JP2002530494A - 乳化重合ポリアクリレートゴム、耐衝撃性改良剤、それから得られるブレンド、並びに製造方法 - Google Patents
乳化重合ポリアクリレートゴム、耐衝撃性改良剤、それから得られるブレンド、並びに製造方法Info
- Publication number
- JP2002530494A JP2002530494A JP2000583981A JP2000583981A JP2002530494A JP 2002530494 A JP2002530494 A JP 2002530494A JP 2000583981 A JP2000583981 A JP 2000583981A JP 2000583981 A JP2000583981 A JP 2000583981A JP 2002530494 A JP2002530494 A JP 2002530494A
- Authority
- JP
- Japan
- Prior art keywords
- rubber
- acrylate
- crosslinked polyacrylate
- emulsion
- polyacrylate rubber
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229920001971 elastomer Polymers 0.000 title claims abstract description 73
- 239000005060 rubber Substances 0.000 title claims abstract description 73
- 239000000203 mixture Substances 0.000 title claims abstract description 54
- 229920000058 polyacrylate Polymers 0.000 title claims abstract description 43
- 238000004519 manufacturing process Methods 0.000 title claims description 7
- 239000004609 Impact Modifier Substances 0.000 title description 7
- 229920001169 thermoplastic Polymers 0.000 claims abstract description 27
- 239000004416 thermosoftening plastic Substances 0.000 claims abstract description 21
- 239000000178 monomer Substances 0.000 claims abstract description 16
- 230000002902 bimodal effect Effects 0.000 claims abstract description 11
- 239000000839 emulsion Substances 0.000 claims abstract description 10
- FZYCEURIEDTWNS-UHFFFAOYSA-N prop-1-en-2-ylbenzene Chemical compound CC(=C)C1=CC=CC=C1.CC(=C)C1=CC=CC=C1 FZYCEURIEDTWNS-UHFFFAOYSA-N 0.000 claims abstract description 10
- 229920000578 graft copolymer Polymers 0.000 claims abstract description 8
- 239000002245 particle Substances 0.000 claims description 26
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 21
- 238000000034 method Methods 0.000 claims description 21
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 14
- 230000008961 swelling Effects 0.000 claims description 13
- 150000001875 compounds Chemical class 0.000 claims description 12
- -1 acrylate ester Chemical class 0.000 claims description 10
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 9
- 238000007720 emulsion polymerization reaction Methods 0.000 claims description 8
- 229920001577 copolymer Polymers 0.000 claims description 7
- 238000004132 cross linking Methods 0.000 claims description 7
- JMIZWXDKTUGEES-UHFFFAOYSA-N 2,2-di(cyclopenten-1-yloxy)ethyl 2-methylprop-2-enoate Chemical group C=1CCCC=1OC(COC(=O)C(=C)C)OC1=CCCC1 JMIZWXDKTUGEES-UHFFFAOYSA-N 0.000 claims description 4
- GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 claims description 4
- 229920000728 polyester Polymers 0.000 claims description 4
- 229920000800 acrylic rubber Polymers 0.000 claims description 3
- 229920000642 polymer Polymers 0.000 claims description 3
- 238000006116 polymerization reaction Methods 0.000 claims description 3
- BJELTSYBAHKXRW-UHFFFAOYSA-N 2,4,6-triallyloxy-1,3,5-triazine Chemical compound C=CCOC1=NC(OCC=C)=NC(OCC=C)=N1 BJELTSYBAHKXRW-UHFFFAOYSA-N 0.000 claims description 2
- 239000004952 Polyamide Substances 0.000 claims description 2
- 150000004649 carbonic acid derivatives Chemical class 0.000 claims description 2
- 229920002647 polyamide Polymers 0.000 claims description 2
- 229920000515 polycarbonate Polymers 0.000 claims description 2
- 239000004417 polycarbonate Substances 0.000 claims description 2
- 229920001601 polyetherimide Polymers 0.000 claims description 2
- 229920001955 polyphenylene ether Polymers 0.000 claims description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 claims 1
- 239000004793 Polystyrene Substances 0.000 claims 1
- 238000006243 chemical reaction Methods 0.000 claims 1
- 229920002223 polystyrene Polymers 0.000 claims 1
- 238000010348 incorporation Methods 0.000 abstract description 3
- 239000011145 styrene acrylonitrile resin Substances 0.000 abstract 1
- 229920001485 poly(butyl acrylate) polymer Polymers 0.000 description 13
- 125000005250 alkyl acrylate group Chemical group 0.000 description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
- 239000012153 distilled water Substances 0.000 description 7
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 5
- 238000009826 distribution Methods 0.000 description 5
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 4
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 4
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 4
- 229920000126 latex Polymers 0.000 description 4
- SCUZVMOVTVSBLE-UHFFFAOYSA-N prop-2-enenitrile;styrene Chemical compound C=CC#N.C=CC1=CC=CC=C1 SCUZVMOVTVSBLE-UHFFFAOYSA-N 0.000 description 4
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- 239000004816 latex Substances 0.000 description 3
- 239000011541 reaction mixture Substances 0.000 description 3
- 229920005989 resin Polymers 0.000 description 3
- 239000011347 resin Substances 0.000 description 3
- 229920000638 styrene acrylonitrile Polymers 0.000 description 3
- 150000003440 styrenes Chemical class 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 2
- LCPVQAHEFVXVKT-UHFFFAOYSA-N 2-(2,4-difluorophenoxy)pyridin-3-amine Chemical compound NC1=CC=CN=C1OC1=CC=C(F)C=C1F LCPVQAHEFVXVKT-UHFFFAOYSA-N 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- JLBJTVDPSNHSKJ-UHFFFAOYSA-N 4-Methylstyrene Chemical compound CC1=CC=C(C=C)C=C1 JLBJTVDPSNHSKJ-UHFFFAOYSA-N 0.000 description 2
- VVJKKWFAADXIJK-UHFFFAOYSA-N Allylamine Chemical compound NCC=C VVJKKWFAADXIJK-UHFFFAOYSA-N 0.000 description 2
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- 239000008188 pellet Substances 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 229910000029 sodium carbonate Inorganic materials 0.000 description 2
- CHQMHPLRPQMAMX-UHFFFAOYSA-L sodium persulfate Substances [Na+].[Na+].[O-]S(=O)(=O)OOS([O-])(=O)=O CHQMHPLRPQMAMX-UHFFFAOYSA-L 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- ZOKCNEIWFQCSCM-UHFFFAOYSA-N (2-methyl-4-phenylpent-4-en-2-yl)benzene Chemical compound C=1C=CC=CC=1C(C)(C)CC(=C)C1=CC=CC=C1 ZOKCNEIWFQCSCM-UHFFFAOYSA-N 0.000 description 1
- GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical compound CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 description 1
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 1
- ATVJXMYDOSMEPO-UHFFFAOYSA-N 3-prop-2-enoxyprop-1-ene Chemical compound C=CCOCC=C ATVJXMYDOSMEPO-UHFFFAOYSA-N 0.000 description 1
- ACYXOHNDKRVKLH-UHFFFAOYSA-N 5-phenylpenta-2,4-dienenitrile prop-2-enoic acid Chemical compound OC(=O)C=C.N#CC=CC=CC1=CC=CC=C1 ACYXOHNDKRVKLH-UHFFFAOYSA-N 0.000 description 1
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 1
- 229920001893 acrylonitrile styrene Polymers 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 238000005119 centrifugation Methods 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- SSDSCDGVMJFTEQ-UHFFFAOYSA-N octadecyl 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 SSDSCDGVMJFTEQ-UHFFFAOYSA-N 0.000 description 1
- 229920002285 poly(styrene-co-acrylonitrile) Polymers 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000006228 supernatant Substances 0.000 description 1
- 230000002194 synthesizing effect Effects 0.000 description 1
- 239000012815 thermoplastic material Substances 0.000 description 1
- 229920005992 thermoplastic resin Polymers 0.000 description 1
- 238000003466 welding Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/003—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F265/00—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
- C08F265/04—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00 on to polymers of esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L69/00—Compositions of polycarbonates; Compositions of derivatives of polycarbonates
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Graft Or Block Polymers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Polymerisation Methods In General (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US09/197,788 | 1998-11-23 | ||
| US09/197,788 US6054531A (en) | 1998-11-23 | 1998-11-23 | Emulsion polymerized polyacrylate rubber, impact modifiers and blends obtained therefrom, and method for making |
| PCT/US1999/026974 WO2000031158A1 (en) | 1998-11-23 | 1999-11-12 | Emulsion polymerized polyacrylate rubber, impact modifiers and blends obtained therefrom, and method for making |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2002530494A true JP2002530494A (ja) | 2002-09-17 |
| JP2002530494A5 JP2002530494A5 (enExample) | 2007-01-11 |
Family
ID=22730769
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2000583981A Pending JP2002530494A (ja) | 1998-11-23 | 1999-11-12 | 乳化重合ポリアクリレートゴム、耐衝撃性改良剤、それから得られるブレンド、並びに製造方法 |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US6054531A (enExample) |
| EP (1) | EP1137680B1 (enExample) |
| JP (1) | JP2002530494A (enExample) |
| CN (1) | CN1211406C (enExample) |
| AT (1) | ATE302219T1 (enExample) |
| DE (1) | DE69926789T2 (enExample) |
| ES (1) | ES2246587T3 (enExample) |
| WO (1) | WO2000031158A1 (enExample) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2007501892A (ja) * | 2003-05-09 | 2007-02-01 | ゼネラル・エレクトリック・カンパニイ | 耐衝撃性改良組成物及び方法 |
| WO2007114108A1 (ja) * | 2006-03-31 | 2007-10-11 | Zeon Corporation | アクリルゴムおよびその製造方法 |
| JP2013047095A (ja) * | 2004-03-29 | 2013-03-07 | Albis Plastic Gmbh | 照明情報ユニット |
| WO2017022423A1 (ja) * | 2015-07-31 | 2017-02-09 | 綜研化学株式会社 | （メタ）アクリル系架橋粒子およびその製造方法 |
| WO2017099409A1 (ko) | 2015-12-10 | 2017-06-15 | (주) 엘지화학 | 열가소성 그라프트 공중합체 수지, 이를 제조하는 방법, 및 이를 포함하는 열가소성 수지 조성물 |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TWI231305B (en) * | 2000-10-25 | 2005-04-21 | Rohm & Haas | High rubber impact modifier powders |
| KR100417062B1 (ko) * | 2001-01-11 | 2004-02-05 | 주식회사 엘지화학 | 바이모달 입자분포로 이루어진 아크릴계 고무라텍스의제조방법 |
| US20020167112A1 (en) * | 2001-02-06 | 2002-11-14 | Colburn Peter D. | Modified acrylic based compositions of enhanced optics and low temperature impact strength |
| ES2294203T3 (es) * | 2001-11-07 | 2008-04-01 | Nuplex Resins B.V. | Composicion de polimero entrecruzable. |
| US7550536B2 (en) * | 2001-12-25 | 2009-06-23 | Jsr Corporation | Acrylic rubber, process for its production, and rubber compositions, oil-and weather-resistant rubber compositions, and oil-and weather -resistant rubbers, containing the same |
| US7396871B2 (en) * | 2002-01-14 | 2008-07-08 | Eastman Chemical Comapny | Rubber modified acrylic and/or vinyl hybrid resins |
| KR102204133B1 (ko) * | 2013-04-23 | 2021-01-18 | 롬 앤드 하스 캄파니 | 중합체 분말 조성물 및 그의 제조방법 |
| KR102329711B1 (ko) * | 2014-03-31 | 2021-11-19 | 이네오스 스티롤루션 그룹 게엠베하 | 응집물 형성이 감소된 아크릴레이트 고무의 제조 방법 |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2646423A (en) * | 1951-05-25 | 1953-07-21 | Dow Chemical Co | Polymers of alkenyl aromatic compounds and acrylonitrile and method of making the same |
| DE1902646A1 (de) * | 1968-01-22 | 1969-09-04 | Fuji Photo Film Co Ltd | Verfahren zum Suspensionspolymerisieren |
| DE1911882B2 (de) * | 1969-03-08 | 1975-04-17 | Basf Ag, 6700 Ludwigshafen | Schlagfeste thermoplastische Massen |
| JPS5034592B1 (enExample) * | 1970-12-18 | 1975-11-10 | ||
| DE2826925A1 (de) * | 1978-06-20 | 1980-01-17 | Basf Ag | Witterungsbestaendige, schlagzaehe thermoplastische massen mit guter einfaerbbarkeit |
| US4341883A (en) * | 1980-10-29 | 1982-07-27 | Plaskolite, Inc. | Impact resistant blends of acrylate thermoplastic with sequentially polymerized four composition particulate additive |
| US4753988A (en) * | 1987-02-18 | 1988-06-28 | The Dow Chemical Company | High gloss acrylate rubber-modified weatherable resins |
| AU604179B2 (en) * | 1988-01-25 | 1990-12-06 | Mitsubishi Rayon Company Limited | Vinyl chloride resin composition |
| JP2674246B2 (ja) * | 1989-12-13 | 1997-11-12 | 日本合成ゴム株式会社 | 熱硬化性樹脂組成物 |
| JPH0912647A (ja) * | 1995-07-03 | 1997-01-14 | Sumika A B S Ratetsukusu Kk | 共重合体ラテックスの製造方法 |
-
1998
- 1998-11-23 US US09/197,788 patent/US6054531A/en not_active Expired - Lifetime
-
1999
- 1999-11-12 ES ES99964986T patent/ES2246587T3/es not_active Expired - Lifetime
- 1999-11-12 DE DE69926789T patent/DE69926789T2/de not_active Expired - Lifetime
- 1999-11-12 AT AT99964986T patent/ATE302219T1/de not_active IP Right Cessation
- 1999-11-12 EP EP99964986A patent/EP1137680B1/en not_active Expired - Lifetime
- 1999-11-12 CN CNB99813550XA patent/CN1211406C/zh not_active Expired - Fee Related
- 1999-11-12 JP JP2000583981A patent/JP2002530494A/ja active Pending
- 1999-11-12 WO PCT/US1999/026974 patent/WO2000031158A1/en not_active Ceased
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2007501892A (ja) * | 2003-05-09 | 2007-02-01 | ゼネラル・エレクトリック・カンパニイ | 耐衝撃性改良組成物及び方法 |
| JP2013047095A (ja) * | 2004-03-29 | 2013-03-07 | Albis Plastic Gmbh | 照明情報ユニット |
| WO2007114108A1 (ja) * | 2006-03-31 | 2007-10-11 | Zeon Corporation | アクリルゴムおよびその製造方法 |
| WO2017022423A1 (ja) * | 2015-07-31 | 2017-02-09 | 綜研化学株式会社 | （メタ）アクリル系架橋粒子およびその製造方法 |
| JPWO2017022423A1 (ja) * | 2015-07-31 | 2018-05-17 | 綜研化学株式会社 | （メタ）アクリル系架橋粒子およびその製造方法 |
| WO2017099409A1 (ko) | 2015-12-10 | 2017-06-15 | (주) 엘지화학 | 열가소성 그라프트 공중합체 수지, 이를 제조하는 방법, 및 이를 포함하는 열가소성 수지 조성물 |
| KR20170068746A (ko) | 2015-12-10 | 2017-06-20 | 주식회사 엘지화학 | 열가소성 그라프트 공중합체 수지, 이를 제조하는 방법, 및 이를 포함하는 열가소성 수지 조성물 |
| US10450453B2 (en) | 2015-12-10 | 2019-10-22 | Lg Chem, Ltd. | Thermoplastic graft copolymer resin, method of preparing the same, and thermoplastic resin composition including the same |
Also Published As
| Publication number | Publication date |
|---|---|
| EP1137680A1 (en) | 2001-10-04 |
| DE69926789T2 (de) | 2006-06-29 |
| WO2000031158A1 (en) | 2000-06-02 |
| DE69926789D1 (de) | 2005-09-22 |
| EP1137680B1 (en) | 2005-08-17 |
| US6054531A (en) | 2000-04-25 |
| ATE302219T1 (de) | 2005-09-15 |
| ES2246587T3 (es) | 2006-02-16 |
| CN1211406C (zh) | 2005-07-20 |
| CN1326474A (zh) | 2001-12-12 |
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