical compound CCCCCCC1=CC=CC=C1O ABMULKFGWTYIIK-UHFFFAOYSA-N 0.000 description 1
- OMIGHNLMNHATMP-UHFFFAOYSA-N 2-hydroxyethyl prop-2-enoate Chemical compound OCCOC(=O)C=C OMIGHNLMNHATMP-UHFFFAOYSA-N 0.000 description 1
- NWIIFBPIDORBCY-UHFFFAOYSA-N 2-methylprop-2-enoic acid;propane-1,2,3-triol;prop-2-enoic acid Chemical compound OC(=O)C=C.CC(=C)C(O)=O.OCC(O)CO NWIIFBPIDORBCY-UHFFFAOYSA-N 0.000 description 1
- DUIOKRXOKLLURE-UHFFFAOYSA-N 2-octylphenol Chemical compound CCCCCCCCC1=CC=CC=C1O DUIOKRXOKLLURE-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- HMBNQNDUEFFFNZ-UHFFFAOYSA-N 4-ethenoxybutan-1-ol Chemical compound OCCCCOC=C HMBNQNDUEFFFNZ-UHFFFAOYSA-N 0.000 description 1
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- 150000003973 alkyl amines Chemical class 0.000 description 1
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- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 1
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- 239000004753 textile Substances 0.000 description 1
- 238000013519 translation Methods 0.000 description 1
- CEYYIKYYFSTQRU-UHFFFAOYSA-M trimethyl(tetradecyl)azanium;chloride Chemical compound [Cl-].CCCCCCCCCCCCCC[N+](C)(C)C CEYYIKYYFSTQRU-UHFFFAOYSA-M 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 238000004383 yellowing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/22—Esters containing halogen
- C08F220/24—Esters containing halogen containing perhaloalkyl radicals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
- C08F2/22—Emulsion polymerisation
- C08F2/24—Emulsion polymerisation with the aid of emulsifying agents
- C08F2/28—Emulsion polymerisation with the aid of emulsifying agents cationic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
- C08F2/22—Emulsion polymerisation
- C08F2/24—Emulsion polymerisation with the aid of emulsifying agents
- C08F2/30—Emulsion polymerisation with the aid of emulsifying agents non-ionic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
- C08F220/1818—C13or longer chain (meth)acrylate, e.g. stearyl (meth)acrylate
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Materials Applied To Surfaces To Minimize Adherence Of Mist Or Water (AREA)
- Polymerisation Methods In General (AREA)
Priority Applications (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2004086082A JP2005272557A (ja) | 2004-03-24 | 2004-03-24 | アクリル系共重合体の製造法 |
| DE112005000316T DE112005000316T5 (de) | 2004-03-24 | 2005-03-22 | Verfahren zur Herstellung eines Acrylcopolymers |
| US10/587,640 US20070106043A1 (en) | 2004-03-24 | 2005-03-22 | Method of producing acrylic copolymer |
| CNB2005800095886A CN100467500C (zh) | 2004-03-24 | 2005-03-22 | 丙烯酸类共聚物的制备方法 |
| PCT/JP2005/005114 WO2005090420A1 (ja) | 2004-03-24 | 2005-03-22 | アクリル系共重合体の製造法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2004086082A JP2005272557A (ja) | 2004-03-24 | 2004-03-24 | アクリル系共重合体の製造法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2005272557A true JP2005272557A (ja) | 2005-10-06 |
| JP2005272557A5 JP2005272557A5 (enExample) | 2006-08-03 |
Family
ID=34993647
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2004086082A Pending JP2005272557A (ja) | 2004-03-24 | 2004-03-24 | アクリル系共重合体の製造法 |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US20070106043A1 (enExample) |
| JP (1) | JP2005272557A (enExample) |
| CN (1) | CN100467500C (enExample) |
| DE (1) | DE112005000316T5 (enExample) |
| WO (1) | WO2005090420A1 (enExample) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2008231397A (ja) * | 2007-02-23 | 2008-10-02 | Sekisui Plastics Co Ltd | 陽イオン性重合体粒子の水系分散液及びその製造方法 |
| WO2009008512A1 (ja) * | 2007-07-11 | 2009-01-15 | Asahi Glass Company, Limited | 撥水撥油剤組成物の製造方法および物品 |
| WO2010101091A1 (ja) * | 2009-03-04 | 2010-09-10 | ユニマテック株式会社 | 含フッ素重合体を有効成分とする表面改質剤 |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7754838B2 (en) | 2006-08-08 | 2010-07-13 | E.I. Du Pont De Nemours And Company | Poly(meth)acrylamides and poly(meth)acrylates containing fluorinated amide |
| CN102174143B (zh) * | 2011-01-29 | 2013-01-09 | 锦州惠发天合化学有限公司 | 一种含氟丙烯酸酯乳液的制备方法 |
| CN102587141B (zh) * | 2012-01-18 | 2013-12-18 | 常州化工研究所有限公司 | 含氟织物整理剂及其制备方法 |
| CN105505087A (zh) * | 2015-12-14 | 2016-04-20 | 苏州市官田电子有限公司 | 一种疏水疏油抗污玻璃基材及其生产方法 |
| CN105411938A (zh) * | 2015-12-18 | 2016-03-23 | 岳双辰 | 一种植物新型清水黑发染发剂 |
| CN105712708B (zh) * | 2016-01-12 | 2018-02-13 | 西南民族大学 | 一种高效节能陶瓷材料 |
| CN105712711B (zh) * | 2016-01-12 | 2018-06-26 | 西南民族大学 | 一种高性能微波介质陶瓷材料及其制备方法 |
| EP3336202A1 (de) * | 2016-12-13 | 2018-06-20 | LANXESS Deutschland GmbH | Verfahren zur herstellung hydrophobierender lederbehandlungsmittel |
| CN109054567A (zh) * | 2018-09-03 | 2018-12-21 | 广州市绿森环保设备有限公司 | 透明超疏水超疏油喷剂及其制备方法 |
| CN112194920A (zh) * | 2020-09-22 | 2021-01-08 | 沪宝新材料科技（上海）股份有限公司 | 一种防水防油污水性外墙漆及其制备方法 |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6456711A (en) * | 1987-05-25 | 1989-03-03 | Daikin Ind Ltd | Novel copolymer and water-and-oil repellent therefrom |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0294648B1 (en) * | 1987-05-25 | 1993-01-07 | Daikin Industries, Limited | Novel copolymer and water- and oil-repellent comprising the same |
| JP2605168B2 (ja) * | 1990-07-20 | 1997-04-30 | 旭硝子株式会社 | 水分散型撥水撥油剤 |
| JP3624615B2 (ja) * | 1997-02-28 | 2005-03-02 | ユニマテック株式会社 | 新規共重合体およびそれを含有する撥水撥油剤 |
| JP4300678B2 (ja) * | 1999-08-03 | 2009-07-22 | ユニマテック株式会社 | 防汚加工剤の製造法 |
| DE60041121D1 (de) * | 1999-10-29 | 2009-01-29 | Asahi Glass Co Ltd | In wasser dispergierte wasser- und ölabweisende zusammensetzung und verfahren zu ihrer herstellung |
| JP2002241441A (ja) * | 2001-02-15 | 2002-08-28 | Asahi Glass Co Ltd | 水分散型含フッ素共重合体組成物 |
| JP2002256257A (ja) * | 2001-03-05 | 2002-09-11 | Asahi Glass Co Ltd | 水分散型撥水撥油剤組成物および処理物品 |
-
2004
- 2004-03-24 JP JP2004086082A patent/JP2005272557A/ja active Pending
-
2005
- 2005-03-22 WO PCT/JP2005/005114 patent/WO2005090420A1/ja not_active Ceased
- 2005-03-22 DE DE112005000316T patent/DE112005000316T5/de not_active Withdrawn
- 2005-03-22 US US10/587,640 patent/US20070106043A1/en not_active Abandoned
- 2005-03-22 CN CNB2005800095886A patent/CN100467500C/zh not_active Expired - Fee Related
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6456711A (en) * | 1987-05-25 | 1989-03-03 | Daikin Ind Ltd | Novel copolymer and water-and-oil repellent therefrom |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2008231397A (ja) * | 2007-02-23 | 2008-10-02 | Sekisui Plastics Co Ltd | 陽イオン性重合体粒子の水系分散液及びその製造方法 |
| WO2009008512A1 (ja) * | 2007-07-11 | 2009-01-15 | Asahi Glass Company, Limited | 撥水撥油剤組成物の製造方法および物品 |
| JPWO2009008512A1 (ja) * | 2007-07-11 | 2010-09-09 | 旭硝子株式会社 | 撥水撥油剤組成物の製造方法および物品 |
| US7989567B2 (en) | 2007-07-11 | 2011-08-02 | Asahi Glass Company, Limited | Method for production of water/oil repellent composition and article |
| WO2010101091A1 (ja) * | 2009-03-04 | 2010-09-10 | ユニマテック株式会社 | 含フッ素重合体を有効成分とする表面改質剤 |
Also Published As
| Publication number | Publication date |
|---|---|
| WO2005090420A1 (ja) | 2005-09-29 |
| US20070106043A1 (en) | 2007-05-10 |
| CN1934147A (zh) | 2007-03-21 |
| DE112005000316T5 (de) | 2007-02-08 |
| CN100467500C (zh) | 2009-03-11 |
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