JP2002507975A - 親水性重合体及びその製造方法 - Google Patents
親水性重合体及びその製造方法Info
- Publication number
- JP2002507975A JP2002507975A JP50561199A JP50561199A JP2002507975A JP 2002507975 A JP2002507975 A JP 2002507975A JP 50561199 A JP50561199 A JP 50561199A JP 50561199 A JP50561199 A JP 50561199A JP 2002507975 A JP2002507975 A JP 2002507975A
- Authority
- JP
- Japan
- Prior art keywords
- emulsion
- hydrophilic
- polymer
- microbeads
- oil
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
- 229920001477 hydrophilic polymer Polymers 0.000 title claims abstract description 81
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 30
- 239000011325 microbead Substances 0.000 claims abstract description 157
- 239000000839 emulsion Substances 0.000 claims abstract description 151
- 239000000178 monomer Substances 0.000 claims abstract description 92
- 229920000642 polymer Polymers 0.000 claims abstract description 78
- 238000000034 method Methods 0.000 claims abstract description 61
- 239000012053 oil suspension Substances 0.000 claims abstract description 28
- 239000011148 porous material Substances 0.000 claims abstract description 14
- 238000006116 polymerization reaction Methods 0.000 claims description 53
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 42
- 238000010521 absorption reaction Methods 0.000 claims description 40
- 239000002609 medium Substances 0.000 claims description 40
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 37
- 239000003381 stabilizer Substances 0.000 claims description 35
- 239000000725 suspension Substances 0.000 claims description 31
- 239000003995 emulsifying agent Substances 0.000 claims description 23
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 22
- 239000002904 solvent Substances 0.000 claims description 22
- 239000003431 cross linking reagent Substances 0.000 claims description 18
- 239000011800 void material Substances 0.000 claims description 18
- 229920002678 cellulose Polymers 0.000 claims description 15
- 230000002209 hydrophobic effect Effects 0.000 claims description 15
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 13
- 239000011324 bead Substances 0.000 claims description 13
- 239000001913 cellulose Substances 0.000 claims description 13
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 12
- 239000007864 aqueous solution Substances 0.000 claims description 12
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 10
- 150000001875 compounds Chemical class 0.000 claims description 10
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 9
- 239000003960 organic solvent Substances 0.000 claims description 9
- 239000003505 polymerization initiator Substances 0.000 claims description 9
- 229920000609 methyl cellulose Polymers 0.000 claims description 8
- 239000001923 methylcellulose Substances 0.000 claims description 8
- 235000010981 methylcellulose Nutrition 0.000 claims description 8
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 claims description 7
- 230000000379 polymerizing effect Effects 0.000 claims description 7
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical group C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 6
- AFOSIXZFDONLBT-UHFFFAOYSA-N divinyl sulfone Chemical compound C=CS(=O)(=O)C=C AFOSIXZFDONLBT-UHFFFAOYSA-N 0.000 claims description 6
- ZIUHHBKFKCYYJD-UHFFFAOYSA-N n,n'-methylenebisacrylamide Chemical group C=CC(=O)NCNC(=O)C=C ZIUHHBKFKCYYJD-UHFFFAOYSA-N 0.000 claims description 6
- 239000000375 suspending agent Substances 0.000 claims description 6
- 239000001856 Ethyl cellulose Substances 0.000 claims description 5
- ZZSNKZQZMQGXPY-UHFFFAOYSA-N Ethyl cellulose Chemical compound CCOCC1OC(OC)C(OCC)C(OCC)C1OC1C(O)C(O)C(OC)C(CO)O1 ZZSNKZQZMQGXPY-UHFFFAOYSA-N 0.000 claims description 5
- 229920001059 synthetic polymer Polymers 0.000 claims description 5
- 125000001033 ether group Chemical group 0.000 claims description 4
- 229920001249 ethyl cellulose Polymers 0.000 claims description 4
- 235000019325 ethyl cellulose Nutrition 0.000 claims description 4
- SAMJGBVVQUEMGC-UHFFFAOYSA-N 1-ethenoxy-2-(2-ethenoxyethoxy)ethane Chemical compound C=COCCOCCOC=C SAMJGBVVQUEMGC-UHFFFAOYSA-N 0.000 claims description 3
- 239000004354 Hydroxyethyl cellulose Substances 0.000 claims description 3
- 125000004122 cyclic group Chemical group 0.000 claims description 3
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 claims description 3
- 229920005615 natural polymer Polymers 0.000 claims description 3
- 125000000217 alkyl group Chemical group 0.000 claims description 2
- 229920006037 cross link polymer Polymers 0.000 claims description 2
- 125000003944 tolyl group Chemical group 0.000 claims description 2
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 claims 8
- 229920000570 polyether Polymers 0.000 claims 7
- 238000002360 preparation method Methods 0.000 claims 7
- 239000004721 Polyphenylene oxide Substances 0.000 claims 5
- 235000006995 Syzygium moorei Nutrition 0.000 claims 4
- 240000002976 Syzygium moorei Species 0.000 claims 4
- 229910001870 ammonium persulfate Inorganic materials 0.000 claims 4
- 125000002877 alkyl aryl group Chemical group 0.000 claims 3
- 230000002906 microbiologic effect Effects 0.000 claims 3
- 229920001479 Hydroxyethyl methyl cellulose Polymers 0.000 claims 2
- 241000596422 Pithecellobium Species 0.000 claims 2
- 235000002194 Pithecellobium dulce Nutrition 0.000 claims 2
- 235000007891 Pithecellobium lobatum Nutrition 0.000 claims 2
- 239000004533 oil dispersion Substances 0.000 claims 2
- 239000003245 coal Substances 0.000 claims 1
- 235000010944 ethyl methyl cellulose Nutrition 0.000 claims 1
- 229920003087 methylethyl cellulose Polymers 0.000 claims 1
- 239000000463 material Substances 0.000 abstract description 6
- 239000012071 phase Substances 0.000 description 78
- 238000004132 cross linking Methods 0.000 description 33
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 26
- 241001122767 Theaceae Species 0.000 description 19
- 239000000203 mixture Substances 0.000 description 19
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 18
- 239000003638 chemical reducing agent Substances 0.000 description 18
- 239000011780 sodium chloride Substances 0.000 description 18
- 239000003054 catalyst Substances 0.000 description 17
- 239000003999 initiator Substances 0.000 description 16
- 239000000126 substance Substances 0.000 description 16
- 239000007788 liquid Substances 0.000 description 14
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical group N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 13
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 12
- 239000004971 Cross linker Substances 0.000 description 12
- 238000001035 drying Methods 0.000 description 12
- 239000000243 solution Substances 0.000 description 12
- 238000003756 stirring Methods 0.000 description 12
- -1 Alkali metal salts Chemical class 0.000 description 11
- YMWUJEATGCHHMB-UHFFFAOYSA-N dichloromethane Natural products ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 11
- 239000003795 chemical substances by application Substances 0.000 description 9
- 238000013019 agitation Methods 0.000 description 8
- 230000005484 gravity Effects 0.000 description 8
- 150000003839 salts Chemical class 0.000 description 8
- 238000012360 testing method Methods 0.000 description 8
- 229910001873 dinitrogen Inorganic materials 0.000 description 7
- 230000015572 biosynthetic process Effects 0.000 description 6
- 229910052757 nitrogen Inorganic materials 0.000 description 6
- 239000007787 solid Substances 0.000 description 6
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 5
- 239000000123 paper Substances 0.000 description 5
- 229920002554 vinyl polymer Polymers 0.000 description 5
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 4
- WOBHKFSMXKNTIM-UHFFFAOYSA-N Hydroxyethyl methacrylate Chemical compound CC(=C)C(=O)OCCO WOBHKFSMXKNTIM-UHFFFAOYSA-N 0.000 description 4
- 238000012662 bulk polymerization Methods 0.000 description 4
- 239000000470 constituent Substances 0.000 description 4
- 150000001923 cyclic compounds Chemical class 0.000 description 4
- 229940063557 methacrylate Drugs 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- 238000001878 scanning electron micrograph Methods 0.000 description 4
- 238000010008 shearing Methods 0.000 description 4
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 4
- 238000010557 suspension polymerization reaction Methods 0.000 description 4
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 4
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 4
- 239000002023 wood Substances 0.000 description 4
- OMIGHNLMNHATMP-UHFFFAOYSA-N 2-hydroxyethyl prop-2-enoate Chemical compound OCCOC(=O)C=C OMIGHNLMNHATMP-UHFFFAOYSA-N 0.000 description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 3
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 3
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 3
- 239000002202 Polyethylene glycol Substances 0.000 description 3
- 239000004372 Polyvinyl alcohol Substances 0.000 description 3
- 239000002250 absorbent Substances 0.000 description 3
- 230000002745 absorbent Effects 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 239000008346 aqueous phase Substances 0.000 description 3
- 229940079593 drug Drugs 0.000 description 3
- 239000003814 drug Substances 0.000 description 3
- 238000001914 filtration Methods 0.000 description 3
- 239000011521 glass Substances 0.000 description 3
- 150000002433 hydrophilic molecules Chemical class 0.000 description 3
- 230000000977 initiatory effect Effects 0.000 description 3
- JRKICGRDRMAZLK-UHFFFAOYSA-L persulfate group Chemical group S(=O)(=O)([O-])OOS(=O)(=O)[O-] JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 3
- 229920001223 polyethylene glycol Polymers 0.000 description 3
- 229920002451 polyvinyl alcohol Polymers 0.000 description 3
- 235000019422 polyvinyl alcohol Nutrition 0.000 description 3
- 229920006395 saturated elastomer Polymers 0.000 description 3
- 229920002818 (Hydroxyethyl)methacrylate Polymers 0.000 description 2
- KUDUQBURMYMBIJ-UHFFFAOYSA-N 2-prop-2-enoyloxyethyl prop-2-enoate Chemical compound C=CC(=O)OCCOC(=O)C=C KUDUQBURMYMBIJ-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical group C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- RGSFGYAAUTVSQA-UHFFFAOYSA-N Cyclopentane Chemical compound C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical group CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 2
- KWYHDKDOAIKMQN-UHFFFAOYSA-N N,N,N',N'-tetramethylethylenediamine Chemical compound CN(C)CCN(C)C KWYHDKDOAIKMQN-UHFFFAOYSA-N 0.000 description 2
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 2
- 229920002125 Sokalan® Polymers 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 238000002835 absorbance Methods 0.000 description 2
- 238000007605 air drying Methods 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 125000003277 amino group Chemical group 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- 239000010839 body fluid Substances 0.000 description 2
- 210000001124 body fluid Anatomy 0.000 description 2
- 150000001735 carboxylic acids Chemical class 0.000 description 2
- 238000005119 centrifugation Methods 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 238000004581 coalescence Methods 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 239000002612 dispersion medium Substances 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 238000007720 emulsion polymerization reaction Methods 0.000 description 2
- 238000000605 extraction Methods 0.000 description 2
- 238000000227 grinding Methods 0.000 description 2
- 230000008595 infiltration Effects 0.000 description 2
- 238000001764 infiltration Methods 0.000 description 2
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 2
- UAEPNZWRGJTJPN-UHFFFAOYSA-N methylcyclohexane Chemical compound CC1CCCCC1 UAEPNZWRGJTJPN-UHFFFAOYSA-N 0.000 description 2
- DYUWTXWIYMHBQS-UHFFFAOYSA-N n-prop-2-enylprop-2-en-1-amine Chemical compound C=CCNCC=C DYUWTXWIYMHBQS-UHFFFAOYSA-N 0.000 description 2
- 230000035515 penetration Effects 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 239000004584 polyacrylic acid Substances 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 230000002829 reductive effect Effects 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 235000010265 sodium sulphite Nutrition 0.000 description 2
- 235000000346 sugar Nutrition 0.000 description 2
- 229920003169 water-soluble polymer Polymers 0.000 description 2
- UOCLXMDMGBRAIB-UHFFFAOYSA-N 1,1,1-trichloroethane Chemical compound CC(Cl)(Cl)Cl UOCLXMDMGBRAIB-UHFFFAOYSA-N 0.000 description 1
- SCYULBFZEHDVBN-UHFFFAOYSA-N 1,1-Dichloroethane Chemical compound CC(Cl)Cl SCYULBFZEHDVBN-UHFFFAOYSA-N 0.000 description 1
- ZXHDVRATSGZISC-UHFFFAOYSA-N 1,2-bis(ethenoxy)ethane Chemical compound C=COCCOC=C ZXHDVRATSGZISC-UHFFFAOYSA-N 0.000 description 1
- XLPJNCYCZORXHG-UHFFFAOYSA-N 1-morpholin-4-ylprop-2-en-1-one Chemical compound C=CC(=O)N1CCOCC1 XLPJNCYCZORXHG-UHFFFAOYSA-N 0.000 description 1
- NEBBLNDVSSWJLL-UHFFFAOYSA-N 2,3-bis(2-methylprop-2-enoyloxy)propyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC(OC(=O)C(C)=C)COC(=O)C(C)=C NEBBLNDVSSWJLL-UHFFFAOYSA-N 0.000 description 1
- BJELTSYBAHKXRW-UHFFFAOYSA-N 2,4,6-triallyloxy-1,3,5-triazine Chemical compound C=CCOC1=NC(OCC=C)=NC(OCC=C)=N1 BJELTSYBAHKXRW-UHFFFAOYSA-N 0.000 description 1
- SJIXRGNQPBQWMK-UHFFFAOYSA-N 2-(diethylamino)ethyl 2-methylprop-2-enoate Chemical compound CCN(CC)CCOC(=O)C(C)=C SJIXRGNQPBQWMK-UHFFFAOYSA-N 0.000 description 1
- QHVBLSNVXDSMEB-UHFFFAOYSA-N 2-(diethylamino)ethyl prop-2-enoate Chemical compound CCN(CC)CCOC(=O)C=C QHVBLSNVXDSMEB-UHFFFAOYSA-N 0.000 description 1
- JKNCOURZONDCGV-UHFFFAOYSA-N 2-(dimethylamino)ethyl 2-methylprop-2-enoate Chemical group CN(C)CCOC(=O)C(C)=C JKNCOURZONDCGV-UHFFFAOYSA-N 0.000 description 1
- NDAJNMAAXXIADY-UHFFFAOYSA-N 2-methylpropanimidamide Chemical compound CC(C)C(N)=N NDAJNMAAXXIADY-UHFFFAOYSA-N 0.000 description 1
- KGIGUEBEKRSTEW-UHFFFAOYSA-N 2-vinylpyridine Chemical compound C=CC1=CC=CC=N1 KGIGUEBEKRSTEW-UHFFFAOYSA-N 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
- GAWIXWVDTYZWAW-UHFFFAOYSA-N C[CH]O Chemical group C[CH]O GAWIXWVDTYZWAW-UHFFFAOYSA-N 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 239000004641 Diallyl-phthalate Substances 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- 102000004190 Enzymes Human genes 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- 229920000896 Ethulose Polymers 0.000 description 1
- 239000001859 Ethyl hydroxyethyl cellulose Substances 0.000 description 1
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
- 238000006424 Flood reaction Methods 0.000 description 1
- 229920002907 Guar gum Polymers 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 1
- 229920002153 Hydroxypropyl cellulose Polymers 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- ZRKLEAHGBNDKHM-UHFFFAOYSA-N N,n'-diallyl-2,3-dihydroxysuccinamide Chemical compound C=CCNC(=O)C(O)C(O)C(=O)NCC=C ZRKLEAHGBNDKHM-UHFFFAOYSA-N 0.000 description 1
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 241001122315 Polites Species 0.000 description 1
- 229920002845 Poly(methacrylic acid) Polymers 0.000 description 1
- 239000005062 Polybutadiene Substances 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- DWAQJAXMDSEUJJ-UHFFFAOYSA-M Sodium bisulfite Chemical compound [Na+].OS([O-])=O DWAQJAXMDSEUJJ-UHFFFAOYSA-M 0.000 description 1
- 238000000944 Soxhlet extraction Methods 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical group [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 241000545760 Unio Species 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- GQBMZQUFIOSOMB-UHFFFAOYSA-N [Na].C(C)(=O)OO Chemical compound [Na].C(C)(=O)OO GQBMZQUFIOSOMB-UHFFFAOYSA-N 0.000 description 1
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 239000003463 adsorbent Substances 0.000 description 1
- 238000004220 aggregation Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 239000003125 aqueous solvent Substances 0.000 description 1
- 239000007900 aqueous suspension Substances 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 229910052785 arsenic Inorganic materials 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical group [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 238000010923 batch production Methods 0.000 description 1
- 230000001588 bifunctional effect Effects 0.000 description 1
- ZPOLOEWJWXZUSP-WAYWQWQTSA-N bis(prop-2-enyl) (z)-but-2-enedioate Chemical compound C=CCOC(=O)\C=C/C(=O)OCC=C ZPOLOEWJWXZUSP-WAYWQWQTSA-N 0.000 description 1
- QUDWYFHPNIMBFC-UHFFFAOYSA-N bis(prop-2-enyl) benzene-1,2-dicarboxylate Chemical compound C=CCOC(=O)C1=CC=CC=C1C(=O)OCC=C QUDWYFHPNIMBFC-UHFFFAOYSA-N 0.000 description 1
- ZDNFTNPFYCKVTB-UHFFFAOYSA-N bis(prop-2-enyl) benzene-1,4-dicarboxylate Chemical compound C=CCOC(=O)C1=CC=C(C(=O)OCC=C)C=C1 ZDNFTNPFYCKVTB-UHFFFAOYSA-N 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 150000007942 carboxylates Chemical group 0.000 description 1
- 229920002301 cellulose acetate Polymers 0.000 description 1
- 229920003086 cellulose ether Polymers 0.000 description 1
- 238000013375 chromatographic separation Methods 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 229920001940 conductive polymer Polymers 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 125000000753 cycloalkyl group Chemical group 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000000502 dialysis Methods 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 229910001882 dioxygen Inorganic materials 0.000 description 1
- VTIIJXUACCWYHX-UHFFFAOYSA-L disodium;carboxylatooxy carbonate Chemical compound [Na+].[Na+].[O-]C(=O)OOC([O-])=O VTIIJXUACCWYHX-UHFFFAOYSA-L 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 125000003700 epoxy group Chemical group 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 229940052303 ethers for general anesthesia Drugs 0.000 description 1
- 235000019326 ethyl hydroxyethyl cellulose Nutrition 0.000 description 1
- 229940093476 ethylene glycol Drugs 0.000 description 1
- 239000000284 extract Substances 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 239000003337 fertilizer Substances 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 239000001530 fumaric acid Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000000451 gelidium spp. gum Substances 0.000 description 1
- 239000000665 guar gum Substances 0.000 description 1
- 235000010417 guar gum Nutrition 0.000 description 1
- 229960002154 guar gum Drugs 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- DMEGYFMYUHOHGS-UHFFFAOYSA-N heptamethylene Natural products C1CCCCCC1 DMEGYFMYUHOHGS-UHFFFAOYSA-N 0.000 description 1
- PYGSKMBEVAICCR-UHFFFAOYSA-N hexa-1,5-diene Chemical group C=CCCC=C PYGSKMBEVAICCR-UHFFFAOYSA-N 0.000 description 1
- 150000004687 hexahydrates Chemical class 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 1
- 125000001165 hydrophobic group Chemical group 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 229920003063 hydroxymethyl cellulose Polymers 0.000 description 1
- 229940031574 hydroxymethyl cellulose Drugs 0.000 description 1
- 239000001863 hydroxypropyl cellulose Substances 0.000 description 1
- 235000010977 hydroxypropyl cellulose Nutrition 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000002917 insecticide Substances 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 239000012212 insulator Substances 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- 125000003010 ionic group Chemical group 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- WOSISLOTWLGNKT-UHFFFAOYSA-L iron(2+);dichloride;hexahydrate Chemical compound O.O.O.O.O.O.Cl[Fe]Cl WOSISLOTWLGNKT-UHFFFAOYSA-L 0.000 description 1
- 230000000670 limiting effect Effects 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- 210000004962 mammalian cell Anatomy 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000000401 methanolic extract Substances 0.000 description 1
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 1
- GYNNXHKOJHMOHS-UHFFFAOYSA-N methyl-cycloheptane Natural products CC1CCCCCC1 GYNNXHKOJHMOHS-UHFFFAOYSA-N 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 238000001000 micrograph Methods 0.000 description 1
- 239000004005 microsphere Substances 0.000 description 1
- WFKDPJRCBCBQNT-UHFFFAOYSA-N n,2-dimethylprop-2-enamide Chemical compound CNC(=O)C(C)=C WFKDPJRCBCBQNT-UHFFFAOYSA-N 0.000 description 1
- WAUMXMQJIMQTJK-UHFFFAOYSA-N n,n'-dihydroxyocta-2,6-dienediamide Chemical compound ONC(=O)C=CCCC=CC(=O)NO WAUMXMQJIMQTJK-UHFFFAOYSA-N 0.000 description 1
- BLYOHBPLFYXHQA-UHFFFAOYSA-N n,n-bis(prop-2-enyl)prop-2-enamide Chemical compound C=CCN(CC=C)C(=O)C=C BLYOHBPLFYXHQA-UHFFFAOYSA-N 0.000 description 1
- DJVKJGIZQFBFGS-UHFFFAOYSA-N n-[2-[2-(prop-2-enoylamino)ethyldisulfanyl]ethyl]prop-2-enamide Chemical compound C=CC(=O)NCCSSCCNC(=O)C=C DJVKJGIZQFBFGS-UHFFFAOYSA-N 0.000 description 1
- 229930014626 natural product Natural products 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 238000005192 partition Methods 0.000 description 1
- 238000010647 peptide synthesis reaction Methods 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 125000000951 phenoxy group Chemical group [H]C1=C([H])C([H])=C(O*)C([H])=C1[H] 0.000 description 1
- NXGWSWBWEQYMND-UHFFFAOYSA-N piperazine;prop-2-enamide Chemical compound NC(=O)C=C.NC(=O)C=C.C1CNCCN1 NXGWSWBWEQYMND-UHFFFAOYSA-N 0.000 description 1
- 229920001467 poly(styrenesulfonates) Polymers 0.000 description 1
- 229920013639 polyalphaolefin Polymers 0.000 description 1
- 229920002857 polybutadiene Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 229920000193 polymethacrylate Polymers 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920003053 polystyrene-divinylbenzene Polymers 0.000 description 1
- 229940068984 polyvinyl alcohol Drugs 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- UIIIBRHUICCMAI-UHFFFAOYSA-N prop-2-ene-1-sulfonic acid Chemical compound OS(=O)(=O)CC=C UIIIBRHUICCMAI-UHFFFAOYSA-N 0.000 description 1
- FBCQUCJYYPMKRO-UHFFFAOYSA-N prop-2-enyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC=C FBCQUCJYYPMKRO-UHFFFAOYSA-N 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 238000007717 redox polymerization reaction Methods 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 239000012266 salt solution Substances 0.000 description 1
- 238000013341 scale-up Methods 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 230000001568 sexual effect Effects 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 235000010267 sodium hydrogen sulphite Nutrition 0.000 description 1
- 229940045872 sodium percarbonate Drugs 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 238000010532 solid phase synthesis reaction Methods 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 150000008163 sugars Chemical class 0.000 description 1
- 238000006277 sulfonation reaction Methods 0.000 description 1
- 125000001174 sulfone group Chemical group 0.000 description 1
- 125000000542 sulfonic acid group Chemical group 0.000 description 1
- 150000003460 sulfonic acids Chemical class 0.000 description 1
- 229910052717 sulfur Chemical group 0.000 description 1
- 239000011593 sulfur Chemical group 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
- DHCDFWKWKRSZHF-UHFFFAOYSA-N sulfurothioic S-acid Chemical compound OS(O)(=O)=S DHCDFWKWKRSZHF-UHFFFAOYSA-N 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 238000013268 sustained release Methods 0.000 description 1
- 239000012730 sustained-release form Substances 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 238000004448 titration Methods 0.000 description 1
- PLCFYBDYBCOLSP-UHFFFAOYSA-N tris(prop-2-enyl) 2-hydroxypropane-1,2,3-tricarboxylate Chemical compound C=CCOC(=O)CC(O)(CC(=O)OCC=C)C(=O)OCC=C PLCFYBDYBCOLSP-UHFFFAOYSA-N 0.000 description 1
- XHGIFBQQEGRTPB-UHFFFAOYSA-N tris(prop-2-enyl) phosphate Chemical compound C=CCOP(=O)(OCC=C)OCC=C XHGIFBQQEGRTPB-UHFFFAOYSA-N 0.000 description 1
- GPRLSGONYQIRFK-MNYXATJNSA-N triton Chemical compound [3H+] GPRLSGONYQIRFK-MNYXATJNSA-N 0.000 description 1
- 238000009827 uniform distribution Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/28—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof by elimination of a liquid phase from a macromolecular composition or article, e.g. drying of coagulum
- C08J9/286—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof by elimination of a liquid phase from a macromolecular composition or article, e.g. drying of coagulum the liquid phase being a solvent for the monomers but not for the resulting macromolecular composition, i.e. macroporous or macroreticular polymers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L15/00—Chemical aspects of, or use of materials for, bandages, dressings or absorbent pads
- A61L15/16—Bandages, dressings or absorbent pads for physiological fluids such as urine or blood, e.g. sanitary towels, tampons
- A61L15/42—Use of materials characterised by their function or physical properties
- A61L15/425—Porous materials, e.g. foams or sponges
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L15/00—Chemical aspects of, or use of materials for, bandages, dressings or absorbent pads
- A61L15/16—Bandages, dressings or absorbent pads for physiological fluids such as urine or blood, e.g. sanitary towels, tampons
- A61L15/42—Use of materials characterised by their function or physical properties
- A61L15/60—Liquid-swellable gel-forming materials, e.g. super-absorbents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
- B01J20/26—Synthetic macromolecular compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Epidemiology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Dispersion Chemistry (AREA)
- Hematology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Analytical Chemistry (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Polymerisation Methods In General (AREA)
- Medicinal Preparation (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US08/883,950 US6048908A (en) | 1997-06-27 | 1997-06-27 | Hydrophilic polymeric material |
| US08/883,950 | 1997-06-27 | ||
| PCT/US1998/012797 WO1999000187A1 (en) | 1997-06-27 | 1998-06-24 | Hydrophilic polymeric material and method of preparation |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2002507975A true JP2002507975A (ja) | 2002-03-12 |
| JP2002507975A5 JP2002507975A5 (enExample) | 2005-12-22 |
Family
ID=25383648
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP50561199A Ceased JP2002507975A (ja) | 1997-06-27 | 1998-06-24 | 親水性重合体及びその製造方法 |
Country Status (6)
| Country | Link |
|---|---|
| US (2) | US6048908A (enExample) |
| EP (1) | EP0993337B1 (enExample) |
| JP (1) | JP2002507975A (enExample) |
| AU (1) | AU8154298A (enExample) |
| DE (1) | DE69823196T2 (enExample) |
| WO (1) | WO1999000187A1 (enExample) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2001526207A (ja) * | 1997-12-22 | 2001-12-18 | クウォドラント、ホールディングズ、ケンブリッジ、リミテッド | マイクロ粒子およびそれらの治療または診断使用 |
| JP2010535341A (ja) * | 2007-08-01 | 2010-11-18 | 日立化成工業株式会社 | 大容量微粒子サンプル中の病原体検出 |
| JP2011522919A (ja) * | 2008-06-09 | 2011-08-04 | コミッサリア ア レネルジー アトミーク エ オ ゼネルジ ザルタナテイヴ | 高強度のポリｈｉｐｅ材料、その製造方法、その製造に有用なエマルジョン、およびこの材料からなる物品 |
| JP2011168484A (ja) * | 2000-08-09 | 2011-09-01 | British American Tobacco (Investments) Ltd | 多孔性炭素 |
| JP2020510745A (ja) * | 2017-03-06 | 2020-04-09 | モアシス インコーポレイテッド | 親水性ポリマーを含有する高内相エマルションから調製する多孔性架橋親水性ポリマー材料 |
| JP2021106648A (ja) * | 2019-12-27 | 2021-07-29 | ユニ・チャーム株式会社 | 吸収性物品 |
Families Citing this family (96)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6835783B1 (en) * | 1999-02-24 | 2004-12-28 | Dow Global Technologies Inc. | Manufacture of superabsorbents in high internal phase emulsions |
| CN1191097C (zh) * | 1999-02-24 | 2005-03-02 | 陶氏环球技术公司 | 在高内相乳液中的超吸收剂的生产 |
| IN192012B (enExample) * | 1999-03-19 | 2004-02-07 | Vinod Chintamani Malshe | |
| US6395793B1 (en) * | 1999-11-18 | 2002-05-28 | Nippon Shokubai Co., Ltd. | Method for production of porous material |
| DE19962197A1 (de) * | 1999-12-22 | 2001-07-05 | Innovation Pro Terra Gmbh & Co | Absorber, vorzugsweise Stoff zur Aufnahme und/oder zum Austausch von Ionen |
| KR20080046750A (ko) * | 2000-03-24 | 2008-05-27 | 바이오스피어 메디칼 인코포레이티드 | 능동 색전화용 미소구 |
| US20030212022A1 (en) * | 2001-03-23 | 2003-11-13 | Jean-Marie Vogel | Compositions and methods for gene therapy |
| US8591855B2 (en) * | 2000-08-09 | 2013-11-26 | British American Tobacco (Investments) Limited | Porous carbons |
| WO2002040559A2 (en) * | 2000-11-20 | 2002-05-23 | Matrix Innovation Inc. | Amphiphile solid support for peptide synthesis, bioorganic and organic chemistry |
| US20030072804A1 (en) * | 2001-03-19 | 2003-04-17 | The Procter & Gamble Company | Use of non-digestible polymeric foams to sequester ingested materials thereby inhibiting their absorption by the body |
| US6897247B2 (en) * | 2001-08-14 | 2005-05-24 | Polye Inc. | High internal phase polymeric emulsion composition |
| US7131997B2 (en) * | 2002-03-29 | 2006-11-07 | Scimed Life Systems, Inc. | Tissue treatment |
| US7462366B2 (en) * | 2002-03-29 | 2008-12-09 | Boston Scientific Scimed, Inc. | Drug delivery particle |
| US7094369B2 (en) * | 2002-03-29 | 2006-08-22 | Scimed Life Systems, Inc. | Processes for manufacturing polymeric microspheres |
| US7053134B2 (en) * | 2002-04-04 | 2006-05-30 | Scimed Life Systems, Inc. | Forming a chemically cross-linked particle of a desired shape and diameter |
| GB0215833D0 (en) * | 2002-07-09 | 2002-08-14 | Akay Galip | Rotating porous disk reactors their contraction and use |
| GB2399084B (en) * | 2002-07-30 | 2007-01-31 | Univ Liverpool | Porous beads and method of production thereof |
| US7842377B2 (en) * | 2003-08-08 | 2010-11-30 | Boston Scientific Scimed, Inc. | Porous polymeric particle comprising polyvinyl alcohol and having interior to surface porosity-gradient |
| US7449236B2 (en) * | 2002-08-09 | 2008-11-11 | Boston Scientific Scimed, Inc. | Porous polymeric particle comprising polyvinyl alcohol and having interior to surface porosity-gradient |
| US8012454B2 (en) * | 2002-08-30 | 2011-09-06 | Boston Scientific Scimed, Inc. | Embolization |
| US7588825B2 (en) * | 2002-10-23 | 2009-09-15 | Boston Scientific Scimed, Inc. | Embolic compositions |
| US7883490B2 (en) * | 2002-10-23 | 2011-02-08 | Boston Scientific Scimed, Inc. | Mixing and delivery of therapeutic compositions |
| DE10251144A1 (de) * | 2002-10-31 | 2004-05-19 | Röhm GmbH & Co. KG | Makroporöses Kunststoffperlenmaterial |
| US7976823B2 (en) | 2003-08-29 | 2011-07-12 | Boston Scientific Scimed, Inc. | Ferromagnetic particles and methods |
| US7901770B2 (en) | 2003-11-04 | 2011-03-08 | Boston Scientific Scimed, Inc. | Embolic compositions |
| US20050113780A1 (en) * | 2003-11-21 | 2005-05-26 | The Procter & Gamble Company | Tampon |
| GB0401947D0 (en) * | 2004-01-28 | 2004-03-03 | Unilever Plc | Porous bodies and method of production thereof |
| GB0401950D0 (en) * | 2004-01-28 | 2004-03-03 | Unilever Plc | Porous bodies and method of production thereof |
| WO2005073300A1 (en) * | 2004-01-28 | 2005-08-11 | Unilever Plc | Porous bodies and method of production thereof |
| US7736671B2 (en) | 2004-03-02 | 2010-06-15 | Boston Scientific Scimed, Inc. | Embolization |
| US8173176B2 (en) | 2004-03-30 | 2012-05-08 | Boston Scientific Scimed, Inc. | Embolization |
| US20050238870A1 (en) * | 2004-04-22 | 2005-10-27 | Marcia Buiser | Embolization |
| US7311861B2 (en) * | 2004-06-01 | 2007-12-25 | Boston Scientific Scimed, Inc. | Embolization |
| FR2874824B1 (fr) | 2004-09-09 | 2006-12-01 | Oreal | Composition de coiffage comprenant l'association d'un materiau polymerique hydrophile de haute porosite et polymere fixant |
| US20060057094A1 (en) * | 2004-09-09 | 2006-03-16 | Estelle Mathonneau | Hair styling composition comprising at least one hydrophilic polymeric high porosity material and at least one fixing polymer |
| US20060073208A1 (en) * | 2004-10-01 | 2006-04-06 | Allergan, Inc. | Cosmetic neurotoxin compositions and methods |
| US8425550B2 (en) | 2004-12-01 | 2013-04-23 | Boston Scientific Scimed, Inc. | Embolic coils |
| US7727555B2 (en) * | 2005-03-02 | 2010-06-01 | Boston Scientific Scimed, Inc. | Particles |
| US7858183B2 (en) * | 2005-03-02 | 2010-12-28 | Boston Scientific Scimed, Inc. | Particles |
| US7963287B2 (en) | 2005-04-28 | 2011-06-21 | Boston Scientific Scimed, Inc. | Tissue-treatment methods |
| MX2007013914A (es) | 2005-05-09 | 2008-02-22 | Biosphere Medical S A | Composiciones y metodos que usan microesferas y agentes de contraste no ionicos. |
| US20070004973A1 (en) * | 2005-06-15 | 2007-01-04 | Tan Sharon M L | Tissue treatment methods |
| US9463426B2 (en) * | 2005-06-24 | 2016-10-11 | Boston Scientific Scimed, Inc. | Methods and systems for coating particles |
| US8007509B2 (en) | 2005-10-12 | 2011-08-30 | Boston Scientific Scimed, Inc. | Coil assemblies, components and methods |
| US8101197B2 (en) | 2005-12-19 | 2012-01-24 | Stryker Corporation | Forming coils |
| US8152839B2 (en) | 2005-12-19 | 2012-04-10 | Boston Scientific Scimed, Inc. | Embolic coils |
| US20070142560A1 (en) * | 2005-12-21 | 2007-06-21 | Young-Ho Song | Block copolymer particles |
| US7947368B2 (en) * | 2005-12-21 | 2011-05-24 | Boston Scientific Scimed, Inc. | Block copolymer particles |
| US7501179B2 (en) * | 2005-12-21 | 2009-03-10 | Boston Scientific Scimed, Inc. | Block copolymer particles |
| US20080033366A1 (en) * | 2006-01-30 | 2008-02-07 | Surgica Corporation | Compressible intravascular embolization particles and related methods and delivery systems |
| EP1986706B1 (en) * | 2006-01-30 | 2011-08-17 | Biosphere Medical, Inc. | Porous intravascular embolization particles and methods of making them |
| KR101410152B1 (ko) * | 2006-03-10 | 2014-06-20 | 바스프 에스이 | 절지동물 해충, 달팽이 및 선충류를 퇴치하기 위한 살충제 조성물 |
| US7838035B2 (en) * | 2006-04-11 | 2010-11-23 | E. I. Du Pont De Nemours And Company | Microsphere powder of high density, swellable, deformable, durable occlusion-forming microspheres |
| US8062673B2 (en) | 2006-04-11 | 2011-11-22 | E I Du Pont De Nemours And Company | Process for embolization using swellable and deformable microspheres |
| US8252339B2 (en) * | 2006-04-11 | 2012-08-28 | Massachusetts Institute Of Technology | Medical treatment applications of swellable and deformable microspheres |
| US7794755B2 (en) * | 2006-04-11 | 2010-09-14 | E.I. Du Pont De Nemours And Company | Process for preparation of swellable and deformable microspheres |
| US20100028295A1 (en) | 2006-09-14 | 2010-02-04 | Claude Taranta | Pesticide Composition |
| US8187636B2 (en) | 2006-09-25 | 2012-05-29 | Atlantic Pharmaceuticals, Inc. | Dosage forms for tamper prone therapeutic agents |
| US8414927B2 (en) | 2006-11-03 | 2013-04-09 | Boston Scientific Scimed, Inc. | Cross-linked polymer particles |
| US9874501B2 (en) | 2006-11-24 | 2018-01-23 | Curiox Biosystems Pte Ltd. | Use of chemically patterned substrate for liquid handling, chemical and biological reactions |
| WO2008063135A1 (en) | 2006-11-24 | 2008-05-29 | Agency For Science, Technology And Research | Apparatus for processing a sample in a liquid droplet and method of using the same |
| WO2010120249A1 (en) | 2009-04-17 | 2010-10-21 | Curiox Biosystems Pte Ltd | Use of chemically patterned substrate for liquid handling, chemical and biological reactions |
| US7887846B2 (en) * | 2007-08-07 | 2011-02-15 | E. I. Du Pont De Nemours And Company | Process for preparation of swellable and degradable microspheres |
| US8241609B2 (en) * | 2007-08-24 | 2012-08-14 | E I Du Pont De Nemours And Company | Method for embolization using liquid embolic materials |
| US20110091512A1 (en) * | 2007-09-05 | 2011-04-21 | Sunstorm Research Corporation | Highly porous, large polymeric particles and methods of preparation and use |
| US8940362B2 (en) * | 2007-10-11 | 2015-01-27 | Eastman Kodak Company | Method for manufacturing porous particles with non-porous shell |
| US10725020B2 (en) | 2007-11-14 | 2020-07-28 | Curiox Biosystems Pte Ltd. | High throughput miniaturized assay system and methods |
| WO2013114217A1 (en) | 2012-02-05 | 2013-08-08 | Curiox Biosystems Pte Ltd. | Array plates and methods for making and using same |
| WO2009111684A1 (en) * | 2008-03-06 | 2009-09-11 | E. I. Du Pont De Nemours And Company | Process for making coated, water-swellable hydrogel microspheres |
| JP5274647B2 (ja) * | 2008-04-18 | 2013-08-28 | サンーゴバン アブレイシブズ，インコーポレイティド | 高空隙率研摩材物品およびその製造方法 |
| US20110212179A1 (en) * | 2008-10-30 | 2011-09-01 | David Liu | Micro-spherical porous biocompatible scaffolds and methods and apparatus for fabricating same |
| US20100215700A1 (en) * | 2009-02-25 | 2010-08-26 | Conopco, Inc., D/B/A Unilever | Shear Gels and Compositions Comprising Shear Gels |
| JP5697654B2 (ja) | 2009-03-19 | 2015-04-08 | エージェンシー フォー サイエンス，テクノロジー アンド リサーチ | 親水性の異なるモノマーを含む両連続マイクロエマルションからのコポリマーの形成 |
| WO2010129623A2 (en) * | 2009-05-04 | 2010-11-11 | Sunstorm Research Corporation | Process for reducing residual surface material from porous polymers |
| WO2012011877A2 (en) | 2010-07-23 | 2012-01-26 | Curiox Biosystems Pte Ltd | Apparatus and method for multiple reactions in small volumes |
| US8668916B2 (en) * | 2010-09-24 | 2014-03-11 | Conopco, Inc. | HIPE-gelation process for making highly concentrated, spherical biopolymer gel particle suspensions |
| FR2974312B1 (fr) | 2011-04-20 | 2013-05-17 | Agronomique Inst Nat Rech | Procede d'obtention d'emulsions a haute phase interne |
| DE102011107197A1 (de) * | 2011-07-13 | 2013-01-17 | Instraction Gmbh | Ionenaustauschermaterial mit hoher Salztoleranz |
| FR2996848B1 (fr) | 2012-10-16 | 2014-10-31 | Agronomique Inst Nat Rech | Composition comprenant une phase interne dispersee dans une phase continue hydrophile |
| US9557318B2 (en) | 2013-07-09 | 2017-01-31 | Curiox Biosystems Pte Ltd. | Array plates for washing samples |
| BR112016005768B1 (pt) | 2013-09-19 | 2021-09-21 | Microvention, Inc | Películas de polímero |
| CA2923753C (en) | 2013-09-19 | 2021-10-12 | Terumo Corporation | Polymer particles |
| EP3065719A4 (en) | 2013-11-08 | 2017-08-09 | Terumo Corporation | Polymer particles |
| US10413881B2 (en) | 2013-12-18 | 2019-09-17 | 3M Innovative Properties Company | Porous articles for separation |
| US10072161B2 (en) | 2014-01-23 | 2018-09-11 | Bar Ilan University | Polyamide nanoparticles and uses thereof |
| US10286100B2 (en) | 2014-10-01 | 2019-05-14 | 3M Innovative Properties Company | Medical dressings comprising fluid management articles and methods of using same |
| WO2016053830A1 (en) | 2014-10-01 | 2016-04-07 | 3M Innovative Properties Company | Articles including fibrous substrates and porous polymeric particles and methods of making same |
| JP6975640B2 (ja) | 2015-03-06 | 2021-12-01 | スリーエム イノベイティブ プロパティズ カンパニー | 多孔質ポリマー粒子を含む組成物及び接着剤物品、並びに基材をコーティングする方法 |
| US20180057770A1 (en) | 2015-03-23 | 2018-03-01 | 3M Innovative Properties Company | Polymeric composite particles |
| US9907880B2 (en) | 2015-03-26 | 2018-03-06 | Microvention, Inc. | Particles |
| US10545139B2 (en) | 2015-06-16 | 2020-01-28 | Curiox Biosystems Pte Ltd. | Methods and devices for performing biological assays using magnetic components |
| IL247302B (en) | 2016-08-16 | 2019-03-31 | Technion Res & Dev Foundation | Systems for releasing materials based on polymer emulsions |
| CA3038642C (en) | 2016-09-28 | 2021-11-02 | Terumo Corporation | Polymer particles comprising polymerizable pharmaceutical agents |
| WO2018117548A1 (ko) * | 2016-12-23 | 2018-06-28 | 주식회사 엘지화학 | 다공성 고흡수성 수지의 제조 방법 및 다공성 고흡수성 수지 |
| KR20220132668A (ko) | 2017-04-05 | 2022-09-30 | 큐리옥스 바이오시스템즈 피티이 엘티디. | 어레이 플레이트 상의 샘플을 세정하기 위한 방법, 디바이스 및 장치 |
| CN120285261B (zh) * | 2025-05-28 | 2025-10-14 | 广东宜柔健康产品有限公司 | 一种超吸收纸尿裤及其制备方法和应用 |
Family Cites Families (81)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1137554B (de) * | 1961-06-21 | 1962-10-04 | Bayer Ag | Verfahren zur Polymerisation von wasserunloeslichen Monomeren |
| US3460972A (en) * | 1965-09-29 | 1969-08-12 | Battelle Development Corp | Liquid encapsulation |
| AU439432B2 (en) * | 1968-11-28 | 1972-08-15 | Dulux Australia Ltd | Polymer and coating composition |
| US3933579A (en) * | 1968-11-28 | 1976-01-20 | Dulux Australia Limited | Vesiculated polymer granules |
| BE759698A (fr) * | 1969-12-01 | 1971-06-01 | Balm Paints Ltd | Polymere vesiculeux |
| GB1332469A (en) * | 1969-12-22 | 1973-10-03 | Balm Paints Ltd | Polymer and process |
| US3822224A (en) * | 1969-12-22 | 1974-07-02 | Balm Paints Ltd | Process of preparing vesiculated crosslinked polyester resin granules |
| DE2010115A1 (de) * | 1970-03-04 | 1971-09-16 | Farbenfabriken Bayer Ag, 5090 Leverkusen | Verfahren zur Herstellung von Mikrogranulaten |
| JPS528795B2 (enExample) * | 1971-12-30 | 1977-03-11 | ||
| US4137380A (en) * | 1972-11-13 | 1979-01-30 | Dulux Australia Ltd. | Polyester granules and process |
| AR206777A1 (es) * | 1972-11-13 | 1976-08-23 | Dulux Australia Ltd | Procedimiento para preparar suspension acuosa de granulos vesiculares de resina poliester resiculares de resina poliester retenida |
| US3988508A (en) * | 1973-03-08 | 1976-10-26 | Petrolite Corporation | High internal phase ratio emulsion polymers |
| AU481144B2 (en) * | 1973-10-04 | 1977-02-21 | Dulux Australia Ltd. | POLYMER BEAD PROCESS Specification |
| AU533959B2 (en) * | 1979-12-07 | 1983-12-22 | Orica Australia Pty Ltd | Polymerisation to form granules of unsaturated polyester resin |
| US4401456A (en) * | 1980-01-09 | 1983-08-30 | The United States Of America As Represented By The Secretary Of Agriculture | Controlled release of bioactive materials using alginate gel beads |
| US4384975A (en) * | 1980-06-13 | 1983-05-24 | Sandoz, Inc. | Process for preparation of microspheres |
| NZ199916A (en) * | 1981-03-11 | 1985-07-12 | Unilever Plc | Low density polymeric block material for use as carrier for included liquids |
| ZW17683A1 (en) * | 1982-08-10 | 1985-03-06 | Dulux Australia Ltd | Process of preparing vesiculated polyester granules |
| NZ205449A (en) * | 1982-09-07 | 1986-10-08 | Unilever Plc | Sulphonated,porous,cross-linked polymeric material |
| JPS59193901A (ja) * | 1983-04-20 | 1984-11-02 | Pola Chem Ind Inc | 球状の空胞を有する球状重合体の製造法 |
| US4818542A (en) * | 1983-11-14 | 1989-04-04 | The University Of Kentucky Research Foundation | Porous microspheres for drug delivery and methods for making same |
| GB8405680D0 (en) * | 1984-03-05 | 1984-04-11 | Unilever Plc | Porous polymers |
| GB8511048D0 (en) * | 1985-05-01 | 1985-06-12 | Unilever Plc | Inorganic structures |
| US4690825A (en) * | 1985-10-04 | 1987-09-01 | Advanced Polymer Systems, Inc. | Method for delivering an active ingredient by controlled time release utilizing a novel delivery vehicle which can be prepared by a process utilizing the active ingredient as a porogen |
| US5246714A (en) * | 1985-10-11 | 1993-09-21 | Aktiebolaget Hassle | Drug preparation |
| US4742086A (en) * | 1985-11-02 | 1988-05-03 | Lion Corporation | Process for manufacturing porous polymer |
| CA1291110C (en) * | 1985-11-18 | 1991-10-22 | Christopher John Carruthers Edwards | Porous carbon structures and methods for their preparation |
| US5145675A (en) * | 1986-03-31 | 1992-09-08 | Advanced Polymer Systems, Inc. | Two step method for preparation of controlled release formulations |
| US4629742A (en) * | 1986-01-27 | 1986-12-16 | Akzo America Inc. | Hydrolysis of fats |
| GB8607535D0 (en) * | 1986-03-26 | 1986-04-30 | Unilever Plc | Elastic cross-linked polymeric materials |
| GB8608155D0 (en) * | 1986-04-03 | 1986-05-08 | Unilever Plc | Modified filters |
| US4741872A (en) * | 1986-05-16 | 1988-05-03 | The University Of Kentucky Research Foundation | Preparation of biodegradable microspheres useful as carriers for macromolecules |
| GB2199541A (en) * | 1986-10-16 | 1988-07-13 | Rig Design Services | Production of engineering drawings |
| NZ224284A (en) * | 1987-04-24 | 1990-11-27 | Unilever Plc | Porous substrate containing gel for use in chemical synthesis, separation etc |
| GB8709688D0 (en) * | 1987-04-24 | 1987-05-28 | Unilever Plc | Porous material |
| ES2029345T3 (es) * | 1987-08-26 | 1992-08-01 | Ciba-Geigy Ag | Blanqueadores opticos de dispersion. |
| GB8729889D0 (en) * | 1987-12-22 | 1988-02-03 | Unilever Plc | Bio-catalysts support systems |
| US4898734A (en) * | 1988-02-29 | 1990-02-06 | Massachusetts Institute Of Technology | Polymer composite for controlled release or membrane formation |
| ZA892859B (en) * | 1988-04-22 | 1989-12-27 | Advanced Polymer Systems Inc | Porous particles in preparations involving immiscible phases |
| US4873091A (en) * | 1988-05-23 | 1989-10-10 | Advanced Polymer Systems, Inc. | Controlled release formulating employing resilient microbeads |
| US5840293A (en) * | 1988-11-16 | 1998-11-24 | Advanced Polymer Systems, Inc. | Ionic beads for controlled release and adsorption |
| US5169904A (en) * | 1989-04-07 | 1992-12-08 | Dow Corning Corporation | Method of making hydrophobic copolymers hydrophilic |
| US5135872A (en) * | 1989-04-28 | 1992-08-04 | Sangstat Medical Corporation | Matrix controlled method of delayed fluid delivery for assays |
| US5073365A (en) * | 1989-06-01 | 1991-12-17 | Advanced Polymer Systems | Clinical and personal care articles enhanced by lubricants and adjuvants |
| JP2641620B2 (ja) * | 1989-11-09 | 1997-08-20 | アドバンスト ポリマー システムズ，インコーポレイティド | 経口導入製品に味付けする方法及び組成物 |
| IT1237904B (it) * | 1989-12-14 | 1993-06-18 | Ubaldo Conte | Compresse a rilascio a velocita' controllata delle sostanze attive |
| DE69114006T2 (de) * | 1990-06-20 | 1996-05-02 | Advanced Polymer Systems Inc | Zusammensetzungen und verfahren für die kontrollierte freisetzung von löslichen wirkstoffen. |
| GB9014689D0 (en) * | 1990-07-02 | 1990-08-22 | Tioxide Group Services Ltd | Supports for active entities |
| JP2967952B2 (ja) * | 1991-07-23 | 1999-10-25 | 日本化薬株式会社 | 多孔性ポリマーの製造方法 |
| US5352711A (en) * | 1991-08-12 | 1994-10-04 | The Proctor & Gamble Company | Method for hydrophilizing absorbent foam materials |
| US5147345A (en) * | 1991-08-12 | 1992-09-15 | The Procter & Gamble Company | High efficiency absorbent articles for incontinence management |
| US5387207A (en) * | 1991-08-12 | 1995-02-07 | The Procter & Gamble Company | Thin-unit-wet absorbent foam materials for aqueous body fluids and process for making same |
| TW246682B (enExample) * | 1991-08-12 | 1995-05-01 | Procter & Gamble | |
| US5149720A (en) * | 1991-08-12 | 1992-09-22 | The Procter & Gamble Company | Process for preparing emulsions that are polymerizable to absorbent foam materials |
| US5268224A (en) * | 1991-08-12 | 1993-12-07 | The Procter & Gamble Company | Absorbent foam materials for aqueous body fluids and absorbent articles containing such materials |
| US5154713A (en) * | 1991-10-22 | 1992-10-13 | Nalco Chemical Company | Enhancing absorption rates of superabsorbents by incorporating a blowing agent |
| US5200433A (en) * | 1992-04-20 | 1993-04-06 | Shell Oil Company | Process for preparing low density porous crosslinked polymeric materials |
| US5393528A (en) * | 1992-05-07 | 1995-02-28 | Staab; Robert J. | Dissolvable device for contraception or delivery of medication |
| US5252619A (en) * | 1992-05-29 | 1993-10-12 | Shell Oil Company | Process for preparing low density porous crosslinked polymeric materials |
| US5189070A (en) * | 1992-05-29 | 1993-02-23 | Shell Oil Company | Process for preparing low density porous crosslinked polymeric materials |
| US5268097A (en) * | 1992-06-19 | 1993-12-07 | Sepracor Inc. | Passivated and stabilized porous mineral oxide supports and method for the preparation and use of same |
| US5397316A (en) * | 1993-06-25 | 1995-03-14 | The Procter & Gamble Company | Slitted absorbent members for aqueous body fluids formed of expandable absorbent materials |
| US5306733A (en) * | 1993-08-30 | 1994-04-26 | Shell Oil Company | Low density porous crosslinked polymeric materials |
| US5306734A (en) * | 1993-09-08 | 1994-04-26 | Shell Oil Company | Use of viscosity as an in-line diagnostic for high internal phase emulsion generation |
| US5425265A (en) * | 1993-12-20 | 1995-06-20 | Jaisinghani; Rajan A. | Apparatus and method for measuring the capillary pressure distribution of porous materials |
| AU7094094A (en) * | 1994-05-13 | 1995-12-05 | University Of Cincinnati, The | Microporous fast response gels and methods of use |
| JP3608625B2 (ja) * | 1994-05-15 | 2005-01-12 | アメルシャム・バイオサイエンシーズ・アクチボラグ | 粒子の製造方法、及び該方法によって製造され得る粒子 |
| US5571531A (en) * | 1994-05-18 | 1996-11-05 | Mcmaster University | Microparticle delivery system with a functionalized silicone bonded to the matrix |
| US5583162A (en) * | 1994-06-06 | 1996-12-10 | Biopore Corporation | Polymeric microbeads and method of preparation |
| US5767168A (en) * | 1995-03-30 | 1998-06-16 | The Proctor & Gamble Company | Biodegradable and/or compostable polymers made from conjugated dienes such as isoprene and 2,3-dimethyl-1, 3-butadiene |
| US5650222A (en) * | 1995-01-10 | 1997-07-22 | The Procter & Gamble Company | Absorbent foam materials for aqueous fluids made from high internal phase emulsions having very high water-to-oil ratios |
| US5922780A (en) * | 1995-01-10 | 1999-07-13 | The Procter & Gamble Company | Crosslinked polymers made from 1,3,7-octatriene and like conjugated polyenes |
| US5500451A (en) * | 1995-01-10 | 1996-03-19 | The Procter & Gamble Company | Use of polyglycerol aliphatic ether emulsifiers in making high internal phase emulsions that can be polymerized to provide absorbent foams |
| MY132433A (en) * | 1995-01-10 | 2007-10-31 | Procter & Gamble | Foams made from high internal phase emulsions useful as absorbent members for catamenial pads |
| US5759569A (en) * | 1995-01-10 | 1998-06-02 | The Procter & Gamble Company | Biodegradable articles made from certain trans-polymers and blends thereof with other biodegradable components |
| US5563179A (en) * | 1995-01-10 | 1996-10-08 | The Proctor & Gamble Company | Absorbent foams made from high internal phase emulsions useful for acquiring and distributing aqueous fluids |
| US5873869A (en) * | 1995-03-02 | 1999-02-23 | The Procter & Gamble Company | Absorbent article with foam absorbent structure providing improved menses acquisition and fit |
| US5633291A (en) * | 1995-06-07 | 1997-05-27 | The Procter & Gamble Company | Use of foam materials derived from high internal phase emulsions for insulation |
| US5770634A (en) * | 1995-06-07 | 1998-06-23 | The Procter & Gamble Company | Foam materials for insulation, derived from high internal phase emulsions |
| US5550167A (en) * | 1995-08-30 | 1996-08-27 | The Procter & Gamble Company | Absorbent foams made from high internal phase emulsions useful for acquiring aqueous fluids |
| US5817704A (en) * | 1996-03-08 | 1998-10-06 | The Procter & Gamble Company | Heterogeneous foam materials |
-
1997
- 1997-06-27 US US08/883,950 patent/US6048908A/en not_active Expired - Lifetime
-
1998
- 1998-06-24 DE DE69823196T patent/DE69823196T2/de not_active Expired - Lifetime
- 1998-06-24 AU AU81542/98A patent/AU8154298A/en not_active Abandoned
- 1998-06-24 WO PCT/US1998/012797 patent/WO1999000187A1/en not_active Ceased
- 1998-06-24 JP JP50561199A patent/JP2002507975A/ja not_active Ceased
- 1998-06-24 EP EP98931399A patent/EP0993337B1/en not_active Expired - Lifetime
-
2000
- 2000-07-25 US US09/624,711 patent/US6218440B1/en not_active Expired - Lifetime
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2001526207A (ja) * | 1997-12-22 | 2001-12-18 | クウォドラント、ホールディングズ、ケンブリッジ、リミテッド | マイクロ粒子およびそれらの治療または診断使用 |
| JP2011168484A (ja) * | 2000-08-09 | 2011-09-01 | British American Tobacco (Investments) Ltd | 多孔性炭素 |
| JP2010535341A (ja) * | 2007-08-01 | 2010-11-18 | 日立化成工業株式会社 | 大容量微粒子サンプル中の病原体検出 |
| JP2011522919A (ja) * | 2008-06-09 | 2011-08-04 | コミッサリア ア レネルジー アトミーク エ オ ゼネルジ ザルタナテイヴ | 高強度のポリｈｉｐｅ材料、その製造方法、その製造に有用なエマルジョン、およびこの材料からなる物品 |
| JP2020510745A (ja) * | 2017-03-06 | 2020-04-09 | モアシス インコーポレイテッド | 親水性ポリマーを含有する高内相エマルションから調製する多孔性架橋親水性ポリマー材料 |
| JP2021106648A (ja) * | 2019-12-27 | 2021-07-29 | ユニ・チャーム株式会社 | 吸収性物品 |
| JP2024014926A (ja) * | 2019-12-27 | 2024-02-01 | ユニ・チャーム株式会社 | 吸収性物品 |
| JP7467115B2 (ja) | 2019-12-27 | 2024-04-15 | ユニ・チャーム株式会社 | 吸収性物品 |
| JP7657890B2 (ja) | 2019-12-27 | 2025-04-07 | ユニ・チャーム株式会社 | 吸収性物品 |
Also Published As
| Publication number | Publication date |
|---|---|
| DE69823196T2 (de) | 2005-04-14 |
| AU8154298A (en) | 1999-01-19 |
| US6218440B1 (en) | 2001-04-17 |
| US6048908A (en) | 2000-04-11 |
| DE69823196D1 (de) | 2004-05-19 |
| WO1999000187A1 (en) | 1999-01-07 |
| EP0993337A1 (en) | 2000-04-19 |
| EP0993337B1 (en) | 2004-04-14 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP2002507975A (ja) | 親水性重合体及びその製造方法 | |
| EP0516925B1 (en) | Wrinkled absorbent particles of high effective surface area having fast absorption rate | |
| EP0060138B1 (en) | Low density porous cross-linked polymeric materials and their preparation | |
| DE69531617T3 (de) | Polymere mikrokugen und herstellungsverfahren | |
| Gao et al. | Double emulsion templated microcapsules with single hollow cavities and thickness-controllable shells | |
| SA93130564B1 (ar) | عملية لتحضير مواد بوليمرية Polymeric Materials متقاطعة الروابط crosslinked ومسامية ومنخفضة الكثافة low density | |
| US20110091512A1 (en) | Highly porous, large polymeric particles and methods of preparation and use | |
| TWI757039B (zh) | 用於製造多孔微結構的方法 | |
| WO1994019377A1 (en) | Suspension polymerized aqueous absorbent polymer particles | |
| US6949601B1 (en) | Single stage seed polymerization for the production of large polymer particles with a narrow size distribution | |
| JPH1036411A (ja) | 多孔質架橋ポリマー材料の製造方法 | |
| JPH0366323B2 (enExample) | ||
| Ponrathnam et al. | Highly interconnected porous monolithic and beaded polymers using high internal phase emulsion polymerization: tuning porous architecture through synthesis variables | |
| WO2003091321A1 (en) | Porous polymer material and method of production thereof | |
| KR100519661B1 (ko) | 단분산성 다공질 입자의 제조방법 | |
| EP0990667B1 (en) | Porous copolymer particles, process for preparing the same and use of the same | |
| WO1993019099A1 (en) | Wrinkled absorbent particles of high effective surface area having fast absorption rate | |
| CN108129602B (zh) | 一种表面具有微孔道中空聚合物弹性微球及其制备方法和应用 | |
| JPH0885709A (ja) | 吸水性樹脂の製造方法 | |
| JPS6057893B2 (ja) | 半透膜を壁とするマイクロカプセルの製造法 | |
| JPH1045929A (ja) | 多孔質架橋ポリマー材料の製造方法 | |
| CZ291396B6 (cs) | Způsob přípravy sférických polymerních sorbentů |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A711 | Notification of change in applicant |
Free format text: JAPANESE INTERMEDIATE CODE: A711 Effective date: 20040303 |
|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20050624 |
|
| A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20050624 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20080108 |
|
| A601 | Written request for extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A601 Effective date: 20080404 |
|
| RD02 | Notification of acceptance of power of attorney |
Free format text: JAPANESE INTERMEDIATE CODE: A7422 Effective date: 20080404 |
|
| RD04 | Notification of resignation of power of attorney |
Free format text: JAPANESE INTERMEDIATE CODE: A7424 Effective date: 20080404 |
|
| A602 | Written permission of extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A602 Effective date: 20080718 |
|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20080708 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20081125 |
|
| A313 | Final decision of rejection without a dissenting response from the applicant |
Free format text: JAPANESE INTERMEDIATE CODE: A313 Effective date: 20090420 |
|
| A02 | Decision of refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A02 Effective date: 20090602 |