JP2002506455A - 新しい触媒 - Google Patents
新しい触媒Info
- Publication number
- JP2002506455A JP2002506455A JP50526299A JP50526299A JP2002506455A JP 2002506455 A JP2002506455 A JP 2002506455A JP 50526299 A JP50526299 A JP 50526299A JP 50526299 A JP50526299 A JP 50526299A JP 2002506455 A JP2002506455 A JP 2002506455A
- Authority
- JP
- Japan
- Prior art keywords
- formula
- alkyl
- tert
- butyl
- group
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
- B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
- B01J31/181—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
- B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
- B01J31/181—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
- B01J31/1825—Ligands comprising condensed ring systems, e.g. acridine, carbazole
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2265—Carbenes or carbynes, i.e.(image)
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2282—Unsaturated compounds used as ligands
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
- B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
- C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
- C07F15/0013—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group without a metal-carbon linkage
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
- C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
- C07F15/002—Osmium compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
- C08G61/02—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes
- C08G61/04—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms
- C08G61/06—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms prepared by ring-opening of carbocyclic compounds
- C08G61/08—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms prepared by ring-opening of carbocyclic compounds of carbocyclic compounds containing one or more carbon-to-carbon double bonds in the ring
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/10—Polymerisation reactions involving at least dual use catalysts, e.g. for both oligomerisation and polymerisation
- B01J2231/14—Other (co) polymerisation, e.g. of lactides or epoxides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/50—Redistribution or isomerisation reactions of C-C, C=C or C-C triple bonds
- B01J2231/54—Metathesis reactions, e.g. olefin metathesis
- B01J2231/543—Metathesis reactions, e.g. olefin metathesis alkene metathesis
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/82—Metals of the platinum group
- B01J2531/821—Ruthenium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/82—Metals of the platinum group
- B01J2531/825—Osmium
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CH1562/97 | 1997-06-27 | ||
| CH156297 | 1997-06-27 | ||
| PCT/EP1998/003781 WO1999000397A1 (en) | 1997-06-27 | 1998-06-20 | Ruthenium and osmium catalysts |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2002506455A true JP2002506455A (ja) | 2002-02-26 |
| JP2002506455A5 JP2002506455A5 (https=) | 2005-12-22 |
Family
ID=4213330
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP50526299A Withdrawn JP2002506455A (ja) | 1997-06-27 | 1998-06-20 | 新しい触媒 |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US6306987B1 (https=) |
| EP (1) | EP0993466B1 (https=) |
| JP (1) | JP2002506455A (https=) |
| KR (1) | KR100569620B1 (https=) |
| AU (1) | AU8800498A (https=) |
| BR (1) | BR9810488A (https=) |
| CA (1) | CA2289709A1 (https=) |
| DE (1) | DE69819501T2 (https=) |
| ES (1) | ES2209185T3 (https=) |
| MX (1) | MX210210B (https=) |
| WO (1) | WO1999000397A1 (https=) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2003512470A (ja) * | 1999-10-28 | 2003-04-02 | シジェア ソシエタ ア レスポンサビリタ リミタータ | 抗腫瘍活性及び抗転移活性を有するルテニウム(ii)錯体 |
| JP2007530706A (ja) * | 2004-03-29 | 2007-11-01 | カリフォルニア インスティテュート オブ テクノロジー | N−複素環カルベンリガンドを含有する高活性潜伏オレフィン複分解触媒 |
| WO2009123209A1 (ja) * | 2008-03-31 | 2009-10-08 | 日本ゼオン株式会社 | 重合性組成物、樹脂成形体、及び架橋樹脂成形体 |
| JP2009541414A (ja) * | 2006-06-30 | 2009-11-26 | エフ.ホフマン−ラ ロシュ アーゲー | メタセシス反応用触媒としての新規ルテニウム錯体 |
| WO2017135638A1 (ko) * | 2016-02-01 | 2017-08-10 | 서울대학교산학협력단 | 설폰아미드기 또는 아미드기를 포함하는 올레핀 복분해 반응용 전이금속 착물 및 이의 응용 |
Families Citing this family (38)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7507854B2 (en) | 1998-09-01 | 2009-03-24 | Materia, Inc. | Impurity reduction in Olefin metathesis reactions |
| US6696597B2 (en) | 1998-09-01 | 2004-02-24 | Tilliechem, Inc. | Metathesis syntheses of pheromones or their components |
| US6900347B2 (en) | 1998-09-01 | 2005-05-31 | Tilliechem, Inc. | Impurity inhibition in olefin metathesis reactions |
| DE19840107A1 (de) * | 1998-09-03 | 2000-03-09 | Bayer Ag | Verfahren zur Synthese alpha-substituierter Ringsysteme |
| WO2002076920A1 (en) | 2001-03-26 | 2002-10-03 | Dow Global Technologies Inc. | Metathesis of unsaturated fatty acid esters or unsaturated fatty acids with lower olefins |
| DE60229158D1 (de) * | 2001-08-30 | 2008-11-13 | Materia Inc | Infusion von zyklischen olefinharzen in poröse materialien |
| JP4138417B2 (ja) * | 2001-09-28 | 2008-08-27 | 積水化学工業株式会社 | 有機金属化合物の合成方法 |
| US6620955B1 (en) | 2001-11-15 | 2003-09-16 | Richard L. Pederson | Chelating carbene ligand precursors and their use in the synthesis of metathesis catalysts |
| RU2352549C2 (ru) | 2002-04-29 | 2009-04-20 | Дау Глобал Текнолоджиз Инк. | Интегрированные химические способы промышленного применения растительных масел из семян |
| AU2003232067A1 (en) | 2002-05-06 | 2003-11-17 | Kerr Corporation | Composition curable by metathesis reaction |
| US7683148B2 (en) | 2003-05-06 | 2010-03-23 | Kerr Corporation | Metathesis-curable composition with a reaction control agent |
| US7060769B2 (en) * | 2003-05-06 | 2006-06-13 | Kerr Corporation | Method of curing composition by metathesis reaction using reaction control agent |
| US7173097B2 (en) | 2003-05-06 | 2007-02-06 | Kerr Corporation | Metathesis-curable composition with a reaction control agent |
| US7060770B2 (en) * | 2003-05-06 | 2006-06-13 | Kerr Corporation | Metathesis-curable composition with a reaction control agent |
| CN100588638C (zh) | 2003-10-09 | 2010-02-10 | 陶氏环球技术公司 | 合成不饱和醇的改进方法 |
| US7109344B2 (en) * | 2003-12-04 | 2006-09-19 | Boehringer Ingelheim International Gmbh | Ruthenium catalyst |
| ES2320776T3 (es) * | 2003-12-08 | 2009-05-28 | Boehringer Ingelheim International Gmbh | Eliminacion de subproductos de rutenio por tratamiento con fluidos supercriticos. |
| DE102004002178A1 (de) | 2004-01-15 | 2005-08-11 | Ivoclar Vivadent Ag | Dentalmeterialien auf der Basis von RÖMP-Kompositen |
| AU2011205218B2 (en) * | 2004-03-29 | 2015-12-17 | California Institute Of Technology | Latent, high-activity olefin metathesis catalysts containing an N-heterocyclic carbene ligand |
| US7001590B1 (en) | 2004-11-15 | 2006-02-21 | Kerr Corporation | Metathesis-curable composition |
| US7645443B2 (en) | 2004-11-15 | 2010-01-12 | Kerr Corporation | Polyether-based composition curable by metathesis reaction |
| US7625551B2 (en) | 2004-11-15 | 2009-12-01 | Kerr Corporation | Polyether-based dental impression material curable by metathesis reaction |
| AU2006220708B9 (en) | 2005-03-08 | 2013-01-17 | Boehringer Ingelheim International Gmbh | Process for preparing macrocyclic compounds |
| EP1934243B1 (en) | 2005-09-09 | 2011-05-25 | Boehringer Ingelheim International GmbH | Ring-closing metathesis process for the preparation of macrocyclic peptides |
| EP1948671B1 (en) * | 2005-11-09 | 2010-09-29 | Boehringer Ingelheim International GmbH | Preparation of catalysts |
| NZ568325A (en) | 2005-11-16 | 2011-05-27 | S Bio Pte Ltd | Macrocyclic oxygen linked pyrimidine derivatives |
| EP1847245A1 (en) | 2006-02-21 | 2007-10-24 | Kerr Corporation | Method for making alkoxy-siloxane polyether carboxylates terminated with functional olefin groups |
| PL379879A1 (pl) | 2006-06-07 | 2007-12-10 | Umicore Ag & Co.Kg. | Kompleksy rutenu i osmu, sposób ich wytwarzania oraz ich zastosowanie jako (pre)katalizatorów reakcji metatezy |
| DE102007020694A1 (de) | 2007-05-03 | 2008-11-06 | Evonik Degussa Gmbh | Schwefelhaltige Metathesekatalysatoren |
| US8241575B2 (en) | 2008-01-28 | 2012-08-14 | The Johns Hopkins University | Molecularly imprinted polymer sensor device |
| WO2010051268A1 (en) | 2008-10-31 | 2010-05-06 | Dow Global Technologies Inc. | Olefin metathesis process employing bimetallic ruthenium complex with bridging hydrido ligands |
| BRPI1008853A2 (pt) * | 2009-02-18 | 2016-03-15 | Henkel Corp | iniciadores de rutênio termicamente comutáveis |
| ES2391340B1 (es) | 2010-05-11 | 2013-09-30 | Melchor Daumal Castellón | Conjunto soporte multifuncion para columna de direccion |
| KR101297431B1 (ko) * | 2011-04-18 | 2013-08-19 | 주식회사 폴리사이언텍 | 폴리프로필렌계 수지조성물 및 이로부터 제조된 스크래치 자기재생성 성형품 |
| PL220408B1 (pl) * | 2011-09-26 | 2015-10-30 | Inst Chemii Organicznej Polskiej Akademii Nauk | Kompleks rutentu, sposób jego wytwarzania oraz zastosowanie |
| CN114106057B (zh) * | 2016-10-19 | 2023-06-23 | 优美科股份公司及两合公司 | Ru亚烷基络合物的合成与表征 |
| CN116157262A (zh) * | 2020-08-28 | 2023-05-23 | Rimtec株式会社 | 阻氧性环烯烃系树脂固化物 |
| JP2024534168A (ja) * | 2021-08-31 | 2024-09-18 | メルク パテント ゲゼルシャフト ミット ベシュレンクテル ハフツング | 組成物 |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3067031B2 (ja) | 1992-04-03 | 2000-07-17 | カリフォルニア インスティチュート オブ テクノロジー | オレフィンメタセシス重合方法 |
-
1998
- 1998-06-20 ES ES98939522T patent/ES2209185T3/es not_active Expired - Lifetime
- 1998-06-20 BR BR9810488-8A patent/BR9810488A/pt not_active Application Discontinuation
- 1998-06-20 KR KR19997012334A patent/KR100569620B1/ko not_active Expired - Fee Related
- 1998-06-20 WO PCT/EP1998/003781 patent/WO1999000397A1/en not_active Ceased
- 1998-06-20 EP EP98939522A patent/EP0993466B1/en not_active Expired - Lifetime
- 1998-06-20 MX MX9911931A patent/MX210210B/es not_active IP Right Cessation
- 1998-06-20 DE DE69819501T patent/DE69819501T2/de not_active Expired - Fee Related
- 1998-06-20 US US09/446,052 patent/US6306987B1/en not_active Expired - Lifetime
- 1998-06-20 CA CA002289709A patent/CA2289709A1/en not_active Abandoned
- 1998-06-20 JP JP50526299A patent/JP2002506455A/ja not_active Withdrawn
- 1998-06-20 AU AU88004/98A patent/AU8800498A/en not_active Abandoned
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2003512470A (ja) * | 1999-10-28 | 2003-04-02 | シジェア ソシエタ ア レスポンサビリタ リミタータ | 抗腫瘍活性及び抗転移活性を有するルテニウム(ii)錯体 |
| JP2007530706A (ja) * | 2004-03-29 | 2007-11-01 | カリフォルニア インスティテュート オブ テクノロジー | N−複素環カルベンリガンドを含有する高活性潜伏オレフィン複分解触媒 |
| JP2012082435A (ja) * | 2004-03-29 | 2012-04-26 | California Inst Of Technology | N−複素環カルベンリガンドを含有する高活性潜伏オレフィン複分解触媒 |
| JP2009541414A (ja) * | 2006-06-30 | 2009-11-26 | エフ.ホフマン−ラ ロシュ アーゲー | メタセシス反応用触媒としての新規ルテニウム錯体 |
| WO2009123209A1 (ja) * | 2008-03-31 | 2009-10-08 | 日本ゼオン株式会社 | 重合性組成物、樹脂成形体、及び架橋樹脂成形体 |
| JP5365625B2 (ja) * | 2008-03-31 | 2013-12-11 | 日本ゼオン株式会社 | 重合性組成物、樹脂成形体、及び架橋樹脂成形体 |
| WO2017135638A1 (ko) * | 2016-02-01 | 2017-08-10 | 서울대학교산학협력단 | 설폰아미드기 또는 아미드기를 포함하는 올레핀 복분해 반응용 전이금속 착물 및 이의 응용 |
Also Published As
| Publication number | Publication date |
|---|---|
| DE69819501D1 (de) | 2003-12-11 |
| MX9911931A (es) | 2000-03-31 |
| BR9810488A (pt) | 2000-09-12 |
| KR100569620B1 (ko) | 2006-04-11 |
| US6306987B1 (en) | 2001-10-23 |
| EP0993466B1 (en) | 2003-11-05 |
| ES2209185T3 (es) | 2004-06-16 |
| DE69819501T2 (de) | 2004-09-23 |
| WO1999000397A1 (en) | 1999-01-07 |
| AU8800498A (en) | 1999-01-19 |
| EP0993466A1 (en) | 2000-04-19 |
| CA2289709A1 (en) | 1999-01-07 |
| MX210210B (es) | 2002-09-06 |
| KR20010014234A (ko) | 2001-02-26 |
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Legal Events
| Date | Code | Title | Description |
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