JP2004531529A5 - - Google Patents
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- JP2004531529A5 JP2004531529A5 JP2002581454A JP2002581454A JP2004531529A5 JP 2004531529 A5 JP2004531529 A5 JP 2004531529A5 JP 2002581454 A JP2002581454 A JP 2002581454A JP 2002581454 A JP2002581454 A JP 2002581454A JP 2004531529 A5 JP2004531529 A5 JP 2004531529A5
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- Japan
- Prior art keywords
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- formula
- compound
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- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000000460 chlorine Substances 0.000 claims 11
- 150000001875 compounds Chemical class 0.000 claims 10
- 229910052801 chlorine Inorganic materials 0.000 claims 9
- -1 4-tertbutyl-cyclopentadienyl Chemical group 0.000 claims 8
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims 8
- 229910052794 bromium Inorganic materials 0.000 claims 7
- 238000000034 method Methods 0.000 claims 7
- 239000000203 mixture Substances 0.000 claims 7
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims 6
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims 6
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims 6
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 claims 5
- 150000001342 alkaline earth metals Chemical class 0.000 claims 5
- 125000003118 aryl group Chemical group 0.000 claims 5
- 229910052740 iodine Inorganic materials 0.000 claims 5
- 239000011630 iodine Substances 0.000 claims 5
- 239000003446 ligand Substances 0.000 claims 5
- 239000003795 chemical substances by application Substances 0.000 claims 4
- 230000002140 halogenating effect Effects 0.000 claims 4
- 239000011777 magnesium Substances 0.000 claims 4
- 229920006395 saturated elastomer Polymers 0.000 claims 4
- 229910052710 silicon Inorganic materials 0.000 claims 4
- 239000003513 alkali Substances 0.000 claims 3
- 229910052783 alkali metal Inorganic materials 0.000 claims 3
- 150000001340 alkali metals Chemical group 0.000 claims 3
- 125000002877 alkyl aryl group Chemical group 0.000 claims 3
- 125000003710 aryl alkyl group Chemical group 0.000 claims 3
- 229910052799 carbon Inorganic materials 0.000 claims 3
- 125000000753 cycloalkyl group Chemical group 0.000 claims 3
- 229910052732 germanium Inorganic materials 0.000 claims 3
- 229910052739 hydrogen Inorganic materials 0.000 claims 3
- 239000001257 hydrogen Substances 0.000 claims 3
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims 2
- 125000000217 alkyl group Chemical group 0.000 claims 2
- 125000000058 cyclopentadienyl group Chemical group C1(=CC=CC1)* 0.000 claims 2
- 125000005842 heteroatom Chemical group 0.000 claims 2
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims 2
- 229910052749 magnesium Inorganic materials 0.000 claims 2
- 238000004519 manufacturing process Methods 0.000 claims 2
- 229910052757 nitrogen Inorganic materials 0.000 claims 2
- 230000000737 periodic effect Effects 0.000 claims 2
- 229910052698 phosphorus Inorganic materials 0.000 claims 2
- YBYIRNPNPLQARY-UHFFFAOYSA-N 1H-indene Natural products C1=CC=C2CC=CC2=C1 YBYIRNPNPLQARY-UHFFFAOYSA-N 0.000 claims 1
- 229910021591 Copper(I) chloride Inorganic materials 0.000 claims 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 1
- 229910003902 SiCl 4 Inorganic materials 0.000 claims 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical group [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical group [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims 1
- 229910007926 ZrCl Inorganic materials 0.000 claims 1
- 125000001931 aliphatic group Chemical group 0.000 claims 1
- 125000004429 atom Chemical group 0.000 claims 1
- 125000004432 carbon atom Chemical group C* 0.000 claims 1
- OXBLHERUFWYNTN-UHFFFAOYSA-M copper(I) chloride Chemical compound [Cu]Cl OXBLHERUFWYNTN-UHFFFAOYSA-M 0.000 claims 1
- ZSWFCLXCOIISFI-UHFFFAOYSA-N endo-cyclopentadiene Natural products C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 claims 1
- 125000003983 fluorenyl group Chemical group C1(=CC=CC=2C3=CC=CC=C3CC12)* 0.000 claims 1
- 229910052735 hafnium Chemical group 0.000 claims 1
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical group [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 claims 1
- 125000003454 indenyl group Chemical group C1(C=CC2=CC=CC=C12)* 0.000 claims 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 claims 1
- 229910052751 metal Inorganic materials 0.000 claims 1
- 239000002184 metal Substances 0.000 claims 1
- 229910052760 oxygen Inorganic materials 0.000 claims 1
- RLOWWWKZYUNIDI-UHFFFAOYSA-N phosphinic chloride Chemical compound ClP=O RLOWWWKZYUNIDI-UHFFFAOYSA-N 0.000 claims 1
- 238000000746 purification Methods 0.000 claims 1
- 239000000376 reactant Substances 0.000 claims 1
- 239000011541 reaction mixture Substances 0.000 claims 1
- 125000001424 substituent group Chemical group 0.000 claims 1
- 229910052717 sulfur Inorganic materials 0.000 claims 1
- 229910052719 titanium Inorganic materials 0.000 claims 1
- 239000010936 titanium Chemical group 0.000 claims 1
- 125000004417 unsaturated alkyl group Chemical group 0.000 claims 1
- 229910052726 zirconium Inorganic materials 0.000 claims 1
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP01201327 | 2001-04-10 | ||
| PCT/EP2002/003697 WO2002083699A2 (en) | 2001-04-10 | 2002-04-03 | Process for the production of monohalide or dihalide metallocene compounds |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2004531529A JP2004531529A (ja) | 2004-10-14 |
| JP2004531529A5 true JP2004531529A5 (enExample) | 2005-12-22 |
| JP3986441B2 JP3986441B2 (ja) | 2007-10-03 |
Family
ID=8180134
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2002581454A Expired - Lifetime JP3986441B2 (ja) | 2001-04-10 | 2002-04-03 | モノハライドまたはジハライドメタロセン化合物の製造方法 |
Country Status (6)
| Country | Link |
|---|---|
| US (2) | US6987196B2 (enExample) |
| EP (1) | EP1381618B1 (enExample) |
| JP (1) | JP3986441B2 (enExample) |
| AT (1) | ATE394407T1 (enExample) |
| DE (1) | DE60226427D1 (enExample) |
| WO (1) | WO2002083699A2 (enExample) |
Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4332029B2 (ja) * | 2001-06-12 | 2009-09-16 | バーゼル・ポリオレフィン・ゲーエムベーハー | １−ブテンの重合方法 |
| JP4571798B2 (ja) * | 2001-06-12 | 2010-10-27 | バーゼル・ポリオレフィン・ゲーエムベーハー | １−ブテンの重合方法 |
| WO2003000706A1 (en) | 2001-06-22 | 2003-01-03 | Basell Polyolefine Gmbh | Metallocenes, use in catalyst systems for producing olefin polymers |
| EP1448578B1 (en) | 2001-11-30 | 2006-07-26 | Basell Polyolefine GmbH | Metallocene compounds and process for the preparation of propylene polymers |
| ATE445651T1 (de) * | 2002-09-06 | 2009-10-15 | Basell Polyolefine Gmbh | Verfahren zur copolymerisation von ethylen |
| DE60329523D1 (de) * | 2002-12-04 | 2009-11-12 | Basell Polyolefine Gmbh | 1-Buten-Copolymere und Herstellungsverfahren dafür |
| US7589160B2 (en) * | 2002-12-04 | 2009-09-15 | Basell Polyolefine Gmbh | Process for preparing 1-butene polymers |
| RU2335504C2 (ru) * | 2003-05-08 | 2008-10-10 | Базелль Полиолефине Гмбх | Способ получения галогенидметаллоценовых соединений |
| CN100448883C (zh) | 2003-09-29 | 2009-01-07 | 巴塞尔聚烯烃股份有限公司 | 金属茂化合物的异构化方法 |
| SG11201700464RA (en) * | 2014-07-21 | 2017-02-27 | Tinymos Private Ltd | Image capturing device and method |
| US9796795B2 (en) | 2015-01-14 | 2017-10-24 | Exxonmobil Chemical Patents Inc. | Tetrahydroindacenyl catalyst composition, catalyst system, and processes for use thereof |
| CN107636029B (zh) | 2015-04-20 | 2020-05-22 | 埃克森美孚化学专利公司 | 包含氟化载体的催化剂组合物及其使用方法 |
| US10717790B2 (en) | 2015-04-20 | 2020-07-21 | Exxonmobil Chemical Patents Inc. | Catalyst composition comprising fluorided support and processes for use thereof |
| US9803037B1 (en) | 2016-05-03 | 2017-10-31 | Exxonmobil Chemical Patents Inc. | Tetrahydro-as-indacenyl catalyst composition, catalyst system, and processes for use thereof |
| US10703838B2 (en) | 2017-10-31 | 2020-07-07 | Exxonmobil Chemical Patents Inc. | Mixed catalyst systems with four metallocenes on a single support |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ZA844157B (en) | 1983-06-06 | 1986-01-29 | Exxon Research Engineering Co | Process and catalyst for polyolefin density and molecular weight control |
| TW294669B (enExample) * | 1992-06-27 | 1997-01-01 | Hoechst Ag | |
| ES2166465T3 (es) | 1995-09-07 | 2002-04-16 | Merck & Co Inc | Procedimiento para la preparacion de dimetiltitanoceno. |
| JP3694371B2 (ja) | 1996-10-04 | 2005-09-14 | 関東化学株式会社 | メタロセン化合物の新規な合成方法 |
| JP3228328B2 (ja) | 1996-12-25 | 2001-11-12 | 日亜化学工業株式会社 | メタロセン化合物の合成方法 |
| WO1998057996A1 (en) | 1997-06-14 | 1998-12-23 | The Board Of Trustees Of The Leland Stanford, Jr. University | ETHYLENE ENHANCEMENT OF PROCESSES FOR SYNTHESIS OF HIGH MELTING THERMOPLASTIC ELASTOMERIC α-OLEFIN POLYMERS (PRE/EPE EFFECTS) |
| JP4208265B2 (ja) | 1998-01-14 | 2009-01-14 | バセル テクノロジー カンパニー ベスローテン フェンノートシャップ | メタロセン化合物の製造方法 |
| JP2003501436A (ja) | 1999-06-04 | 2003-01-14 | バセル テクノロジー カンパニー ビー．ブイ． | チタン錯体の製造法 |
| US6730754B2 (en) | 2000-01-18 | 2004-05-04 | Basell Polyolefine Gmbh | Process for producing substantially amorphous propylene-based polymers |
| JP2002088092A (ja) | 2000-09-12 | 2002-03-27 | Kanto Chem Co Inc | 新規な有機金属錯体及びこれを中間体とした高純度有機金属錯体の合成方法 |
-
2002
- 2002-04-03 AT AT02745208T patent/ATE394407T1/de not_active IP Right Cessation
- 2002-04-03 JP JP2002581454A patent/JP3986441B2/ja not_active Expired - Lifetime
- 2002-04-03 EP EP02745208A patent/EP1381618B1/en not_active Expired - Lifetime
- 2002-04-03 DE DE60226427T patent/DE60226427D1/de not_active Expired - Lifetime
- 2002-04-03 WO PCT/EP2002/003697 patent/WO2002083699A2/en not_active Ceased
- 2002-04-03 US US10/474,596 patent/US6987196B2/en not_active Expired - Lifetime
-
2005
- 2005-09-27 US US11/237,588 patent/US7115761B2/en not_active Expired - Lifetime
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