GB1384821A - Daylight fluorescent pigments - Google Patents

Daylight fluorescent pigments

Info

Publication number
GB1384821A
GB1384821A GB294672A GB294672A GB1384821A GB 1384821 A GB1384821 A GB 1384821A GB 294672 A GB294672 A GB 294672A GB 294672 A GB294672 A GB 294672A GB 1384821 A GB1384821 A GB 1384821A
Authority
GB
United Kingdom
Prior art keywords
produced
fluorescent
dyestuff
copolymer
acid anhydride
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB294672A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hoechst AG
Original Assignee
Hoechst AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from DE19712102942 external-priority patent/DE2102942A1/en
Priority claimed from DE19712104717 external-priority patent/DE2104717A1/en
Application filed by Hoechst AG filed Critical Hoechst AG
Publication of GB1384821A publication Critical patent/GB1384821A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09BORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B67/00Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
    • C09B67/006Preparation of organic pigments
    • C09B67/0061Preparation of organic pigments by grinding a dyed resin
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00Chemical modification by after-treatment
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/0008Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
    • C08K5/0041Optical brightening agents, organic pigments

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inks, Pencil-Leads, Or Crayons (AREA)
  • Macromonomer-Based Addition Polymer (AREA)

Abstract

1384821 Fluorescent pigments HOECHST AG 21 Jan 1972 [22 Jan 1971 2 Feb 1971] 2946/72 Headings C3R and C3P A daylight fluorescent pigment suitable for use in colouring lacquers, printing inks, paints, plastics, paper, caoutchaic and textiles, is produced by dissolving or dispersing in an organic diluent containing no active hydrogen atoms (a) an organic fluorescent dyestuff, and dissolving in the diluent (b) a polyester containing hydroxyl groups, or a copolymer of an olefinically unsaturated compound containing hydroxyl groups and an olefinically unsaturated compound not containing hydroxyl groups and (c) a cross-linking agent for the-polymer, subsequently curing the mixture and grinding the cured product. The polyester may have a hydroxyl number of 200-600 and a molecular weight of 300-3000 and the copolymer may have a molecular weight of 10,000-80,000. The cross-linking agent (c) may be an aliphatic, cycloaliphatic or aromatic di- or polyisocyanate or a cyclic di- or tetra-carboxylic acid anhydride, the fluorescent dyestuff (a) may be a rhodamine, sulphorhodamine, naphthalimide, benzoxanthene or thiobenzoxanthene dyestuff and the organic diluent may be a glycol monoalkyl ether ester, dimethyl formamide, dimethylsulphoxide or dioxane. In a modification of the process the fluorescent dyestuff (a) is used in a form chemically bound to the crosslinking agent (c). In examples pigments which may be used in polyvinyl chloride compositions or in lacquers containing alkyd and melamine resins, are produced using a copolymer produced from methyl- or n-butyl methacrylate and #-hydroxyethyl or #-hydroxypropyl methacrylate optionally in admixture with styrene or vinyl acetate or a polyester produced by the reaction of dimethyl terephthalate with 1,1,1- trimethylol propane, and as cross-linking agent a polyisocyanate containing biuret groups prepared by the reaction of hexamethylene-1,6- diisocyanate with water, a reaction product of hexamethylene - 1,6 - diisocyanate with trimethylol propane, phthalic acid anhydride or tetrahydrophthalic acid anhydride.
GB294672A 1971-01-22 1972-01-21 Daylight fluorescent pigments Expired GB1384821A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19712102942 DE2102942A1 (en) 1971-01-22 1971-01-22 Polyurethane resins and their use in daytime luminous pigments
DE19712104717 DE2104717A1 (en) 1971-02-02 1971-02-02 Polyester resins and their use in daytime luminous pigments

Publications (1)

Publication Number Publication Date
GB1384821A true GB1384821A (en) 1975-02-26

Family

ID=25760560

Family Applications (1)

Application Number Title Priority Date Filing Date
GB294672A Expired GB1384821A (en) 1971-01-22 1972-01-21 Daylight fluorescent pigments

Country Status (8)

Country Link
AT (1) AT315322B (en)
BE (1) BE778422A (en)
CA (1) CA982805A (en)
CH (1) CH562309A5 (en)
FR (1) FR2122611B1 (en)
GB (1) GB1384821A (en)
IT (1) IT946741B (en)
NL (1) NL7200653A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2001025347A1 (en) * 1999-10-01 2001-04-12 Ppg Industries Ohio, Inc. Coating with optical taggent
EP3275844A1 (en) 2012-12-28 2018-01-31 Ecolab USA Inc. Fluorescent monomers for the preparation of tagged treatment polymers useful in industrial water systems

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5888699A (en) * 1981-11-20 1983-05-26 富士写真フイルム株式会社 Radiation image conversion panel
US4975220A (en) * 1989-11-09 1990-12-04 Nalco Chemical Company Polyamide-polyester fluorescent pigments
CA2026161A1 (en) * 1990-06-25 1991-12-26 Thomas C. Dipietro Fluorescent pigments
US5128419A (en) * 1990-08-20 1992-07-07 Nalco Chemical Company Synthesis of tagged polymers by post-polymerization (trans) amidation reaction

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2001025347A1 (en) * 1999-10-01 2001-04-12 Ppg Industries Ohio, Inc. Coating with optical taggent
EP3275844A1 (en) 2012-12-28 2018-01-31 Ecolab USA Inc. Fluorescent monomers for the preparation of tagged treatment polymers useful in industrial water systems

Also Published As

Publication number Publication date
FR2122611A1 (en) 1972-09-01
NL7200653A (en) 1972-07-25
BE778422A (en) 1972-07-24
AU3809172A (en) 1973-07-26
AT315322B (en) 1974-05-27
IT946741B (en) 1973-05-21
FR2122611B1 (en) 1976-10-29
CH562309A5 (en) 1975-05-30
CA982805A (en) 1976-02-03

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Legal Events

Date Code Title Description
PS Patent sealed
PLNP Patent lapsed through nonpayment of renewal fees