GB1332469A - Polymer and process - Google Patents
Polymer and processInfo
- Publication number
- GB1332469A GB1332469A GB5951870A GB5951870A GB1332469A GB 1332469 A GB1332469 A GB 1332469A GB 5951870 A GB5951870 A GB 5951870A GB 5951870 A GB5951870 A GB 5951870A GB 1332469 A GB1332469 A GB 1332469A
- Authority
- GB
- United Kingdom
- Prior art keywords
- granules
- solution
- polyester resin
- polyester
- base
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
- C08F283/01—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to unsaturated polyesters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/28—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof by elimination of a liquid phase from a macromolecular composition or article, e.g. drying of coagulum
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/28—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof by elimination of a liquid phase from a macromolecular composition or article, e.g. drying of coagulum
- C08J9/283—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof by elimination of a liquid phase from a macromolecular composition or article, e.g. drying of coagulum a discontinuous liquid phase emulsified in a continuous macromolecular phase
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/42—Gloss-reducing agents
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Materials Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Macromonomer-Based Addition Polymer (AREA)
- Paints Or Removers (AREA)
- Polymerisation Methods In General (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
1332469 Porous polyester granules BALM PAINTS Ltd 15 Dec 1970 [22 Dec 1969] 59518/70 Headings C3C and C3P Porous cross-linked polyester granules are made by forming a solution of an unsaturated xylene soluble polyester resin containing free carboxyl groups in an essentially water insoluble polymerizable unsaturated monomer and suspending this solution as discrete globules in an aqueous continuous phase in the presence of from 0À3 to 10À0 equivalents per free carboxy group of a base having a dissociation exponent i.e. -log 10 K b where K b is the dissociation constant of the base in water at 25‹ C., less than 8, initiating polymerization to cross-link the polyester resin, recovering the granules and allowing them to dry in air until the liquid has diffused out of them. If desired droplets of an aqueous liquid may be pre-dispersed within the polyester solution before dispersion of this solution in the continuous phase. The polyester resin is selected by the following test, to a xylene solution of the resin is added with mild agitation 5% by weight of an aqueous solution of ammonia and the mixture examined under an electron microscope to determine if a stable dispersion of droplets has formed and provided the mixture is essentially free of disperse particles greater than 5 microns and remains so for up to 30 minutes the resin is regarded as satisfactory. The unsaturated polyester resin contains an alpha, beta, ethylenically unsaturated acid such as maleic, fumaric, itaconic, citraconic or mesaconic acid. The preferred monomers are styrene, alpha-methyl styrene, divinyl benzene and nucular-substituted vinyl toluene. In addition minor amounts of other polymerizable monomers may be present such as acrylic and methacrylic acid esters, acrylonitrile, vinyl acetate, tetra-allyl ethoxyethane, ethylene glycol dimethacrylate, or triallyl cyanurate. The base may be an inorganic base of which ammonium hydroxide is preferred, or an aliphatic amine of which a long list is given. The polymerization within the globules is initiated by free radical compounds such as an organic peroxide or azo-compound or by exposure to a radiation source such as radioactive cobalt of ultra-violet light. The polyester resin may contain pigments e.g. TiO 2 . The aqueous phase may contain surface active agents, and thickeners such as hydroxyethylcellulose or polyvinyl alcohol. Exemplified polyesters are made from fumaric acid, phthalic anhydride and propylene glycol and maleic anhydride, phthalic anhydride and propylene glycol. The granules are used as matt texturing, flatting and opacifying agents in paint compositions. The granules may also contain pigment particles e.g. TiO 2 , by forming the granules in the presence of the pigment. Examples 7, 8, 10 and 11 relate to paint compositions and example 9 to the preparation of an opaque sheet.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AU6564569 | 1969-12-22 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1332469A true GB1332469A (en) | 1973-10-03 |
Family
ID=3750315
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB5951870A Expired GB1332469A (en) | 1969-12-22 | 1970-12-15 | Polymer and process |
Country Status (11)
Country | Link |
---|---|
JP (1) | JPS5017115B1 (en) |
BE (1) | BE760690A (en) |
DE (1) | DE2063239C2 (en) |
DK (1) | DK130415B (en) |
FR (1) | FR2074188A5 (en) |
GB (1) | GB1332469A (en) |
IE (1) | IE34828B1 (en) |
NL (1) | NL166036C (en) |
NO (1) | NO131428C (en) |
SE (1) | SE364880B (en) |
ZA (1) | ZA708592B (en) |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2485023A1 (en) * | 1980-05-09 | 1981-12-24 | Tioxide Group Ltd | PROCESS FOR PRODUCING RIGID CROSSLINKED POLYESTER RESIN BEADS |
US4461848A (en) * | 1981-11-20 | 1984-07-24 | Tioxide Group Plc. | Production of vesiculated polymer beads |
US4717620A (en) * | 1985-02-22 | 1988-01-05 | Imperial Chemical Industries Plc | Decorative coatings providing a multicolor, textured surface |
GB2231334A (en) * | 1989-03-21 | 1990-11-14 | Tioxide Group Plc | Powder coating compositions |
US5055513A (en) * | 1989-03-04 | 1991-10-08 | Tioxide Group Plc | Polymer granules and compositions containing them |
US5583162A (en) * | 1994-06-06 | 1996-12-10 | Biopore Corporation | Polymeric microbeads and method of preparation |
US6048908A (en) * | 1997-06-27 | 2000-04-11 | Biopore Corporation | Hydrophilic polymeric material |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
AR206777A1 (en) * | 1972-11-13 | 1976-08-23 | Dulux Australia Ltd | PROCEDURE FOR PREPARING AQUEOUS SUSPENSION OF VESICULAR GRANULES OF POLYESTER RESIN RESICULARS OF RETAINED POLYESTER RESIN |
AU1232876A (en) * | 1975-04-21 | 1977-10-13 | Dulux Australia Limited | Polymer process and paint |
JPS537221U (en) * | 1976-07-01 | 1978-01-21 | ||
US4808633A (en) * | 1987-09-08 | 1989-02-28 | C-I-L Inc. | Vesiculated polymer granules |
-
1970
- 1970-12-15 GB GB5951870A patent/GB1332469A/en not_active Expired
- 1970-12-18 IE IE1618/70A patent/IE34828B1/en unknown
- 1970-12-21 SE SE17312/70A patent/SE364880B/xx unknown
- 1970-12-22 FR FR7046335A patent/FR2074188A5/fr not_active Expired
- 1970-12-22 DE DE2063239A patent/DE2063239C2/en not_active Expired
- 1970-12-22 NL NL7018633.A patent/NL166036C/en active
- 1970-12-22 JP JP45115270A patent/JPS5017115B1/ja active Pending
- 1970-12-22 ZA ZA708592A patent/ZA708592B/en unknown
- 1970-12-22 DK DK653470AA patent/DK130415B/en not_active IP Right Cessation
- 1970-12-22 BE BE760690A patent/BE760690A/en not_active IP Right Cessation
- 1970-12-22 NO NO4902/70A patent/NO131428C/no unknown
Cited By (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2485023A1 (en) * | 1980-05-09 | 1981-12-24 | Tioxide Group Ltd | PROCESS FOR PRODUCING RIGID CROSSLINKED POLYESTER RESIN BEADS |
DE3118159A1 (en) * | 1980-05-09 | 1982-02-04 | Tioxide Group Ltd., London | PEARL POLYMERIZATION METHOD |
US4363888A (en) | 1980-05-09 | 1982-12-14 | Tioxide Group Limited | Bead polymerization process |
US4461848A (en) * | 1981-11-20 | 1984-07-24 | Tioxide Group Plc. | Production of vesiculated polymer beads |
US4717620A (en) * | 1985-02-22 | 1988-01-05 | Imperial Chemical Industries Plc | Decorative coatings providing a multicolor, textured surface |
US5055513A (en) * | 1989-03-04 | 1991-10-08 | Tioxide Group Plc | Polymer granules and compositions containing them |
GB2231334A (en) * | 1989-03-21 | 1990-11-14 | Tioxide Group Plc | Powder coating compositions |
GB2231334B (en) * | 1989-03-21 | 1992-11-18 | Tioxide Group Plc | Resinous compositions |
US5583162A (en) * | 1994-06-06 | 1996-12-10 | Biopore Corporation | Polymeric microbeads and method of preparation |
US5653922A (en) * | 1994-06-06 | 1997-08-05 | Biopore Corporation | Polymeric microbeads and method of preparation |
US5760097A (en) * | 1994-06-06 | 1998-06-02 | Biopore Corporation | Methods of preparing polymeric microbeds |
US5863957A (en) * | 1994-06-06 | 1999-01-26 | Biopore Corporation | Polymeric microbeads |
US6100306A (en) * | 1994-06-06 | 2000-08-08 | Biopore Corporation | Polymeric microbeads and methods of preparation |
US6048908A (en) * | 1997-06-27 | 2000-04-11 | Biopore Corporation | Hydrophilic polymeric material |
Also Published As
Publication number | Publication date |
---|---|
IE34828B1 (en) | 1975-09-03 |
DE2063239A1 (en) | 1971-07-15 |
NO131428B (en) | 1975-02-17 |
FR2074188A5 (en) | 1971-10-01 |
IE34828L (en) | 1971-06-22 |
JPS5017115B1 (en) | 1975-06-18 |
NO131428C (en) | 1975-05-28 |
SE364880B (en) | 1974-03-11 |
DK130415B (en) | 1975-02-17 |
BE760690A (en) | 1971-06-22 |
NL7018633A (en) | 1971-06-24 |
NL166036C (en) | 1981-06-15 |
DK130415C (en) | 1975-07-14 |
DE2063239C2 (en) | 1982-10-21 |
ZA708592B (en) | 1972-08-30 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PS | Patent sealed | ||
PCNP | Patent ceased through non-payment of renewal fee |