ITMI931960A1 - Procedimento per la preparazione di polimeri dell'etilene e prodotti ottenuti - Google Patents
Procedimento per la preparazione di polimeri dell'etilene e prodotti ottenutiInfo
- Publication number
- ITMI931960A1 ITMI931960A1 IT93MI001960A ITMI931960A ITMI931960A1 IT MI931960 A1 ITMI931960 A1 IT MI931960A1 IT 93MI001960 A IT93MI001960 A IT 93MI001960A IT MI931960 A ITMI931960 A IT MI931960A IT MI931960 A1 ITMI931960 A1 IT MI931960A1
- Authority
- IT
- Italy
- Prior art keywords
- procedure
- preparation
- ethylene polymers
- obtained products
- metallogen
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
- C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
OMOPOLIMERI E COPOLIMERI DELL'ETILENE DOTATI DI ELEVATO PESO MOLECOLARE E STRETTA DISTIRBUZIONE DEI PESI MOLECOLARI SONO OTTENIBILI CONDUCENDO LA REAZIONE DI POLIMERIZZAZIONE IN PRESENZA DI UN METALLOGENE STEREORIGIDO NELLA FORMA ISOMERICA MESO.
Priority Applications (19)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| ITMI931960A IT1271406B (it) | 1993-09-13 | 1993-09-13 | Procedimento per la preparazione di polimeri dell'etilene e prodotti ottenuti |
| EP94113559A EP0643078B1 (en) | 1993-09-13 | 1994-08-31 | Process for the preparation of ethylene polymers and products obtained therefrom |
| DE69432040T DE69432040T2 (de) | 1993-09-13 | 1994-08-31 | Verfahren zur Herstellung von Ethylenpolymeren und daraus erhaltene Produkte |
| ES94113559T ES2188600T3 (es) | 1993-09-13 | 1994-08-31 | Procedimiento de preparacion de polimeros de etileno y productos de esta forma obtenidos. |
| AU72869/94A AU690127B2 (en) | 1993-09-13 | 1994-09-09 | Process for the preparation of ethylene polymers and products obtained therefrom |
| IL11090594A IL110905A (en) | 1993-09-13 | 1994-09-09 | Process for the preparation of ethylene polymers and copolymers and products obtained therefrom |
| BR9403069A BR9403069A (pt) | 1993-09-13 | 1994-09-12 | Processo para a preparaçao de polimeros de etileno e produtos dele obtidos. |
| RU94033101/04A RU2161627C2 (ru) | 1993-09-13 | 1994-09-12 | Способ получения полимеров этилена и продукты, полученные из них |
| US08/304,379 US5585448A (en) | 1993-09-13 | 1994-09-12 | Process for the preparation of ethylene polymers and products obtained therefrom |
| FI944193A FI944193A7 (fi) | 1993-09-13 | 1994-09-12 | Menetelmä eteenipolymeerien valmistamiseksi ja menetelmällä saatuja tuotteita |
| CA002131940A CA2131940A1 (en) | 1993-09-13 | 1994-09-13 | Process for the preparation of ethylene polymers and products obtained therefrom |
| TR00951/94A TR27973A (tr) | 1993-09-13 | 1994-09-13 | Etilen polimerlerinin hazirlanmasi icin islem ve bu polimerlerden elde edilen ürünler. |
| JP6219285A JPH07165813A (ja) | 1993-09-13 | 1994-09-13 | エチレン系ポリマーの製造法およびこれから得られる製品 |
| CN94117887A CN1069651C (zh) | 1993-09-13 | 1994-09-13 | 乙烯聚合物的制备方法 |
| KR1019940023100A KR100328099B1 (ko) | 1993-09-13 | 1994-09-13 | 에틸렌중합체의제조방법및이방법으로부터수득한생성물 |
| CN96108535A CN1149586A (zh) | 1993-09-13 | 1996-07-29 | 立体刚性的金属茂化合物 |
| US08/720,537 US5886123A (en) | 1993-09-13 | 1996-09-30 | Elastomeric copolymers of ethylene with at least one alpha-olefin |
| CN00121652A CN1308090A (zh) | 1993-09-13 | 2000-07-17 | 乙烯弹性共聚物 |
| KR1020010073400A KR100328114B1 (ko) | 1993-09-13 | 2001-11-23 | 에틸렌의 엘라스토머성 공중합체 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| ITMI931960A IT1271406B (it) | 1993-09-13 | 1993-09-13 | Procedimento per la preparazione di polimeri dell'etilene e prodotti ottenuti |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| ITMI931960A0 ITMI931960A0 (it) | 1993-09-13 |
| ITMI931960A1 true ITMI931960A1 (it) | 1995-03-13 |
| IT1271406B IT1271406B (it) | 1997-05-28 |
Family
ID=11366885
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ITMI931960A IT1271406B (it) | 1993-09-13 | 1993-09-13 | Procedimento per la preparazione di polimeri dell'etilene e prodotti ottenuti |
Country Status (15)
| Country | Link |
|---|---|
| US (2) | US5585448A (it) |
| EP (1) | EP0643078B1 (it) |
| JP (1) | JPH07165813A (it) |
| KR (2) | KR100328099B1 (it) |
| CN (3) | CN1069651C (it) |
| AU (1) | AU690127B2 (it) |
| BR (1) | BR9403069A (it) |
| CA (1) | CA2131940A1 (it) |
| DE (1) | DE69432040T2 (it) |
| ES (1) | ES2188600T3 (it) |
| FI (1) | FI944193A7 (it) |
| IL (1) | IL110905A (it) |
| IT (1) | IT1271406B (it) |
| RU (1) | RU2161627C2 (it) |
| TR (1) | TR27973A (it) |
Families Citing this family (66)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IT1271407B (it) * | 1993-09-13 | 1997-05-28 | Spherilene Srl | Procedimento per la preparazione di copolimeri elastomerici dell'etilene e prodotti ottenuti |
| EP0654476B1 (de) * | 1993-11-24 | 2001-01-24 | TARGOR GmbH | Metallocene, Verfahren zu ihrer Herstellung und ihrer Verwendung als Katalysatoren |
| IT1270253B (it) * | 1994-06-20 | 1997-04-29 | Spherilene Srl | Copolimeri dell'etilene e procedimento per la preparazione di polimeri dell'etilene |
| IT1273660B (it) * | 1994-07-20 | 1997-07-09 | Spherilene Srl | Procedimento per la preparazione di polimeri amorfi del propilene |
| IT1270125B (it) * | 1994-10-05 | 1997-04-28 | Spherilene Srl | Processo per la ( co) polimerizzazione di olefine |
| TW383313B (en) * | 1994-12-20 | 2000-03-01 | Mitsui Petrochemical Ind | Preparation of ethylene-alpha-olefin-nonconjugate polyene random copolymers, the copolymers obtaining which, and the use of the copolymers |
| IT1272922B (it) * | 1995-01-23 | 1997-07-01 | Spherilene Srl | Procedimento per la preparazione di composti metallocenici |
| WO1996023750A1 (de) * | 1995-02-01 | 1996-08-08 | Basf Aktiengesellschaft | Verfahren zur herstellung von olefin-oligomeren |
| IT1275856B1 (it) * | 1995-03-03 | 1997-10-24 | Spherilene Srl | Composti metallocenici bis-fluorenilici, procedimento per la loro preparazione e loro utilizzo in catalizzatori per la polimerizzazione |
| IT1275857B1 (it) * | 1995-03-03 | 1997-10-24 | Spherilene Srl | Copolimeri atattici del propilene con l'etilene |
| IT1274469B (it) * | 1995-05-11 | 1997-07-17 | Spherilene Spa | Composizioni poliolefiniche vulcanizzabili dinamicamente |
| PT743324E (pt) * | 1995-05-16 | 2003-01-31 | Univation Tech Llc | Producao de polietileno usando metalocenos estereoisomericos |
| US6225426B1 (en) * | 1996-04-10 | 2001-05-01 | Uniroyal Chemical Company, Inc. | Process for producing polyolefin elastomer employing a metallocene catalyst |
| IT1283630B1 (it) * | 1996-05-09 | 1998-04-23 | Enichem Spa | Procedimento per la preparazione di copolimeri elastomerici ep(d)m |
| FR2749018B1 (fr) * | 1996-05-21 | 1998-07-31 | Hutchinson | Elastomere reticule a transformation thermoplastique, son procede de fabrication et ses utilisations |
| IT1284097B1 (it) * | 1996-07-02 | 1998-05-08 | Montell Tecnology Company Bv | Processo in sospensione per la preparazione di copolimeri elastomerici dell'etilene |
| DE69720609T2 (de) * | 1996-07-16 | 2003-11-13 | Basell Polyolefine Gmbh | Verfahren zur Modifikation von die Rac/Meso-Verhältnis einer Metallocenverbindung |
| CN1113890C (zh) * | 1996-11-15 | 2003-07-09 | 蒙特尔技术有限公司 | 杂环金属茂和聚合催化剂 |
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| NL1006346C2 (nl) * | 1997-06-18 | 1998-12-21 | Dsm Nv | Werkwijze voor de bereiding van polyolefines bij hoge temperatuur met behulp van Zr-metallocenen. |
| US7232871B2 (en) | 1997-08-12 | 2007-06-19 | Exxonmobil Chemical Patents Inc. | Propylene ethylene polymers and production process |
| US7026404B2 (en) * | 1997-08-12 | 2006-04-11 | Exxonmobil Chemical Patents Inc. | Articles made from blends made from propylene ethylene polymers |
| US6921794B2 (en) | 1997-08-12 | 2005-07-26 | Exxonmobil Chemical Patents Inc. | Blends made from propylene ethylene polymers |
| US6635715B1 (en) | 1997-08-12 | 2003-10-21 | Sudhin Datta | Thermoplastic polymer blends of isotactic polypropylene and alpha-olefin/propylene copolymers |
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| AU2111599A (en) | 1998-01-09 | 1999-07-26 | Board Of Trustees Of The Leland Stanford Junior University | High-melting polyolefin copolymer elastomers, catalysts and methods of synthesis |
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| US6469188B1 (en) | 1999-01-20 | 2002-10-22 | California Institute Of Technology | Catalyst system for the polymerization of alkenes to polyolefins |
| AU782786B2 (en) * | 1999-12-01 | 2005-08-25 | Exxonmobil Chemical Patents Inc | Catalyst compounds, catalyst systems thereof and their use in a polymerization process |
| US6534153B1 (en) | 1999-12-09 | 2003-03-18 | Exxonmobil Oil Corporation | Matte surface film with improved matte appearance |
| ATE485319T1 (de) | 2001-04-12 | 2010-11-15 | Exxonmobil Chem Patents Inc | Verfahren zur polymerisation von propylen und ethylen in lösung |
| KR100458600B1 (ko) * | 2002-02-07 | 2004-12-03 | 주식회사 엘지화학 | 메틸렌 브릿지된 메탈로센 촉매를 이용한 올레핀-시클릭올레핀 공중합체의 제조 방법 |
| US6706828B2 (en) * | 2002-06-04 | 2004-03-16 | Crompton Corporation | Process for the oligomerization of α-olefins having low unsaturation |
| JP2006502260A (ja) * | 2002-10-10 | 2006-01-19 | バセル ポリオレフィン ジーエムビーエイチ | エチレンの共重合方法 |
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| DE10360060A1 (de) | 2003-12-19 | 2005-07-21 | Basell Polyolefine Gmbh | Verfahren zur meso-selektiven Synthese von anso-Metallocen |
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| WO2009104783A1 (en) | 2008-02-20 | 2009-08-27 | Sumitomo Chemical Company, Limited | Catalyst component for polymerization of ethylene and process for producing ethylene polymer (2) |
| CN103237817B (zh) * | 2010-07-01 | 2016-03-16 | 道达尔研究技术弗吕公司 | 改性的催化剂载体 |
| BR112012032539A2 (pt) | 2010-07-06 | 2016-11-22 | Ticona Gmbh | processo para produção de polietileno de alto peso molecular |
| WO2012004675A2 (en) | 2010-07-06 | 2012-01-12 | Ticona Gmbh | Process for producing high molecular weight polyethylene |
| BR112012032615A2 (pt) | 2010-07-06 | 2017-06-20 | Ticona Gmbh | "fibras e membranas de polietileno de alto peso molecular,sua produção e uso" |
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| KR20130124169A (ko) | 2010-07-06 | 2013-11-13 | 티코나 게엠베하 | 고 분자량 폴리에틸렌의 제조 방법 |
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| KR101457120B1 (ko) | 2012-08-03 | 2014-10-31 | 주식회사 엘지화학 | 전이 금속 화합물을 포함하는 전이 금속 촉매 조성물 및 상기 촉매 조성물을 이용한 폴리 올레핀의 제조 방법 |
| CN110922516B (zh) * | 2018-09-20 | 2022-12-30 | 中国石油化工股份有限公司 | 一种乙烯共聚物及其制备方法 |
| CN114716599B (zh) * | 2021-01-05 | 2024-02-13 | 中国石油化工股份有限公司 | 一种烯烃共聚物及其制备方法与应用 |
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| WO1991002012A1 (en) * | 1989-08-03 | 1991-02-21 | Exxon Chemical Patents Inc. | Very high molecular weight polyethylene |
| EP0551277B2 (en) * | 1990-06-22 | 2005-03-09 | ExxonMobil Chemical Patents Inc. | Aluminum-free monocyclopentadienyl metallocene catalysts for olefin polymerization |
| ES2071888T3 (es) * | 1990-11-12 | 1995-07-01 | Hoechst Ag | Bisindenilmetalocenos sustituidos en posicion 2, procedimiento para su preparacion y su utilizacion como catalizadores en la polimerizacion de olefinas. |
| US5134209A (en) * | 1990-12-26 | 1992-07-28 | Shell Oil Company | Process of producing ethylene-propylene rubbery copolymer |
| ES2127199T3 (es) * | 1991-02-27 | 1999-04-16 | Ticona Gmbh | Proceso para la preparacion de (co)polimeros de cicloolefinas con distribucion estrecha de pesos moleculares. |
| EP0729977B1 (de) * | 1991-03-09 | 2002-09-04 | Basell Polyolefine GmbH | Metallocen und Katalysator |
| US5436305A (en) * | 1991-05-09 | 1995-07-25 | Phillips Petroleum Company | Organometallic fluorenyl compounds, preparation, and use |
| TW300901B (it) * | 1991-08-26 | 1997-03-21 | Hoechst Ag | |
| DE59210001D1 (de) * | 1991-10-15 | 2005-02-17 | Basell Polyolefine Gmbh | Verfahren zur Herstellung eines Olefinpolymers unter Verwendung von Metallocenen mit speziell substituierten Indenylliganden |
| TW318184B (it) * | 1991-11-30 | 1997-10-21 | Hoechst Ag | |
| EP0552945B1 (en) * | 1992-01-23 | 1997-05-07 | Mitsui Petrochemical Industries, Ltd. | Process for the preparation of polyolefin |
| US5620760A (en) * | 1992-06-30 | 1997-04-15 | Montell Technology Company Bv | Shaped articles for biomedical use |
| ATE177436T1 (de) * | 1992-08-15 | 1999-03-15 | Targor Gmbh | Verfahren zur herstellung von polyolefinen |
| IT1264680B1 (it) * | 1993-07-07 | 1996-10-04 | Spherilene Srl | Catalizzatori supportati per la polimerizzazione delle olefine |
| US5491207A (en) * | 1993-12-14 | 1996-02-13 | Exxon Chemical Patents Inc. | Process of producing high molecular weight ethylene-α-olefin elastomers with an indenyl metallocene catalyst system |
-
1993
- 1993-09-13 IT ITMI931960A patent/IT1271406B/it active IP Right Grant
-
1994
- 1994-08-31 EP EP94113559A patent/EP0643078B1/en not_active Expired - Lifetime
- 1994-08-31 DE DE69432040T patent/DE69432040T2/de not_active Expired - Fee Related
- 1994-08-31 ES ES94113559T patent/ES2188600T3/es not_active Expired - Lifetime
- 1994-09-09 AU AU72869/94A patent/AU690127B2/en not_active Ceased
- 1994-09-09 IL IL11090594A patent/IL110905A/en not_active IP Right Cessation
- 1994-09-12 BR BR9403069A patent/BR9403069A/pt not_active IP Right Cessation
- 1994-09-12 US US08/304,379 patent/US5585448A/en not_active Expired - Lifetime
- 1994-09-12 RU RU94033101/04A patent/RU2161627C2/ru active
- 1994-09-12 FI FI944193A patent/FI944193A7/fi unknown
- 1994-09-13 TR TR00951/94A patent/TR27973A/xx unknown
- 1994-09-13 JP JP6219285A patent/JPH07165813A/ja active Pending
- 1994-09-13 CN CN94117887A patent/CN1069651C/zh not_active Expired - Fee Related
- 1994-09-13 KR KR1019940023100A patent/KR100328099B1/ko not_active Expired - Fee Related
- 1994-09-13 CA CA002131940A patent/CA2131940A1/en not_active Abandoned
-
1996
- 1996-07-29 CN CN96108535A patent/CN1149586A/zh active Pending
- 1996-09-30 US US08/720,537 patent/US5886123A/en not_active Expired - Fee Related
-
2000
- 2000-07-17 CN CN00121652A patent/CN1308090A/zh active Pending
-
2001
- 2001-11-23 KR KR1020010073400A patent/KR100328114B1/ko not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| KR100328099B1 (ko) | 2002-06-22 |
| AU7286994A (en) | 1995-03-23 |
| FI944193A0 (fi) | 1994-09-12 |
| IL110905A (en) | 2001-08-08 |
| KR950008543A (ko) | 1995-04-19 |
| JPH07165813A (ja) | 1995-06-27 |
| CN1149586A (zh) | 1997-05-14 |
| EP0643078A2 (en) | 1995-03-15 |
| KR100328114B1 (ko) | 2002-03-09 |
| CA2131940A1 (en) | 1995-03-14 |
| BR9403069A (pt) | 1995-05-02 |
| DE69432040D1 (de) | 2003-02-27 |
| EP0643078B1 (en) | 2003-01-22 |
| US5886123A (en) | 1999-03-23 |
| CN1308090A (zh) | 2001-08-15 |
| AU690127B2 (en) | 1998-04-23 |
| FI944193L (fi) | 1995-03-14 |
| FI944193A7 (fi) | 1995-03-14 |
| EP0643078A3 (en) | 1995-04-26 |
| CN1069651C (zh) | 2001-08-15 |
| ES2188600T3 (es) | 2003-07-01 |
| TR27973A (tr) | 1995-11-07 |
| RU94033101A (ru) | 1996-07-20 |
| DE69432040T2 (de) | 2003-08-14 |
| ITMI931960A0 (it) | 1993-09-13 |
| IT1271406B (it) | 1997-05-28 |
| IL110905A0 (en) | 1994-11-28 |
| RU2161627C2 (ru) | 2001-01-10 |
| CN1105674A (zh) | 1995-07-26 |
| US5585448A (en) | 1996-12-17 |
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| Date | Code | Title | Description |
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| 0001 | Granted | ||
| TA | Fee payment date (situation as of event date), data collected since 19931001 |
Effective date: 19970923 |