JP2003507581A - 水溶液からのアルカリ金属の電気化学的製造 - Google Patents

水溶液からのアルカリ金属の電気化学的製造

Info

Publication number
JP2003507581A
JP2003507581A JP2001518481A JP2001518481A JP2003507581A JP 2003507581 A JP2003507581 A JP 2003507581A JP 2001518481 A JP2001518481 A JP 2001518481A JP 2001518481 A JP2001518481 A JP 2001518481A JP 2003507581 A JP2003507581 A JP 2003507581A
Authority
JP
Japan
Prior art keywords
alkali metal
salt
mixture
lithium
metal salt
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
JP2001518481A
Other languages
English (en)
Japanese (ja)
Other versions
JP2003507581A5 (enExample
Inventor
ピュター，ヘルマン
フーバー，ギュンター
シールレ−アルント，ケルスティン
シュレファー，ディーター
グート，ヨーゼフ
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE filed Critical BASF SE
Publication of JP2003507581A publication Critical patent/JP2003507581A/ja
Publication of JP2003507581A5 publication Critical patent/JP2003507581A5/ja
Withdrawn legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
    • C25C1/00—Electrolytic production, recovery or refining of metals by electrolysis of solutions
    • C25C1/02—Electrolytic production, recovery or refining of metals by electrolysis of solutions of light metals
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Electrolytic Production Of Metals (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
JP2001518481A 1999-08-24 2000-08-24 水溶液からのアルカリ金属の電気化学的製造 Withdrawn JP2003507581A (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE19940069A DE19940069A1 (de) 1999-08-24 1999-08-24 Verfahren zur elektrochemischen Herstellung eines Alkalimetalls aus wäßriger Lösung
DE19940069.5 1999-08-24
PCT/EP2000/008278 WO2001014616A1 (de) 1999-08-24 2000-08-24 Verfahren zur elektrochemischen herstellung eines alkalimetalls aus wässriger lösung

Publications (2)

Publication Number Publication Date
JP2003507581A true JP2003507581A (ja) 2003-02-25
JP2003507581A5 JP2003507581A5 (enExample) 2007-07-12

Family

ID=7919400

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2001518481A Withdrawn JP2003507581A (ja) 1999-08-24 2000-08-24 水溶液からのアルカリ金属の電気化学的製造

Country Status (9)

Country Link
US (1) US6770187B1 (enExample)
EP (1) EP1210471B1 (enExample)
JP (1) JP2003507581A (enExample)
CN (1) CN1284884C (enExample)
AT (1) ATE346179T1 (enExample)
DE (2) DE19940069A1 (enExample)
RU (1) RU2253703C2 (enExample)
TW (1) TWI229148B (enExample)
WO (1) WO2001014616A1 (enExample)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2010013673A (ja) * 2008-07-01 2010-01-21 Hokkaido Univ アルカリ金属の製造方法およびアルカリ金属製造装置
KR101669890B1 (ko) * 2015-10-01 2016-10-27 재단법인 포항산업과학연구원 리튬 회수 장치 및 이를 이용한 리튬 회수 방법
JP2017528603A (ja) * 2013-07-10 2017-09-28 クリーン リチウム コーポレーション リチウムの生成

Families Citing this family (87)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20070221265A1 (en) 2006-03-22 2007-09-27 Sion Power Corporation Rechargeable lithium/water, lithium/air batteries
US7247408B2 (en) * 1999-11-23 2007-07-24 Sion Power Corporation Lithium anodes for electrochemical cells
US20110165471A9 (en) * 1999-11-23 2011-07-07 Sion Power Corporation Protection of anodes for electrochemical cells
EP1312700A3 (de) * 2001-11-02 2003-05-28 Degussa AG Verfahren zur Herstellung von Alkalialkoholaten
BR0315274B1 (pt) * 2002-10-15 2012-04-03 componente de dispositivo eletroquìmico, separador de bateria de compósito protetor, método para fabricar um componente de dispositivo eletroquìmico, célula de bateria, e, método para produzir a mesma.
US7645543B2 (en) 2002-10-15 2010-01-12 Polyplus Battery Company Active metal/aqueous electrochemical cells and systems
US20080057386A1 (en) 2002-10-15 2008-03-06 Polyplus Battery Company Ionically conductive membranes for protection of active metal anodes and battery cells
US7282302B2 (en) * 2002-10-15 2007-10-16 Polyplus Battery Company Ionically conductive composites for protection of active metal anodes
US7608178B2 (en) * 2003-11-10 2009-10-27 Polyplus Battery Company Active metal electrolyzer
US7491458B2 (en) 2003-11-10 2009-02-17 Polyplus Battery Company Active metal fuel cells
US7824536B2 (en) * 2003-12-11 2010-11-02 Ceramatec, Inc. Electrolytic method to make alkali alcoholates using ceramic ion conducting solid membranes
EP1702089A2 (en) * 2003-12-11 2006-09-20 American Pacific Corporation Electrolytic method to make alkali alcoholates using ceramic ion conducting solid membranes
US20080173551A1 (en) * 2003-12-11 2008-07-24 Joshi Ashok V Electrolytic Method to Make Alkali Alcoholates
US8075758B2 (en) * 2003-12-11 2011-12-13 Ceramatec, Inc. Electrolytic method to make alkali alcoholates using ion conducting alkali electrolyte/separator
US20080173540A1 (en) * 2003-12-11 2008-07-24 Joshi Ashok V Electrolytic Cell for Producing Alkali Alcoholates
DE10360758A1 (de) * 2003-12-23 2005-07-28 Degussa Ag Elektrochemische Herstellung von Alkalialkoholaten mit Hilfe einer keramischen Festelektrolytmembran
US10629947B2 (en) 2008-08-05 2020-04-21 Sion Power Corporation Electrochemical cell
US9368775B2 (en) 2004-02-06 2016-06-14 Polyplus Battery Company Protected lithium electrodes having porous ceramic separators, including an integrated structure of porous and dense Li ion conducting garnet solid electrolyte layers
US7282295B2 (en) 2004-02-06 2007-10-16 Polyplus Battery Company Protected active metal electrode and battery cell structures with non-aqueous interlayer architecture
US20060078790A1 (en) * 2004-10-05 2006-04-13 Polyplus Battery Company Solid electrolytes based on lithium hafnium phosphate for active metal anode protection
EP1809456A1 (en) * 2004-10-13 2007-07-25 E.I.Du pont de nemours and company Anti-stick coating for surfaces
US20060079601A1 (en) * 2004-10-13 2006-04-13 Gullo Mark J Foundry sandcore mold release composition
US20060102491A1 (en) * 2004-11-10 2006-05-18 Kelly Michael T Processes for separating metals from metal salts
WO2007062220A2 (en) 2005-11-23 2007-05-31 Polyplus Battery Company Li/air non-aqueous batteries
WO2007075867A2 (en) 2005-12-19 2007-07-05 Polyplus Battery Company Composite solid electrolyte for protection of active metal anodes
WO2007075865A2 (en) * 2005-12-20 2007-07-05 Ceramatec, Inc. Electrolytic process to produce sodium hypochlorite using sodium ion conductive ceramic membranes
WO2007082092A2 (en) * 2006-01-11 2007-07-19 Ceramatec, Inc. Synthesis of biodiesel using alkali ion conductive ceramic membranes
JP5564260B2 (ja) * 2006-12-04 2014-07-30 シオン・パワー・コーポレーション リチウム電池内における電解質の分離
EP2142277A4 (en) * 2007-04-03 2012-01-04 Ceramatec Inc ELECTROCHEMICAL METHOD FOR RECYCLING AQUEOUS ALKALICHEMICIA USING CERAMIC ION-LEADING SOLID MEMBRANES
JP5627576B2 (ja) 2008-06-16 2014-11-19 ポリプラス バッテリー カンパニーＰｏｌｙＰｌｕｓ Ｂａｔｔｅｒｙ Ｃｏｍｐａｎｙ 水性リチウム−空気バッテリセル
US8728295B2 (en) * 2008-10-09 2014-05-20 Ceramatec, Inc. Apparatus and method for reducing an alkali metal electrochemically at a temperature below the metal's melting temperature
US9475998B2 (en) 2008-10-09 2016-10-25 Ceramatec, Inc. Process for recovering alkali metals and sulfur from alkali metal sulfides and polysulfides
KR101433086B1 (ko) * 2008-11-17 2014-08-25 록우드 리튬 잉크 수용액으로부터 리튬의 회수
US8637428B1 (en) 2009-12-18 2014-01-28 Simbol Inc. Lithium extraction composition and method of preparation thereof
US8741256B1 (en) 2009-04-24 2014-06-03 Simbol Inc. Preparation of lithium carbonate from lithium chloride containing brines
US9034294B1 (en) 2009-04-24 2015-05-19 Simbol, Inc. Preparation of lithium carbonate from lithium chloride containing brines
US9051827B1 (en) 2009-09-02 2015-06-09 Simbol Mining Corporation Selective removal of silica from silica containing brines
US10190030B2 (en) 2009-04-24 2019-01-29 Alger Alternative Energy, Llc Treated geothermal brine compositions with reduced concentrations of silica, iron and lithium
US12168748B2 (en) 2009-04-24 2024-12-17 Terralithium Llc Treated geothermal brine compositions with reduced concentration of silica, iron and lithium
US10683563B2 (en) 2009-06-24 2020-06-16 Terralithium Llc Treated geothermal brine compositions with reduced concentrations of silica, iron and manganese
US10935006B2 (en) 2009-06-24 2021-03-02 Terralithium Llc Process for producing geothermal power, selective removal of silica and iron from brines, and improved injectivity of treated brines
CN102947225A (zh) * 2010-02-17 2013-02-27 辛博尔股份有限公司 高纯碳酸锂和其它高纯含锂化合物的制备方法
JP2013531738A (ja) 2010-06-30 2013-08-08 シー アメンドラ スティーヴン リチウム金属の電解生成
CN103097586B (zh) * 2010-08-12 2015-09-02 浦项产业科学研究院 通过电解从含锂溶液中提取高纯度锂的方法
WO2012048032A2 (en) 2010-10-07 2012-04-12 Ceramatec, Inc. Chemical systems and methods for operating an electrochemical cell with an acidic anolyte
WO2012048280A2 (en) * 2010-10-08 2012-04-12 Ceramatec, Inc. Electrochemical systems and methods for operating electrochemical cell with an acidic anolyte
EP2633092A2 (en) * 2010-10-29 2013-09-04 Ceramatec, Inc Device and method for recovery or extraction of lithium
JP6228915B2 (ja) 2011-06-17 2017-11-08 シオン・パワー・コーポレーション 電極用プレーティング技術
WO2013028574A2 (en) 2011-08-19 2013-02-28 Polyplus Battery Company Aqueous lithium air batteries
CN103031567B (zh) * 2011-10-08 2016-04-20 中国科学院青岛生物能源与过程研究所 一种电解制取金属钠的方法
CN103031568B (zh) * 2011-10-08 2016-04-20 中国科学院青岛生物能源与过程研究所 一种电解制备金属锂的方法
KR101905233B1 (ko) 2011-10-13 2018-10-05 시온 파워 코퍼레이션 전극 구조물 및 그의 제조 방법
US9660265B2 (en) 2011-11-15 2017-05-23 Polyplus Battery Company Lithium sulfur batteries and electrolytes and sulfur cathodes thereof
US8828574B2 (en) 2011-11-15 2014-09-09 Polyplus Battery Company Electrolyte compositions for aqueous electrolyte lithium sulfur batteries
US8828575B2 (en) 2011-11-15 2014-09-09 PolyPlus Batter Company Aqueous electrolyte lithium sulfur batteries
US8828573B2 (en) 2011-11-15 2014-09-09 Polyplus Battery Company Electrode structures for aqueous electrolyte lithium sulfur batteries
US10355305B2 (en) * 2012-01-16 2019-07-16 Enlighten Innovations Inc. Alkali metal intercalation material as an electrode in an electrolytic cell
EP2804967B1 (en) * 2012-01-16 2019-06-19 Enlighten Innovations Inc. Composite alkali ion conductive solid electrolyte
WO2013140574A1 (ja) * 2012-03-22 2013-09-26 株式会社 東芝 固体電解質材料、固体電解質及び電池
CA3118987C (en) 2012-04-23 2023-09-19 Nemaska Lithium Inc. Process for preparing lithium sulphate
US8932771B2 (en) 2012-05-03 2015-01-13 Polyplus Battery Company Cathode architectures for alkali metal / oxygen batteries
AU2013270412C1 (en) 2012-05-30 2017-04-06 Nemaska Lithium Inc. Processes for preparing lithium carbonate
WO2014016247A1 (de) 2012-07-27 2014-01-30 Basf Se Verfahren zur herstellung eines alkalimetalls
US20140076734A1 (en) * 2012-09-19 2014-03-20 Consejo Nacional De Investigaciones Cientificas Y Tecnicas (Conicet) Method and electrochemical device for low environmental impact lithium recovery from aqueous solutions
US9005311B2 (en) 2012-11-02 2015-04-14 Sion Power Corporation Electrode active surface pretreatment
DE102013202976A1 (de) * 2013-02-22 2014-08-28 Siemens Aktiengesellschaft Niedertemperaturverfahren zur Herstellung von Lithium aus schwerlöslichen Lithiumsalzen
US12261284B2 (en) 2013-03-15 2025-03-25 Sion Power Corporation Protective structures for electrodes
EP4424408A3 (en) 2013-03-15 2025-04-09 Nemaska Lithium Inc. Processes for preparing lithium hydroxide
US9905860B2 (en) 2013-06-28 2018-02-27 Polyplus Battery Company Water activated battery system having enhanced start-up behavior
DK3060522T3 (da) 2013-10-23 2019-08-26 Nemaska Lithium Inc Processer til forberedelse af lithiumkarbonat
KR102099714B1 (ko) 2013-10-23 2020-04-13 네마스카 리튬 인코포레이션 리튬 하이드록사이드 제조 공정 및 시스템
EP3805430A1 (en) 2014-02-24 2021-04-14 Nemaska Lithium Inc. Methods for treating lithium-containing materials
US20150267316A1 (en) 2014-03-19 2015-09-24 Sandia Corporation Electrochemical Ion Separation in Molten Salts
JP6770952B2 (ja) 2014-09-09 2020-10-21 シオン・パワー・コーポレーション リチウムイオン電気化学電池における保護層、並びに関連する電極および方法
JP6964003B2 (ja) 2015-05-20 2021-11-10 シオン・パワー・コーポレーション 電極用保護層
CA2996651C (en) 2015-08-27 2021-06-01 Nemaska Lithium Inc. Method for preparing lithium hydroxide and lithium sulfate monohydrate using hydrogen depolarized anode
RU2633673C1 (ru) * 2016-04-13 2017-10-16 Алексей Гаврилович Мешандин Способ получения металлического кальция
CN109155441B (zh) 2016-05-20 2022-11-01 锡安能量公司 用于电极和电化学电池的保护层
CA2940509A1 (en) 2016-08-26 2018-02-26 Nemaska Lithium Inc. Processes for treating aqueous compositions comprising lithium sulfate and sulfuric acid
US10604414B2 (en) 2017-06-15 2020-03-31 Energysource Minerals Llc System and process for recovery of lithium from a geothermal brine
US20190048483A1 (en) * 2017-08-08 2019-02-14 Alpha-En Corporation Producing lithium directly from lithium feed sources
KR20240075840A (ko) 2017-11-22 2024-05-29 네마스카 리튬 인코포레이션 다양한 금속의 하이드록사이드와 옥사이드 및 이들의 유도체를 제조하는 방법
CN109097791B (zh) * 2018-07-23 2021-03-19 南京大学 基于锂离子固态电解质的海水提锂方法和装置
CA3141478A1 (en) 2019-05-22 2020-11-26 Nemaska Lithium Inc. Processes for preparing hydroxides and oxides of various metals and derivatives thereof
CN111088506A (zh) * 2019-12-09 2020-05-01 北京化工大学 一种较低温度熔融电解制备金属锂的方法
CN110923739B (zh) * 2019-12-17 2022-04-22 中南大学 一种利用盐湖卤水剥离二维材料及同步生产高纯氢氧化锂的方法
RU2763535C1 (ru) * 2020-07-24 2021-12-30 Федеральное государственное бюджетное образовательное учреждение высшего образования «Тамбовский государственный технический университет» (ФГБОУ ВО «ТГТУ») Способ электрохимического получения наноразмерных пластинок графита

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1155927A (en) 1967-02-20 1969-06-25 Ici Ltd Electrolytic manufacture of alkali metals.
US4108743A (en) * 1977-05-02 1978-08-22 Ford Motor Company Method and apparatus for separating a metal from a salt thereof
US4156635A (en) 1978-03-29 1979-05-29 The United States Of America As Represented By The United States Department Of Energy Electrolytic method for the production of lithium using a lithium-amalgam electrode
IT1122699B (it) * 1979-08-03 1986-04-23 Oronzio De Nora Impianti Collettore elettrico resiliente e cella elettrochimica ad elettrolita solido comprendente lo stesso
DE3203515A1 (de) * 1982-02-02 1983-08-04 Max Planck Gesellschaft Verfahren zur oberflaechenbehandlung von ionenleitenden, kristallinen festelektrolyten
US5290405A (en) * 1991-05-24 1994-03-01 Ceramatec, Inc. NaOH production from ceramic electrolytic cell
EP0835951B1 (en) * 1996-09-26 2002-05-08 Ngk Spark Plug Co., Ltd. Method and apparatus for extracting lithium by applying voltage across lithium-ion conducting solid electrolyte
US6368486B1 (en) * 2000-03-28 2002-04-09 E. I. Du Pont De Nemours And Company Low temperature alkali metal electrolysis

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2010013673A (ja) * 2008-07-01 2010-01-21 Hokkaido Univ アルカリ金属の製造方法およびアルカリ金属製造装置
JP2017528603A (ja) * 2013-07-10 2017-09-28 クリーン リチウム コーポレーション リチウムの生成
KR101669890B1 (ko) * 2015-10-01 2016-10-27 재단법인 포항산업과학연구원 리튬 회수 장치 및 이를 이용한 리튬 회수 방법

Also Published As

Publication number Publication date
WO2001014616A1 (de) 2001-03-01
TWI229148B (en) 2005-03-11
DE50013788D1 (de) 2007-01-04
DE19940069A1 (de) 2001-03-08
EP1210471A1 (de) 2002-06-05
US6770187B1 (en) 2004-08-03
EP1210471B1 (de) 2006-11-22
CN1284884C (zh) 2006-11-15
CN1369023A (zh) 2002-09-11
RU2253703C2 (ru) 2005-06-10
ATE346179T1 (de) 2006-12-15

Similar Documents

Publication Publication Date Title
JP2003507581A (ja) 水溶液からのアルカリ金属の電気化学的製造
US6730210B2 (en) Low temperature alkali metal electrolysis
US6787019B2 (en) Low temperature alkali metal electrolysis
US20200149174A1 (en) Producing lithium
CN103097587B (zh) 锂金属的电解产物
US9856569B2 (en) Apparatus and method of producing metal in a nasicon electrolytic cell
US6287448B1 (en) Electrochemical production of lithium using a lithium amalgam anode
JP2003507581A5 (enExample)
KR101952218B1 (ko) 리튬 금속 제조용 세라믹 분리막 및 이를 포함하는 리튬 금속 제조 시스템
DK156731B (da) Fremgangsmaade til fremstilling af metal eller metalloid
US4156635A (en) Electrolytic method for the production of lithium using a lithium-amalgam electrode
CN112760672B (zh) 一种甲基磺酰氯电化学制备三氟甲基磺酰氟的方法
Yasinskiy et al. Electrochemical reduction and dissolution of liquid aluminium in thin layers of molten halides
US9315914B2 (en) Light metal production
CN103031567A (zh) 一种电解制取金属钠的方法
Fray Electrochemical processing using slags, fluxes and salts
ES8104440A1 (es) Cuba electrolitica para la electrodeposicion de aluminio.
EP0109164A1 (en) Production of metallic sodium from sodium carbonate by fused salt electrolysis
US20020134688A1 (en) Electrochemical process for preparation of zinc powder
CN114016083B (zh) 一种碱金属热还原金属氧化物制备金属过程中再生碱金属还原剂的方法
US2986502A (en) Purification of titanium
CN121472935A (zh) 一种高纯固态镓金属电极的应用、制备装置及方法
Atanasoski et al. Electrochemical reduction of potassium from potassium chloride in propylene carbonate electrolyte with aluminium anodes
Lee et al. Electrorefining of Indium Metal From Impure In-Sn Alloy in Fluoride Molten Salt
Zwilling High purity gadolinium by the electrolysis of GdF3

Legal Events

Date Code Title Description
A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20070524

A621 Written request for application examination

Free format text: JAPANESE INTERMEDIATE CODE: A621

Effective date: 20070524

A761 Written withdrawal of application

Free format text: JAPANESE INTERMEDIATE CODE: A761

Effective date: 20080108