JP2002533216A - ゼオライト膜およびその製造方法 - Google Patents
ゼオライト膜およびその製造方法Info
- Publication number
- JP2002533216A JP2002533216A JP2000590845A JP2000590845A JP2002533216A JP 2002533216 A JP2002533216 A JP 2002533216A JP 2000590845 A JP2000590845 A JP 2000590845A JP 2000590845 A JP2000590845 A JP 2000590845A JP 2002533216 A JP2002533216 A JP 2002533216A
- Authority
- JP
- Japan
- Prior art keywords
- zeolite
- alumina
- porous ceramic
- substrate
- mixture
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 title claims abstract description 187
- 239000010457 zeolite Substances 0.000 title claims abstract description 186
- 229910021536 Zeolite Inorganic materials 0.000 title claims abstract description 181
- 239000012528 membrane Substances 0.000 title claims abstract description 89
- 238000004519 manufacturing process Methods 0.000 title description 6
- 239000000758 substrate Substances 0.000 claims abstract description 98
- 239000013078 crystal Substances 0.000 claims abstract description 83
- 238000000034 method Methods 0.000 claims abstract description 71
- 239000000203 mixture Substances 0.000 claims abstract description 68
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims abstract description 66
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims abstract description 61
- 239000000919 ceramic Substances 0.000 claims abstract description 56
- 239000000243 solution Substances 0.000 claims abstract description 47
- KZHJGOXRZJKJNY-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Si]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O KZHJGOXRZJKJNY-UHFFFAOYSA-N 0.000 claims abstract description 42
- 229910052863 mullite Inorganic materials 0.000 claims abstract description 42
- 238000006243 chemical reaction Methods 0.000 claims abstract description 21
- 229910010293 ceramic material Inorganic materials 0.000 claims abstract description 18
- 239000011148 porous material Substances 0.000 claims abstract description 17
- 230000008439 repair process Effects 0.000 claims abstract description 11
- 229910001948 sodium oxide Inorganic materials 0.000 claims abstract description 8
- 239000007864 aqueous solution Substances 0.000 claims abstract description 6
- 229910052878 cordierite Inorganic materials 0.000 claims abstract description 6
- JSKIRARMQDRGJZ-UHFFFAOYSA-N dimagnesium dioxido-bis[(1-oxido-3-oxo-2,4,6,8,9-pentaoxa-1,3-disila-5,7-dialuminabicyclo[3.3.1]nonan-7-yl)oxy]silane Chemical compound [Mg++].[Mg++].[O-][Si]([O-])(O[Al]1O[Al]2O[Si](=O)O[Si]([O-])(O1)O2)O[Al]1O[Al]2O[Si](=O)O[Si]([O-])(O1)O2 JSKIRARMQDRGJZ-UHFFFAOYSA-N 0.000 claims abstract description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 41
- 238000010335 hydrothermal treatment Methods 0.000 claims description 23
- 238000000926 separation method Methods 0.000 claims description 22
- 150000001336 alkenes Chemical class 0.000 claims description 19
- 230000008569 process Effects 0.000 claims description 17
- YNQLUTRBYVCPMQ-UHFFFAOYSA-N Ethylbenzene Chemical compound CCC1=CC=CC=C1 YNQLUTRBYVCPMQ-UHFFFAOYSA-N 0.000 claims description 14
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims description 12
- 238000010899 nucleation Methods 0.000 claims description 11
- 230000006911 nucleation Effects 0.000 claims description 11
- 230000002708 enhancing effect Effects 0.000 claims description 10
- 239000001257 hydrogen Substances 0.000 claims description 10
- 229910052739 hydrogen Inorganic materials 0.000 claims description 10
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 10
- 239000003054 catalyst Substances 0.000 claims description 8
- 239000000376 reactant Substances 0.000 claims description 8
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 7
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 7
- 229930195733 hydrocarbon Natural products 0.000 claims description 7
- 150000002430 hydrocarbons Chemical class 0.000 claims description 7
- 239000008096 xylene Substances 0.000 claims description 6
- 238000009792 diffusion process Methods 0.000 claims description 5
- 239000000047 product Substances 0.000 claims description 5
- -1 sodium-pl Inorganic materials 0.000 claims description 5
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 4
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 claims description 4
- 238000001833 catalytic reforming Methods 0.000 claims description 4
- 239000007795 chemical reaction product Substances 0.000 claims description 4
- 230000001747 exhibiting effect Effects 0.000 claims description 4
- 239000012188 paraffin wax Substances 0.000 claims description 4
- 238000002459 porosimetry Methods 0.000 claims description 4
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 4
- 239000011734 sodium Substances 0.000 claims description 4
- 239000004215 Carbon black (E152) Substances 0.000 claims description 3
- 229910052906 cristobalite Inorganic materials 0.000 claims description 3
- 150000002431 hydrogen Chemical class 0.000 claims description 3
- 239000003350 kerosene Substances 0.000 claims description 3
- 229910052680 mordenite Inorganic materials 0.000 claims description 3
- 239000003345 natural gas Substances 0.000 claims description 3
- 239000003209 petroleum derivative Substances 0.000 claims description 3
- 229910052665 sodalite Inorganic materials 0.000 claims description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 2
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 claims description 2
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 claims description 2
- 229910052799 carbon Inorganic materials 0.000 claims description 2
- 238000009826 distribution Methods 0.000 claims description 2
- 239000003208 petroleum Substances 0.000 claims description 2
- 239000001294 propane Substances 0.000 claims description 2
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 2
- 239000011541 reaction mixture Substances 0.000 claims description 2
- IJDNQMDRQITEOD-UHFFFAOYSA-N sec-butylidene Natural products CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 claims description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims 6
- 229910017464 nitrogen compound Inorganic materials 0.000 claims 6
- 150000002830 nitrogen compounds Chemical class 0.000 claims 6
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims 4
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims 4
- 239000011593 sulfur Substances 0.000 claims 4
- 229910052717 sulfur Inorganic materials 0.000 claims 4
- 239000011159 matrix material Substances 0.000 claims 3
- 229910052757 nitrogen Inorganic materials 0.000 claims 3
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 claims 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 claims 2
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical compound CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 claims 2
- 229910021529 ammonia Inorganic materials 0.000 claims 2
- HOWJQLVNDUGZBI-UHFFFAOYSA-N butane;propane Chemical compound CCC.CCCC HOWJQLVNDUGZBI-UHFFFAOYSA-N 0.000 claims 2
- 239000000571 coke Substances 0.000 claims 2
- NXHUHEUOFBLGGT-UHFFFAOYSA-N ethane;ethylbenzene Chemical compound CC.CCC1=CC=CC=C1 NXHUHEUOFBLGGT-UHFFFAOYSA-N 0.000 claims 2
- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 claims 2
- QWTDNUCVQCZILF-UHFFFAOYSA-N isopentane Chemical compound CCC(C)C QWTDNUCVQCZILF-UHFFFAOYSA-N 0.000 claims 2
- 150000003464 sulfur compounds Chemical class 0.000 claims 2
- 150000003738 xylenes Chemical class 0.000 claims 2
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 claims 1
- YHQXBTXEYZIYOV-UHFFFAOYSA-N 3-methylbut-1-ene Chemical compound CC(C)C=C YHQXBTXEYZIYOV-UHFFFAOYSA-N 0.000 claims 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims 1
- 239000003570 air Substances 0.000 claims 1
- 229910052786 argon Inorganic materials 0.000 claims 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims 1
- IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 claims 1
- 238000003421 catalytic decomposition reaction Methods 0.000 claims 1
- AFABGHUZZDYHJO-UHFFFAOYSA-N dimethyl butane Natural products CCCC(C)C AFABGHUZZDYHJO-UHFFFAOYSA-N 0.000 claims 1
- 239000007789 gas Substances 0.000 claims 1
- 239000001307 helium Substances 0.000 claims 1
- 229910052734 helium Inorganic materials 0.000 claims 1
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 claims 1
- 239000001282 iso-butane Substances 0.000 claims 1
- 239000007788 liquid Substances 0.000 claims 1
- 229910052754 neon Inorganic materials 0.000 claims 1
- GKAOGPIIYCISHV-UHFFFAOYSA-N neon atom Chemical compound [Ne] GKAOGPIIYCISHV-UHFFFAOYSA-N 0.000 claims 1
- 239000001301 oxygen Substances 0.000 claims 1
- 229910052760 oxygen Inorganic materials 0.000 claims 1
- YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 claims 1
- KKCBUQHMOMHUOY-UHFFFAOYSA-N sodium oxide Chemical compound [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 abstract description 7
- 239000010410 layer Substances 0.000 description 54
- 238000002441 X-ray diffraction Methods 0.000 description 19
- 239000000377 silicon dioxide Substances 0.000 description 18
- 238000001878 scanning electron micrograph Methods 0.000 description 14
- 150000001335 aliphatic alkanes Chemical class 0.000 description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 12
- 230000015572 biosynthetic process Effects 0.000 description 10
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 8
- 239000000463 material Substances 0.000 description 8
- 238000012545 processing Methods 0.000 description 8
- 230000007547 defect Effects 0.000 description 7
- 238000006356 dehydrogenation reaction Methods 0.000 description 7
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- URLKBWYHVLBVBO-UHFFFAOYSA-N Para-Xylene Chemical group CC1=CC=C(C)C=C1 URLKBWYHVLBVBO-UHFFFAOYSA-N 0.000 description 6
- 125000003118 aryl group Chemical class 0.000 description 6
- 230000003197 catalytic effect Effects 0.000 description 6
- 238000006317 isomerization reaction Methods 0.000 description 6
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 6
- 238000000879 optical micrograph Methods 0.000 description 6
- 239000003513 alkali Substances 0.000 description 5
- 239000011230 binding agent Substances 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 5
- 239000002994 raw material Substances 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 238000004090 dissolution Methods 0.000 description 3
- 239000012153 distilled water Substances 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 239000002243 precursor Substances 0.000 description 3
- 239000002356 single layer Substances 0.000 description 3
- 229910001220 stainless steel Inorganic materials 0.000 description 3
- 239000010935 stainless steel Substances 0.000 description 3
- 230000008093 supporting effect Effects 0.000 description 3
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 2
- 239000005977 Ethylene Substances 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 229910010413 TiO 2 Inorganic materials 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 238000004523 catalytic cracking Methods 0.000 description 2
- 150000001768 cations Chemical class 0.000 description 2
- 239000003518 caustics Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 239000012084 conversion product Substances 0.000 description 2
- 238000002425 crystallisation Methods 0.000 description 2
- 230000008025 crystallization Effects 0.000 description 2
- RWGFKTVRMDUZSP-UHFFFAOYSA-N cumene Chemical compound CC(C)C1=CC=CC=C1 RWGFKTVRMDUZSP-UHFFFAOYSA-N 0.000 description 2
- 230000029087 digestion Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 230000035699 permeability Effects 0.000 description 2
- 239000004810 polytetrafluoroethylene Substances 0.000 description 2
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 239000002244 precipitate Substances 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- 238000002407 reforming Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- 239000005995 Aluminium silicate Substances 0.000 description 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 150000001491 aromatic compounds Chemical class 0.000 description 1
- 239000010426 asphalt Substances 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 239000003637 basic solution Substances 0.000 description 1
- 239000001273 butane Substances 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 238000001311 chemical methods and process Methods 0.000 description 1
- 238000012993 chemical processing Methods 0.000 description 1
- 239000007805 chemical reaction reactant Substances 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 229910052570 clay Inorganic materials 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 239000012792 core layer Substances 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 239000002178 crystalline material Substances 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 238000010304 firing Methods 0.000 description 1
- 239000003502 gasoline Substances 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 230000001976 improved effect Effects 0.000 description 1
- 230000001939 inductive effect Effects 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 239000011229 interlayer Substances 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 235000010981 methylcellulose Nutrition 0.000 description 1
- 238000001000 micrograph Methods 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 230000000116 mitigating effect Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000002808 molecular sieve Substances 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000000197 pyrolysis Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
- RYYKJJJTJZKILX-UHFFFAOYSA-M sodium octadecanoate Chemical compound [Na+].CCCCCCCCCCCCCCCCCC([O-])=O RYYKJJJTJZKILX-UHFFFAOYSA-M 0.000 description 1
- 230000002269 spontaneous effect Effects 0.000 description 1
- BGQMOFGZRJUORO-UHFFFAOYSA-M tetrapropylammonium bromide Chemical compound [Br-].CCC[N+](CCC)(CCC)CCC BGQMOFGZRJUORO-UHFFFAOYSA-M 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 239000011800 void material Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/03—Catalysts comprising molecular sieves not having base-exchange properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
- B01J20/28014—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their form
- B01J20/28033—Membrane, sheet, cloth, pad, lamellar or mat
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D63/00—Apparatus in general for separation processes using semi-permeable membranes
- B01D63/06—Tubular membrane modules
- B01D63/066—Tubular membrane modules with a porous block having membrane coated passages
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
- B01D67/0039—Inorganic membrane manufacture
- B01D67/0051—Inorganic membrane manufacture by controlled crystallisation, e,.g. hydrothermal growth
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
- B01D71/02—Inorganic material
- B01D71/028—Molecular sieves
- B01D71/0281—Zeolites
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
- B01J20/16—Alumino-silicates
- B01J20/18—Synthetic zeolitic molecular sieves
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
- B01J20/28014—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their form
- B01J20/2803—Sorbents comprising a binder, e.g. for forming aggregated, agglomerated or granulated products
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
- B01J20/28014—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their form
- B01J20/28042—Shaped bodies; Monolithic structures
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
- B01J20/28054—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
- B01J20/28069—Pore volume, e.g. total pore volume, mesopore volume, micropore volume
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- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
- B01J20/28054—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
- B01J20/28078—Pore diameter
- B01J20/28085—Pore diameter being more than 50 nm, i.e. macropores
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- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
- B01J35/58—Fabrics or filaments
- B01J35/59—Membranes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/024—Multiple impregnation or coating
- B01J37/0246—Coatings comprising a zeolite
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/009—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
- C04B41/5024—Silicates
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/85—Coating or impregnation with inorganic materials
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2325/00—Details relating to properties of membranes
- B01D2325/04—Characteristic thickness
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2325/00—Details relating to properties of membranes
- B01D2325/10—Catalysts being present on the surface of the membrane or in the pores
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2325/00—Details relating to properties of membranes
- B01D2325/12—Adsorbents being present on the surface of the membranes or in the pores
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2325/00—Details relating to properties of membranes
- B01D2325/48—Antimicrobial properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/60—Synthesis on support
- B01J2229/64—Synthesis on support in or on refractory materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
- C04B2111/00793—Uses not provided for elsewhere in C04B2111/00 as filters or diaphragms
- C04B2111/00801—Membranes; Diaphragms
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Analytical Chemistry (AREA)
- Ceramic Engineering (AREA)
- Inorganic Chemistry (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Nanotechnology (AREA)
- Crystallography & Structural Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
- Catalysts (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US11428098P | 1998-12-30 | 1998-12-30 | |
| US60/114,280 | 1998-12-30 | ||
| PCT/US1999/031166 WO2000038910A1 (en) | 1998-12-30 | 1999-12-29 | Zeolite membrane and a process for the production thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2002533216A true JP2002533216A (ja) | 2002-10-08 |
| JP2002533216A5 JP2002533216A5 (enExample) | 2007-02-15 |
Family
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2000590845A Pending JP2002533216A (ja) | 1998-12-30 | 1999-12-29 | ゼオライト膜およびその製造方法 |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US6440885B1 (enExample) |
| EP (1) | EP1152887A4 (enExample) |
| JP (1) | JP2002533216A (enExample) |
| KR (1) | KR20010089744A (enExample) |
| CN (1) | CN1126658C (enExample) |
| WO (1) | WO2000038910A1 (enExample) |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2001240411A (ja) * | 2000-02-28 | 2001-09-04 | Ngk Insulators Ltd | モルデナイトゼオライト膜およびその製造方法 |
| WO2007043511A1 (ja) * | 2005-10-07 | 2007-04-19 | Osaka University | 分離モジュール及び分離モジュールの製造方法 |
| JP2011520739A (ja) * | 2007-11-15 | 2011-07-21 | ラトガーズ， ザ ステイト ユニバーシティ オブ ニュー ジャージー | セラミック材料の熱水液相焼結方法及びそれによって得られる生成物 |
| JP2014516771A (ja) * | 2011-04-29 | 2014-07-17 | コーニング インコーポレイテッド | 熱交換能力を有するｃｏ２回収用物品 |
| JP2016107320A (ja) * | 2014-12-09 | 2016-06-20 | キンセイマテック株式会社 | 鋳型砂とその製造方法 |
| JP2019030910A (ja) * | 2018-10-25 | 2019-02-28 | キンセイマテック株式会社 | 鋳型砂とその製造方法 |
| JP2021023863A (ja) * | 2019-08-02 | 2021-02-22 | 三菱ケミカル株式会社 | 気体の濃縮方法 |
| JP7655026B2 (ja) | 2021-03-18 | 2025-04-02 | 東京電力ホールディングス株式会社 | 汚染水浄化用吸着材 |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6623707B1 (en) * | 2000-06-19 | 2003-09-23 | Corning Incorporated | Monolithic catalyst dehydrogenation reactor |
| FR2820342B1 (fr) * | 2001-02-07 | 2003-12-05 | Inst Francais Du Petrole | Procede de preparation de membranes zeolithiques supportees par cristallisation controlee en temperature |
| US7476635B2 (en) * | 2002-06-03 | 2009-01-13 | Institut Francais Du Petrole | Process for making supported thin zeolite membrane |
| DE10250468A1 (de) * | 2002-10-30 | 2004-05-19 | Basf Ag | Verfahren zur Herstellung von Oligomeren abgeleitet von Butenen |
| US20050067344A1 (en) * | 2003-09-30 | 2005-03-31 | Kabushiki Kaisha Kobe Seiko Sho (Kobe Steel, Ltd.) | Zeolite membrane support and zeolite composite membrane |
| US20070138083A1 (en) * | 2004-03-17 | 2007-06-21 | Masanobu Aizawa | Separation membrane |
| CN100344352C (zh) * | 2005-06-03 | 2007-10-24 | 大连理工大学 | X型沸石膜用于苯和氮气混合物分离的方法 |
| CN100334041C (zh) * | 2005-06-23 | 2007-08-29 | 华东理工大学 | 多孔陶瓷的制备方法 |
| JP5324067B2 (ja) * | 2006-08-22 | 2013-10-23 | 日本碍子株式会社 | ゼオライト膜の製造方法 |
| US20090000475A1 (en) * | 2007-06-29 | 2009-01-01 | Curtis Robert Fekety | Zeolite membrane structures and methods of making zeolite membrane structures |
| CN101654257B (zh) * | 2009-10-21 | 2011-10-26 | 中国铝业股份有限公司 | 一种连续晶化制备4a沸石的方法 |
| CN102274744B (zh) * | 2010-06-12 | 2013-05-22 | 中国科学院金属研究所 | 多孔碳化硅表面单层、b轴取向ZSM-5沸石涂层材料的制备方法 |
| KR101248880B1 (ko) * | 2010-07-06 | 2013-03-29 | 한국에너지기술연구원 | 열균열이 방지된 제올라이트 분리막 및 그 제조 방법 |
| US8647997B2 (en) | 2010-11-30 | 2014-02-11 | General Electric Company | Zeolite membrane and methods of making the same |
| UA113844C2 (xx) | 2011-03-05 | 2017-03-27 | Зв'язуючий елемент, зв'язуюча матриця і композитний матеріал, що має зв'язуючий елемент, та спосіб його виготовлення | |
| CN103717548B (zh) | 2011-06-09 | 2016-08-17 | 新泽西州州立大学(拉特格斯) | 合成配制物及其制备和使用方法 |
| EP2818232B1 (en) * | 2012-02-24 | 2018-08-22 | Mitsubishi Chemical Corporation | Zeolite membrane complex |
| WO2015021099A1 (en) | 2013-08-06 | 2015-02-12 | Bettergy Corp. | Metal doped zeolite membrane for gas separation |
| US9481844B2 (en) | 2013-12-09 | 2016-11-01 | Uop Llc | Process and adsorbent for removal of diolefins and other contaminants from liquefied petroleum gas |
| CN106999866A (zh) | 2014-11-25 | 2017-08-01 | 三菱化学株式会社 | 多孔支持体‑沸石膜复合体以及多孔支持体‑沸石膜复合体的制造方法 |
| US10773999B2 (en) * | 2018-02-23 | 2020-09-15 | Honeywell International Inc. | Rare earth silicate coatings solvothermally grown over high temperature ceramic components |
| CN108889272A (zh) * | 2018-07-03 | 2018-11-27 | 北京卫星环境工程研究所 | 航天器在轨分子污染吸附装置 |
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| CN113860325B (zh) * | 2020-06-30 | 2023-04-11 | 中国石油化工股份有限公司 | 一种多级孔ZSM-5@β核壳型分子筛合成方法 |
| CN115703982B (zh) * | 2021-08-17 | 2024-05-10 | 中国石油天然气股份有限公司 | 一种含硫站场综合供能系统 |
| CN115028174B (zh) * | 2022-05-26 | 2023-11-24 | 中南大学 | 一种细化金属基体表面沸石涂层中沸石晶粒的方法 |
| ES3004182A1 (es) * | 2023-09-08 | 2025-03-11 | Univ Madrid Autonoma | Procedimiento de fabricacion de material zeolitizado o geopolimerizado y material producido |
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| JPS63291809A (ja) * | 1987-05-26 | 1988-11-29 | Idemitsu Kosan Co Ltd | 膜状合成ゼオライトの製造方法 |
| JPH0971481A (ja) * | 1995-09-05 | 1997-03-18 | Nitsukatoo:Kk | セラミックス多孔質支持体 |
| JPH10506363A (ja) * | 1994-07-08 | 1998-06-23 | エクソン リサーチ アンド エンジニアリング カンパニー | 本来の場所で結晶化されたゼオライト含有組成物（ｌａｉ−ｉｓｃ） |
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| US3523092A (en) | 1967-11-14 | 1970-08-04 | Exxon Research Engineering Co | Method of preparing supported crystalline alumino-silicate zeolites |
| US3730910A (en) | 1971-02-02 | 1973-05-01 | Grace W R & Co | Novel zeolite surfaces |
| CA1195311A (en) | 1983-04-26 | 1985-10-15 | Peter H. Bird | Composite zeolite-asbestos catalysts |
| US4800187A (en) | 1987-10-28 | 1989-01-24 | Corning Glass Works | Method of crystallizing a zeolite on the surface of a monolithic ceramic substrate |
| GB9022836D0 (en) | 1990-10-19 | 1990-12-05 | British Petroleum Co Plc | Membranes |
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| SG49056A1 (en) | 1991-10-23 | 1998-05-18 | Exxon Chemical Patents Inc | Nanometer-sized molecular sieve crystals or agglomerates and processes for their production |
| US5258339A (en) * | 1992-03-12 | 1993-11-02 | Worcester Polytechnic Institute | Formation of zeolite membranes from sols |
| DE4216846A1 (de) | 1992-05-21 | 1993-11-25 | Basf Ag | Verfahren zur Fixierung großer zeolithischer und zeolithanaloger Molekularsieb-Kristalle auf Formkörper |
| NL9201940A (nl) * | 1992-11-05 | 1994-06-01 | Univ Delft Tech | Katalysatorsysteem van het gestructureerde type. |
| US5248643A (en) | 1992-11-23 | 1993-09-28 | Corning Incorporated | Mixed zeolites and method for producing same |
| DE69406282T3 (de) | 1993-04-23 | 2002-10-31 | Exxon Chemical Ltd., Abingdon | Verfahren zur herstellung von molekularsiebschichten |
| US5464798A (en) * | 1994-02-24 | 1995-11-07 | Jia; Meng-Dong | Ceramic-zeolite composite membranes and use for separation of vapor/gas mixtures |
| DE69533510T2 (de) | 1994-07-08 | 2005-09-15 | Exxon Research And Engineering Co. | Zeolith enthaltende zusammensetzung mit einer selektivität erhhöhenden beschichtung |
| US5824617A (en) | 1994-07-08 | 1998-10-20 | Exxon Research & Engineering Company | Low alkaline inverted in-situ crystallized zeolite membrane |
| US5871650A (en) | 1994-07-08 | 1999-02-16 | Exxon Research And Engineering Company | Supported zeolite membranes with controlled crystal width and preferred orientation grown on a growth enhancing layer |
| US5716527A (en) * | 1994-07-08 | 1998-02-10 | Exxon Research & Engineering Company | Zeolite membrane with a selectivity enhancing coating |
| EP0775015B1 (en) | 1994-07-08 | 2004-09-15 | ExxonMobil Research and Engineering Company | Zeolite layers with controlled crystal width and preferred orientation grown on a growth enhancing layer |
| SE9600970D0 (sv) * | 1996-03-14 | 1996-03-14 | Johan Sterte | Förfarande för framställning av mycket tunna filmer av molekylsiktar |
-
1999
- 1999-12-28 US US09/473,930 patent/US6440885B1/en not_active Expired - Fee Related
- 1999-12-29 WO PCT/US1999/031166 patent/WO2000038910A1/en not_active Ceased
- 1999-12-29 JP JP2000590845A patent/JP2002533216A/ja active Pending
- 1999-12-29 CN CN99815208A patent/CN1126658C/zh not_active Expired - Fee Related
- 1999-12-29 EP EP99967741A patent/EP1152887A4/en not_active Ceased
- 1999-12-29 KR KR1020017008365A patent/KR20010089744A/ko not_active Abandoned
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
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| JPS63291809A (ja) * | 1987-05-26 | 1988-11-29 | Idemitsu Kosan Co Ltd | 膜状合成ゼオライトの製造方法 |
| JPH10506363A (ja) * | 1994-07-08 | 1998-06-23 | エクソン リサーチ アンド エンジニアリング カンパニー | 本来の場所で結晶化されたゼオライト含有組成物（ｌａｉ−ｉｓｃ） |
| JPH0971481A (ja) * | 1995-09-05 | 1997-03-18 | Nitsukatoo:Kk | セラミックス多孔質支持体 |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2001240411A (ja) * | 2000-02-28 | 2001-09-04 | Ngk Insulators Ltd | モルデナイトゼオライト膜およびその製造方法 |
| WO2007043511A1 (ja) * | 2005-10-07 | 2007-04-19 | Osaka University | 分離モジュール及び分離モジュールの製造方法 |
| JP2011520739A (ja) * | 2007-11-15 | 2011-07-21 | ラトガーズ， ザ ステイト ユニバーシティ オブ ニュー ジャージー | セラミック材料の熱水液相焼結方法及びそれによって得られる生成物 |
| JP2014516771A (ja) * | 2011-04-29 | 2014-07-17 | コーニング インコーポレイテッド | 熱交換能力を有するｃｏ２回収用物品 |
| JP2016107320A (ja) * | 2014-12-09 | 2016-06-20 | キンセイマテック株式会社 | 鋳型砂とその製造方法 |
| JP2019030910A (ja) * | 2018-10-25 | 2019-02-28 | キンセイマテック株式会社 | 鋳型砂とその製造方法 |
| JP2021023863A (ja) * | 2019-08-02 | 2021-02-22 | 三菱ケミカル株式会社 | 気体の濃縮方法 |
| JP7306145B2 (ja) | 2019-08-02 | 2023-07-11 | 三菱ケミカル株式会社 | 気体の濃縮方法 |
| JP7655026B2 (ja) | 2021-03-18 | 2025-04-02 | 東京電力ホールディングス株式会社 | 汚染水浄化用吸着材 |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1126658C (zh) | 2003-11-05 |
| KR20010089744A (ko) | 2001-10-08 |
| EP1152887A4 (en) | 2003-04-02 |
| US6440885B1 (en) | 2002-08-27 |
| WO2000038910A1 (en) | 2000-07-06 |
| CN1332671A (zh) | 2002-01-23 |
| EP1152887A1 (en) | 2001-11-14 |
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