JP2003501406A5 - - Google Patents
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- Publication number
- JP2003501406A5 JP2003501406A5 JP2001501371A JP2001501371A JP2003501406A5 JP 2003501406 A5 JP2003501406 A5 JP 2003501406A5 JP 2001501371 A JP2001501371 A JP 2001501371A JP 2001501371 A JP2001501371 A JP 2001501371A JP 2003501406 A5 JP2003501406 A5 JP 2003501406A5
- Authority
- JP
- Japan
- Prior art keywords
- molecular sieve
- sapo
- silicoaluminophosphate molecular
- temperature
- silicoaluminophosphate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000000034 method Methods 0.000 claims description 56
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 claims description 43
- 239000002808 molecular sieve Substances 0.000 claims description 41
- 239000003795 chemical substances by application Substances 0.000 claims description 15
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 12
- 239000007789 gas Substances 0.000 claims description 12
- 230000003197 catalytic effect Effects 0.000 claims description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 11
- 239000000203 mixture Substances 0.000 claims description 9
- 150000001336 alkenes Chemical class 0.000 claims description 8
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 8
- 239000007788 liquid Substances 0.000 claims description 7
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 claims description 6
- 238000010438 heat treatment Methods 0.000 claims description 6
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 5
- 239000003575 carbonaceous material Substances 0.000 claims description 5
- 239000001301 oxygen Substances 0.000 claims description 5
- 229910052760 oxygen Inorganic materials 0.000 claims description 5
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 claims description 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 4
- YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical compound C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 claims description 4
- NQRYJNQNLNOLGT-UHFFFAOYSA-N Piperidine Chemical compound C1CCNCC1 NQRYJNQNLNOLGT-UHFFFAOYSA-N 0.000 claims description 4
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 claims description 4
- 229910002091 carbon monoxide Inorganic materials 0.000 claims description 4
- PAFZNILMFXTMIY-UHFFFAOYSA-N cyclohexylamine Chemical compound NC1CCCCC1 PAFZNILMFXTMIY-UHFFFAOYSA-N 0.000 claims description 4
- 150000001335 aliphatic alkanes Chemical class 0.000 claims description 3
- 150000001924 cycloalkanes Chemical class 0.000 claims description 3
- MICRDKKVJPDJHX-UHFFFAOYSA-N 4-amino-3-ethylhexan-3-ol Chemical compound CCC(N)C(O)(CC)CC MICRDKKVJPDJHX-UHFFFAOYSA-N 0.000 claims description 2
- 150000001298 alcohols Chemical class 0.000 claims description 2
- 229910052786 argon Inorganic materials 0.000 claims description 2
- AVKNGPAMCBSNSO-UHFFFAOYSA-N cyclohexylmethanamine Chemical compound NCC1CCCCC1 AVKNGPAMCBSNSO-UHFFFAOYSA-N 0.000 claims description 2
- NISGSNTVMOOSJQ-UHFFFAOYSA-N cyclopentanamine Chemical compound NC1CCCC1 NISGSNTVMOOSJQ-UHFFFAOYSA-N 0.000 claims description 2
- WEHWNAOGRSTTBQ-UHFFFAOYSA-N dipropylamine Chemical compound CCCNCCC WEHWNAOGRSTTBQ-UHFFFAOYSA-N 0.000 claims description 2
- 239000001307 helium Substances 0.000 claims description 2
- 229910052734 helium Inorganic materials 0.000 claims description 2
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 claims description 2
- JJWLVOIRVHMVIS-UHFFFAOYSA-N isopropylamine Chemical compound CC(C)N JJWLVOIRVHMVIS-UHFFFAOYSA-N 0.000 claims description 2
- 229910052757 nitrogen Inorganic materials 0.000 claims description 2
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 claims description 2
- CBXCPBUEXACCNR-UHFFFAOYSA-N tetraethylammonium Chemical class CC[N+](CC)(CC)CC CBXCPBUEXACCNR-UHFFFAOYSA-N 0.000 claims description 2
- GBXQPDCOMJJCMJ-UHFFFAOYSA-M trimethyl-[6-(trimethylazaniumyl)hexyl]azanium;bromide Chemical compound [Br-].C[N+](C)(C)CCCCCC[N+](C)(C)C GBXQPDCOMJJCMJ-UHFFFAOYSA-M 0.000 claims description 2
- 239000000047 product Substances 0.000 claims 6
- 238000001354 calcination Methods 0.000 claims 3
- 239000012065 filter cake Substances 0.000 claims 3
- 239000002184 metal Substances 0.000 claims 3
- 229910052751 metal Inorganic materials 0.000 claims 3
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 claims 2
- 239000003054 catalyst Substances 0.000 claims 2
- 239000011148 porous material Substances 0.000 claims 2
- 230000003213 activating effect Effects 0.000 claims 1
- 239000003570 air Substances 0.000 claims 1
- 150000001491 aromatic compounds Chemical class 0.000 claims 1
- -1 ethylene, propylene Chemical group 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 claims 1
- 239000000463 material Substances 0.000 claims 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US13793399P | 1999-06-07 | 1999-06-07 | |
| US60/137,933 | 1999-06-07 | ||
| PCT/US2000/015468 WO2000074848A1 (en) | 1999-06-07 | 2000-06-05 | Protecting catalytic activity of a sapo molecular sieve |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2007149260A Division JP2007275892A (ja) | 1999-06-07 | 2007-06-05 | Ｓａｐｏモレキュラーシーブの触媒活性の保護方法及びそれに用いるｓａｐｏモレキュラーシーブ |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2003501406A JP2003501406A (ja) | 2003-01-14 |
| JP2003501406A5 true JP2003501406A5 (enExample) | 2007-07-26 |
Family
ID=22479696
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2001501371A Pending JP2003501406A (ja) | 1999-06-07 | 2000-06-05 | Ｓａｐｏモレキュラーシーブの触媒活性の保護 |
| JP2007149260A Withdrawn JP2007275892A (ja) | 1999-06-07 | 2007-06-05 | Ｓａｐｏモレキュラーシーブの触媒活性の保護方法及びそれに用いるｓａｐｏモレキュラーシーブ |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2007149260A Withdrawn JP2007275892A (ja) | 1999-06-07 | 2007-06-05 | Ｓａｐｏモレキュラーシーブの触媒活性の保護方法及びそれに用いるｓａｐｏモレキュラーシーブ |
Country Status (19)
| Country | Link |
|---|---|
| US (2) | US6316683B1 (enExample) |
| EP (3) | EP1192003B1 (enExample) |
| JP (2) | JP2003501406A (enExample) |
| KR (1) | KR100699654B1 (enExample) |
| CN (2) | CN1131109C (enExample) |
| AR (2) | AR024869A1 (enExample) |
| AT (2) | ATE284755T1 (enExample) |
| AU (1) | AU772744B2 (enExample) |
| BR (1) | BR0011682B1 (enExample) |
| CA (1) | CA2371102A1 (enExample) |
| DE (2) | DE60036570T2 (enExample) |
| ES (2) | ES2294385T3 (enExample) |
| GC (1) | GC0000193A (enExample) |
| MX (1) | MXPA01012626A (enExample) |
| MY (2) | MY120272A (enExample) |
| NO (1) | NO323823B1 (enExample) |
| TW (1) | TWI264328B (enExample) |
| WO (1) | WO2000074848A1 (enExample) |
| ZA (1) | ZA200110056B (enExample) |
Families Citing this family (59)
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| US6498120B1 (en) * | 2000-04-26 | 2002-12-24 | Exxonmobil Chemical Patents Inc. | Rejuvenating SAPO molecular sieve with anhydrous liquid or vapor |
| US6580010B2 (en) | 2001-01-03 | 2003-06-17 | Exxonmobil Chemical Patents, Inc. | Olefin recovery in an olefin production process |
| US6756516B2 (en) | 2001-07-02 | 2004-06-29 | Exxonmobil Chemical Patents Inc. | Treatment of acid catalysts |
| WO2003006414A2 (en) * | 2001-07-12 | 2003-01-23 | Exxonmobil Chemical Patents Inc. | Producing maleic anhydride from a c4 stream in an oxygenate to olefin process |
| US6897175B2 (en) * | 2001-10-09 | 2005-05-24 | General Electric | Catalyst and method for the alkylation of hydroxyaromatic compounds |
| CN1282632C (zh) | 2002-01-03 | 2006-11-01 | 埃克森美孚化学专利公司 | 酸催化剂的稳定方法 |
| US7208442B2 (en) * | 2002-02-28 | 2007-04-24 | Exxonmobil Chemical Patents Inc. | Molecular sieve compositions, catalyst thereof, their making and use in conversion processes |
| US7271123B2 (en) * | 2002-03-20 | 2007-09-18 | Exxonmobil Chemical Patents Inc. | Molecular sieve catalyst composition, its making and use in conversion process |
| US6897179B2 (en) * | 2003-06-13 | 2005-05-24 | Exxonmobil Chemical Patents Inc. | Method of protecting SAPO molecular sieve from loss of catalytic activity |
| US7015174B2 (en) * | 2003-06-20 | 2006-03-21 | Exxonmobil Chemical Patents Inc. | Maintaining molecular sieve catalytic activity under water vapor conditions |
| US7081432B2 (en) | 2003-07-10 | 2006-07-25 | General Electric Company | Alkylation catalyst and method for making alkylated phenols |
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| US7259287B2 (en) * | 2003-08-15 | 2007-08-21 | Exxonmobil Chemical Patents Inc. | Method of starting up a reaction system |
| US7241716B2 (en) * | 2003-11-10 | 2007-07-10 | Exxonmobil Chemical Patents Inc. | Protecting catalytic sites of metalloaluminophosphate molecular sieves |
| US7084319B2 (en) * | 2003-12-05 | 2006-08-01 | Exxonmobil Chemical Patents Inc. | Catalyst fluidization in oxygenate to olefin reaction systems |
| US7033971B2 (en) * | 2004-02-09 | 2006-04-25 | Exxonmobil Chemical Patents Inc. | Method for using stabilizing catalyst activity during MTO unit operation |
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| US7223714B2 (en) * | 2004-11-04 | 2007-05-29 | Exxonmobil Chemical Patents Inc. | Method of transferring catalyst in a reaction system |
| US7619128B2 (en) * | 2005-03-25 | 2009-11-17 | Exxonmobil Chemical Patents Inc. | Stabilizing catalyst activity during catalyst regeneration |
| US8129576B2 (en) * | 2005-06-30 | 2012-03-06 | Uop Llc | Protection of solid acid catalysts from damage by volatile species |
| US8262773B2 (en) | 2005-07-26 | 2012-09-11 | Exxonmobil Upstream Research Company | Method of purifying hydrocarbons and regeneration of adsorbents used therein |
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| US7998893B2 (en) * | 2005-11-22 | 2011-08-16 | Uop Llc | Treatment of air to a catalyst regenerator to maintain catalyst activity |
| US20070142212A1 (en) * | 2005-11-22 | 2007-06-21 | Pujado Peter R | Treatment of air to a catalyst regenerator to maintain catalyst activity |
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| US7744746B2 (en) | 2006-03-31 | 2010-06-29 | Exxonmobil Research And Engineering Company | FCC catalyst stripper configuration |
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| CN101121149A (zh) * | 2006-08-08 | 2008-02-13 | 中国科学院大连化学物理研究所 | 一种控制焙烧条件保护微球催化剂催化活性的方法 |
| CN101121146B (zh) * | 2006-08-08 | 2011-09-14 | 中国科学院大连化学物理研究所 | 一种含氧化合物转化制烯烃微球催化剂的保存方法 |
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| KR101193973B1 (ko) | 2009-10-22 | 2012-10-24 | 현대엔지니어링 주식회사 | 고강도를 갖는 ｓａｐｏ-34 미소구형체 촉매, 이의 제조방법 및 이를 이용한 경질올레핀의 제조방법 |
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| KR101034664B1 (ko) * | 2011-04-13 | 2011-05-16 | 주식회사 남부지엔씨 | 건설폐기물용 다단 파쇄기 및 이를 이용한 건설 및 생활폐기물의 중간처리 과정 중에서 발생되는 순환골재 생산시설 |
| CN103143390A (zh) * | 2013-03-15 | 2013-06-12 | 华东师范大学 | 一种微球钛硅分子筛催化剂的改性方法 |
| US10179753B2 (en) | 2015-10-21 | 2019-01-15 | Exelus, Inc. | Process of making olefins or alkylate by reaction of methanol and/or DME or by reaction of methanol and/or DME and butane |
| FR3067020B1 (fr) * | 2017-05-31 | 2022-03-18 | Ifp Energies Now | Synthese directe d'un materiau sapo de structure afx comprenant du cuivre et utilisation de ce materiau |
| CN109465031B (zh) * | 2017-09-07 | 2021-07-20 | 中国科学院大连化学物理研究所 | 一种以afo型结构分子筛为载体的异构化催化剂制备方法 |
| CN108862315B (zh) * | 2018-07-03 | 2020-05-01 | 天津大学 | 一种sapo-56/sapo-34复合分子筛的制备方法 |
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| CN120790211B (zh) * | 2025-09-11 | 2025-12-09 | 上海翔威新能源科技有限公司 | 一种加氢异构催化剂及其制备方法、应用 |
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| US6051745A (en) * | 1999-03-04 | 2000-04-18 | Phillips Petroleum Company | Silicoaluminophosphate material, a method of making such improved material and the use thereof in the conversion of oxygenated hydrocarbons to olefins |
| US6046371A (en) * | 1999-05-05 | 2000-04-04 | Phillips Petroleum Company | Silicoaluminophosphate material, a method of making such improved material and the use thereof in the conversion of oxygenated hydrocarbons to olefins |
-
1999
- 1999-09-08 US US09/391,770 patent/US6316683B1/en not_active Expired - Lifetime
-
2000
- 2000-06-01 TW TW089110742A patent/TWI264328B/zh not_active IP Right Cessation
- 2000-06-04 GC GCP2000695 patent/GC0000193A/en active
- 2000-06-05 AU AU54645/00A patent/AU772744B2/en not_active Ceased
- 2000-06-05 CN CN00808614A patent/CN1131109C/zh not_active Expired - Lifetime
- 2000-06-05 JP JP2001501371A patent/JP2003501406A/ja active Pending
- 2000-06-05 DE DE60036570T patent/DE60036570T2/de not_active Expired - Lifetime
- 2000-06-05 EP EP00939575A patent/EP1192003B1/en not_active Expired - Lifetime
- 2000-06-05 CN CNB031557740A patent/CN1239263C/zh not_active Expired - Lifetime
- 2000-06-05 DE DE60016749T patent/DE60016749T2/de not_active Expired - Lifetime
- 2000-06-05 KR KR1020017015780A patent/KR100699654B1/ko not_active Expired - Fee Related
- 2000-06-05 BR BRPI0011682-3A patent/BR0011682B1/pt not_active IP Right Cessation
- 2000-06-05 CA CA002371102A patent/CA2371102A1/en not_active Abandoned
- 2000-06-05 AT AT00939575T patent/ATE284755T1/de not_active IP Right Cessation
- 2000-06-05 WO PCT/US2000/015468 patent/WO2000074848A1/en not_active Ceased
- 2000-06-05 MX MXPA01012626A patent/MXPA01012626A/es active IP Right Grant
- 2000-06-05 EP EP04007379A patent/EP1441022B1/en not_active Expired - Lifetime
- 2000-06-05 ES ES04007379T patent/ES2294385T3/es not_active Expired - Lifetime
- 2000-06-05 AT AT04007379T patent/ATE374234T1/de not_active IP Right Cessation
- 2000-06-05 ES ES00939575T patent/ES2233397T3/es not_active Expired - Lifetime
- 2000-06-05 EP EP03020750A patent/EP1369177A1/en not_active Withdrawn
- 2000-06-06 AR ARP000102795A patent/AR024869A1/es active IP Right Grant
- 2000-06-06 MY MYPI20002535A patent/MY120272A/en unknown
- 2000-06-06 MY MYPI20033460A patent/MY138493A/en unknown
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2001
- 2001-01-12 US US09/760,289 patent/US6455748B2/en not_active Expired - Lifetime
- 2001-12-04 NO NO20015937A patent/NO323823B1/no unknown
- 2001-12-06 ZA ZA200110056A patent/ZA200110056B/xx unknown
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2003
- 2003-08-13 AR AR20030102936A patent/AR040873A2/es active IP Right Grant
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2007
- 2007-06-05 JP JP2007149260A patent/JP2007275892A/ja not_active Withdrawn
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