JP2002535416A5 - - Google Patents
Download PDFInfo
- Publication number
- JP2002535416A5 JP2002535416A5 JP2000596054A JP2000596054A JP2002535416A5 JP 2002535416 A5 JP2002535416 A5 JP 2002535416A5 JP 2000596054 A JP2000596054 A JP 2000596054A JP 2000596054 A JP2000596054 A JP 2000596054A JP 2002535416 A5 JP2002535416 A5 JP 2002535416A5
- Authority
- JP
- Japan
- Prior art keywords
- methyl
- dimethylsilanediyl
- zirconium dichloride
- azapentalene
- dimethyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
- -1 hydrogen Chemical group 0.000 description 78
- VPGLGRNSAYHXPY-UHFFFAOYSA-L zirconium(2+);dichloride Chemical compound Cl[Zr]Cl VPGLGRNSAYHXPY-UHFFFAOYSA-L 0.000 description 53
- LKCNBWOMZOFEGO-UHFFFAOYSA-N 2H-cyclopenta[b]thiophen-5-ylmethylidene(dimethyl)silane Chemical compound C[Si](=CC1=CC2=CCSC2=C1)C LKCNBWOMZOFEGO-UHFFFAOYSA-N 0.000 description 25
- GDZRSSPGIXTSJF-UHFFFAOYSA-N dimethyl-[(5-methylcyclopenta[b]pyrrol-2-yl)methylidene]silane Chemical compound C[Si](=CC1=NC2=CC(=CC2=C1)C)C GDZRSSPGIXTSJF-UHFFFAOYSA-N 0.000 description 24
- VAZKROOLPOKMTJ-UHFFFAOYSA-N cyclopenta[b]pyrrol-5-ylmethylidene(dimethyl)silane Chemical compound C[Si](=CC1=CC2=CC=NC2=C1)C VAZKROOLPOKMTJ-UHFFFAOYSA-N 0.000 description 23
- DGUIDBYKNGVRCS-UHFFFAOYSA-N dimethyl-[(5-methyl-2H-cyclopenta[b]furan-2-yl)methylidene]silane Chemical compound C[Si](=CC1OC2=CC(=CC2=C1)C)C DGUIDBYKNGVRCS-UHFFFAOYSA-N 0.000 description 23
- VAFGZWDYTDHMCR-UHFFFAOYSA-N 2H-cyclopenta[b]furan-5-ylmethylidene(dimethyl)silane Chemical compound C[Si](=CC1=CC2=CCOC2=C1)C VAFGZWDYTDHMCR-UHFFFAOYSA-N 0.000 description 22
- YNIAZEDCCPGOTJ-UHFFFAOYSA-N dimethyl-[(5-methyl-1-phenyl-2H-cyclopenta[b]pyrrol-2-yl)methylidene]silane Chemical compound C[Si](=CC1N(C2=CC(=CC2=C1)C)C1=CC=CC=C1)C YNIAZEDCCPGOTJ-UHFFFAOYSA-N 0.000 description 22
- UOKWFSNVSIMQSB-UHFFFAOYSA-N dimethyl-[(5-methyl-2H-cyclopenta[b]thiophen-2-yl)methylidene]silane Chemical compound C[Si](=CC1C=C2C=C(C=C2S1)C)C UOKWFSNVSIMQSB-UHFFFAOYSA-N 0.000 description 22
- 239000007983 Tris buffer Substances 0.000 description 20
- PXPVIOAGNBJCBG-UHFFFAOYSA-N dimethyl-[(1-phenyl-2H-cyclopenta[b]pyrrol-5-yl)methylidene]silane Chemical compound C[Si](=CC=1C=C2N(CC=C2C=1)C1=CC=CC=C1)C PXPVIOAGNBJCBG-UHFFFAOYSA-N 0.000 description 19
- PBZHFLGIROVUPM-UHFFFAOYSA-N cyclopenta[c]pyrrol-5-ylmethylidene(dimethyl)silane Chemical compound C[Si](=CC1=CC2=CN=CC2=C1)C PBZHFLGIROVUPM-UHFFFAOYSA-N 0.000 description 14
- MWFLBUXIVJTNRA-UHFFFAOYSA-N 1H-cyclopenta[c]furan-5-ylmethylidene(dimethyl)silane Chemical compound C[Si](=CC1=CC2=COCC2=C1)C MWFLBUXIVJTNRA-UHFFFAOYSA-N 0.000 description 13
- MKMUUVUYHMGIFI-UHFFFAOYSA-N dimethyl-[(2-phenyl-1H-cyclopenta[c]pyrrol-5-yl)methylidene]silane Chemical compound C[Si](=CC1=CC2=CN(CC2=C1)C1=CC=CC=C1)C MKMUUVUYHMGIFI-UHFFFAOYSA-N 0.000 description 13
- YJPRSAQSMGYBGL-UHFFFAOYSA-N 1H-cyclopenta[c]thiophen-5-ylmethylidene(dimethyl)silane Chemical compound C[Si](=CC1=CC2=CSCC2=C1)C YJPRSAQSMGYBGL-UHFFFAOYSA-N 0.000 description 12
- 150000001875 compounds Chemical class 0.000 description 12
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 11
- 229910052739 hydrogen Inorganic materials 0.000 description 10
- 239000001257 hydrogen Substances 0.000 description 10
- 229910052801 chlorine Inorganic materials 0.000 description 8
- 239000000460 chlorine Substances 0.000 description 8
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 7
- 229910052731 fluorine Inorganic materials 0.000 description 6
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 5
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 5
- 125000003118 aryl group Chemical group 0.000 description 5
- 239000003054 catalyst Substances 0.000 description 5
- 239000011737 fluorine Substances 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- 229910052726 zirconium Inorganic materials 0.000 description 5
- 239000004215 Carbon black (E152) Substances 0.000 description 4
- 125000001183 hydrocarbyl group Chemical group 0.000 description 4
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 4
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 4
- 125000005018 aryl alkenyl group Chemical group 0.000 description 3
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 3
- 125000005843 halogen group Chemical group 0.000 description 3
- 229920000098 polyolefin Polymers 0.000 description 3
- 125000001424 substituent group Chemical group 0.000 description 3
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 3
- ODYJFRXBTXXNNM-UHFFFAOYSA-N (5-methyl-2H-cyclopenta[b]furan-2-yl)methylidene-diphenylsilane Chemical compound C1(=CC=CC=C1)[Si](=CC1OC2=CC(=CC2=C1)C)C1=CC=CC=C1 ODYJFRXBTXXNNM-UHFFFAOYSA-N 0.000 description 2
- YBYIRNPNPLQARY-UHFFFAOYSA-N 1H-indene Natural products C1=CC=C2CC=CC2=C1 YBYIRNPNPLQARY-UHFFFAOYSA-N 0.000 description 2
- BSUUCQOCNBWYSN-UHFFFAOYSA-N 2,5-dimethyl-1-phenyl-2h-cyclopenta[b]pyrrole Chemical compound CC1C=C2C=C(C)C=C2N1C1=CC=CC=C1 BSUUCQOCNBWYSN-UHFFFAOYSA-N 0.000 description 2
- APEIPNONNWFGEU-UHFFFAOYSA-N 2,5-dimethyl-2h-cyclopenta[b]furan Chemical compound CC1=CC2=CC(C)OC2=C1 APEIPNONNWFGEU-UHFFFAOYSA-N 0.000 description 2
- FLNSMWIFPVKXPV-UHFFFAOYSA-N 2,5-dimethyl-2h-cyclopenta[b]thiophene Chemical compound CC1=CC2=CC(C)SC2=C1 FLNSMWIFPVKXPV-UHFFFAOYSA-N 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- 125000003342 alkenyl group Chemical group 0.000 description 2
- 125000002877 alkyl aryl group Chemical group 0.000 description 2
- 229910052794 bromium Inorganic materials 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- YEDVUDDWJVRKIS-UHFFFAOYSA-N cyclopenta[b]pyrrole Chemical compound C1=C[C]2[N]C=CC2=C1 YEDVUDDWJVRKIS-UHFFFAOYSA-N 0.000 description 2
- UBHZUDXTHNMNLD-UHFFFAOYSA-N dimethylsilane Chemical compound C[SiH2]C UBHZUDXTHNMNLD-UHFFFAOYSA-N 0.000 description 2
- 125000005842 heteroatom Chemical group 0.000 description 2
- 125000003454 indenyl group Chemical group C1(C=CC2=CC=CC=C12)* 0.000 description 2
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 2
- 125000002023 trifluoromethyl group Chemical group FC(F)(F)* 0.000 description 2
- QWUWMCYKGHVNAV-UHFFFAOYSA-N 1,2-dihydrostilbene Chemical group C=1C=CC=CC=1CCC1=CC=CC=C1 QWUWMCYKGHVNAV-UHFFFAOYSA-N 0.000 description 1
- QLQZIQBZJXXBJD-UHFFFAOYSA-N 1H-cyclopenta[c]thiophen-5-ylmethylidene(diphenyl)silane Chemical compound C1(=CC=CC=C1)[Si](=CC1=CC2=CSCC2=C1)C1=CC=CC=C1 QLQZIQBZJXXBJD-UHFFFAOYSA-N 0.000 description 1
- VQFKAQNIDCDETK-UHFFFAOYSA-N 2-ethenyl-5-methyl-2H-cyclopenta[b]thiophene Chemical compound C=CC1SC2=CC(=CC2=C1)C VQFKAQNIDCDETK-UHFFFAOYSA-N 0.000 description 1
- SGSQQFQVCGHENN-UHFFFAOYSA-N 2H-cyclopenta[b]thiophen-5-ylmethylidene-methyl-phenylsilane Chemical compound C[Si](=CC=1C=C2SCC=C2C=1)C1=CC=CC=C1 SGSQQFQVCGHENN-UHFFFAOYSA-N 0.000 description 1
- 125000000590 4-methylphenyl group Chemical group [H]C1=C([H])C(=C([H])C([H])=C1*)C([H])([H])[H] 0.000 description 1
- ZGEGEMSWVWZKKD-UHFFFAOYSA-N 5-methyl-1-phenyl-2h-cyclopenta[b]pyrrole Chemical compound C12=CC(C)=CC2=CCN1C1=CC=CC=C1 ZGEGEMSWVWZKKD-UHFFFAOYSA-N 0.000 description 1
- OZWQRBLECYMXSP-UHFFFAOYSA-N 5-methyl-2-(2-methylprop-1-enyl)-2H-cyclopenta[b]thiophene Chemical compound CC(=CC1C=C2C=C(C=C2S1)C)C OZWQRBLECYMXSP-UHFFFAOYSA-N 0.000 description 1
- NEYIFFPXDIPWFR-UHFFFAOYSA-N 5-methyl-2-(2-methylprop-1-enyl)cyclopenta[b]pyrrole Chemical compound CC(C)=CC1=NC2=CC(=CC2=C1)C NEYIFFPXDIPWFR-UHFFFAOYSA-N 0.000 description 1
- XIVUKUJIUDSEFB-UHFFFAOYSA-N 5-prop-1-enylcyclopenta[b]pyrrole Chemical compound C(C)=CC1=CC2=NC=CC2=C1 XIVUKUJIUDSEFB-UHFFFAOYSA-N 0.000 description 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
- RJRJHEBUMGFPMM-UHFFFAOYSA-N CC1=C(C(F)(F)F)C2=CC=CC=C2C1C1=CC=CC=C1 Chemical compound CC1=C(C(F)(F)F)C2=CC=CC=C2C1C1=CC=CC=C1 RJRJHEBUMGFPMM-UHFFFAOYSA-N 0.000 description 1
- HVVOBVOOJVAECW-UHFFFAOYSA-N C[Ge](=CC1=CC2=CCN(C2=C1)C3=CC=CC=C3)C Chemical compound C[Ge](=CC1=CC2=CCN(C2=C1)C3=CC=CC=C3)C HVVOBVOOJVAECW-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 241000723368 Conium Species 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 125000002178 anthracenyl group Chemical group C1(=CC=CC2=CC3=CC=CC=C3C=C12)* 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- BLFCYYGCMHNPKX-UHFFFAOYSA-N cyclopenta[b]phosphol-5-ylmethylidene(dimethyl)silane Chemical compound C[Si](=CC1=CC2=CC=PC2=C1)C BLFCYYGCMHNPKX-UHFFFAOYSA-N 0.000 description 1
- 125000000058 cyclopentadienyl group Chemical group C1(=CC=CC1)* 0.000 description 1
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 1
- FJRJQYXZKQOGGB-UHFFFAOYSA-N dimethyl-(5-methyl-3h-cyclopenta[b]pyrrol-2-ylidene)silane Chemical compound C[Si](C)=C1CC2=CC(C)=CC2=N1 FJRJQYXZKQOGGB-UHFFFAOYSA-N 0.000 description 1
- UIOSYVXWFXNEAV-UHFFFAOYSA-N dimethyl-[2-(5-propan-2-ylcyclopenta[b]pyrrol-2-yl)propylidene]silane Chemical compound C[Si](=CC(C)C1=CC2=CC(=CC2=N1)C(C)C)C UIOSYVXWFXNEAV-UHFFFAOYSA-N 0.000 description 1
- YPCQOHVOEVKGBS-UHFFFAOYSA-N dimethyl-[[2-(5-methyl-1H-cyclopenta[c]pyrrol-2-yl)phenyl]methylidene]silane Chemical compound C[Si](=CC1=C(C=CC=C1)N1CC2=CC(=CC2=C1)C)C YPCQOHVOEVKGBS-UHFFFAOYSA-N 0.000 description 1
- QKIUAMUSENSFQQ-UHFFFAOYSA-N dimethylazanide Chemical compound C[N-]C QKIUAMUSENSFQQ-UHFFFAOYSA-N 0.000 description 1
- 239000012634 fragment Substances 0.000 description 1
- 229910052732 germanium Inorganic materials 0.000 description 1
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 description 1
- 229910052735 hafnium Inorganic materials 0.000 description 1
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000001624 naphthyl group Chemical group 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 125000001339 silanediyl group Chemical group [H][Si]([H])(*)* 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- DUNKXUFBGCUVQW-UHFFFAOYSA-J zirconium tetrachloride Chemical compound Cl[Zr](Cl)(Cl)Cl DUNKXUFBGCUVQW-UHFFFAOYSA-J 0.000 description 1
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19903306.4 | 1999-01-28 | ||
| DE19903306A DE19903306A1 (de) | 1999-01-28 | 1999-01-28 | Organometallverbindung, Katalysatorsystem enthaltend diese Organometallverbindung und seine Verwendung |
| PCT/EP2000/000471 WO2000044799A1 (de) | 1999-01-28 | 2000-01-22 | Organometallverbindung, katalysatorsystem enthaltend diese organometallverbindung und seine verwendung |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2002535416A JP2002535416A (ja) | 2002-10-22 |
| JP2002535416A5 true JP2002535416A5 (enExample) | 2007-03-29 |
Family
ID=7895623
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2000596054A Ceased JP2002535416A (ja) | 1999-01-28 | 2000-01-22 | 有機金属化合物、この有機金属化合物を含む触媒組成物およびその使用 |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US6469114B1 (enExample) |
| EP (1) | EP1082363A1 (enExample) |
| JP (1) | JP2002535416A (enExample) |
| BR (1) | BR0004493A (enExample) |
| DE (1) | DE19903306A1 (enExample) |
| WO (1) | WO2000044799A1 (enExample) |
Families Citing this family (28)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AU3764600A (en) * | 1999-05-13 | 2000-12-05 | Dow Chemical Company, The | Di- and tri-heteroatom substituted indenyl metal complexes |
| US6211311B1 (en) * | 1999-05-25 | 2001-04-03 | Equistar Chemicals, L.P. | Supported olefin polymerization catalysts |
| EP1074557A3 (de) * | 1999-07-31 | 2003-02-26 | Basell Polyolefine GmbH | Übergangsmetallverbindung, Ligandensystem, Katalysatorsystem und seine Verwendung zur Polymerisation von Olefinen |
| EP1548023B1 (de) | 1999-12-23 | 2013-08-14 | Basell Polyolefine GmbH | Übergangsmetallverbindung, Katalysatorsystem und seine Verwendung zur Polymerisation und Copolymerisation von Olefinen |
| WO2001053201A1 (en) | 2000-01-21 | 2001-07-26 | U.S. Borax Inc. | Nonaborate compositions and their preparation |
| AU2001279978A1 (en) * | 2000-09-26 | 2002-04-08 | Bp Chemicals Limited | Supported catalyst systems |
| WO2002100908A1 (en) * | 2001-06-12 | 2002-12-19 | Basell Polyolefine Gmbh | Process for the polymerization of 1-butene |
| EP1446429B1 (en) | 2001-06-12 | 2009-10-07 | Basell Polyolefine GmbH | Process for the polymerization of 1-butene |
| DE10158656A1 (de) * | 2001-11-30 | 2003-06-26 | Basell Polyolefine Gmbh | Organoübergangsmetallverbindung, Biscyclopentadienylligandsystem, Katalysatorsystem und Verfahren zur Herstellung von Polyolefinen |
| WO2004022613A1 (en) | 2002-09-06 | 2004-03-18 | Basell Polyolefine Gmbh | Process for the copolymerization of ethylene |
| JP2006502260A (ja) * | 2002-10-10 | 2006-01-19 | バセル ポリオレフィン ジーエムビーエイチ | エチレンの共重合方法 |
| WO2004046214A2 (en) | 2002-10-15 | 2004-06-03 | Exxonmobil Chemical Patents Inc. | Multiple catalyst system for olefin polymerization and polymers produced therefrom |
| US7541402B2 (en) | 2002-10-15 | 2009-06-02 | Exxonmobil Chemical Patents Inc. | Blend functionalized polyolefin adhesive |
| US7223822B2 (en) | 2002-10-15 | 2007-05-29 | Exxonmobil Chemical Patents Inc. | Multiple catalyst and reactor system for olefin polymerization and polymers produced therefrom |
| US7550528B2 (en) | 2002-10-15 | 2009-06-23 | Exxonmobil Chemical Patents Inc. | Functionalized olefin polymers |
| DE60329523D1 (de) * | 2002-12-04 | 2009-11-12 | Basell Polyolefine Gmbh | 1-Buten-Copolymere und Herstellungsverfahren dafür |
| US7589160B2 (en) * | 2002-12-04 | 2009-09-15 | Basell Polyolefine Gmbh | Process for preparing 1-butene polymers |
| WO2005023891A1 (en) * | 2003-09-11 | 2005-03-17 | Basell Polyolefine Gmbh | Multistep process for preparing heterophasic propylene copolymers |
| US6903170B2 (en) * | 2003-09-29 | 2005-06-07 | Equistar Chemicals, Lp | Olefin polymerization process using triisobutylaluminum as a scavenger |
| DE102004020525A1 (de) * | 2004-04-26 | 2005-11-10 | Basell Polyolefine Gmbh | Katalysatorsystem zur Olefinpolymerisation, dessen Herstellung und Verwendung |
| JP2008501659A (ja) * | 2004-06-04 | 2008-01-24 | バーゼル、ポリオレフィン、ゲゼルシャフト、ミット、ベシュレンクテル、ハフツング | 遷移金属化合物、リガンド、触媒組成物及びポリオレフィンを製造する方法 |
| US7169864B2 (en) * | 2004-12-01 | 2007-01-30 | Novolen Technology Holdings, C.V. | Metallocene catalysts, their synthesis and their use for the polymerization of olefins |
| US7232869B2 (en) * | 2005-05-17 | 2007-06-19 | Novolen Technology Holdings, C.V. | Catalyst composition for olefin polymerization |
| EP1847555A1 (en) * | 2006-04-18 | 2007-10-24 | Borealis Technology Oy | Multi-branched Polypropylene |
| US8012900B2 (en) * | 2007-12-28 | 2011-09-06 | Chevron Phillips Chemical Company, L.P. | Nano-linked metallocene catalyst compositions and their polymer products |
| EP2573091A1 (en) | 2011-09-23 | 2013-03-27 | Lummus Novolen Technology Gmbh | Process for recycling of free ligand from their corresponding metallocene complexes |
| US12421334B2 (en) | 2019-06-13 | 2025-09-23 | Lg Chem, Ltd. | Hybrid supported metallocene catalyst and method of preparing polypropylene using the same |
| KR102524952B1 (ko) | 2019-06-13 | 2023-04-24 | 주식회사 엘지화학 | 신규 전이금속 화합물 및 이를 이용한 폴리프로필렌의 제조방법 |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ZA9710211B (en) * | 1996-11-15 | 1998-06-03 | Montell Technology Company Bv | Heterocyclic metallocenes and polymerization catalysts. |
| HUP0001331A2 (hu) * | 1997-11-12 | 2000-08-28 | Montell Technology Company B.V. | Metallocének, áthidalt ligandumok, olefinpolimerizációs katalizátorok és eljárás olefinek polimerizálására |
| DE19804970A1 (de) * | 1998-02-07 | 1999-08-12 | Aventis Res & Tech Gmbh & Co | Katalysatorsystem |
-
1999
- 1999-01-28 DE DE19903306A patent/DE19903306A1/de not_active Withdrawn
-
2000
- 2000-01-22 US US09/646,176 patent/US6469114B1/en not_active Expired - Lifetime
- 2000-01-22 EP EP00910601A patent/EP1082363A1/de not_active Withdrawn
- 2000-01-22 BR BR0004493-8A patent/BR0004493A/pt not_active Application Discontinuation
- 2000-01-22 WO PCT/EP2000/000471 patent/WO2000044799A1/de not_active Ceased
- 2000-01-22 JP JP2000596054A patent/JP2002535416A/ja not_active Ceased
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP2002535416A5 (enExample) | ||
| EP0975644B1 (en) | Substituted metallocene compounds for olefin polymerization catalyst systems, their intermediates and methods for preparing them | |
| JP3683040B2 (ja) | シンジオタクチツク／アイソタクチツクブロツクポリオレフインの製造方法 | |
| CA2279242C (en) | New homogeneous olefin polymerization catalyst composition | |
| AU722731B2 (en) | Heteroatom substituted metallocene compounds for olefin polymerization catalyst systems and methods for preparing them | |
| AU731668B2 (en) | Chemical compound | |
| JP4334136B2 (ja) | 化合物 | |
| US6133187A (en) | Hetergeneous metallocene catalysts and use thereof in olefin polymerization process | |
| KR950032252A (ko) | 올레핀 중합에의 사용을 위한 플루오레닐-함유 메탈로센 | |
| JP2003519156A5 (ja) | メタロセン化合物、リガンド、触媒、ポリマーの製造方法及びプロピレンホモポリマー | |
| JP2004502699A5 (enExample) | ||
| JPH10158287A5 (enExample) | ||
| HUT66545A (en) | High-pressure process for producing polypropylene | |
| AU4516399A (en) | Supported olefin polymerization catalyst composition | |
| JPWO2020239603A5 (enExample) | ||
| JP2001031694A5 (enExample) | ||
| KR940005641A (ko) | 리간드로서 아릴- 치환된 인데닐 유도체를 함유하는 메탈로센, 이의 제조방법 및 촉매로서의 이의 용도 | |
| EP0528041A4 (en) | Novel transition metal compound and process for polymerizing olefin by using the same | |
| JPH06122718A (ja) | アイソタクチツクポリオレフイン製造の方法及び触媒 | |
| JP2005522406A5 (enExample) | ||
| JP2000514488A (ja) | シンジオタクチック／アタクチックブロックポリオレフィン類、それを製造するための触媒および方法 | |
| KR101712318B1 (ko) | 메탈로센 이성질체 촉매 및 이를 이용하여 제조된 폴리올레핀 수지 | |
| KR960004380A (ko) | 무정형 프로필렌 중합체의 제조방법 | |
| Gupta et al. | Metallocene complexes of group 4 elements in the polymerization of monoolefins | |
| JP2002513428A (ja) | メタロセン、リガンド及びオレフィン重合 |