JP2005522406A5 - - Google Patents

Download PDF

Info

Publication number
JP2005522406A5
JP2005522406A5 JP2003508964A JP2003508964A JP2005522406A5 JP 2005522406 A5 JP2005522406 A5 JP 2005522406A5 JP 2003508964 A JP2003508964 A JP 2003508964A JP 2003508964 A JP2003508964 A JP 2003508964A JP 2005522406 A5 JP2005522406 A5 JP 2005522406A5
Authority
JP
Japan
Prior art keywords
group
halogen
hydrogen
aryl
compound according
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP2003508964A
Other languages
English (en)
Japanese (ja)
Other versions
JP2005522406A (ja
Filing date
Publication date
Priority claimed from US09/896,496 external-priority patent/US7122498B2/en
Priority claimed from US09/896,494 external-priority patent/US6870016B1/en
Application filed filed Critical
Priority claimed from PCT/US2002/018718 external-priority patent/WO2003002583A2/en
Publication of JP2005522406A publication Critical patent/JP2005522406A/ja
Publication of JP2005522406A5 publication Critical patent/JP2005522406A5/ja
Pending legal-status Critical Current

Links

JP2003508964A 2001-06-29 2002-06-14 メタロセン及び該メタロセン由来の触媒組成物 Pending JP2005522406A (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US09/896,496 US7122498B2 (en) 2000-06-30 2001-06-29 Metallocenes and catalyst compositions derived therefrom
US09/896,494 US6870016B1 (en) 2000-06-30 2001-06-29 Polymerization process and polymer composition
PCT/US2002/018718 WO2003002583A2 (en) 2001-06-29 2002-06-14 Metallocenes and catalyst compositions derived therefrom

Publications (2)

Publication Number Publication Date
JP2005522406A JP2005522406A (ja) 2005-07-28
JP2005522406A5 true JP2005522406A5 (enExample) 2006-01-05

Family

ID=27129143

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2003508964A Pending JP2005522406A (ja) 2001-06-29 2002-06-14 メタロセン及び該メタロセン由来の触媒組成物

Country Status (3)

Country Link
EP (1) EP1421090B1 (enExample)
JP (1) JP2005522406A (enExample)
WO (1) WO2003002583A2 (enExample)

Families Citing this family (29)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE10158656A1 (de) 2001-11-30 2003-06-26 Basell Polyolefine Gmbh Organoübergangsmetallverbindung, Biscyclopentadienylligandsystem, Katalysatorsystem und Verfahren zur Herstellung von Polyolefinen
EP1664139A1 (en) * 2003-09-11 2006-06-07 Basell Polyolefine GmbH Multistep process for preparing heterophasic propylene copolymers
KR100756179B1 (ko) * 2006-01-09 2007-09-05 주식회사 팬택 능동형 알에프아이디 트랜스폰더를 내장한 이동통신 단말기
AU2007211498A1 (en) * 2006-02-02 2007-08-09 Basell Polyolefine Gmbh Propylene melt blown resins, propylene melt blown resin fibers and non-woven fabric made from the same, and methods of making the same
BRPI0722162A2 (pt) 2007-10-25 2014-03-18 Lummus Novolen Technology Gmbh Compostos de metaloceno, catalisadores compreendendo os mesmos, processo para produzir um polímero de olefina pelo uso de catalisadores, e homo-e copolímeros de olefina.
WO2009054833A2 (en) 2007-10-25 2009-04-30 Novolen Technology Holdings, C.V. Metallocene compounds, catalysts comprising them, process for producing an olefin polymer by use of the catalysts, and olefin homo and copolymers
JP5966321B2 (ja) * 2010-11-19 2016-08-10 日本ポリプロ株式会社 メタロセン錯体およびオレフィンの重合方法
JP5880000B2 (ja) * 2011-12-14 2016-03-08 日本ポリプロ株式会社 メタロセン錯体およびオレフィンの重合方法
EP3022236B1 (en) 2013-07-17 2017-11-15 ExxonMobil Chemical Patents Inc. Process using substituted metallocene catalysts and products therefrom
SG10201802959WA (en) 2013-07-17 2018-05-30 Exxonmobil Chemical Patents Inc Cyclopropyl substituted metallocene catalysts
US9938364B2 (en) 2013-07-17 2018-04-10 Exxonmobil Chemical Patents Inc. Substituted metallocene catalysts
CN110845546A (zh) 2013-07-17 2020-02-28 埃克森美孚化学专利公司 取代的茂金属催化剂
US9249239B2 (en) 2013-07-17 2016-02-02 Exxonmobil Chemical Patents Inc. Metallocenes and catalyst compositions derived therefrom
ES2703344T3 (es) 2013-07-17 2019-03-08 Exxonmobil Chemical Patents Inc Metalocenos y composiciones catalíticas derivadas de ellos
US10280233B2 (en) 2015-06-05 2019-05-07 Exxonmobil Chemical Patents Inc. Catalyst systems and methods of making and using the same
EP3303423A1 (en) 2015-06-05 2018-04-11 ExxonMobil Chemical Patents Inc. Single reactor production of polymers in gas or slurry phase
US10329360B2 (en) 2015-06-05 2019-06-25 Exxonmobil Chemical Patents Inc. Catalyst system comprising supported alumoxane and unsupported alumoxane particles
US10294316B2 (en) 2015-06-05 2019-05-21 Exxonmobil Chemical Patents Inc. Silica supports with high aluminoxane loading capability
EP3303422B1 (en) 2015-06-05 2021-03-17 ExxonMobil Chemical Patents Inc. Production of heterophasic polymers in gas or slurry phase
US10723821B2 (en) 2015-06-05 2020-07-28 Exxonmobil Chemical Patents Inc. Supported metallocene catalyst systems for polymerization
US9809664B2 (en) 2015-06-05 2017-11-07 Exxonmobil Chemical Patents Inc. Bimodal propylene polymers and sequential polymerization
US10280235B2 (en) 2015-06-05 2019-05-07 Exxonmobil Chemical Patents Inc. Catalyst system containing high surface area supports and sequential polymerization to produce heterophasic polymers
EP3464390A1 (en) 2016-05-27 2019-04-10 ExxonMobil Chemical Patents Inc. Metallocene catalyst compositions and polymerization process therewith
US10807998B2 (en) 2017-01-13 2020-10-20 Exxonmobil Chemical Patents Inc. Bridged bis(indenyl) transitional metal complexes, production, and use thereof
WO2018132247A2 (en) * 2017-01-13 2018-07-19 Exxonmobil Chemical Patents Inc. Bridged bis(indenyl) transitional metal complexes, production, and use thereof
KR102338106B1 (ko) * 2017-12-20 2021-12-09 주식회사 엘지화학 혼성 담지 메탈로센 촉매 및 이를 이용한 폴리올레핀의 제조 방법
CN118184711A (zh) * 2022-12-14 2024-06-14 中国石油天然气股份有限公司 茂金属催化剂的制备方法
EP4743470A1 (en) 2023-07-14 2026-05-20 Borealis GmbH Catalysts for Olefin Polymerization
EP4743473A1 (en) 2023-07-14 2026-05-20 Borealis GmbH Catalysts for Olefin Polymerization

Family Cites Families (54)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4808561A (en) 1985-06-21 1989-02-28 Exxon Chemical Patents Inc. Supported polymerization catalyst
US4665208A (en) 1985-07-11 1987-05-12 Exxon Chemical Patents Inc. Process for the preparation of alumoxanes
US4701432A (en) 1985-11-15 1987-10-20 Exxon Chemical Patents Inc. Supported polymerization catalyst
DE3782243T2 (de) 1986-08-26 1993-03-04 Mitsui Petrochemical Ind Katalysator zur polymerisierung von alpha-olefin und verfahren.
DE3750818T2 (de) 1986-09-24 1995-04-20 Mitsui Petrochemical Industries, Ltd., Tokio/Tokyo Verfahren zur Polymerisation von Polyolefinen.
JPH0780933B2 (ja) 1986-11-20 1995-08-30 三井石油化学工業株式会社 オレフインの重合方法
JP2618384B2 (ja) 1986-12-27 1997-06-11 三井石油化学工業株式会社 オレフイン重合用固体触媒およびその製法
EP0295312B1 (en) 1986-12-30 1994-04-20 Mitsui Petrochemical Industries, Ltd. Solid catalyst for olefin polymerization and process for its preparation
IL85097A (en) 1987-01-30 1992-02-16 Exxon Chemical Patents Inc Catalysts based on derivatives of a bis(cyclopentadienyl)group ivb metal compound,their preparation and their use in polymerization processes
PL276385A1 (en) 1987-01-30 1989-07-24 Exxon Chemical Patents Inc Method for polymerization of olefines,diolefins and acetylene unsaturated compounds
US5198401A (en) 1987-01-30 1993-03-30 Exxon Chemical Patents Inc. Ionic metallocene catalyst compositions
JPH0742301B2 (ja) 1987-02-14 1995-05-10 三井石油化学工業株式会社 微粒子状アルミノオキサン、その製法およびその用途
JP2538588B2 (ja) 1987-04-03 1996-09-25 三井石油化学工業株式会社 オレフイン重合用固体触媒の製法
US5206199A (en) 1987-04-20 1993-04-27 Mitsui Petrochemical Industries, Ltd. Catalyst for polymerizing an olefin and process for polymerizing an olefin
DE68919156T3 (de) 1988-08-05 2002-08-14 Fina Technology, Inc. Verfahren zur Herstellung grosser symmetrischer Polymerteilchen.
US5091352A (en) 1988-09-14 1992-02-25 Mitsui Petrochemical Industries, Ltd. Olefin polymerization catalyst component, olefin polymerization catalyst and process for the polymerization of olefins
US4908463A (en) 1988-12-05 1990-03-13 Ethyl Corporation Aluminoxane process
US5103031A (en) 1989-02-21 1992-04-07 Ethyl Corporation Falling film aluminoxane process
US4968827A (en) 1989-06-06 1990-11-06 Ethyl Corporation Alkylaluminoxane process
US4924018A (en) 1989-06-26 1990-05-08 Ethyl Corporation Alkylaluminoxane process
US5763549A (en) 1989-10-10 1998-06-09 Fina Technology, Inc. Cationic metallocene catalysts based on organoaluminum anions
CA2027123C (en) 1989-10-30 2001-09-04 Michael J. Elder Metallocene catalysts for polymerization of olefins
EP0672689A1 (en) 1990-06-22 1995-09-20 Exxon Chemical Patents Inc. Aluminum-free monocyclopentadienyl metallocene catalysts for olefin polymerization
CA2066247C (en) 1990-07-24 1998-09-15 Ryuichi Sugimoto Polymerization catalyst for .alpha.-olefin and method for preparing poly-.alpha.-olefin by using it
US5189192A (en) 1991-01-16 1993-02-23 The Dow Chemical Company Process for preparing addition polymerization catalysts via metal center oxidation
US5721185A (en) 1991-06-24 1998-02-24 The Dow Chemical Company Homogeneous olefin polymerization catalyst by abstraction with lewis acids
US5308815A (en) 1991-07-26 1994-05-03 Ethyl Corporation Heterogeneous methylaluminoxane catalyst system
US5235081A (en) 1992-03-18 1993-08-10 Ethyl Corporation Method of removing gel forming materials from methylaluminoxanes
US5329032A (en) 1992-03-18 1994-07-12 Akzo Chemicals Inc. Polymethylaluminoxane of enhanced solution stability
US5240894A (en) 1992-05-18 1993-08-31 Exxon Chemical Patents Inc. Method for making and using a supported metallocene catalyst system
US5434115A (en) 1992-05-22 1995-07-18 Tosoh Corporation Process for producing olefin polymer
TW294669B (enExample) 1992-06-27 1997-01-01 Hoechst Ag
US5248801A (en) 1992-08-27 1993-09-28 Ethyl Corporation Preparation of methylaluminoxanes
FI951548A7 (fi) 1992-10-02 1995-05-29 Dow Global Technologies Inc Kantajalla olevia homogeenisia katalysaattorikomplekseja olefiinipolymerointia varten
US5939346A (en) 1992-11-02 1999-08-17 Akzo Nobel N.V. Catalyst system comprising an aryloxyaluminoxane containing an electron withdrawing group
DE69408989T2 (de) 1993-05-25 1998-11-05 Exxon Chemical Patents Inc Metallocen-katalysatorsysteme auf einem träger für die olefinpolymerisation, ihre herstellung und verwendung
DE69427999T3 (de) 1993-06-07 2012-09-27 Mitsui Chemicals, Inc. Übergangsmetallverbindung, diese enthaltende Olefinpolymerisationskatalysator, Verfahren zur Olefinpolymerisation damit und Homo- und Copolymere des Propylens
JP3699479B2 (ja) 1994-06-24 2005-09-28 エクソンモービル・ケミカル・パテンツ・インク 重合触媒系、それらの製造及び使用
EP0766700B1 (en) 1994-06-24 2000-01-19 Exxon Chemical Patents Inc. Polymerization catalyst systems, their production and use
US5643847A (en) 1994-08-03 1997-07-01 Exxon Chemical Patents Inc. Supported ionic catalyst composition
AU687231B2 (en) 1994-08-03 1998-02-19 Exxon Chemical Patents Inc. Supported ionic catalyst composition
DE69738304T2 (de) * 1996-12-09 2008-09-18 Mitsubishi Chemical Corp. Katalysator zur Alpha-Olefinpolymerisation
US5789634A (en) 1997-02-05 1998-08-04 Boulder Scientific Company Coupling reactions of 2-substituted, 7-haloindenes with aryl substituents to produce metallocene catalyst intermediates
AU7332398A (en) 1997-03-07 1998-09-29 Targor Gmbh Method for producing olefin polymers with a higher melting point
ES2247681T3 (es) * 1997-03-07 2006-03-01 Basell Polyolefine Gmbh Metodo para preparar indanonas sustituidas y metalocenos preparados a partir de ellas.
DE19739946A1 (de) * 1997-09-11 1999-03-18 Targor Gmbh Verfahren zur Herstellung von Metallocenen
US6001766A (en) 1997-12-24 1999-12-14 Mobil Oil Corporation Bimetallic catalysts for ethylene polymerization reactions activated with paraffin-soluble alkylalumoxanes
DE19806918A1 (de) 1998-02-19 1999-08-26 Aventis Res & Tech Gmbh & Co Katalysatorsystem, Verfahren zu seiner Herstellung und seine Verwendung zur Polymerisation von Olefinen
BR9908171A (pt) 1998-03-27 2000-10-31 Exxon Chemical Patents Inc Catalizadores poliméricos suportados para polimerização de olefinas
DE19813656A1 (de) * 1998-03-27 1999-09-30 Aventis Res & Tech Gmbh & Co Übergangsmetallverbindung
DE19813657A1 (de) * 1998-03-27 1999-09-30 Aventis Res & Tech Gmbh & Co Katalysatorsystem, Verfahren zu seiner Herstellung und seine Verwendung zur Polymerisation von Olefinen
US6500949B2 (en) 1998-10-08 2002-12-31 Dow Global Technologies Inc. Bridged metal complexes
US6492465B1 (en) 2000-02-08 2002-12-10 Exxonmobil Chemical Patents, Inc. Propylene impact copolymers
ES2247473T3 (es) * 2000-06-30 2006-03-01 Exxonmobil Chemical Patents Inc. Composiciones de bis-indenil-metaloceno puenteadas.

Similar Documents

Publication Publication Date Title
US6316562B1 (en) Catalyst systems for (co-)polymerization reactions, metallocene amide halogenides, the production and use thereof
US20030008767A1 (en) Metallocene compositions
US6355819B1 (en) Substituted metallocene compounds for olefin polymerization catalyst systems, their intermediates and methods for preparing them
JP2003520869A5 (enExample)
EP0872492A3 (en) Transition metal compound as catalyst component for polymerization, aromatic vinyl compound-olefin copolymer having stereoregularity and method for its preparation by means of the transition metal compound as catalyst component
ATE334135T1 (de) Metallocene und verfahren zur herstellung von propylenpolymeren
JP2001519443A5 (enExample)
JP2002535416A5 (enExample)
JP2009526034A5 (enExample)
JP2001072695A5 (enExample)
JP2003519156A5 (ja) メタロセン化合物、リガンド、触媒、ポリマーの製造方法及びプロピレンホモポリマー
JP2003518530A5 (ja) エチレンポリマー類の製造方法およびメタロセン化合物
JP2004502698A5 (enExample)
EG25084A (en) Improved synthesis of ansa-metallocene and their parent ligands in high yield.
JP2004528421A5 (enExample)
HUP0001331A2 (hu) Metallocének, áthidalt ligandumok, olefinpolimerizációs katalizátorok és eljárás olefinek polimerizálására
JP2020503341A5 (enExample)
JP2009534489A5 (enExample)
JP2004532346A5 (enExample)
JP2002530286A5 (enExample)
JPH093084A (ja) 遷移金属化合物
Nifant’ev et al. Novel Effective Racemoselective Method for the Synthesis of ansa-Zirconocenes and Its Use for the Preparation of C 2-Symmetric Complexes Based on 2-Methyl-4-aryltetrahydro (s) indacene as Catalysts for Isotactic Propylene Polymerization and Ethylene–Propylene Copolymerization
JP2004531529A5 (enExample)
KR960022548A (ko) 메탈로센 화합물 및 촉매 성분으로의 이의 용도
JPH11315089A (ja) 有機金属化合物