JP2006503887A5 - - Google Patents
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- Publication number
- JP2006503887A5 JP2006503887A5 JP2004545930A JP2004545930A JP2006503887A5 JP 2006503887 A5 JP2006503887 A5 JP 2006503887A5 JP 2004545930 A JP2004545930 A JP 2004545930A JP 2004545930 A JP2004545930 A JP 2004545930A JP 2006503887 A5 JP2006503887 A5 JP 2006503887A5
- Authority
- JP
- Japan
- Prior art keywords
- alkyl
- aryl
- different
- same
- cycloalkyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 125000000217 alkyl group Chemical group 0.000 claims 22
- 125000000753 cycloalkyl group Chemical group 0.000 claims 17
- 125000004432 carbon atom Chemical group C* 0.000 claims 12
- 229910052739 hydrogen Inorganic materials 0.000 claims 12
- 239000001257 hydrogen Substances 0.000 claims 12
- 150000002431 hydrogen Chemical class 0.000 claims 8
- 125000000008 (C1-C10) alkyl group Chemical group 0.000 claims 7
- 125000001424 substituent group Chemical group 0.000 claims 7
- 125000002877 alkyl aryl group Chemical group 0.000 claims 6
- 125000003710 aryl alkyl group Chemical group 0.000 claims 6
- 125000003118 aryl group Chemical group 0.000 claims 6
- 150000001875 compounds Chemical class 0.000 claims 6
- 229910052794 bromium Inorganic materials 0.000 claims 4
- 229910052801 chlorine Inorganic materials 0.000 claims 4
- 239000000460 chlorine Substances 0.000 claims 4
- 125000004122 cyclic group Chemical group 0.000 claims 4
- 229910052731 fluorine Inorganic materials 0.000 claims 4
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims 3
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims 3
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 claims 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 3
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims 3
- 239000003054 catalyst Substances 0.000 claims 3
- 239000011737 fluorine Substances 0.000 claims 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical group [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims 2
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical group [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims 2
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical group [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims 2
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical group [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims 2
- 229910001413 alkali metal ion Inorganic materials 0.000 claims 2
- 229910052799 carbon Inorganic materials 0.000 claims 2
- 239000003795 chemical substances by application Substances 0.000 claims 2
- 229910052804 chromium Inorganic materials 0.000 claims 2
- 239000011651 chromium Chemical group 0.000 claims 2
- 229910052732 germanium Inorganic materials 0.000 claims 2
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 claims 2
- 229910052735 hafnium Inorganic materials 0.000 claims 2
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical group [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 claims 2
- 125000005842 heteroatom Chemical group 0.000 claims 2
- PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical compound II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 claims 2
- 229910052747 lanthanoid Inorganic materials 0.000 claims 2
- 150000002602 lanthanoids Chemical class 0.000 claims 2
- -1 methoxy, ethoxy, isopropyloxy, tert-butyloxy, cyclopropyloxy Chemical group 0.000 claims 2
- 229910052750 molybdenum Inorganic materials 0.000 claims 2
- 239000011733 molybdenum Chemical group 0.000 claims 2
- 229910052758 niobium Inorganic materials 0.000 claims 2
- 239000010955 niobium Chemical group 0.000 claims 2
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical group [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 claims 2
- 230000000737 periodic effect Effects 0.000 claims 2
- 229910052710 silicon Inorganic materials 0.000 claims 2
- 239000010703 silicon Substances 0.000 claims 2
- 229910052715 tantalum Inorganic materials 0.000 claims 2
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical group [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 claims 2
- 229910052718 tin Inorganic materials 0.000 claims 2
- 239000010936 titanium Substances 0.000 claims 2
- 229910052719 titanium Inorganic materials 0.000 claims 2
- 230000007704 transition Effects 0.000 claims 2
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical group [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims 2
- 229910052721 tungsten Inorganic materials 0.000 claims 2
- 239000010937 tungsten Chemical group 0.000 claims 2
- 229910052720 vanadium Inorganic materials 0.000 claims 2
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical group [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 claims 2
- 229910052726 zirconium Inorganic materials 0.000 claims 2
- 229910052783 alkali metal Inorganic materials 0.000 claims 1
- 150000001340 alkali metals Chemical class 0.000 claims 1
- 229910001420 alkaline earth metal ion Inorganic materials 0.000 claims 1
- 230000015572 biosynthetic process Effects 0.000 claims 1
- 239000003153 chemical reaction reagent Substances 0.000 claims 1
- 238000010924 continuous production Methods 0.000 claims 1
- 125000002933 cyclohexyloxy group Chemical group C1(CCCCC1)O* 0.000 claims 1
- 230000005595 deprotonation Effects 0.000 claims 1
- 238000010537 deprotonation reaction Methods 0.000 claims 1
- 150000002367 halogens Chemical group 0.000 claims 1
- 238000010438 heat treatment Methods 0.000 claims 1
- 229910052740 iodine Inorganic materials 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 claims 1
- 238000000034 method Methods 0.000 claims 1
- 239000000203 mixture Substances 0.000 claims 1
- 238000006116 polymerization reaction Methods 0.000 claims 1
- 230000000707 stereoselective effect Effects 0.000 claims 1
- 238000003786 synthesis reaction Methods 0.000 claims 1
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE2002150061 DE10250061A1 (de) | 2002-10-25 | 2002-10-25 | Verfahren zur racemoselektiven Darstellung von isolierbaren ansa-Metallocenbiphenolatkomplexen mit kürzeren Isomerisierungszeiten |
| US43220202P | 2002-12-10 | 2002-12-10 | |
| PCT/EP2003/011680 WO2004037839A1 (en) | 2002-10-25 | 2003-10-22 | Racemoselective preparation of isolable ansa-metallocene biphenoxide complexes |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2006503887A JP2006503887A (ja) | 2006-02-02 |
| JP2006503887A5 true JP2006503887A5 (enExample) | 2006-12-07 |
| JP4571500B2 JP4571500B2 (ja) | 2010-10-27 |
Family
ID=32178283
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2004545930A Expired - Lifetime JP4571500B2 (ja) | 2002-10-25 | 2003-10-22 | 比較的短い時間で異性化を可能にするアンサ−メタロセンビフェノキシドのラセモ選択的製造 |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US7193099B2 (enExample) |
| EP (1) | EP1554296B1 (enExample) |
| JP (1) | JP4571500B2 (enExample) |
| AT (1) | ATE411329T1 (enExample) |
| AU (1) | AU2003283286A1 (enExample) |
| DE (1) | DE60324172D1 (enExample) |
| RU (1) | RU2329272C2 (enExample) |
| WO (1) | WO2004037839A1 (enExample) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE10250025A1 (de) * | 2002-10-25 | 2004-05-06 | Basell Polyolefine Gmbh | Verfahren zur Darstellung teilweise hydrierter rac-ansa-Metallocen-Komplexe |
| KR20060028603A (ko) | 2004-09-25 | 2006-03-30 | 주식회사 엘지화학 | 안사-메탈로센 화합물, 그 제조방법 및 이를 이용한폴리올레핀의 제조방법 |
| BR112016019334B1 (pt) | 2014-02-11 | 2021-03-09 | Univation Technologies, Llc | método para formar uma composição de catalisador |
| KR101795748B1 (ko) | 2015-06-15 | 2017-12-01 | 주식회사 엘지화학 | 폴리올레핀의 제조 방법 |
| WO2020009802A1 (en) * | 2018-07-03 | 2020-01-09 | Exxonmobil Chemical Patents Inc. | Metallocene synthesis process |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4380676A (en) | 1980-02-29 | 1983-04-19 | Ciba-Geigy Corporation | Process for the production of 2,2'-dihydroxy-biphenyls |
| DE3844282A1 (de) | 1988-12-30 | 1990-07-05 | Hoechst Ag | Bisindenyl-derivat und verfahren zu seiner herstellung |
| FR2646855B1 (fr) | 1989-05-12 | 1993-03-12 | Bp Chem Int Ltd | Procede de fabrication de nouveaux polymeres silicones, et produits intermediaires obtenus |
| ATE136878T1 (de) | 1990-11-21 | 1996-05-15 | Massachusetts Inst Technology | Neue methoden zur katalytischen reduktion organischer substrate |
| DE4431837A1 (de) | 1994-09-07 | 1996-03-14 | Basf Ag | Geträgerte Metallocen-Katalysatorsysteme |
| DE19741876A1 (de) * | 1997-09-23 | 1999-03-25 | Basf Ag | Verfahren zur selektiven Herstellung racemischer Metallocenkomplexe |
| DE10030638A1 (de) | 2000-06-29 | 2002-01-10 | Basell Polyolefine Gmbh | Verfahren zur selektiven Herstellung racemischer Metallocenkomplexe |
-
2003
- 2003-10-22 AU AU2003283286A patent/AU2003283286A1/en not_active Abandoned
- 2003-10-22 US US10/532,570 patent/US7193099B2/en not_active Expired - Lifetime
- 2003-10-22 WO PCT/EP2003/011680 patent/WO2004037839A1/en not_active Ceased
- 2003-10-22 RU RU2005115872/04A patent/RU2329272C2/ru not_active IP Right Cessation
- 2003-10-22 DE DE60324172T patent/DE60324172D1/de not_active Expired - Lifetime
- 2003-10-22 EP EP03775211A patent/EP1554296B1/en not_active Expired - Lifetime
- 2003-10-22 JP JP2004545930A patent/JP4571500B2/ja not_active Expired - Lifetime
- 2003-10-22 AT AT03775211T patent/ATE411329T1/de not_active IP Right Cessation
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