JP2002533495A - グリシドールに基づく高分岐ポリオールの製造方法 - Google Patents
グリシドールに基づく高分岐ポリオールの製造方法Info
- Publication number
- JP2002533495A JP2002533495A JP2000589598A JP2000589598A JP2002533495A JP 2002533495 A JP2002533495 A JP 2002533495A JP 2000589598 A JP2000589598 A JP 2000589598A JP 2000589598 A JP2000589598 A JP 2000589598A JP 2002533495 A JP2002533495 A JP 2002533495A
- Authority
- JP
- Japan
- Prior art keywords
- polyol
- glycidol
- reaction
- glycidyl ether
- monomer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 229920005862 polyol Polymers 0.000 title claims abstract description 35
- 150000003077 polyols Chemical class 0.000 title claims abstract description 35
- CTKINSOISVBQLD-UHFFFAOYSA-N Glycidol Chemical compound OCC1CO1 CTKINSOISVBQLD-UHFFFAOYSA-N 0.000 title claims abstract description 25
- 238000000034 method Methods 0.000 title claims description 15
- 239000002904 solvent Substances 0.000 claims abstract description 20
- 239000003054 catalyst Substances 0.000 claims abstract description 11
- 239000007858 starting material Substances 0.000 claims abstract description 11
- 238000004519 manufacturing process Methods 0.000 claims abstract description 9
- 238000004821 distillation Methods 0.000 claims abstract description 7
- 238000006243 chemical reaction Methods 0.000 claims description 22
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 claims description 16
- 238000006116 polymerization reaction Methods 0.000 claims description 15
- 239000000178 monomer Substances 0.000 claims description 14
- 239000000203 mixture Substances 0.000 claims description 11
- 238000006555 catalytic reaction Methods 0.000 claims description 7
- 150000002118 epoxides Chemical class 0.000 claims description 6
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 claims description 5
- 239000000654 additive Substances 0.000 claims description 5
- 229920002635 polyurethane Polymers 0.000 claims description 5
- 239000004814 polyurethane Substances 0.000 claims description 5
- GXBYFVGCMPJVJX-UHFFFAOYSA-N Epoxybutene Chemical compound C=CC1CO1 GXBYFVGCMPJVJX-UHFFFAOYSA-N 0.000 claims description 4
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 4
- 239000004480 active ingredient Substances 0.000 claims description 4
- 239000000853 adhesive Substances 0.000 claims description 4
- 230000001070 adhesive effect Effects 0.000 claims description 4
- 229920000249 biocompatible polymer Polymers 0.000 claims description 4
- 238000009472 formulation Methods 0.000 claims description 4
- 239000003973 paint Substances 0.000 claims description 4
- 229920002959 polymer blend Polymers 0.000 claims description 4
- STMDPCBYJCIZOD-UHFFFAOYSA-N 2-(2,4-dinitroanilino)-4-methylpentanoic acid Chemical compound CC(C)CC(C(O)=O)NC1=CC=C([N+]([O-])=O)C=C1[N+]([O-])=O STMDPCBYJCIZOD-UHFFFAOYSA-N 0.000 claims description 3
- 239000004971 Cross linker Substances 0.000 claims description 3
- 239000000969 carrier Substances 0.000 claims description 3
- 239000002105 nanoparticle Substances 0.000 claims description 3
- NWLUZGJDEZBBRH-UHFFFAOYSA-N 2-(propan-2-yloxymethyl)oxirane Chemical compound CC(C)OCC1CO1 NWLUZGJDEZBBRH-UHFFFAOYSA-N 0.000 claims description 2
- FQYUMYWMJTYZTK-UHFFFAOYSA-N Phenyl glycidyl ether Chemical compound C1OC1COC1=CC=CC=C1 FQYUMYWMJTYZTK-UHFFFAOYSA-N 0.000 claims description 2
- 238000007865 diluting Methods 0.000 claims description 2
- 238000001644 13C nuclear magnetic resonance spectroscopy Methods 0.000 claims 1
- 238000004458 analytical method Methods 0.000 claims 1
- 239000000243 solution Substances 0.000 abstract description 9
- 238000010790 dilution Methods 0.000 abstract description 3
- 239000012895 dilution Substances 0.000 abstract description 3
- 230000000379 polymerizing effect Effects 0.000 abstract description 2
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 38
- 239000003999 initiator Substances 0.000 description 19
- 229920000642 polymer Polymers 0.000 description 12
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 7
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 7
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 6
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 6
- 229920001400 block copolymer Polymers 0.000 description 6
- 239000011541 reaction mixture Substances 0.000 description 6
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 5
- 150000004703 alkoxides Chemical group 0.000 description 5
- SBZXBUIDTXKZTM-UHFFFAOYSA-N diglyme Chemical compound COCCOCCOC SBZXBUIDTXKZTM-UHFFFAOYSA-N 0.000 description 5
- 229910052739 hydrogen Inorganic materials 0.000 description 5
- 239000001257 hydrogen Substances 0.000 description 5
- 239000007788 liquid Substances 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- BDAWXSQJJCIFIK-UHFFFAOYSA-N potassium methoxide Chemical compound [K+].[O-]C BDAWXSQJJCIFIK-UHFFFAOYSA-N 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- REYJJPSVUYRZGE-UHFFFAOYSA-N Octadecylamine Chemical compound CCCCCCCCCCCCCCCCCCN REYJJPSVUYRZGE-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 3
- 230000002378 acidificating effect Effects 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- 239000003814 drug Substances 0.000 description 3
- 238000001914 filtration Methods 0.000 description 3
- 239000011261 inert gas Substances 0.000 description 3
- 239000000543 intermediate Substances 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- 229920001451 polypropylene glycol Polymers 0.000 description 3
- 238000001556 precipitation Methods 0.000 description 3
- 238000003786 synthesis reaction Methods 0.000 description 3
- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 2
- QUSNBJAOOMFDIB-UHFFFAOYSA-N Ethylamine Chemical compound CCN QUSNBJAOOMFDIB-UHFFFAOYSA-N 0.000 description 2
- BAVYZALUXZFZLV-UHFFFAOYSA-N Methylamine Chemical compound NC BAVYZALUXZFZLV-UHFFFAOYSA-N 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
- GLUUGHFHXGJENI-UHFFFAOYSA-N Piperazine Chemical compound C1CNCCN1 GLUUGHFHXGJENI-UHFFFAOYSA-N 0.000 description 2
- 239000002202 Polyethylene glycol Substances 0.000 description 2
- 239000004721 Polyphenylene oxide Substances 0.000 description 2
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 2
- XXROGKLTLUQVRX-UHFFFAOYSA-N allyl alcohol Chemical compound OCC=C XXROGKLTLUQVRX-UHFFFAOYSA-N 0.000 description 2
- 150000001450 anions Chemical class 0.000 description 2
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 2
- WGQKYBSKWIADBV-UHFFFAOYSA-N benzylamine Chemical compound NCC1=CC=CC=C1 WGQKYBSKWIADBV-UHFFFAOYSA-N 0.000 description 2
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- HQABUPZFAYXKJW-UHFFFAOYSA-N butan-1-amine Chemical compound CCCCN HQABUPZFAYXKJW-UHFFFAOYSA-N 0.000 description 2
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 2
- 239000003153 chemical reaction reagent Substances 0.000 description 2
- NNBZCPXTIHJBJL-UHFFFAOYSA-N decalin Chemical compound C1CCCC2CCCCC21 NNBZCPXTIHJBJL-UHFFFAOYSA-N 0.000 description 2
- 230000005595 deprotonation Effects 0.000 description 2
- 238000010537 deprotonation reaction Methods 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 239000000706 filtrate Substances 0.000 description 2
- 229920001002 functional polymer Polymers 0.000 description 2
- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 2
- 238000010348 incorporation Methods 0.000 description 2
- 239000012442 inert solvent Substances 0.000 description 2
- 239000003456 ion exchange resin Substances 0.000 description 2
- 229920003303 ion-exchange polymer Polymers 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 229920000570 polyether Polymers 0.000 description 2
- 229920001223 polyethylene glycol Polymers 0.000 description 2
- WGYKZJWCGVVSQN-UHFFFAOYSA-N propylamine Chemical compound CCCN WGYKZJWCGVVSQN-UHFFFAOYSA-N 0.000 description 2
- 238000007363 ring formation reaction Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 125000000424 1,2-diol group Chemical group 0.000 description 1
- GEYOCULIXLDCMW-UHFFFAOYSA-N 1,2-phenylenediamine Chemical compound NC1=CC=CC=C1N GEYOCULIXLDCMW-UHFFFAOYSA-N 0.000 description 1
- WZCQRUWWHSTZEM-UHFFFAOYSA-N 1,3-phenylenediamine Chemical compound NC1=CC=CC(N)=C1 WZCQRUWWHSTZEM-UHFFFAOYSA-N 0.000 description 1
- CBCKQZAAMUWICA-UHFFFAOYSA-N 1,4-phenylenediamine Chemical compound NC1=CC=C(N)C=C1 CBCKQZAAMUWICA-UHFFFAOYSA-N 0.000 description 1
- GIEMHYCMBGELGY-UHFFFAOYSA-N 10-undecen-1-ol Chemical compound OCCCCCCCCCC=C GIEMHYCMBGELGY-UHFFFAOYSA-N 0.000 description 1
- DWOBGCPUQNFAFB-UHFFFAOYSA-N 2-benzylaniline Chemical compound NC1=CC=CC=C1CC1=CC=CC=C1 DWOBGCPUQNFAFB-UHFFFAOYSA-N 0.000 description 1
- JBIJLHTVPXGSAM-UHFFFAOYSA-N 2-naphthylamine Chemical compound C1=CC=CC2=CC(N)=CC=C21 JBIJLHTVPXGSAM-UHFFFAOYSA-N 0.000 description 1
- YBRVSVVVWCFQMG-UHFFFAOYSA-N 4,4'-diaminodiphenylmethane Chemical compound C1=CC(N)=CC=C1CC1=CC=C(N)C=C1 YBRVSVVVWCFQMG-UHFFFAOYSA-N 0.000 description 1
- WDTRNCFZFQIWLM-UHFFFAOYSA-N 4-benzylaniline Chemical compound C1=CC(N)=CC=C1CC1=CC=CC=C1 WDTRNCFZFQIWLM-UHFFFAOYSA-N 0.000 description 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 1
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 1
- BWLUMTFWVZZZND-UHFFFAOYSA-N Dibenzylamine Chemical compound C=1C=CC=CC=1CNCC1=CC=CC=C1 BWLUMTFWVZZZND-UHFFFAOYSA-N 0.000 description 1
- XTHFKEDIFFGKHM-UHFFFAOYSA-N Dimethoxyethane Chemical compound COCCOC XTHFKEDIFFGKHM-UHFFFAOYSA-N 0.000 description 1
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 1
- 229930006000 Sucrose Natural products 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000003463 adsorbent Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 150000008044 alkali metal hydroxides Chemical class 0.000 description 1
- 229910001860 alkaline earth metal hydroxide Inorganic materials 0.000 description 1
- 150000001342 alkaline earth metals Chemical class 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 238000001460 carbon-13 nuclear magnetic resonance spectrum Methods 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 229920001429 chelating resin Polymers 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 238000003776 cleavage reaction Methods 0.000 description 1
- 239000012230 colorless oil Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 239000003431 cross linking reagent Substances 0.000 description 1
- 239000000412 dendrimer Substances 0.000 description 1
- 229920000736 dendritic polymer Polymers 0.000 description 1
- 238000001212 derivatisation Methods 0.000 description 1
- 150000002009 diols Chemical class 0.000 description 1
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 1
- 238000007337 electrophilic addition reaction Methods 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 238000007306 functionalization reaction Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- XXMIOPMDWAUFGU-UHFFFAOYSA-N hexane-1,6-diol Chemical compound OCCCCCCO XXMIOPMDWAUFGU-UHFFFAOYSA-N 0.000 description 1
- 150000004678 hydrides Chemical class 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- HCWCAKKEBCNQJP-UHFFFAOYSA-N magnesium orthosilicate Chemical compound [Mg+2].[Mg+2].[O-][Si]([O-])([O-])[O-] HCWCAKKEBCNQJP-UHFFFAOYSA-N 0.000 description 1
- 239000000391 magnesium silicate Substances 0.000 description 1
- 229910052919 magnesium silicate Inorganic materials 0.000 description 1
- 235000019792 magnesium silicate Nutrition 0.000 description 1
- 238000004949 mass spectrometry Methods 0.000 description 1
- 238000001840 matrix-assisted laser desorption--ionisation time-of-flight mass spectrometry Methods 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 150000007522 mineralic acids Chemical class 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- RZXMPPFPUUCRFN-UHFFFAOYSA-N p-toluidine Chemical compound CC1=CC=C(N)C=C1 RZXMPPFPUUCRFN-UHFFFAOYSA-N 0.000 description 1
- 230000020477 pH reduction Effects 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- 229940057847 polyethylene glycol 600 Drugs 0.000 description 1
- NTTOTNSKUYCDAV-UHFFFAOYSA-N potassium hydride Chemical compound [KH] NTTOTNSKUYCDAV-UHFFFAOYSA-N 0.000 description 1
- 229910000105 potassium hydride Inorganic materials 0.000 description 1
- AOHJOMMDDJHIJH-UHFFFAOYSA-N propylenediamine Chemical compound CC(N)CN AOHJOMMDDJHIJH-UHFFFAOYSA-N 0.000 description 1
- KIDHWZJUCRJVML-UHFFFAOYSA-N putrescine Chemical compound NCCCCN KIDHWZJUCRJVML-UHFFFAOYSA-N 0.000 description 1
- 238000007342 radical addition reaction Methods 0.000 description 1
- 238000007142 ring opening reaction Methods 0.000 description 1
- 230000007017 scission Effects 0.000 description 1
- 238000007086 side reaction Methods 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- 150000003573 thiols Chemical class 0.000 description 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
- YFNKIDBQEZZDLK-UHFFFAOYSA-N triglyme Chemical compound COCCOCCOCCOC YFNKIDBQEZZDLK-UHFFFAOYSA-N 0.000 description 1
- PYGHKJQHDXSHES-UHFFFAOYSA-N undec-10-en-1-amine Chemical compound NCCCCCCCCCC=C PYGHKJQHDXSHES-UHFFFAOYSA-N 0.000 description 1
- PXXNTAGJWPJAGM-UHFFFAOYSA-N vertaline Natural products C1C2C=3C=C(OC)C(OC)=CC=3OC(C=C3)=CC=C3CCC(=O)OC1CC1N2CCCC1 PXXNTAGJWPJAGM-UHFFFAOYSA-N 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
- C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
- C08G65/2642—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds characterised by the catalyst used
- C08G65/2645—Metals or compounds thereof, e.g. salts
- C08G65/2648—Alkali metals or compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
- C08G65/04—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers only
- C08G65/22—Cyclic ethers having at least one atom other than carbon and hydrogen outside the ring
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polyethers (AREA)
- Polyurethanes Or Polyureas (AREA)
- Epoxy Compounds (AREA)
- Adhesives Or Adhesive Processes (AREA)
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19859300.7 | 1998-12-22 | ||
| DE19859300 | 1998-12-22 | ||
| DE19947631A DE19947631A1 (de) | 1998-12-22 | 1999-10-04 | Verfahren zur Herstellung von hochverzweigten Polyolen auf der Basis von Glycidol |
| DE19947631.4 | 1999-10-04 | ||
| PCT/EP1999/009773 WO2000037532A2 (de) | 1998-12-22 | 1999-12-10 | Verfahren zur herstellung von hochverzweigten polyolen auf der basis von glycidol |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2002533495A true JP2002533495A (ja) | 2002-10-08 |
| JP2002533495A5 JP2002533495A5 (enExample) | 2007-02-01 |
Family
ID=26050935
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2000589598A Withdrawn JP2002533495A (ja) | 1998-12-22 | 1999-12-10 | グリシドールに基づく高分岐ポリオールの製造方法 |
Country Status (8)
| Country | Link |
|---|---|
| EP (1) | EP1141083B1 (enExample) |
| JP (1) | JP2002533495A (enExample) |
| AT (1) | ATE274016T1 (enExample) |
| AU (1) | AU2660700A (enExample) |
| CA (1) | CA2355727A1 (enExample) |
| ES (1) | ES2228168T3 (enExample) |
| TW (1) | TW498087B (enExample) |
| WO (1) | WO2000037532A2 (enExample) |
Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2007503514A (ja) * | 2003-08-26 | 2007-02-22 | スミスクライン・ビーチャム・コーポレイション | グリセロールおよびポリエチレングリコールのヘテロ官能性コポリマー、そのコンジュゲートおよび組成物 |
| WO2007037469A1 (en) * | 2005-09-29 | 2007-04-05 | Nippon Shokubai Co., Ltd. | Polyalkylene glycol monomer, polyalkylene glycol polymer containing the same, and application thereof |
| WO2007135770A1 (ja) * | 2006-05-19 | 2007-11-29 | Dow Corning Toray Co., Ltd. | ポリエーテル類およびその製造方法 |
| JP2009249500A (ja) * | 2008-04-07 | 2009-10-29 | Hakuto Co Ltd | 重合性高分岐ポリマー及びその製造方法 |
| JP2009249605A (ja) * | 2008-04-10 | 2009-10-29 | Hakuto Co Ltd | 光重合性組成物 |
| JP2010195775A (ja) * | 2009-01-29 | 2010-09-09 | Kao Corp | ポリグリセリルエーテル誘導体の製造方法 |
| JP2012531511A (ja) * | 2009-06-30 | 2012-12-10 | ビーエーエスエフ ソシエタス・ヨーロピア | ホスフィンが初期装入される超分岐ポリオールの製造方法 |
| JP2017088517A (ja) * | 2015-11-05 | 2017-05-25 | 株式会社ダイセル | ポリグリセリン誘導体、及びこれを含有する皮膚外用剤 |
| KR20200126635A (ko) * | 2019-04-30 | 2020-11-09 | 부산대학교 산학협력단 | 이중 금속 시안화물 촉매를 이용한 초분지 폴리글리시돌 제조 방법 및 이에 의해 제조된 초분지 폴리글리시돌 |
| JP2023502866A (ja) * | 2019-11-29 | 2023-01-26 | シーカ テクノロジー アクチェンゲゼルシャフト | 鉱物バインダー組成物の粘度低下のための添加剤としての分岐コポリマー |
| WO2024053560A1 (ja) * | 2022-09-05 | 2024-03-14 | 株式会社 資生堂 | 化粧料基剤 |
| WO2024142846A1 (ja) * | 2022-12-28 | 2024-07-04 | 株式会社 資生堂 | 化粧料組成物 |
| WO2024142844A1 (ja) * | 2022-12-28 | 2024-07-04 | 株式会社 資生堂 | 洗浄料組成物 |
| WO2024142843A1 (ja) * | 2022-12-28 | 2024-07-04 | 株式会社 資生堂 | 化粧料組成物 |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102008002704A1 (de) | 2007-07-02 | 2009-01-08 | Basf Se | Verfahren zur Verbesserung der Haftung von Verbundstoffen, bestehend aus geschäumten Polyurethan und massiven Materialien |
| CN102428112B (zh) | 2009-05-18 | 2014-01-08 | 爱克发印艺公司 | 可聚合的聚合物光引发剂和辐射可固化组合物 |
| EP2264082A1 (de) | 2009-06-19 | 2010-12-22 | BYK-Chemie GmbH | Terminal ungesättigte, glycidol-basierte Markomonomere, daraus erhältliche Polymere, Herstellung und Verwendung |
| DE102009059104A1 (de) * | 2009-12-18 | 2011-06-22 | Johannes-Gutenberg-Universität Mainz, 55122 | Funktionelle verzweigte Polyether Copolymere sowie Verfahren zu ihrer Herstellung |
| WO2011141266A1 (de) | 2010-04-15 | 2011-11-17 | Basf Se | Verfahren zur herstellung von flammgeschützten polyurethan-schaumstoffen |
| DE102011076019A1 (de) | 2011-05-18 | 2012-11-22 | Evonik Goldschmidt Gmbh | Alkoxylierungsprodukte und Verfahren zu ihrer Herstellung mittels DMC-Katalysatoren |
| RU2717795C2 (ru) | 2013-08-22 | 2020-03-25 | Басф Се | Способ получения эмульсионных полимеров |
| PL3523382T3 (pl) | 2016-10-07 | 2021-05-31 | Basf Se | Sposób wytwarzania wodnych dyspersji |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3233251A1 (de) * | 1982-09-08 | 1984-03-08 | Basf Ag, 6700 Ludwigshafen | Asymmetrische polyether-polyole, verfahren zu deren herstellung und deren verwendung fuer polyurethan-kunststoffe |
| EP0116978A3 (en) * | 1983-02-22 | 1986-04-30 | Union Carbide Corporation | Connected branch copolymers and method for their production |
| JPH09235246A (ja) * | 1996-02-29 | 1997-09-09 | Lion Corp | 分岐状ポリグリセリン鎖を有するポリグリセリン化合物の製造方法 |
-
1999
- 1999-12-10 AU AU26607/00A patent/AU2660700A/en not_active Abandoned
- 1999-12-10 AT AT99968792T patent/ATE274016T1/de not_active IP Right Cessation
- 1999-12-10 ES ES99968792T patent/ES2228168T3/es not_active Expired - Lifetime
- 1999-12-10 WO PCT/EP1999/009773 patent/WO2000037532A2/de not_active Ceased
- 1999-12-10 CA CA002355727A patent/CA2355727A1/en not_active Abandoned
- 1999-12-10 JP JP2000589598A patent/JP2002533495A/ja not_active Withdrawn
- 1999-12-10 EP EP99968792A patent/EP1141083B1/de not_active Expired - Lifetime
- 1999-12-20 TW TW088122375A patent/TW498087B/zh not_active IP Right Cessation
Cited By (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2007503514A (ja) * | 2003-08-26 | 2007-02-22 | スミスクライン・ビーチャム・コーポレイション | グリセロールおよびポリエチレングリコールのヘテロ官能性コポリマー、そのコンジュゲートおよび組成物 |
| WO2007037469A1 (en) * | 2005-09-29 | 2007-04-05 | Nippon Shokubai Co., Ltd. | Polyalkylene glycol monomer, polyalkylene glycol polymer containing the same, and application thereof |
| JP2009510175A (ja) * | 2005-09-29 | 2009-03-12 | 株式会社日本触媒 | ポリアルキレングリコール系単量体とそれを含んでなるポリアルキレングリコール系重合体、及び、その用途 |
| US8916678B2 (en) | 2005-09-29 | 2014-12-23 | Nippon Shokubai Co., Ltd. | Polyalkylene glycol monomer, polyalkylene glycol polymer containing the same, and application thereof |
| JP5525728B2 (ja) * | 2006-05-19 | 2014-06-18 | 東レ・ダウコーニング株式会社 | ポリエーテル類およびその製造方法 |
| WO2007135770A1 (ja) * | 2006-05-19 | 2007-11-29 | Dow Corning Toray Co., Ltd. | ポリエーテル類およびその製造方法 |
| US7989581B2 (en) | 2006-05-19 | 2011-08-02 | Dow Corning Toray Company, Ltd. | Polyether from ring-opening of glycidyl ether with (C2-C5 alkylene oxide) monohydric alcohol |
| JP2009249500A (ja) * | 2008-04-07 | 2009-10-29 | Hakuto Co Ltd | 重合性高分岐ポリマー及びその製造方法 |
| JP2009249605A (ja) * | 2008-04-10 | 2009-10-29 | Hakuto Co Ltd | 光重合性組成物 |
| JP2010195775A (ja) * | 2009-01-29 | 2010-09-09 | Kao Corp | ポリグリセリルエーテル誘導体の製造方法 |
| JP2012531511A (ja) * | 2009-06-30 | 2012-12-10 | ビーエーエスエフ ソシエタス・ヨーロピア | ホスフィンが初期装入される超分岐ポリオールの製造方法 |
| JP2017088517A (ja) * | 2015-11-05 | 2017-05-25 | 株式会社ダイセル | ポリグリセリン誘導体、及びこれを含有する皮膚外用剤 |
| KR20200126635A (ko) * | 2019-04-30 | 2020-11-09 | 부산대학교 산학협력단 | 이중 금속 시안화물 촉매를 이용한 초분지 폴리글리시돌 제조 방법 및 이에 의해 제조된 초분지 폴리글리시돌 |
| KR102241144B1 (ko) | 2019-04-30 | 2021-04-15 | 부산대학교 산학협력단 | 이중 금속 시안화물 촉매를 이용한 초분지 폴리글리시돌 제조 방법 및 이에 의해 제조된 초분지 폴리글리시돌 |
| JP2023502866A (ja) * | 2019-11-29 | 2023-01-26 | シーカ テクノロジー アクチェンゲゼルシャフト | 鉱物バインダー組成物の粘度低下のための添加剤としての分岐コポリマー |
| JP7627691B2 (ja) | 2019-11-29 | 2025-02-06 | シーカ テクノロジー アクチェンゲゼルシャフト | 鉱物バインダー組成物の粘度低下のための添加剤としての分岐コポリマー |
| WO2024053560A1 (ja) * | 2022-09-05 | 2024-03-14 | 株式会社 資生堂 | 化粧料基剤 |
| JP7511798B1 (ja) * | 2022-09-05 | 2024-07-05 | 株式会社 資生堂 | 化粧料基剤 |
| WO2024142846A1 (ja) * | 2022-12-28 | 2024-07-04 | 株式会社 資生堂 | 化粧料組成物 |
| WO2024142844A1 (ja) * | 2022-12-28 | 2024-07-04 | 株式会社 資生堂 | 洗浄料組成物 |
| WO2024142843A1 (ja) * | 2022-12-28 | 2024-07-04 | 株式会社 資生堂 | 化粧料組成物 |
Also Published As
| Publication number | Publication date |
|---|---|
| ES2228168T3 (es) | 2005-04-01 |
| TW498087B (en) | 2002-08-11 |
| AU2660700A (en) | 2000-07-12 |
| ATE274016T1 (de) | 2004-09-15 |
| WO2000037532A3 (de) | 2000-10-12 |
| WO2000037532A2 (de) | 2000-06-29 |
| EP1141083B1 (de) | 2004-08-18 |
| CA2355727A1 (en) | 2000-06-29 |
| EP1141083A2 (de) | 2001-10-10 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP2002533495A (ja) | グリシドールに基づく高分岐ポリオールの製造方法 | |
| US6765082B2 (en) | Method for producing highly-branched glycidol-based polyols | |
| US6455639B1 (en) | Oxirane derivative and process for the preparation thereof | |
| US9068044B2 (en) | Alkoxylation products and process for preparing them by means of DMC catalysts | |
| US6617419B1 (en) | Long-chain polyether polyols with a high proportion of primary oh groups | |
| DE19947631A1 (de) | Verfahren zur Herstellung von hochverzweigten Polyolen auf der Basis von Glycidol | |
| JP2000513389A (ja) | 二金属シアン化物錯体触媒を用いる低濃度の遷移金属を含むポリオキシアルキレンポリエーテルポリオールの製造方法 | |
| EP2543689B1 (en) | Continuous method for the synthesis of polyols | |
| Taton et al. | Novel amphiphilic branched copolymers based on polystyrene and poly (ethylene oxide) | |
| JP2002517578A (ja) | 改良されたエポキシド重合方法 | |
| JP2002506897A (ja) | ポリエーテルポリオールの製造方法及びこれより製造されるポリオール | |
| US20230018204A1 (en) | Polyether-modified polybutadienes and processes for preparation thereof | |
| US5003111A (en) | Isobutylene oxide polyols | |
| Al Assiri et al. | Reactivity of B (C6F5) 3 towards glycidol: The formation of branched cyclic polyglycidol structures | |
| JP2001521957A (ja) | 部分結晶性ポリエーテルポリオールの製造方法 | |
| CN111378107B (zh) | 一种反应型密封胶树脂的制备方法 | |
| JPH10510315A (ja) | ３，４−エポキシ−１−ブテン、テトラヒドロフラン及び開始剤から誘導されたポリエーテルグリコール及びアルコール | |
| EP1448663B1 (en) | Process for the alkoxylation of organic compounds | |
| JPH0434550B2 (enExample) | ||
| SU887584A1 (ru) | Способ получени олигоэфирдиолов | |
| JPS6212805B2 (enExample) | ||
| JPS6214165B2 (enExample) | ||
| JPH04209629A (ja) | ポリオキシアルキレンポリオールの製造方法 | |
| KR20210074618A (ko) | 이산화탄소를 이용한 폴리에테르카보네이트 폴리올의 제조방법 및 폴리에테르카보네이트 폴리올 제조용 촉매의 제조방법 | |
| JPS6212927B2 (enExample) |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20061206 |
|
| A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20061206 |
|
| A761 | Written withdrawal of application |
Free format text: JAPANESE INTERMEDIATE CODE: A761 Effective date: 20080724 |