JP2003514036A - 低結晶度の弗化ビニリデンヘキサフルオルプロピレン共重合体 - Google Patents
低結晶度の弗化ビニリデンヘキサフルオルプロピレン共重合体Info
- Publication number
- JP2003514036A JP2003514036A JP2001535424A JP2001535424A JP2003514036A JP 2003514036 A JP2003514036 A JP 2003514036A JP 2001535424 A JP2001535424 A JP 2001535424A JP 2001535424 A JP2001535424 A JP 2001535424A JP 2003514036 A JP2003514036 A JP 2003514036A
- Authority
- JP
- Japan
- Prior art keywords
- hfp
- weight
- vinylidene fluoride
- hexafluoropropylene
- content
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229920001577 copolymer Polymers 0.000 title claims abstract description 77
- BQCIDUSAKPWEOX-UHFFFAOYSA-N 1,1-Difluoroethene Chemical compound FC(F)=C BQCIDUSAKPWEOX-UHFFFAOYSA-N 0.000 claims abstract description 41
- 238000000034 method Methods 0.000 claims abstract description 29
- HCDGVLDPFQMKDK-UHFFFAOYSA-N hexafluoropropylene Chemical group FC(F)=C(F)C(F)(F)F HCDGVLDPFQMKDK-UHFFFAOYSA-N 0.000 claims abstract description 24
- 238000006243 chemical reaction Methods 0.000 claims description 23
- 238000002844 melting Methods 0.000 claims description 19
- 230000008018 melting Effects 0.000 claims description 19
- 238000006116 polymerization reaction Methods 0.000 claims description 17
- 239000003999 initiator Substances 0.000 claims description 15
- 239000004094 surface-active agent Substances 0.000 claims description 9
- 239000007787 solid Substances 0.000 claims description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 3
- 230000001804 emulsifying effect Effects 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 abstract description 5
- 229920000642 polymer Polymers 0.000 description 34
- 239000000203 mixture Substances 0.000 description 29
- 239000000178 monomer Substances 0.000 description 24
- 239000000523 sample Substances 0.000 description 17
- 239000011347 resin Substances 0.000 description 12
- 229920005989 resin Polymers 0.000 description 12
- 229920001169 thermoplastic Polymers 0.000 description 10
- -1 alkali metal salt Chemical class 0.000 description 8
- 239000004416 thermosoftening plastic Substances 0.000 description 8
- 239000012986 chain transfer agent Substances 0.000 description 7
- 238000000576 coating method Methods 0.000 description 7
- 239000004816 latex Substances 0.000 description 6
- 229920000126 latex Polymers 0.000 description 6
- 230000008569 process Effects 0.000 description 6
- 239000011248 coating agent Substances 0.000 description 5
- 239000013078 crystal Substances 0.000 description 5
- 229910052731 fluorine Inorganic materials 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- 239000002904 solvent Substances 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- IAZDPXIOMUYVGZ-WFGJKAKNSA-N Dimethyl sulfoxide Chemical compound [2H]C([2H])([2H])S(=O)C([2H])([2H])[2H] IAZDPXIOMUYVGZ-WFGJKAKNSA-N 0.000 description 4
- 229920006370 Kynar Polymers 0.000 description 4
- 238000005481 NMR spectroscopy Methods 0.000 description 4
- 239000002253 acid Substances 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 125000002573 ethenylidene group Chemical group [*]=C=C([H])[H] 0.000 description 4
- 238000002474 experimental method Methods 0.000 description 4
- 229920002313 fluoropolymer Polymers 0.000 description 4
- 239000004811 fluoropolymer Substances 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 150000002978 peroxides Chemical class 0.000 description 4
- 230000009467 reduction Effects 0.000 description 4
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- 229910052783 alkali metal Inorganic materials 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 230000015271 coagulation Effects 0.000 description 3
- 238000005345 coagulation Methods 0.000 description 3
- 238000007334 copolymerization reaction Methods 0.000 description 3
- 230000007423 decrease Effects 0.000 description 3
- 238000007720 emulsion polymerization reaction Methods 0.000 description 3
- 239000011737 fluorine Substances 0.000 description 3
- 230000033001 locomotion Effects 0.000 description 3
- 238000000465 moulding Methods 0.000 description 3
- 229920000058 polyacrylate Polymers 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 238000003786 synthesis reaction Methods 0.000 description 3
- 238000010189 synthetic method Methods 0.000 description 3
- 238000012546 transfer Methods 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- CSCPPACGZOOCGX-WFGJKAKNSA-N acetone d6 Chemical compound [2H]C([2H])([2H])C(=O)C([2H])([2H])[2H] CSCPPACGZOOCGX-WFGJKAKNSA-N 0.000 description 2
- 150000003863 ammonium salts Chemical class 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- 239000002585 base Substances 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 239000003638 chemical reducing agent Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 239000008367 deionised water Substances 0.000 description 2
- 229910021641 deionized water Inorganic materials 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- 125000001153 fluoro group Chemical group F* 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 150000002576 ketones Chemical class 0.000 description 2
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 2
- 229910052753 mercury Inorganic materials 0.000 description 2
- 230000003287 optical effect Effects 0.000 description 2
- 150000001451 organic peroxides Chemical class 0.000 description 2
- 239000007800 oxidant agent Substances 0.000 description 2
- 239000003973 paint Substances 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 125000005634 peroxydicarbonate group Chemical group 0.000 description 2
- JRKICGRDRMAZLK-UHFFFAOYSA-L peroxydisulfate Chemical class [O-]S(=O)(=O)OOS([O-])(=O)=O JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- BWJUFXUULUEGMA-UHFFFAOYSA-N propan-2-yl propan-2-yloxycarbonyloxy carbonate Chemical compound CC(C)OC(=O)OOC(=O)OC(C)C BWJUFXUULUEGMA-UHFFFAOYSA-N 0.000 description 2
- 125000001453 quaternary ammonium group Chemical group 0.000 description 2
- 230000002441 reversible effect Effects 0.000 description 2
- 238000001228 spectrum Methods 0.000 description 2
- 238000010561 standard procedure Methods 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- BEQKKZICTDFVMG-UHFFFAOYSA-N 1,2,3,4,6-pentaoxepane-5,7-dione Chemical compound O=C1OOOOC(=O)O1 BEQKKZICTDFVMG-UHFFFAOYSA-N 0.000 description 1
- OHMHBGPWCHTMQE-UHFFFAOYSA-N 2,2-dichloro-1,1,1-trifluoroethane Chemical compound FC(F)(F)C(Cl)Cl OHMHBGPWCHTMQE-UHFFFAOYSA-N 0.000 description 1
- ZACVGCNKGYYQHA-UHFFFAOYSA-N 2-ethylhexoxycarbonyloxy 2-ethylhexyl carbonate Chemical compound CCCCC(CC)COC(=O)OOC(=O)OCC(CC)CCCC ZACVGCNKGYYQHA-UHFFFAOYSA-N 0.000 description 1
- AQKYLAIZOGOPAW-UHFFFAOYSA-N 2-methylbutan-2-yl 2,2-dimethylpropaneperoxoate Chemical compound CCC(C)(C)OOC(=O)C(C)(C)C AQKYLAIZOGOPAW-UHFFFAOYSA-N 0.000 description 1
- FRIBMENBGGCKPD-UHFFFAOYSA-N 3-(2,3-dimethoxyphenyl)prop-2-enal Chemical compound COC1=CC=CC(C=CC=O)=C1OC FRIBMENBGGCKPD-UHFFFAOYSA-N 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- 239000004925 Acrylic resin Substances 0.000 description 1
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Natural products OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical class [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
- 238000004566 IR spectroscopy Methods 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 239000004721 Polyphenylene oxide Chemical class 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- 239000008186 active pharmaceutical agent Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 150000003973 alkyl amines Chemical class 0.000 description 1
- 150000001346 alkyl aryl ethers Chemical class 0.000 description 1
- 125000005599 alkyl carboxylate group Chemical group 0.000 description 1
- 229940045714 alkyl sulfonate alkylating agent Drugs 0.000 description 1
- 150000008052 alkyl sulfonates Chemical class 0.000 description 1
- 239000002519 antifouling agent Substances 0.000 description 1
- 229960005070 ascorbic acid Drugs 0.000 description 1
- 235000010323 ascorbic acid Nutrition 0.000 description 1
- 239000011668 ascorbic acid Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 244000309464 bull Species 0.000 description 1
- NSGQRLUGQNBHLD-UHFFFAOYSA-N butan-2-yl butan-2-yloxycarbonyloxy carbonate Chemical compound CCC(C)OC(=O)OOC(=O)OC(C)CC NSGQRLUGQNBHLD-UHFFFAOYSA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 150000007942 carboxylates Chemical class 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 150000008280 chlorinated hydrocarbons Chemical class 0.000 description 1
- UUAGAQFQZIEFAH-UHFFFAOYSA-N chlorotrifluoroethylene Chemical group FC(F)=C(F)Cl UUAGAQFQZIEFAH-UHFFFAOYSA-N 0.000 description 1
- 230000001276 controlling effect Effects 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 230000002596 correlated effect Effects 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 230000001934 delay Effects 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 description 1
- 238000000113 differential scanning calorimetry Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 239000008393 encapsulating agent Substances 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 229920001973 fluoroelastomer Polymers 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 230000008014 freezing Effects 0.000 description 1
- 238000007710 freezing Methods 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 230000009477 glass transition Effects 0.000 description 1
- 150000008282 halocarbons Chemical class 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- TYQCGQRIZGCHNB-JLAZNSOCSA-N l-ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(O)=C(O)C1=O TYQCGQRIZGCHNB-JLAZNSOCSA-N 0.000 description 1
- 238000009533 lab test Methods 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 238000011020 pilot scale process Methods 0.000 description 1
- 229920001490 poly(butyl methacrylate) polymer Polymers 0.000 description 1
- 229920001483 poly(ethyl methacrylate) polymer Polymers 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 229920000570 polyether Chemical class 0.000 description 1
- 229920006254 polymer film Polymers 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 229920000193 polymethacrylate Polymers 0.000 description 1
- 239000004926 polymethyl methacrylate Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- YPVDWEHVCUBACK-UHFFFAOYSA-N propoxycarbonyloxy propyl carbonate Chemical compound CCCOC(=O)OOC(=O)OCCC YPVDWEHVCUBACK-UHFFFAOYSA-N 0.000 description 1
- 238000010926 purge Methods 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- XWGJFPHUCFXLBL-UHFFFAOYSA-M rongalite Chemical compound [Na+].OCS([O-])=O XWGJFPHUCFXLBL-UHFFFAOYSA-M 0.000 description 1
- 229930195734 saturated hydrocarbon Natural products 0.000 description 1
- 229920006126 semicrystalline polymer Polymers 0.000 description 1
- 238000010008 shearing Methods 0.000 description 1
- 238000007614 solvation Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
- 229920001897 terpolymer Polymers 0.000 description 1
- OPQYOFWUFGEMRZ-UHFFFAOYSA-N tert-butyl 2,2-dimethylpropaneperoxoate Chemical compound CC(C)(C)OOC(=O)C(C)(C)C OPQYOFWUFGEMRZ-UHFFFAOYSA-N 0.000 description 1
- CIHOLLKRGTVIJN-UHFFFAOYSA-N tert‐butyl hydroperoxide Chemical compound CC(C)(C)OO CIHOLLKRGTVIJN-UHFFFAOYSA-N 0.000 description 1
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- CYRMSUTZVYGINF-UHFFFAOYSA-N trichlorofluoromethane Chemical compound FC(Cl)(Cl)Cl CYRMSUTZVYGINF-UHFFFAOYSA-N 0.000 description 1
- 229940029284 trichlorofluoromethane Drugs 0.000 description 1
- 238000009827 uniform distribution Methods 0.000 description 1
- 229930195735 unsaturated hydrocarbon Natural products 0.000 description 1
- 239000002966 varnish Substances 0.000 description 1
- 229920001567 vinyl ester resin Polymers 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920005609 vinylidenefluoride/hexafluoropropylene copolymer Polymers 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F214/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
- C08F214/18—Monomers containing fluorine
- C08F214/28—Hexyfluoropropene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F214/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
- C08F214/18—Monomers containing fluorine
- C08F214/22—Vinylidene fluoride
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerisation Methods In General (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US16322999P | 1999-11-03 | 1999-11-03 | |
| US60/163,229 | 1999-11-03 | ||
| PCT/US2000/030449 WO2001032726A1 (en) | 1999-11-03 | 2000-11-03 | Low crystallinity vinylidene fluoride hexafluoropropylene copolymers |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2012005401A Division JP2012067324A (ja) | 1999-11-03 | 2012-01-13 | 低結晶度の弗化ビニリデンヘキサフルオルプロピレン共重合体 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2003514036A true JP2003514036A (ja) | 2003-04-15 |
| JP2003514036A5 JP2003514036A5 (https=) | 2007-12-20 |
Family
ID=22589039
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2001535424A Pending JP2003514036A (ja) | 1999-11-03 | 2000-11-03 | 低結晶度の弗化ビニリデンヘキサフルオルプロピレン共重合体 |
| JP2012005401A Pending JP2012067324A (ja) | 1999-11-03 | 2012-01-13 | 低結晶度の弗化ビニリデンヘキサフルオルプロピレン共重合体 |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2012005401A Pending JP2012067324A (ja) | 1999-11-03 | 2012-01-13 | 低結晶度の弗化ビニリデンヘキサフルオルプロピレン共重合体 |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US6586547B1 (https=) |
| EP (1) | EP1144469B1 (https=) |
| JP (2) | JP2003514036A (https=) |
| CN (1) | CN1189489C (https=) |
| DE (1) | DE60045408D1 (https=) |
| MX (1) | MXPA01006827A (https=) |
| RU (1) | RU2256669C2 (https=) |
| WO (1) | WO2001032726A1 (https=) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2005314699A (ja) * | 2004-04-27 | 2005-11-10 | Arkema Inc | アルキルスルホン酸塩界面活性剤を使用したフルオロポリマーの製造方法 |
| JP2014508209A (ja) * | 2011-03-16 | 2014-04-03 | アーケマ・インコーポレイテッド | 高融点フルオロポリマー |
| JP2014517128A (ja) * | 2011-06-21 | 2014-07-17 | ソルベイ スペシャルティ ポリマーズ イタリー エス．ピー．エー． | フッ化ビニリデンを重合させる方法 |
| WO2019230075A1 (ja) | 2018-05-31 | 2019-12-05 | 株式会社クレハ | 非水電解質二次電池用樹脂組成物、ならびにこれを用いた非水電解質二次電池用セパレータ、電極合剤層用樹脂組成物、非水電解質二次電池用電極、および非水電解質二次電池 |
Families Citing this family (30)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4049321B2 (ja) * | 2001-11-21 | 2008-02-20 | 日立粉末冶金株式会社 | 燃料電池セパレーター用塗料 |
| EP1479702A1 (fr) * | 2003-05-19 | 2004-11-24 | Atofina | Polymères à base de chlorotrifluoroéthylène/carbonate de vinylène/hexafluoropropène ou tétrafluoroéthylène/carbonate de vinylène/hexafluoropropène |
| BRPI0617248B1 (pt) * | 2005-10-11 | 2020-11-17 | Westrock Dispensing Systems, Inc | produto de fragância |
| US7722819B2 (en) * | 2005-10-11 | 2010-05-25 | Meadwestvaco Calmar, Inc. | Fragrance product, dispenser, and dispenser assembly |
| US20070100099A1 (en) * | 2005-10-28 | 2007-05-03 | Ming-Hong Hung | Copolymers of vinylidene fluoride and vinyl esters |
| EP2054474B2 (en) * | 2006-07-06 | 2016-01-13 | Arkema Inc. | Ultra-high molecular weight poly(vinylidene fluoride) |
| FR2904828B1 (fr) * | 2006-08-08 | 2008-09-19 | Arkema France | Copolymere de fluorure de vinylidene fonctionnalise par greffage par irradiation par un monomere polaire insature |
| FR2918067B1 (fr) * | 2007-06-27 | 2011-07-01 | Arkema France | Materiau composite comprenant des nanotubes disperses dans une matrice polymerique fluroree. |
| WO2009069320A1 (ja) * | 2007-11-28 | 2009-06-04 | Unimatec Co., Ltd. | フルオロエラストマーの製造法 |
| CN101851314B (zh) * | 2009-04-02 | 2014-01-29 | 中化蓝天集团有限公司 | 一种用作锂离子电池隔膜的vdf-hfp共聚物的制备方法 |
| EP2686354A4 (en) | 2011-03-16 | 2014-10-15 | Arkema Inc | SYNTHESIS 2,3,3,3-TETRAFLUORPROPHIC FLUOROPOLYMERS |
| KR101552772B1 (ko) * | 2012-12-06 | 2015-09-11 | 주식회사 엘지화학 | 백시트 |
| CN105026443B (zh) * | 2013-03-15 | 2017-10-31 | 阿科玛股份有限公司 | 氟聚合物 |
| FR3010082A1 (fr) | 2013-09-02 | 2015-03-06 | Arkema France | Procede de preparation d'une composition de polymeres fluores reticules |
| FR3010089B1 (fr) | 2013-09-02 | 2015-08-14 | Arkema France | Composition de polymeres fluores thermoplastiques pour les tubes off-shore |
| CN106659985B (zh) * | 2014-07-22 | 2021-06-15 | 阿科玛股份有限公司 | 基于偏二氟乙烯聚合物的高韧性中空纤维膜 |
| US10774233B2 (en) | 2015-11-25 | 2020-09-15 | Arkema Inc. | Fluoropolymer compositions with improved mechanical dampening |
| FR3055472B1 (fr) * | 2016-08-29 | 2019-03-15 | Arkema France | Protection de dispositifs electroniques |
| FR3067032B1 (fr) * | 2017-06-06 | 2021-10-01 | Arkema France | Elastomere de fluoropolymere thermoplastique |
| FR3067716B1 (fr) | 2017-06-15 | 2020-05-15 | Arkema France | Encre a base de polymere fluore et d'un compose silane |
| FR3067715B1 (fr) | 2017-06-15 | 2019-07-05 | Arkema France | Encre a base de polymere fluore presentant une adhesion amelioree |
| JP7389015B2 (ja) | 2017-07-14 | 2023-11-29 | アーケマ・インコーポレイテッド | 高強度ポリフッ化ビニリデン系サイジング強化繊維 |
| CN112512804B (zh) * | 2018-07-25 | 2023-06-27 | 阿科玛股份有限公司 | 交联的热塑性聚偏二氟乙烯组合物 |
| JP2022512330A (ja) | 2018-12-06 | 2022-02-03 | アーケマ・インコーポレイテッド | フッ素－熱可塑性エラストマーブレンド |
| CN114395094B (zh) * | 2021-12-24 | 2023-12-19 | 乳源东阳光氟树脂有限公司 | 一种有机无机复合pvdf树脂乳液、涂膜液及其制备方法 |
| EP4545574A4 (en) * | 2023-01-13 | 2025-12-31 | Contemporary Amperex Technology Hong Kong Ltd | POLYMER, ELECTRODE SHEET AND BATTERY ELEMENT, BATTERY AND ASSOCIATED ELECTRICAL DEVICE |
| EP4458869A1 (en) * | 2023-05-03 | 2024-11-06 | Arkema, Inc. | Process for the production of polyvinylidene fluoride copolymers |
| FR3157870A1 (fr) | 2023-12-31 | 2025-07-04 | Arkema France | Utilisation d’un polymère comme primaire d’adhérence entre un polymère fluoré et un substrat, procédés de fabrication de revêtements, substrats revêtus et dispositifs les comprenant |
| FR3157871A1 (fr) | 2023-12-31 | 2025-07-04 | Arkema France | Utilisation d’une composition réactive comme précurseur de primaire d’adhérence entre un polymère fluoré et un substrat, procédés de fabrication de revêtements, substrats revêtus et dispositifs les comprenant |
| FR3157869A1 (fr) | 2023-12-31 | 2025-07-04 | Arkema France | Composition de polymère(s) fluoré(s) à adhérence améliorée |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0718002A (ja) * | 1993-07-02 | 1995-01-20 | Asahi Glass Co Ltd | 含フッ素共重合体の製造方法 |
| JPH07216263A (ja) * | 1993-12-23 | 1995-08-15 | Fina Res Sa | 高光沢のフツ素化コーテイングを製造するための方法 |
| WO1996017876A1 (en) * | 1994-12-06 | 1996-06-13 | Daikin Industries, Ltd. | Elastic fluorocopolymer excellent in processability in molding, process for the preparation thereof, and vulcanizable composition excellent in processability in molding |
| JPH10130447A (ja) * | 1996-10-25 | 1998-05-19 | Ausimont Spa | イオン硬化性フルオロエラストマーコポリマー及びそれから得られるｏリング |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4569978A (en) * | 1984-07-25 | 1986-02-11 | Pennwalt Corporation | Emulsion polymerization of vinylidene fluoride polymers in the presence of trichlorofluoromethane as chain transfer agent |
| US5093427A (en) * | 1990-05-10 | 1992-03-03 | Atochem North America, Inc. | Copolymers of vinylidene fluoride and hexafluoropropylene and process for preparing the same |
| US5429891A (en) * | 1993-03-05 | 1995-07-04 | Bell Communications Research, Inc. | Crosslinked hybrid electrolyte film and methods of making and using the same |
| IT1271622B (it) * | 1994-03-21 | 1997-06-04 | Ausimont Spa | Processo di (co) polimerizzazione in sospensione per la preparazione ddi fluoropolimeri termoplastici contenenti idrogeno |
| US5478905A (en) | 1995-02-06 | 1995-12-26 | E. I. Du Pont De Nemours And Company | Amorphous tetrafluoroethylene/hexafluoropropylene copolymers |
| CN1217727A (zh) * | 1997-02-28 | 1999-05-26 | 北美埃尔夫爱托化学股份有限公司 | 可萃取量减少、溶液透明性改善的偏氟乙烯和六氟丙烯共聚物 |
| US6403740B1 (en) * | 1997-04-15 | 2002-06-11 | E. I. Du Pont De Nemours And Company | Vinyl fluoride interpolymers |
-
2000
- 2000-11-03 RU RU2001121682/04A patent/RU2256669C2/ru not_active IP Right Cessation
- 2000-11-03 US US09/869,449 patent/US6586547B1/en not_active Expired - Lifetime
- 2000-11-03 WO PCT/US2000/030449 patent/WO2001032726A1/en not_active Ceased
- 2000-11-03 DE DE60045408T patent/DE60045408D1/de not_active Expired - Lifetime
- 2000-11-03 CN CNB008023573A patent/CN1189489C/zh not_active Expired - Lifetime
- 2000-11-03 MX MXPA01006827A patent/MXPA01006827A/es unknown
- 2000-11-03 JP JP2001535424A patent/JP2003514036A/ja active Pending
- 2000-11-03 EP EP00976943A patent/EP1144469B1/en not_active Expired - Lifetime
-
2012
- 2012-01-13 JP JP2012005401A patent/JP2012067324A/ja active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0718002A (ja) * | 1993-07-02 | 1995-01-20 | Asahi Glass Co Ltd | 含フッ素共重合体の製造方法 |
| JPH07216263A (ja) * | 1993-12-23 | 1995-08-15 | Fina Res Sa | 高光沢のフツ素化コーテイングを製造するための方法 |
| WO1996017876A1 (en) * | 1994-12-06 | 1996-06-13 | Daikin Industries, Ltd. | Elastic fluorocopolymer excellent in processability in molding, process for the preparation thereof, and vulcanizable composition excellent in processability in molding |
| JPH10130447A (ja) * | 1996-10-25 | 1998-05-19 | Ausimont Spa | イオン硬化性フルオロエラストマーコポリマー及びそれから得られるｏリング |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2005314699A (ja) * | 2004-04-27 | 2005-11-10 | Arkema Inc | アルキルスルホン酸塩界面活性剤を使用したフルオロポリマーの製造方法 |
| JP2014508209A (ja) * | 2011-03-16 | 2014-04-03 | アーケマ・インコーポレイテッド | 高融点フルオロポリマー |
| JP2014517128A (ja) * | 2011-06-21 | 2014-07-17 | ソルベイ スペシャルティ ポリマーズ イタリー エス．ピー．エー． | フッ化ビニリデンを重合させる方法 |
| WO2019230075A1 (ja) | 2018-05-31 | 2019-12-05 | 株式会社クレハ | 非水電解質二次電池用樹脂組成物、ならびにこれを用いた非水電解質二次電池用セパレータ、電極合剤層用樹脂組成物、非水電解質二次電池用電極、および非水電解質二次電池 |
| KR20200142097A (ko) | 2018-05-31 | 2020-12-21 | 가부시끼가이샤 구레하 | 비수 전해질 이차전지용 수지 조성물 및 이를 이용한 비수 전해질 이차전지용 세퍼레이터, 전극 합제층용 수지 조성물, 비수 전해질 이차전지용 전극, 및 비수 전해질 이차전지 |
| US11380935B2 (en) | 2018-05-31 | 2022-07-05 | Kureha Corporation | Resin composition for nonaqueous electrolyte secondary battery, separator for nonaqueous electrolyte secondary battery using same, resin composition for electrode mixture layer, electrode for nonaqueous electrolyte secondary battery, and nonaqueous electrolyte secondary battery |
Also Published As
| Publication number | Publication date |
|---|---|
| EP1144469B1 (en) | 2010-12-22 |
| RU2256669C2 (ru) | 2005-07-20 |
| WO2001032726A1 (en) | 2001-05-10 |
| DE60045408D1 (de) | 2011-02-03 |
| EP1144469A4 (en) | 2005-02-09 |
| MXPA01006827A (es) | 2004-08-19 |
| EP1144469A1 (en) | 2001-10-17 |
| JP2012067324A (ja) | 2012-04-05 |
| US6586547B1 (en) | 2003-07-01 |
| CN1189489C (zh) | 2005-02-16 |
| CN1327455A (zh) | 2001-12-19 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP2003514036A (ja) | 低結晶度の弗化ビニリデンヘキサフルオルプロピレン共重合体 | |
| JP7719404B2 (ja) | フルオロポリマーの製造方法、ポリテトラフルオロエチレンの製造方法、パーフルオロエラストマーの製造方法および組成物 | |
| US5932673A (en) | Tetrafluoroethylene copolymer | |
| US6187885B1 (en) | Copolymers of vinylidene fluoride and hexafluoropropylene and process for preparing the same | |
| JP6124807B2 (ja) | 高融点フルオロポリマー | |
| EP3039073B1 (en) | Fluoropolymer blend | |
| EP2297213B1 (en) | Novel vinylidene fluoride copolymers | |
| US20110040021A1 (en) | Methods for melt-processing thermoplastic fluoropolymers | |
| US9029477B2 (en) | Compositions comprising melt-processable thermoplastic fluoropolymers and methods of making the same | |
| EP0759446B1 (en) | Tetrafluoroethylene terpolymer | |
| JPH07304809A (ja) | 水素含有熱可塑性フッ化ポリマーの製造のための懸濁重合方法 | |
| US9493595B2 (en) | Vinylidene fluoride copolymers | |
| US7700700B2 (en) | Vinylidene fluoride copolymer composition with improved low-temperature impact properties | |
| JPS5950163B2 (ja) | エチレン−四弗化エチレン系共重合体及びその製法 | |
| US8557938B2 (en) | Branched fluoropolymers | |
| JPH09202814A (ja) | テトラフルオロエチレンおよびヘキサフルオロプロピレンの共重合体の重合方法 | |
| JP2002012626A (ja) | 含フッ素共重合体及び成形体 | |
| CN118159572A (zh) | 低温制备含氟聚合物 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20071101 |
|
| A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20071101 |
|
| A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20101117 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20110118 |
|
| A601 | Written request for extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A601 Effective date: 20110418 |
|
| RD02 | Notification of acceptance of power of attorney |
Free format text: JAPANESE INTERMEDIATE CODE: A7422 Effective date: 20110418 |
|
| A602 | Written permission of extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A602 Effective date: 20110425 |
|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20110518 |
|
| A02 | Decision of refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A02 Effective date: 20110913 |