JP2003522111A5 - - Google Patents
Download PDFInfo
- Publication number
- JP2003522111A5 JP2003522111A5 JP2000575850A JP2000575850A JP2003522111A5 JP 2003522111 A5 JP2003522111 A5 JP 2003522111A5 JP 2000575850 A JP2000575850 A JP 2000575850A JP 2000575850 A JP2000575850 A JP 2000575850A JP 2003522111 A5 JP2003522111 A5 JP 2003522111A5
- Authority
- JP
- Japan
- Prior art keywords
- mesh
- catalyst
- support
- supported
- coating
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003054 catalyst Substances 0.000 description 108
- 238000007254 oxidation reaction Methods 0.000 description 58
- 230000003647 oxidation Effects 0.000 description 56
- 239000002245 particle Substances 0.000 description 50
- 238000000034 method Methods 0.000 description 47
- 239000011248 coating agent Substances 0.000 description 39
- 238000000576 coating method Methods 0.000 description 39
- 238000006243 chemical reaction Methods 0.000 description 32
- 239000000835 fiber Substances 0.000 description 27
- 239000000463 material Substances 0.000 description 21
- 229910052751 metal Inorganic materials 0.000 description 19
- 239000002184 metal Substances 0.000 description 19
- 230000008569 process Effects 0.000 description 19
- 239000000203 mixture Substances 0.000 description 18
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 16
- 239000002002 slurry Substances 0.000 description 15
- HGINCPLSRVDWNT-UHFFFAOYSA-N Acrolein Chemical compound C=CC=O HGINCPLSRVDWNT-UHFFFAOYSA-N 0.000 description 14
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 13
- 239000010410 layer Substances 0.000 description 13
- 239000011800 void material Substances 0.000 description 13
- 239000007789 gas Substances 0.000 description 12
- 239000007788 liquid Substances 0.000 description 12
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 10
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 10
- 239000005977 Ethylene Substances 0.000 description 10
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 10
- 239000008199 coating composition Substances 0.000 description 10
- 239000001301 oxygen Substances 0.000 description 10
- 229910052760 oxygen Inorganic materials 0.000 description 10
- LGRFSURHDFAFJT-UHFFFAOYSA-N phthalic anhydride Chemical compound C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 10
- JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 description 9
- 238000001035 drying Methods 0.000 description 9
- 239000008096 xylene Substances 0.000 description 9
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 8
- 150000001336 alkenes Chemical class 0.000 description 8
- 239000000047 product Substances 0.000 description 8
- 229910052709 silver Inorganic materials 0.000 description 7
- 239000004332 silver Substances 0.000 description 7
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 6
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 6
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 6
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 6
- 125000002947 alkylene group Chemical group 0.000 description 6
- 238000007598 dipping method Methods 0.000 description 6
- NIXOWILDQLNWCW-UHFFFAOYSA-N Acrylic acid Chemical compound OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 5
- 229910002092 carbon dioxide Inorganic materials 0.000 description 5
- 238000011068 loading method Methods 0.000 description 5
- 150000002894 organic compounds Chemical class 0.000 description 5
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical group O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- 239000000654 additive Substances 0.000 description 4
- 239000001569 carbon dioxide Substances 0.000 description 4
- 239000012018 catalyst precursor Substances 0.000 description 4
- 229910001882 dioxygen Inorganic materials 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 4
- 238000012856 packing Methods 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 150000001299 aldehydes Chemical class 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 3
- 239000011230 binding agent Substances 0.000 description 3
- 229910052792 caesium Inorganic materials 0.000 description 3
- TVFDJXOCXUVLDH-UHFFFAOYSA-N caesium atom Chemical compound [Cs] TVFDJXOCXUVLDH-UHFFFAOYSA-N 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 239000002609 medium Substances 0.000 description 3
- 150000002739 metals Chemical class 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 239000003960 organic solvent Substances 0.000 description 3
- 239000011148 porous material Substances 0.000 description 3
- 239000001294 propane Substances 0.000 description 3
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 3
- 230000000717 retained effect Effects 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 238000005507 spraying Methods 0.000 description 3
- MFGOFGRYDNHJTA-UHFFFAOYSA-N 2-amino-1-(2-fluorophenyl)ethanol Chemical compound NCC(O)C1=CC=CC=C1F MFGOFGRYDNHJTA-UHFFFAOYSA-N 0.000 description 2
- WNZQDUSMALZDQF-UHFFFAOYSA-N 2-benzofuran-1(3H)-one Chemical compound C1=CC=C2C(=O)OCC2=C1 WNZQDUSMALZDQF-UHFFFAOYSA-N 0.000 description 2
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 2
- ZHNUHDYFZUAESO-UHFFFAOYSA-N Formamide Chemical compound NC=O ZHNUHDYFZUAESO-UHFFFAOYSA-N 0.000 description 2
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 150000001335 aliphatic alkanes Chemical class 0.000 description 2
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 2
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical compound O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 description 2
- HUCVOHYBFXVBRW-UHFFFAOYSA-M caesium hydroxide Inorganic materials [OH-].[Cs+] HUCVOHYBFXVBRW-UHFFFAOYSA-M 0.000 description 2
- 230000003197 catalytic effect Effects 0.000 description 2
- 239000002826 coolant Substances 0.000 description 2
- 239000003085 diluting agent Substances 0.000 description 2
- 239000012738 dissolution medium Substances 0.000 description 2
- 239000012153 distilled water Substances 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000006735 epoxidation reaction Methods 0.000 description 2
- 238000004880 explosion Methods 0.000 description 2
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 2
- 229910044991 metal oxide Inorganic materials 0.000 description 2
- VUZPPFZMUPKLLV-UHFFFAOYSA-N methane;hydrate Chemical compound C.O VUZPPFZMUPKLLV-UHFFFAOYSA-N 0.000 description 2
- 239000012046 mixed solvent Substances 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 238000000643 oven drying Methods 0.000 description 2
- OGUCKKLSDGRKSH-UHFFFAOYSA-N oxalic acid oxovanadium Chemical compound [V].[O].C(C(=O)O)(=O)O OGUCKKLSDGRKSH-UHFFFAOYSA-N 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- 230000035515 penetration Effects 0.000 description 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 229910052701 rubidium Inorganic materials 0.000 description 2
- IGLNJRXAVVLDKE-UHFFFAOYSA-N rubidium atom Chemical compound [Rb] IGLNJRXAVVLDKE-UHFFFAOYSA-N 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- XNGYKPINNDWGGF-UHFFFAOYSA-L silver oxalate Chemical compound [Ag+].[Ag+].[O-]C(=O)C([O-])=O XNGYKPINNDWGGF-UHFFFAOYSA-L 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 1
- -1 2-20% and 5-20% Chemical compound 0.000 description 1
- ZSLUVFAKFWKJRC-IGMARMGPSA-N 232Th Chemical compound [232Th] ZSLUVFAKFWKJRC-IGMARMGPSA-N 0.000 description 1
- 229910000619 316 stainless steel Inorganic materials 0.000 description 1
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 1
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 1
- 239000004254 Ammonium phosphate Substances 0.000 description 1
- 238000004438 BET method Methods 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
- 229920001410 Microfiber Polymers 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- IOVCWXUNBOPUCH-UHFFFAOYSA-N Nitrous acid Chemical compound ON=O IOVCWXUNBOPUCH-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- 229910052776 Thorium Inorganic materials 0.000 description 1
- 241000170489 Upis Species 0.000 description 1
- 229910021553 Vanadium(V) chloride Inorganic materials 0.000 description 1
- XHCLAFWTIXFWPH-UHFFFAOYSA-N [O-2].[O-2].[O-2].[O-2].[O-2].[V+5].[V+5] Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[V+5].[V+5] XHCLAFWTIXFWPH-UHFFFAOYSA-N 0.000 description 1
- 239000011149 active material Substances 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 229910000148 ammonium phosphate Inorganic materials 0.000 description 1
- 235000019289 ammonium phosphates Nutrition 0.000 description 1
- 150000008064 anhydrides Chemical class 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000001273 butane Substances 0.000 description 1
- IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- KOPBYBDAPCDYFK-UHFFFAOYSA-N caesium oxide Chemical compound [O-2].[Cs+].[Cs+] KOPBYBDAPCDYFK-UHFFFAOYSA-N 0.000 description 1
- 229910001942 caesium oxide Inorganic materials 0.000 description 1
- 238000001354 calcination Methods 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000007385 chemical modification Methods 0.000 description 1
- 239000006255 coating slurry Substances 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 238000010960 commercial process Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 description 1
- 238000003618 dip coating Methods 0.000 description 1
- 230000008034 disappearance Effects 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 239000000374 eutectic mixture Substances 0.000 description 1
- 229910052734 helium Inorganic materials 0.000 description 1
- 239000001307 helium Substances 0.000 description 1
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 229940057995 liquid paraffin Drugs 0.000 description 1
- 230000001404 mediated effect Effects 0.000 description 1
- 150000001247 metal acetylides Chemical class 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 239000003658 microfiber Substances 0.000 description 1
- 238000003801 milling Methods 0.000 description 1
- 239000011259 mixed solution Substances 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 1
- 239000011664 nicotinic acid Substances 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical compound [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- RPESBQCJGHJMTK-UHFFFAOYSA-I pentachlorovanadium Chemical compound [Cl-].[Cl-].[Cl-].[Cl-].[Cl-].[V+5] RPESBQCJGHJMTK-UHFFFAOYSA-I 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229910001392 phosphorus oxide Inorganic materials 0.000 description 1
- 150000003022 phthalic acids Chemical class 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 239000004323 potassium nitrate Substances 0.000 description 1
- 235000010333 potassium nitrate Nutrition 0.000 description 1
- 150000003138 primary alcohols Chemical class 0.000 description 1
- PBDKKYFZLPVGMK-UHFFFAOYSA-N prop-2-enal;prop-1-ene Chemical compound CC=C.C=CC=O PBDKKYFZLPVGMK-UHFFFAOYSA-N 0.000 description 1
- 150000003856 quaternary ammonium compounds Chemical class 0.000 description 1
- 239000012495 reaction gas Substances 0.000 description 1
- 229910001952 rubidium oxide Inorganic materials 0.000 description 1
- CWBWCLMMHLCMAM-UHFFFAOYSA-M rubidium(1+);hydroxide Chemical compound [OH-].[Rb+].[Rb+] CWBWCLMMHLCMAM-UHFFFAOYSA-M 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 1
- 229910010271 silicon carbide Inorganic materials 0.000 description 1
- 239000002356 single layer Substances 0.000 description 1
- 238000007581 slurry coating method Methods 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 239000012798 spherical particle Substances 0.000 description 1
- 230000002269 spontaneous effect Effects 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- VSAISIQCTGDGPU-UHFFFAOYSA-N tetraphosphorus hexaoxide Chemical compound O1P(O2)OP3OP1OP2O3 VSAISIQCTGDGPU-UHFFFAOYSA-N 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 229910001935 vanadium oxide Inorganic materials 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US10371798P | 1998-10-09 | 1998-10-09 | |
| US60/103,717 | 1998-10-09 | ||
| US09/407,436 | 1999-09-29 | ||
| US09/407,436 US6417376B1 (en) | 1998-10-09 | 1999-09-29 | Selective oxidation process and catalyst therefor |
| PCT/US1999/023347 WO2000021944A2 (en) | 1998-10-09 | 1999-10-07 | Selective oxidation process and catalyst therefor |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2003522111A JP2003522111A (ja) | 2003-07-22 |
| JP2003522111A5 true JP2003522111A5 (enExample) | 2006-11-24 |
| JP5153034B2 JP5153034B2 (ja) | 2013-02-27 |
Family
ID=26800777
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2000575850A Expired - Lifetime JP5153034B2 (ja) | 1998-10-09 | 1999-10-07 | 選択的酸化プロセスとその触媒 |
Country Status (15)
| Country | Link |
|---|---|
| US (1) | US6417376B1 (enExample) |
| EP (1) | EP1119410B1 (enExample) |
| JP (1) | JP5153034B2 (enExample) |
| KR (1) | KR100611443B1 (enExample) |
| CN (1) | CN1332764C (enExample) |
| AR (1) | AR020759A1 (enExample) |
| AT (1) | ATE314145T1 (enExample) |
| AU (1) | AU760603B2 (enExample) |
| BR (1) | BR9914121A (enExample) |
| DE (1) | DE69929222T2 (enExample) |
| ES (1) | ES2257100T3 (enExample) |
| ID (1) | ID29043A (enExample) |
| MX (1) | MXPA01003318A (enExample) |
| MY (1) | MY119687A (enExample) |
| WO (1) | WO2000021944A2 (enExample) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19931902A1 (de) * | 1999-07-08 | 2001-01-18 | Consortium Elektrochem Ind | Verfahren zur Herstellung von monolithischen Oxidationskatalysatoren und deren Verwendung bei der Gasphasenoxidation von Kohlenwasserstoffen |
| US6667017B2 (en) * | 1999-10-15 | 2003-12-23 | Abb Lummus Global, Inc. | Process for removing environmentally harmful compounds |
| JP4995373B2 (ja) * | 2001-02-20 | 2012-08-08 | 三菱レイヨン株式会社 | 反応管、触媒の製造方法、不飽和アルデヒドおよび不飽和カルボン酸の製造方法 |
| EP1648632A4 (en) * | 2003-07-30 | 2009-04-08 | Corning Inc | METAL BEES NECK SUBSTRATES FOR CHEMICAL AND THERMAL APPLICATIONS |
| US7067455B2 (en) * | 2003-11-21 | 2006-06-27 | Conocophillips Company | Copper modified catalysts for oxidative dehydrogenation |
| DE102008025843A1 (de) * | 2008-05-29 | 2009-12-03 | Bayer Technology Services Gmbh | Verfahren zur Herstellung von Phthalsäureanhydrid |
| US20130184505A1 (en) * | 2009-10-27 | 2013-07-18 | Ignite Energy Resources Limited | Methods for Producing Hydrocarbon Products from Bio-Oils and/or Coal-Oils |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US218124A (en) * | 1879-08-05 | Improvement in seed-sower and fertilizer-distributer | ||
| US3713281A (en) | 1971-11-02 | 1973-01-30 | G Asker | Heat and moisture exchange packing |
| EP0061304A1 (en) | 1981-03-18 | 1982-09-29 | Johnson Matthey Public Limited Company | Three dimensional interstitial catalyst support, its manufacture and use |
| JPS58153538A (ja) | 1982-03-08 | 1983-09-12 | Matsushita Electric Ind Co Ltd | 酸化触媒体 |
| CH653917A5 (de) | 1982-04-07 | 1986-01-31 | Alusuisse | Katalysatortraeger und seine verwendung. |
| DE3513726A1 (de) | 1985-04-17 | 1986-10-23 | Basf Ag, 6700 Ludwigshafen | Verfahren zur herstellung von katalysatoren fuer die abgasentgiftung |
| DE3533573A1 (de) | 1985-09-20 | 1987-03-26 | Basf Ag | Traegerkatalysator, verfahren zu seiner herstellung und seine verwendung |
| CN1048892A (zh) | 1989-05-24 | 1991-01-30 | 奥本大学 | 混合纤维复合材料结构及其制法和用途 |
| US5080963A (en) | 1989-05-24 | 1992-01-14 | Auburn University | Mixed fiber composite structures high surface area-high conductivity mixtures |
| US5102745A (en) * | 1989-11-13 | 1992-04-07 | Auburn University | Mixed fiber composite structures |
| US5118868A (en) * | 1989-10-16 | 1992-06-02 | Haldor Topsoe A/S | Catalyst for preparing aldehyde |
| US5096663A (en) | 1990-05-29 | 1992-03-17 | Auburn University | Method of optimizing composite preparation for electrical properties: maximum capacitance electrodes |
| US20020068026A1 (en) * | 1997-08-08 | 2002-06-06 | Lawrence L. Murrell | Reactor |
-
1999
- 1999-09-29 US US09/407,436 patent/US6417376B1/en not_active Expired - Lifetime
- 1999-10-07 WO PCT/US1999/023347 patent/WO2000021944A2/en not_active Ceased
- 1999-10-07 AU AU12010/00A patent/AU760603B2/en not_active Ceased
- 1999-10-07 EP EP99970388A patent/EP1119410B1/en not_active Expired - Lifetime
- 1999-10-07 ID IDW00200101026A patent/ID29043A/id unknown
- 1999-10-07 BR BR9914121-3A patent/BR9914121A/pt not_active IP Right Cessation
- 1999-10-07 AT AT99970388T patent/ATE314145T1/de not_active IP Right Cessation
- 1999-10-07 JP JP2000575850A patent/JP5153034B2/ja not_active Expired - Lifetime
- 1999-10-07 DE DE69929222T patent/DE69929222T2/de not_active Expired - Lifetime
- 1999-10-07 ES ES99970388T patent/ES2257100T3/es not_active Expired - Lifetime
- 1999-10-07 MX MXPA01003318 patent/MXPA01003318A/es unknown
- 1999-10-07 KR KR20017004479A patent/KR100611443B1/ko not_active Expired - Fee Related
- 1999-10-07 CN CNB998118486A patent/CN1332764C/zh not_active Expired - Lifetime
- 1999-10-08 AR ARP990105110A patent/AR020759A1/es active IP Right Grant
- 1999-10-08 MY MYPI99004362A patent/MY119687A/en unknown
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP3248560B2 (ja) | 気相酸化反応用担持触媒 | |
| JP5377851B2 (ja) | 不飽和炭化水素製造のためのナノカーボン構造含有触媒 | |
| KR100374692B1 (ko) | 은촉매제조방법 | |
| JP5118628B2 (ja) | 触媒コーティングした担体、その生産方法、それを含む反応器、およびその使用 | |
| US5532199A (en) | Carrier-supported catalyst for the synthesis of unsaturated aldehydes and unsaturated carboxylic acids and process for preparing the same | |
| US4077984A (en) | Manufacture of phthalic anhydride from o-xylene or naphthalene | |
| JPS63253080A (ja) | 無水フタル酸の製造方法 | |
| CN1859973B (zh) | 通过在流化床装置中涂覆载体材料生产气相氧化催化剂的方法 | |
| JP3757111B2 (ja) | 担体触媒 | |
| JP2009537314A (ja) | 特に無水フタル酸を製造するための二酸化チタンを含有した触媒の適用ならびにそれを使用するプロセス | |
| JPS5927614B2 (ja) | バナジウム及びチタンを含有する担持触媒 | |
| EP0574895A1 (en) | Carrier-supported catalyst for the synthesis of unsaturated aldehydes and unsaturated carboxylic acids, and process for preparing the same | |
| JP5153034B2 (ja) | 選択的酸化プロセスとその触媒 | |
| JP2003522111A5 (enExample) | ||
| JPS62168547A (ja) | 銀触媒及びそれの製造方法 | |
| US6344568B1 (en) | Catalyst for gas phase partial oxidation | |
| KR101869683B1 (ko) | 프탈산 무수물을 제조하기 위한 최적 간극량을 갖는 촉매 배열체 | |
| TWI247005B (en) | Selective oxidation process and composition therefor | |
| EP0756519A1 (en) | Process for preparing an oxidation catalyst and use thereof | |
| US5252752A (en) | Process for the production of carboxylic anhydrides | |
| JP4263815B2 (ja) | 芳香族化合物の気相酸化用触媒 | |
| JP2005349393A (ja) | オルソキシレンおよび／またはナフタレンから無水フタル酸を製造する気相酸化用触媒、その調製方法、およびその触媒を用いた気相酸化方法 | |
| JP2001062303A5 (enExample) | ||
| JPS63255274A (ja) | 無水フタル酸の製造方法 | |
| JPH0218900B2 (enExample) |