JP2002502897A - デュアルサイト触媒の使用により得られるポリエチレン - Google Patents
デュアルサイト触媒の使用により得られるポリエチレンInfo
- Publication number
- JP2002502897A JP2002502897A JP2000530558A JP2000530558A JP2002502897A JP 2002502897 A JP2002502897 A JP 2002502897A JP 2000530558 A JP2000530558 A JP 2000530558A JP 2000530558 A JP2000530558 A JP 2000530558A JP 2002502897 A JP2002502897 A JP 2002502897A
- Authority
- JP
- Japan
- Prior art keywords
- polyethylene
- catalyst
- polymer
- polymerization
- produced
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000003054 catalyst Substances 0.000 title claims abstract description 111
- -1 Polyethylene Polymers 0.000 title claims abstract description 106
- 229920000573 polyethylene Polymers 0.000 title claims abstract description 106
- 239000004698 Polyethylene Substances 0.000 title claims abstract description 104
- 229920000642 polymer Polymers 0.000 claims abstract description 78
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims abstract description 22
- 239000005977 Ethylene Substances 0.000 claims abstract description 22
- 239000004711 α-olefin Substances 0.000 claims abstract description 6
- 238000006116 polymerization reaction Methods 0.000 claims description 45
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 26
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 claims description 22
- 229910000423 chromium oxide Inorganic materials 0.000 claims description 22
- 238000000034 method Methods 0.000 claims description 22
- 239000000377 silicon dioxide Substances 0.000 claims description 13
- 239000000155 melt Substances 0.000 claims description 10
- 229910052723 transition metal Inorganic materials 0.000 claims description 10
- 150000003624 transition metals Chemical group 0.000 claims description 8
- 125000000058 cyclopentadienyl group Chemical group C1(=CC=CC1)* 0.000 claims description 6
- 230000003647 oxidation Effects 0.000 claims description 6
- 238000007254 oxidation reaction Methods 0.000 claims description 6
- 239000000178 monomer Substances 0.000 claims description 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 3
- 125000005842 heteroatom Chemical group 0.000 claims description 3
- 125000000753 cycloalkyl group Chemical group 0.000 claims 1
- 239000000463 material Substances 0.000 claims 1
- 239000011651 chromium Substances 0.000 description 35
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 27
- 229910052804 chromium Inorganic materials 0.000 description 26
- 238000009826 distribution Methods 0.000 description 23
- 230000000052 comparative effect Effects 0.000 description 13
- CPOFMOWDMVWCLF-UHFFFAOYSA-N methyl(oxo)alumane Chemical compound C[Al]=O CPOFMOWDMVWCLF-UHFFFAOYSA-N 0.000 description 13
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 12
- 239000002245 particle Substances 0.000 description 11
- 239000012018 catalyst precursor Substances 0.000 description 10
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 9
- 238000001125 extrusion Methods 0.000 description 9
- 238000005227 gel permeation chromatography Methods 0.000 description 9
- 239000012968 metallocene catalyst Substances 0.000 description 9
- 150000001845 chromium compounds Chemical class 0.000 description 8
- 150000001875 compounds Chemical class 0.000 description 8
- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 description 8
- 239000000203 mixture Substances 0.000 description 6
- 150000003623 transition metal compounds Chemical class 0.000 description 6
- 229910004298 SiO 2 Inorganic materials 0.000 description 5
- 239000012190 activator Substances 0.000 description 5
- 238000012545 processing Methods 0.000 description 5
- 230000009467 reduction Effects 0.000 description 5
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 4
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 4
- 229910002091 carbon monoxide Inorganic materials 0.000 description 4
- 239000001257 hydrogen Substances 0.000 description 4
- 229910052739 hydrogen Inorganic materials 0.000 description 4
- 238000005470 impregnation Methods 0.000 description 4
- 239000001282 iso-butane Substances 0.000 description 4
- 229910052757 nitrogen Inorganic materials 0.000 description 4
- 239000002685 polymerization catalyst Substances 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 3
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 230000002902 bimodal effect Effects 0.000 description 3
- 238000012512 characterization method Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 229910001220 stainless steel Inorganic materials 0.000 description 3
- 239000010935 stainless steel Substances 0.000 description 3
- 229910052719 titanium Inorganic materials 0.000 description 3
- 239000010936 titanium Substances 0.000 description 3
- 229910052726 zirconium Inorganic materials 0.000 description 3
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 2
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 2
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 2
- RSPAIISXQHXRKX-UHFFFAOYSA-L 5-butylcyclopenta-1,3-diene;zirconium(4+);dichloride Chemical compound Cl[Zr+2]Cl.CCCCC1=CC=C[CH-]1.CCCCC1=CC=C[CH-]1 RSPAIISXQHXRKX-UHFFFAOYSA-L 0.000 description 2
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- 239000004712 Metallocene polyethylene (PE-MC) Substances 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 150000001336 alkenes Chemical class 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- 238000000071 blow moulding Methods 0.000 description 2
- 238000001354 calcination Methods 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 230000003197 catalytic effect Effects 0.000 description 2
- 150000001844 chromium Chemical class 0.000 description 2
- 229910052735 hafnium Inorganic materials 0.000 description 2
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 description 2
- 229920001903 high density polyethylene Polymers 0.000 description 2
- 239000004700 high-density polyethylene Substances 0.000 description 2
- 150000002430 hydrocarbons Chemical group 0.000 description 2
- 150000002431 hydrogen Chemical class 0.000 description 2
- 239000003446 ligand Substances 0.000 description 2
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 2
- 239000002952 polymeric resin Substances 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- 229920003002 synthetic resin Polymers 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 241001631457 Cannula Species 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 229920010126 Linear Low Density Polyethylene (LLDPE) Polymers 0.000 description 1
- 239000004594 Masterbatch (MB) Substances 0.000 description 1
- NKKALSOFYFMKGW-UHFFFAOYSA-L [Cl-].[Cl-].C(CCC)C1=CC=CC1[Zr+2] Chemical compound [Cl-].[Cl-].C(CCC)C1=CC=CC1[Zr+2] NKKALSOFYFMKGW-UHFFFAOYSA-L 0.000 description 1
- IQTGDGZBSKVCKJ-UHFFFAOYSA-L [Cl-].[Cl-].CCCCC1([Hf++]C2(CCCC)C=CC=C2)C=CC=C1 Chemical compound [Cl-].[Cl-].CCCCC1([Hf++]C2(CCCC)C=CC=C2)C=CC=C1 IQTGDGZBSKVCKJ-UHFFFAOYSA-L 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 125000003545 alkoxy group Chemical group 0.000 description 1
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 1
- 150000001408 amides Chemical group 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- UOUJSJZBMCDAEU-UHFFFAOYSA-N chromium(3+);oxygen(2-) Chemical class [O-2].[O-2].[O-2].[Cr+3].[Cr+3] UOUJSJZBMCDAEU-UHFFFAOYSA-N 0.000 description 1
- 239000011247 coating layer Substances 0.000 description 1
- 230000001143 conditioned effect Effects 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 230000009849 deactivation Effects 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 230000009977 dual effect Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 238000010096 film blowing Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000012685 gas phase polymerization Methods 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229920006158 high molecular weight polymer Polymers 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 150000004678 hydrides Chemical class 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 125000001183 hydrocarbyl group Chemical group 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 230000006698 induction Effects 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 239000010410 layer Substances 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- KJJBSBKRXUVBMX-UHFFFAOYSA-N magnesium;butane Chemical compound [Mg+2].CCC[CH2-].CCC[CH2-] KJJBSBKRXUVBMX-UHFFFAOYSA-N 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- JFNLZVQOOSMTJK-KNVOCYPGSA-N norbornene Chemical compound C1[C@@H]2CC[C@H]1C=C2 JFNLZVQOOSMTJK-KNVOCYPGSA-N 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920013716 polyethylene resin Polymers 0.000 description 1
- 238000010094 polymer processing Methods 0.000 description 1
- 230000037048 polymerization activity Effects 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 238000010926 purge Methods 0.000 description 1
- 239000012429 reaction media Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 238000000518 rheometry Methods 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- 239000011343 solid material Substances 0.000 description 1
- 238000001694 spray drying Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 238000005482 strain hardening Methods 0.000 description 1
- 238000010557 suspension polymerization reaction Methods 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 238000009827 uniform distribution Methods 0.000 description 1
- 238000007666 vacuum forming Methods 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/69—Chromium, molybdenum, tungsten or compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
- C08F4/63912—Component covered by group C08F4/62 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
- C08F4/63916—Component covered by group C08F4/62 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
- C08F4/6392—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/63922—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
- C08F4/63925—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually non-bridged
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
- C08F4/65925—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually non-bridged
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Peptides Or Proteins (AREA)
- Polymerisation Methods In General (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| NO980552A NO980552D0 (no) | 1998-02-09 | 1998-02-09 | Katalysatorbestandel og katalysator for (ko)polymerisering av etylen, og fremgangsmåte for fremstilling av slik |
| NO19980552 | 1998-02-09 | ||
| PCT/NO1999/000044 WO1999040131A1 (en) | 1998-02-09 | 1999-02-09 | Polyethylenes obtained by use of dual site catalyst |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JP2002502897A true JP2002502897A (ja) | 2002-01-29 |
Family
ID=19901654
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2000530558A Pending JP2002502897A (ja) | 1998-02-09 | 1999-02-09 | デュアルサイト触媒の使用により得られるポリエチレン |
| JP2000530553A Pending JP2002502895A (ja) | 1998-02-09 | 1999-02-09 | エチレン（共）重合用触媒及びその製造法 |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2000530553A Pending JP2002502895A (ja) | 1998-02-09 | 1999-02-09 | エチレン（共）重合用触媒及びその製造法 |
Country Status (14)
| Country | Link |
|---|---|
| US (2) | US6780809B1 (enExample) |
| EP (2) | EP1053264A1 (enExample) |
| JP (2) | JP2002502897A (enExample) |
| KR (1) | KR20010040769A (enExample) |
| CN (2) | CN1136241C (enExample) |
| AR (1) | AR018078A1 (enExample) |
| AT (1) | ATE283866T1 (enExample) |
| AU (2) | AU740974B2 (enExample) |
| BR (2) | BR9907708A (enExample) |
| CA (2) | CA2320436C (enExample) |
| DE (1) | DE69922340T2 (enExample) |
| ES (1) | ES2234237T3 (enExample) |
| NO (1) | NO980552D0 (enExample) |
| WO (2) | WO1999040131A1 (enExample) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2003534428A (ja) * | 2000-05-24 | 2003-11-18 | フイリツプス ピトローリアム カンパニー | ポリマー組成物の製法 |
Families Citing this family (33)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NO980552D0 (no) * | 1998-02-09 | 1998-02-09 | Borealis As | Katalysatorbestandel og katalysator for (ko)polymerisering av etylen, og fremgangsmåte for fremstilling av slik |
| NO981631L (no) * | 1998-04-08 | 1999-10-11 | Borealis As | Katalysator for polymerisasjon av etylen, og fremgangsmaate for fremstilling av denne |
| US6272384B1 (en) | 1999-05-27 | 2001-08-07 | Urologix, Inc. | Microwave therapy apparatus |
| GB9919718D0 (en) | 1999-08-19 | 1999-10-20 | Borealis As | Process |
| US6433133B1 (en) * | 1999-11-16 | 2002-08-13 | Eastman Chemical Company | Process for reducing the weight average molecular weight and melt index ratio of polyethylenes and polyethylene products |
| KR100893971B1 (ko) | 2001-04-30 | 2009-04-20 | 더블유.알. 그레이스 앤드 캄파니-콘. | 지지된 이중 전이금속 촉매 시스템 |
| US6943224B2 (en) | 2001-04-30 | 2005-09-13 | W. R. Grace & Co.-Conn. | Process for preparing supported transition metal catalyst systems and catalyst systems prepared thereby |
| CN100549037C (zh) * | 2002-12-17 | 2009-10-14 | 英诺文尼欧洲有限公司 | 烯烃聚合载体催化剂 |
| US20040192864A1 (en) * | 2003-03-31 | 2004-09-30 | Exxonmobil Chemical Company | Utility conduit resin |
| US7384885B2 (en) | 2003-03-31 | 2008-06-10 | Exxonmobil Chemical Patents Inc. | Catalyst activation and resins therefrom |
| US20040192865A1 (en) * | 2003-03-31 | 2004-09-30 | Roger Scott T. | Resin for extruded pipe |
| WO2004096868A1 (en) * | 2003-03-31 | 2004-11-11 | Exxonmobil Chemical Patents Inc. | Resin for extruded pipe |
| AU2003226161A1 (en) * | 2003-03-31 | 2004-11-23 | Exxonmobil Chemical Patents Inc. | Utility conduit resin |
| DE102005019395A1 (de) * | 2005-04-25 | 2006-10-26 | Basell Polyolefine Gmbh | Formmasse aus Polyethylen zur Folienherstellung und Verfahren zum Herstellen der Formmasse in Gegenwart eines Mischkatalysators |
| DE102005019393A1 (de) | 2005-04-25 | 2006-10-26 | Basell Polyolefine Gmbh | Polyethylenformmassen für Spritzgussanwendungen |
| US8129472B2 (en) * | 2006-04-07 | 2012-03-06 | Dow Global Technologies Llc | Polyolefin compositions, articles made therefrom and methods for preparing the same |
| CA2605044C (en) * | 2007-10-01 | 2014-12-02 | Nova Chemicals Corporation | Polymerization process using a mixed catalyst system |
| CA2605077C (en) * | 2007-10-01 | 2014-07-08 | Nova Chemicals Corporation | A co-supported catalyst system |
| CA2753550C (en) * | 2009-02-27 | 2017-08-08 | Chevron Phillips Chemical Company Lp | Polyethylene film having improved barrier properties and methods of making same |
| US7951881B2 (en) | 2009-02-27 | 2011-05-31 | Chevron Phillips Chemical Company Lp | Polyethylene film having improved barrier properties and methods of making same |
| US8852748B2 (en) | 2009-02-27 | 2014-10-07 | Chevron Phillips Chemical Company Lp | Polyethylene film having improved barrier properties and methods of making same |
| CA2713042C (en) | 2010-08-11 | 2017-10-24 | Nova Chemicals Corporation | Method of controlling polymer architecture |
| US8148470B1 (en) | 2010-11-19 | 2012-04-03 | Exxonmobil Chemical Patents Inc. | Processes for making multimodal molecular weight distribution polyolefins |
| BR112013002457B1 (pt) * | 2010-11-19 | 2022-04-26 | Univation Technologies, Llc | Processo para fazer uma composição de poliolefina multimodal e sistema de catalisador misto |
| US8653208B2 (en) * | 2012-05-18 | 2014-02-18 | Union Carbide Chemicals & Plastics Technology Llc | Process for preparing catalysts and catalysts made thereby |
| CA2783494C (en) | 2012-07-23 | 2019-07-30 | Nova Chemicals Corporation | Adjusting polymer composition |
| CN104877051B (zh) * | 2015-05-06 | 2018-04-13 | 无锡耀汇科技有限公司 | 一种聚烯烃催化剂 |
| CN104877052B (zh) * | 2015-05-06 | 2018-04-13 | 无锡耀汇科技有限公司 | 一种聚乙烯树脂 |
| EP3445790B1 (en) * | 2016-04-20 | 2023-07-12 | Univation Technologies, LLC | Polymer flow index modifier |
| CN110167975A (zh) | 2017-01-11 | 2019-08-23 | Sabic环球技术有限责任公司 | 用于乙烯聚合的氧化铬催化剂 |
| WO2018130539A1 (en) * | 2017-01-11 | 2018-07-19 | Sabic Global Technologies B.V. | Chromium oxide catalyst for ethylene polymerization |
| US11952480B2 (en) | 2018-02-05 | 2024-04-09 | Exxonmobil Chemical Patents Inc. | Enhanced processability of LLDPE by addition of ultra-high molecular weight density polyethylene |
| KR20230056023A (ko) * | 2020-08-24 | 2023-04-26 | 셀라니즈 인터내셔날 코포레이션 | 좁은 분자량 분포를 갖는 고밀도 폴리에틸렌으로 제조된 겔 압출 물품 |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB8333032D0 (en) | 1983-12-10 | 1984-01-18 | Bp Chem Int Ltd | Orientated polyolefins |
| DE68913226T2 (de) | 1988-04-26 | 1994-09-29 | Showa Denko Kk | Verfahren zur Herstellung von Ethylenpolymeren. |
| DE69422410T2 (de) | 1993-08-06 | 2000-07-06 | Exxon Chemical Patents, Inc. | Polymerisationskataylsatoren, ihre herstellung und verwendung |
| US5614456A (en) | 1993-11-15 | 1997-03-25 | Mobil Oil Corporation | Catalyst for bimodal molecular weight distribution ethylene polymers and copolymers |
| BE1009186A3 (fr) | 1995-03-13 | 1996-12-03 | Solvay | Solide catalytique pour la (co)polymerisation d'ethylene, procede pour sa preparation, systeme catalytique pour la (co)polymerisation d'ethylene et procede de (co)polymerisation d'ethylene. |
| DE59606391D1 (de) * | 1995-08-22 | 2001-03-01 | Basf Ag | Polymerisate des ethylens mit hoher spannungsrissbeständigkeit und katalysatorsystem für deren herstellung |
| DE19716239A1 (de) * | 1997-04-18 | 1998-10-22 | Basf Ag | Verfahren zur Polymerisation von alpha-Olefinen in der Gasphase |
| GB9712663D0 (en) * | 1997-06-16 | 1997-08-20 | Borealis As | Process |
| NO980552D0 (no) * | 1998-02-09 | 1998-02-09 | Borealis As | Katalysatorbestandel og katalysator for (ko)polymerisering av etylen, og fremgangsmåte for fremstilling av slik |
| US6013596A (en) * | 1998-05-18 | 2000-01-11 | Arco Chemical Technology, L.P. | Double metal cyanide catalysts containing cyclic, bidentate complexing agents |
| EP1127079B1 (en) * | 1998-06-16 | 2005-06-15 | Borealis Technology Oy | Olefin polymerization process |
| ES2201821T3 (es) * | 1998-12-16 | 2004-03-16 | Borealis Technology Oy | Procedimiento en varias etapas para preparar poliolefinas con resistencia elevada en estado fundido. |
| DE60002056T2 (de) * | 1999-02-22 | 2003-11-06 | Borealis Technology Oy, Porvoo | Olefinpolymerisationsverfahren |
-
1998
- 1998-02-09 NO NO980552A patent/NO980552D0/no unknown
-
1999
- 1999-02-08 AR ARP990100534A patent/AR018078A1/es active IP Right Grant
- 1999-02-09 CA CA002320436A patent/CA2320436C/en not_active Expired - Fee Related
- 1999-02-09 US US09/601,652 patent/US6780809B1/en not_active Expired - Fee Related
- 1999-02-09 WO PCT/NO1999/000044 patent/WO1999040131A1/en not_active Ceased
- 1999-02-09 EP EP99903959A patent/EP1053264A1/en not_active Withdrawn
- 1999-02-09 CA CA002320271A patent/CA2320271C/en not_active Expired - Fee Related
- 1999-02-09 US US09/601,654 patent/US6541581B1/en not_active Expired - Fee Related
- 1999-02-09 CN CNB998028142A patent/CN1136241C/zh not_active Expired - Fee Related
- 1999-02-09 KR KR1020007008658A patent/KR20010040769A/ko not_active Abandoned
- 1999-02-09 ES ES99903958T patent/ES2234237T3/es not_active Expired - Lifetime
- 1999-02-09 DE DE69922340T patent/DE69922340T2/de not_active Expired - Fee Related
- 1999-02-09 BR BR9907708-6A patent/BR9907708A/pt not_active Application Discontinuation
- 1999-02-09 AU AU24431/99A patent/AU740974B2/en not_active Ceased
- 1999-02-09 JP JP2000530558A patent/JP2002502897A/ja active Pending
- 1999-02-09 CN CN998028177A patent/CN1132853C/zh not_active Expired - Fee Related
- 1999-02-09 AT AT99903958T patent/ATE283866T1/de not_active IP Right Cessation
- 1999-02-09 EP EP99903958A patent/EP1045866B1/en not_active Expired - Lifetime
- 1999-02-09 WO PCT/NO1999/000043 patent/WO1999040126A1/en not_active Ceased
- 1999-02-09 BR BR9907702-7A patent/BR9907702A/pt not_active IP Right Cessation
- 1999-02-09 AU AU24430/99A patent/AU738712B2/en not_active Ceased
- 1999-02-09 JP JP2000530553A patent/JP2002502895A/ja active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2003534428A (ja) * | 2000-05-24 | 2003-11-18 | フイリツプス ピトローリアム カンパニー | ポリマー組成物の製法 |
Also Published As
| Publication number | Publication date |
|---|---|
| CA2320436A1 (en) | 1999-08-12 |
| CN1290272A (zh) | 2001-04-04 |
| CA2320436C (en) | 2007-08-14 |
| AU740974B2 (en) | 2001-11-15 |
| EP1045866B1 (en) | 2004-12-01 |
| EP1045866A1 (en) | 2000-10-25 |
| NO980552D0 (no) | 1998-02-09 |
| AU738712B2 (en) | 2001-09-27 |
| DE69922340D1 (de) | 2005-01-05 |
| AU2443099A (en) | 1999-08-23 |
| WO1999040131A1 (en) | 1999-08-12 |
| EP1053264A1 (en) | 2000-11-22 |
| US6541581B1 (en) | 2003-04-01 |
| DE69922340T2 (de) | 2005-11-10 |
| US6780809B1 (en) | 2004-08-24 |
| WO1999040126A9 (en) | 1999-10-21 |
| BR9907708A (pt) | 2000-11-14 |
| CN1132853C (zh) | 2003-12-31 |
| CN1290274A (zh) | 2001-04-04 |
| JP2002502895A (ja) | 2002-01-29 |
| ES2234237T3 (es) | 2005-06-16 |
| KR20010040769A (ko) | 2001-05-15 |
| ATE283866T1 (de) | 2004-12-15 |
| WO1999040126A1 (en) | 1999-08-12 |
| AR018078A1 (es) | 2001-10-31 |
| AU2443199A (en) | 1999-08-23 |
| CA2320271C (en) | 2007-07-17 |
| CA2320271A1 (en) | 1999-08-12 |
| CN1136241C (zh) | 2004-01-28 |
| BR9907702A (pt) | 2000-11-14 |
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