JP2000514361A - 外側表面に金属被覆を有する銅または銅合金の冷却壁を備えた金属連続鋳造用鋳型の部品と、その被覆方法 - Google Patents
外側表面に金属被覆を有する銅または銅合金の冷却壁を備えた金属連続鋳造用鋳型の部品と、その被覆方法Info
- Publication number
- JP2000514361A JP2000514361A JP10505653A JP50565398A JP2000514361A JP 2000514361 A JP2000514361 A JP 2000514361A JP 10505653 A JP10505653 A JP 10505653A JP 50565398 A JP50565398 A JP 50565398A JP 2000514361 A JP2000514361 A JP 2000514361A
- Authority
- JP
- Japan
- Prior art keywords
- silver
- copper
- wall
- metal
- layer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 title claims abstract description 43
- 229910052802 copper Inorganic materials 0.000 title claims abstract description 43
- 239000010949 copper Substances 0.000 title claims abstract description 43
- 238000000576 coating method Methods 0.000 title claims abstract description 39
- 239000011248 coating agent Substances 0.000 title claims abstract description 37
- 229910052751 metal Inorganic materials 0.000 title claims abstract description 26
- 239000002184 metal Substances 0.000 title claims abstract description 26
- 229910000881 Cu alloy Inorganic materials 0.000 title claims abstract description 19
- 238000009749 continuous casting Methods 0.000 title claims abstract description 13
- 238000001816 cooling Methods 0.000 title claims abstract description 9
- 229910052709 silver Inorganic materials 0.000 claims abstract description 124
- 239000004332 silver Substances 0.000 claims abstract description 124
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims abstract description 123
- 238000000034 method Methods 0.000 claims abstract description 38
- 238000000151 deposition Methods 0.000 claims abstract description 9
- LFAGQMCIGQNPJG-UHFFFAOYSA-N silver cyanide Chemical compound [Ag+].N#[C-] LFAGQMCIGQNPJG-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000007864 aqueous solution Substances 0.000 claims abstract description 8
- 229940098221 silver cyanide Drugs 0.000 claims abstract description 8
- 229910052783 alkali metal Inorganic materials 0.000 claims abstract description 7
- -1 alkali metal cyanide Chemical class 0.000 claims abstract description 6
- 229910001338 liquidmetal Inorganic materials 0.000 claims abstract description 6
- 238000005058 metal casting Methods 0.000 claims abstract description 5
- 229910000288 alkali metal carbonate Inorganic materials 0.000 claims abstract description 4
- 150000008041 alkali metal carbonates Chemical class 0.000 claims abstract description 4
- 238000007747 plating Methods 0.000 claims description 45
- XFXPMWWXUTWYJX-UHFFFAOYSA-N Cyanide Chemical compound N#[C-] XFXPMWWXUTWYJX-UHFFFAOYSA-N 0.000 claims description 9
- 239000002253 acid Substances 0.000 claims description 5
- 238000004140 cleaning Methods 0.000 claims description 4
- 230000001590 oxidative effect Effects 0.000 claims description 4
- 238000005554 pickling Methods 0.000 claims description 4
- 238000005282 brightening Methods 0.000 claims description 3
- 230000001172 regenerating effect Effects 0.000 claims description 3
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 2
- 239000003112 inhibitor Substances 0.000 claims description 2
- 229910017604 nitric acid Inorganic materials 0.000 claims description 2
- GGCZERPQGJTIQP-UHFFFAOYSA-N sodium;9,10-dioxoanthracene-2-sulfonic acid Chemical compound [Na+].C1=CC=C2C(=O)C3=CC(S(=O)(=O)O)=CC=C3C(=O)C2=C1 GGCZERPQGJTIQP-UHFFFAOYSA-N 0.000 claims description 2
- 230000001052 transient effect Effects 0.000 claims description 2
- 150000001340 alkali metals Chemical class 0.000 claims 2
- 239000003513 alkali Substances 0.000 claims 1
- 150000008044 alkali metal hydroxides Chemical class 0.000 claims 1
- 239000003610 charcoal Substances 0.000 claims 1
- PQTCMBYFWMFIGM-UHFFFAOYSA-N gold silver Chemical compound [Ag].[Au] PQTCMBYFWMFIGM-UHFFFAOYSA-N 0.000 claims 1
- 150000003839 salts Chemical class 0.000 claims 1
- 230000008929 regeneration Effects 0.000 abstract description 7
- 238000011069 regeneration method Methods 0.000 abstract description 7
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 70
- 239000010410 layer Substances 0.000 description 36
- 229910052759 nickel Inorganic materials 0.000 description 36
- 239000000243 solution Substances 0.000 description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 12
- 238000005266 casting Methods 0.000 description 11
- 239000003792 electrolyte Substances 0.000 description 10
- 229910000831 Steel Inorganic materials 0.000 description 8
- 239000010959 steel Substances 0.000 description 8
- 238000005868 electrolysis reaction Methods 0.000 description 7
- 238000002161 passivation Methods 0.000 description 7
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 230000008901 benefit Effects 0.000 description 6
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 6
- 238000012545 processing Methods 0.000 description 6
- 239000000126 substance Substances 0.000 description 5
- 238000005406 washing Methods 0.000 description 5
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
- 230000003750 conditioning effect Effects 0.000 description 4
- 239000008151 electrolyte solution Substances 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 239000010936 titanium Substances 0.000 description 4
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 3
- KXZJHVJKXJLBKO-UHFFFAOYSA-N chembl1408157 Chemical compound N=1C2=CC=CC=C2C(C(=O)O)=CC=1C1=CC=C(O)C=C1 KXZJHVJKXJLBKO-UHFFFAOYSA-N 0.000 description 3
- 239000011651 chromium Substances 0.000 description 3
- 230000008021 deposition Effects 0.000 description 3
- 230000001627 detrimental effect Effects 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 150000002815 nickel Chemical class 0.000 description 3
- 229910000027 potassium carbonate Inorganic materials 0.000 description 3
- NNFCIKHAZHQZJG-UHFFFAOYSA-N potassium cyanide Chemical compound [K+].N#[C-] NNFCIKHAZHQZJG-UHFFFAOYSA-N 0.000 description 3
- 238000005507 spraying Methods 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- 229910001093 Zr alloy Inorganic materials 0.000 description 2
- 238000004210 cathodic protection Methods 0.000 description 2
- 229910052804 chromium Inorganic materials 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 238000004090 dissolution Methods 0.000 description 2
- 230000005611 electricity Effects 0.000 description 2
- 238000005098 hot rolling Methods 0.000 description 2
- 238000007654 immersion Methods 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 239000011261 inert gas Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000010956 nickel silver Substances 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 229910052719 titanium Inorganic materials 0.000 description 2
- ATRRKUHOCOJYRX-UHFFFAOYSA-N Ammonium bicarbonate Chemical compound [NH4+].OC([O-])=O ATRRKUHOCOJYRX-UHFFFAOYSA-N 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- 229910000599 Cr alloy Inorganic materials 0.000 description 1
- 229910001208 Crucible steel Inorganic materials 0.000 description 1
- 229910017526 Cu-Cr-Zr Inorganic materials 0.000 description 1
- 229910017810 Cu—Cr—Zr Inorganic materials 0.000 description 1
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- KRVSOGSZCMJSLX-UHFFFAOYSA-L chromic acid Substances O[Cr](O)(=O)=O KRVSOGSZCMJSLX-UHFFFAOYSA-L 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 239000002826 coolant Substances 0.000 description 1
- 239000000110 cooling liquid Substances 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- AWJWCTOOIBYHON-UHFFFAOYSA-N furo[3,4-b]pyrazine-5,7-dione Chemical compound C1=CN=C2C(=O)OC(=O)C2=N1 AWJWCTOOIBYHON-UHFFFAOYSA-N 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000011810 insulating material Substances 0.000 description 1
- 238000003754 machining Methods 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 238000010297 mechanical methods and process Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 150000002825 nitriles Chemical class 0.000 description 1
- 229910000510 noble metal Inorganic materials 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 230000002093 peripheral effect Effects 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
- 230000008439 repair process Effects 0.000 description 1
- 238000004904 shortening Methods 0.000 description 1
- 238000005480 shot peening Methods 0.000 description 1
- 150000003378 silver Chemical class 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 230000003746 surface roughness Effects 0.000 description 1
- 239000002470 thermal conductor Substances 0.000 description 1
- 150000003608 titanium Chemical class 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 238000009827 uniform distribution Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D11/00—Continuous casting of metals, i.e. casting in indefinite lengths
- B22D11/04—Continuous casting of metals, i.e. casting in indefinite lengths into open-ended moulds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D11/00—Continuous casting of metals, i.e. casting in indefinite lengths
- B22D11/04—Continuous casting of metals, i.e. casting in indefinite lengths into open-ended moulds
- B22D11/059—Mould materials or platings
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D3/00—Electroplating: Baths therefor
- C25D3/02—Electroplating: Baths therefor from solutions
- C25D3/46—Electroplating: Baths therefor from solutions of silver
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D5/00—Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
- C25D5/10—Electroplating with more than one layer of the same or of different metals
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D5/00—Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
- C25D5/60—Electroplating characterised by the structure or texture of the layers
- C25D5/615—Microstructure of the layers, e.g. mixed structure
- C25D5/617—Crystalline layers
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D5/00—Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
- C25D5/67—Electroplating to repair workpiece
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Crystallography & Structural Chemistry (AREA)
- Mechanical Engineering (AREA)
- Continuous Casting (AREA)
- Electroplating Methods And Accessories (AREA)
- Moulds For Moulding Plastics Or The Like (AREA)
- Coating With Molten Metal (AREA)
- Electroplating And Plating Baths Therefor (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR96/08658 | 1996-07-11 | ||
| FR9608658A FR2750903B1 (fr) | 1996-07-11 | 1996-07-11 | Element d'une lingotiere pour la coulee continue des metaux, comprenant une paroi refroidie en cuivre ou en alliage de cuivre comportant sur sa surface externe un revetement metallique et procede pour son revetement |
| PCT/FR1997/001139 WO1998002263A1 (fr) | 1996-07-11 | 1997-06-26 | Element d'une lingotiere pour la coulee continue des metaux, comprenant une paroi refroidie en cuivre ou en alliage de cuivre comportant sur sa surface externe un revetement metallique, et procede pour son revetement |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JP2000514361A true JP2000514361A (ja) | 2000-10-31 |
Family
ID=9493938
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP10505653A Pending JP2000514361A (ja) | 1996-07-11 | 1997-06-26 | 外側表面に金属被覆を有する銅または銅合金の冷却壁を備えた金属連続鋳造用鋳型の部品と、その被覆方法 |
Country Status (23)
| Country | Link |
|---|---|
| EP (1) | EP0910489B1 (cs) |
| JP (1) | JP2000514361A (cs) |
| KR (1) | KR20000022396A (cs) |
| CN (1) | CN1072047C (cs) |
| AT (1) | ATE192951T1 (cs) |
| AU (1) | AU710657B2 (cs) |
| BR (1) | BR9710229A (cs) |
| CA (1) | CA2258927A1 (cs) |
| CZ (1) | CZ6499A3 (cs) |
| DE (1) | DE69702064T2 (cs) |
| DK (1) | DK0910489T3 (cs) |
| ES (1) | ES2148994T3 (cs) |
| FR (1) | FR2750903B1 (cs) |
| GR (1) | GR3034001T3 (cs) |
| PL (1) | PL331180A1 (cs) |
| PT (1) | PT910489E (cs) |
| RO (1) | RO119994B1 (cs) |
| RU (1) | RU2181315C2 (cs) |
| SK (1) | SK299A3 (cs) |
| TR (1) | TR199900041T2 (cs) |
| TW (1) | TW438911B (cs) |
| WO (1) | WO1998002263A1 (cs) |
| ZA (1) | ZA975970B (cs) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AU2001245432B2 (en) * | 2000-03-03 | 2006-04-27 | Cook Medical Technologies Llc | Bulbous valve and stent for treating vascular reflux |
| CN100335200C (zh) * | 2002-05-27 | 2007-09-05 | 康卡斯特股份公司 | 电镀连续铸型的方法 |
| EA008676B1 (ru) * | 2005-08-22 | 2007-06-29 | Республиканское Унитарное Предприятие "Белорусский Металлургический Завод" | Способ нанесения двухслойного гальванического покрытия на медные гильзы и плиты кристаллизаторов |
| DE202009013126U1 (de) * | 2009-09-29 | 2009-12-10 | Egon Evertz Kg (Gmbh & Co.) | Kokille zum Stranggießen |
| CN102672437B (zh) * | 2012-06-04 | 2014-07-30 | 无锡市三方轧辊有限公司 | 热轧铝板轧辊再生利用的加工工艺 |
| FI20126350A7 (fi) * | 2012-12-20 | 2014-06-21 | Fiskars Brands Finland Oy Ab | Pilkkomista helpottava laite käytettäväksi polttopuun pilkkomisessa |
| EP2942168B1 (en) | 2014-05-09 | 2018-02-07 | Fiskars Finland Oy Ab | Chopping aid |
| CN107254697B (zh) * | 2017-06-06 | 2020-02-14 | 秦皇岛瀚丰长白结晶器有限责任公司 | 结晶器铜板镍钴合金镀层钴的梯度分布工艺及电镀装置 |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2450937C2 (de) * | 1974-10-23 | 1983-02-24 | Schering Ag, 1000 Berlin Und 4619 Bergkamen | Vorversilberungsbad |
| JPS5570452A (en) * | 1978-11-20 | 1980-05-27 | Nishio Metaraijingu:Kk | Continuous casting mold |
| DE3038289A1 (de) * | 1980-10-10 | 1982-05-27 | Egon 5650 Solingen Evertz | Verfahren zum abscheiden von metallschichten auf den waenden von kokillen |
| DE3118596A1 (de) * | 1981-05-11 | 1982-11-25 | Hilti AG, 9494 Schaan | Spreizduebel |
| DE3211199A1 (de) * | 1982-03-26 | 1983-09-29 | Egon 5650 Solingen Evertz | Verfahren zum vernickeln von kokillenwaenden |
| FR2622901B1 (fr) * | 1987-11-05 | 1990-02-09 | Snecma | Procede electrolytique d'argentage en couche mince et application a des chemins de roulement |
| RU2006530C1 (ru) * | 1992-06-24 | 1994-01-30 | Научно-исследовательский институт радиокомпонентов | Способ электролитического серебрения |
-
1996
- 1996-07-11 FR FR9608658A patent/FR2750903B1/fr not_active Expired - Fee Related
-
1997
- 1997-06-26 SK SK2-99A patent/SK299A3/sk unknown
- 1997-06-26 CA CA002258927A patent/CA2258927A1/fr not_active Abandoned
- 1997-06-26 BR BR9710229A patent/BR9710229A/pt active Search and Examination
- 1997-06-26 KR KR1019980710827A patent/KR20000022396A/ko not_active Ceased
- 1997-06-26 DE DE69702064T patent/DE69702064T2/de not_active Expired - Fee Related
- 1997-06-26 ES ES97930592T patent/ES2148994T3/es not_active Expired - Lifetime
- 1997-06-26 RU RU99102726/02A patent/RU2181315C2/ru active
- 1997-06-26 CZ CZ9964A patent/CZ6499A3/cs unknown
- 1997-06-26 WO PCT/FR1997/001139 patent/WO1998002263A1/fr not_active Ceased
- 1997-06-26 RO RO99-00014A patent/RO119994B1/ro unknown
- 1997-06-26 TR TR1999/00041T patent/TR199900041T2/xx unknown
- 1997-06-26 PT PT97930592T patent/PT910489E/pt unknown
- 1997-06-26 DK DK97930592T patent/DK0910489T3/da active
- 1997-06-26 AU AU34488/97A patent/AU710657B2/en not_active Ceased
- 1997-06-26 JP JP10505653A patent/JP2000514361A/ja active Pending
- 1997-06-26 PL PL97331180A patent/PL331180A1/xx unknown
- 1997-06-26 EP EP97930592A patent/EP0910489B1/fr not_active Expired - Lifetime
- 1997-06-26 CN CN97196281A patent/CN1072047C/zh not_active Expired - Fee Related
- 1997-06-26 AT AT97930592T patent/ATE192951T1/de not_active IP Right Cessation
- 1997-07-03 ZA ZA9705970A patent/ZA975970B/xx unknown
- 1997-08-27 TW TW086112299A patent/TW438911B/zh not_active IP Right Cessation
-
2000
- 2000-07-24 GR GR20000401687T patent/GR3034001T3/el not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| BR9710229A (pt) | 1999-08-10 |
| ES2148994T3 (es) | 2000-10-16 |
| CA2258927A1 (fr) | 1998-01-22 |
| DK0910489T3 (da) | 2000-10-09 |
| ZA975970B (en) | 1998-01-30 |
| RU2181315C2 (ru) | 2002-04-20 |
| PL331180A1 (en) | 1999-06-21 |
| CZ6499A3 (cs) | 1999-10-13 |
| WO1998002263A1 (fr) | 1998-01-22 |
| DE69702064D1 (de) | 2000-06-21 |
| EP0910489A1 (fr) | 1999-04-28 |
| PT910489E (pt) | 2000-10-31 |
| ATE192951T1 (de) | 2000-06-15 |
| DE69702064T2 (de) | 2001-01-11 |
| TR199900041T2 (xx) | 1999-06-21 |
| FR2750903B1 (fr) | 1998-09-18 |
| CN1072047C (zh) | 2001-10-03 |
| TW438911B (en) | 2001-06-07 |
| GR3034001T3 (en) | 2000-11-30 |
| EP0910489B1 (fr) | 2000-05-17 |
| AU710657B2 (en) | 1999-09-23 |
| KR20000022396A (ko) | 2000-04-25 |
| RO119994B1 (ro) | 2005-07-29 |
| SK299A3 (en) | 1999-05-07 |
| FR2750903A1 (fr) | 1998-01-16 |
| AU3448897A (en) | 1998-02-09 |
| CN1225046A (zh) | 1999-08-04 |
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