IT1091110B - Acetanilidi - Google Patents
AcetanilidiInfo
- Publication number
- IT1091110B IT1091110B IT51518/77A IT5151877A IT1091110B IT 1091110 B IT1091110 B IT 1091110B IT 51518/77 A IT51518/77 A IT 51518/77A IT 5151877 A IT5151877 A IT 5151877A IT 1091110 B IT1091110 B IT 1091110B
- Authority
- IT
- Italy
- Prior art keywords
- acetanilide
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D257/00—Heterocyclic compounds containing rings having four nitrogen atoms as the only ring hetero atoms
- C07D257/02—Heterocyclic compounds containing rings having four nitrogen atoms as the only ring hetero atoms not condensed with other rings
- C07D257/04—Five-membered rings
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/36—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom five-membered rings
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/50—1,3-Diazoles; Hydrogenated 1,3-diazoles
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
- A01N43/647—Triazoles; Hydrogenated triazoles
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
- A01N43/647—Triazoles; Hydrogenated triazoles
- A01N43/653—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/713—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with four or more nitrogen atoms as the only ring hetero atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D231/00—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
- C07D231/02—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
- C07D231/10—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
- C07D231/12—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D233/00—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings
- C07D233/54—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members
- C07D233/56—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members with only hydrogen atoms or radicals containing only hydrogen and carbon atoms, attached to ring carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D233/00—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings
- C07D233/54—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members
- C07D233/66—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D233/68—Halogen atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D249/00—Heterocyclic compounds containing five-membered rings having three nitrogen atoms as the only ring hetero atoms
- C07D249/02—Heterocyclic compounds containing five-membered rings having three nitrogen atoms as the only ring hetero atoms not condensed with other rings
- C07D249/04—1,2,3-Triazoles; Hydrogenated 1,2,3-triazoles
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D249/00—Heterocyclic compounds containing five-membered rings having three nitrogen atoms as the only ring hetero atoms
- C07D249/02—Heterocyclic compounds containing five-membered rings having three nitrogen atoms as the only ring hetero atoms not condensed with other rings
- C07D249/04—1,2,3-Triazoles; Hydrogenated 1,2,3-triazoles
- C07D249/06—1,2,3-Triazoles; Hydrogenated 1,2,3-triazoles with aryl radicals directly attached to ring atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D249/00—Heterocyclic compounds containing five-membered rings having three nitrogen atoms as the only ring hetero atoms
- C07D249/02—Heterocyclic compounds containing five-membered rings having three nitrogen atoms as the only ring hetero atoms not condensed with other rings
- C07D249/08—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D249/00—Heterocyclic compounds containing five-membered rings having three nitrogen atoms as the only ring hetero atoms
- C07D249/02—Heterocyclic compounds containing five-membered rings having three nitrogen atoms as the only ring hetero atoms not condensed with other rings
- C07D249/08—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
- C07D249/10—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE2648008A DE2648008C3 (de) | 1976-10-23 | 1976-10-23 | Acetanilide |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| IT1091110B true IT1091110B (it) | 1985-06-26 |
Family
ID=5991191
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| IT51518/77A IT1091110B (it) | 1976-10-23 | 1977-10-21 | Acetanilidi |
Country Status (34)
| Country | Link |
|---|---|
| US (1) | US4593104A (it) |
| JP (1) | JPS5353651A (it) |
| AR (1) | AR226276A1 (it) |
| AT (1) | AT356965B (it) |
| AU (1) | AU513441B2 (it) |
| BE (1) | BE860043A (it) |
| BR (1) | BR7706995A (it) |
| CA (1) | CA1240682A (it) |
| CH (1) | CH629362A5 (it) |
| CS (1) | CS194818B2 (it) |
| DD (1) | DD133392A5 (it) |
| DE (1) | DE2648008C3 (it) |
| DK (1) | DK151011C (it) |
| FI (1) | FI64355C (it) |
| FR (1) | FR2368476A1 (it) |
| GB (1) | GB1588874A (it) |
| GR (1) | GR61166B (it) |
| HU (1) | HU177168B (it) |
| IE (1) | IE46260B1 (it) |
| IL (1) | IL53014A (it) |
| IN (1) | IN149141B (it) |
| IT (1) | IT1091110B (it) |
| KE (1) | KE3162A (it) |
| LU (1) | LU78353A1 (it) |
| MY (1) | MY8200148A (it) |
| NL (1) | NL189279C (it) |
| NO (1) | NO146910C (it) |
| NZ (1) | NZ185482A (it) |
| PH (1) | PH17884A (it) |
| PL (1) | PL104859B1 (it) |
| SE (1) | SE442399B (it) |
| SU (1) | SU670197A3 (it) |
| UA (1) | UA7012A1 (it) |
| ZA (1) | ZA776278B (it) |
Families Citing this family (39)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IL53938A0 (en) * | 1977-02-02 | 1978-04-30 | Bayer Ag | Novel n-substituted halogenoacetanilides, their preparation and their use as herbicides |
| DE2744396A1 (de) * | 1977-10-03 | 1979-04-12 | Basf Ag | Acetanilide |
| US4243408A (en) | 1978-05-11 | 1981-01-06 | Chevron Research Company | Herbicidal N-triazolylmethyl-substituted alpha-haloacetanilide |
| DE2828303A1 (de) * | 1978-06-28 | 1980-01-17 | Bayer Ag | Verwendung von n,n-diallyl-dichloracetamid zur verbesserung der kulturpflanzen- vertraeglichkeit von herbizid wirksamen acetaniliden |
| DE2828222A1 (de) * | 1978-06-28 | 1980-01-10 | Bayer Ag | Gegenmittel zum schutz von kulturpflanzen vor schaedigungen durch herbizide |
| DE2830764A1 (de) * | 1978-07-13 | 1980-01-31 | Basf Ag | Acetanilide |
| DE2832046A1 (de) * | 1978-07-21 | 1980-01-31 | Basf Ag | Herbizide mittel auf der basis von acetaniliden |
| GR66644B (it) * | 1978-07-27 | 1981-04-03 | Basf Ag | |
| DE2832940A1 (de) * | 1978-07-27 | 1980-02-14 | Basf Ag | Herbizide mittel |
| DE2832950A1 (de) * | 1978-07-27 | 1980-02-21 | Basf Ag | Herbizide mittel |
| DE2835156A1 (de) * | 1978-08-10 | 1980-02-14 | Bayer Ag | Substituierte n-pyrazolylmethyl -halogenacetanilide, verfahren zu ihrer herstellung sowie ihre verwendung als herbizide |
| DE2835157A1 (de) * | 1978-08-10 | 1980-02-21 | Bayer Ag | Verfahren zur herstellung von n-substituierten alpha -halogenacetaniliden |
| DE2842003A1 (de) * | 1978-09-27 | 1980-04-10 | Bayer Ag | Mittel zur selektiven unkrautbekaempfung |
| DE2842280A1 (de) * | 1978-09-28 | 1980-04-10 | Bayer Ag | N-(1,3-azolyl)-alkyl-halogenacetanilide, verfahren zu ihrer herstellung sowie ihre verwendung als herbizide |
| DE2842284A1 (de) * | 1978-09-28 | 1980-04-17 | Bayer Ag | N-diazolylalkyl-halogenacetanilide, verfahren zu ihrer herstellung sowie ihre verwendung als herbizide |
| DE2843869A1 (de) | 1978-10-07 | 1980-04-24 | Basf Ag | Acetanilide |
| DE2854599A1 (de) * | 1978-12-18 | 1980-06-26 | Basf Ag | Substituierte n-halogenmethylanilide und verfahren zu ihrer herstellung und verwendung |
| DE2854598A1 (de) * | 1978-12-18 | 1980-07-03 | Basf Ag | N-substituierte carbonsaeureanilide, verfahren zu ihrer herstellung sowie ihre verwendung als fungizide |
| DE2901593A1 (de) | 1979-01-17 | 1980-08-07 | Basf Ag | N-azolylessigsaeureanilide |
| DE2948535A1 (de) * | 1979-12-03 | 1981-06-25 | Basf Ag, 6700 Ludwigshafen | Dichloracetamide, herbizide mittel, die acetanilide als herbizide wirkstoffe und diese dichloracetamide als antagonistische mittel enthalten, sowie ihre verwendung zur bekaempfung unerwuenschten pflanzenwuchses |
| DE2919293A1 (de) * | 1979-05-12 | 1980-11-20 | Bayer Ag | N-(2,5-diazolyl)alkyl-halogenacetanilide, verfahren zu ihrer herstellung sowie ihre verwendung als herbizide |
| DE2920300A1 (de) | 1979-05-19 | 1980-11-20 | Basf Ag | Herbizide mittel auf der basis von n-azolyl-methyl-acetaniliden und cyclohexan-1,3-dionderivaten |
| DE3035394A1 (de) * | 1980-09-19 | 1982-05-06 | Bayer Ag, 5090 Leverkusen | Verfahren zur herstellung von pyrazol |
| DE3035395A1 (de) * | 1980-09-19 | 1982-05-06 | Bayer Ag, 5090 Leverkusen | Verfahren zur herstellung von pyrazol |
| DE3373973D1 (en) * | 1982-07-13 | 1987-11-12 | Schering Agrochemicals Ltd | Herbicidal mixtures |
| DE3419050A1 (de) * | 1984-05-22 | 1985-11-28 | Lentia GmbH Chem. u. pharm. Erzeugnisse - Industriebedarf, 8000 München | Herbizides mittel |
| JPS6157540A (ja) * | 1984-08-29 | 1986-03-24 | Mitsubishi Petrochem Co Ltd | 新規なアセトアニリド誘導体及びこれを含む除草剤 |
| DE3925253A1 (de) * | 1989-07-29 | 1991-01-31 | Basf Ag | Monoklines metazachlor und verfahren zu seiner herstellung |
| US5250503A (en) * | 1989-07-29 | 1993-10-05 | Basf Aktiengesellschaft | Monoclinic metazachlor and composition |
| DE4429014A1 (de) | 1994-08-16 | 1996-02-22 | Basf Ag | Verfahren zur Herstellung von cyclischen Aminen |
| DE4436293A1 (de) | 1994-10-11 | 1996-04-18 | Basf Ag | Stabile Mischung, welche Wasser und Metazachlor enthält |
| DE10343277A1 (de) | 2003-09-18 | 2005-04-21 | Piesteritz Stickstoff | N-(1H-Azolyl-methyl)amide, Verfahren zu ihrer Herstellung und ihre Verwendung als Nitrifikationsinhibitoren |
| EP2052606A1 (de) | 2007-10-24 | 2009-04-29 | Bayer CropScience AG | Herbizid-Kombination |
| DE102008037620A1 (de) * | 2008-08-14 | 2010-02-18 | Bayer Crop Science Ag | Herbizid-Kombination mit Dimethoxytriazinyl-substituierten Difluormethansulfonylaniliden |
| SI3284346T1 (sl) | 2010-10-15 | 2021-11-30 | Bayer Cropscience Aktiengesellschaft | Uporaba herbicidov zaviralcev ALS za zatiranje neželene vegetacije v rastlinah Beta vulgaris, ki so tolerantne na herbicide zaviralce ALS |
| WO2012150333A1 (en) | 2011-05-04 | 2012-11-08 | Bayer Intellectual Property Gmbh | Use of als inhibitor herbicides for control of unwanted vegetation in als inhibitor herbicide tolerant brassica, such as b. napus, plants |
| US9079862B2 (en) | 2012-01-13 | 2015-07-14 | Basf Se | Process for preparing acetanilides |
| DK2931034T4 (da) | 2012-12-13 | 2022-07-18 | Bayer Cropscience Ag | Anvendelse af als-inhibitorherbicider til bekæmpelse af uønsket vegetation i als-inhibitorherbicidtolerante beta vulgaris-planter |
| WO2023062184A1 (en) | 2021-10-15 | 2023-04-20 | KWS SAAT SE & Co. KGaA | Als inhibitor herbicide tolerant beta vulgaris mutants |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE532981A (it) * | 1953-10-30 | |||
| US3547620A (en) * | 1969-01-23 | 1970-12-15 | Monsanto Co | N-(oxamethyl)alpha-halo-acetanilide herbicides |
| US3907544A (en) * | 1971-06-01 | 1975-09-23 | Monsanto Co | Herbicidal 2-halo-N-(cyclicimidoalkylene)-substituted acetanilides |
| US3769301A (en) * | 1971-06-01 | 1973-10-30 | Monsanto Co | Herbicidal-n-(acyl-tertiary-amidoalkyl)anilides |
| CA1019752A (en) * | 1973-02-12 | 1977-10-25 | Sidney B. Richter | Heterocyclic anilids |
| US4098895A (en) * | 1975-09-30 | 1978-07-04 | Ciba-Geigy Corporation | Triazolylacetanilide compounds and microbicidal compositions |
| US4055410A (en) * | 1976-03-15 | 1977-10-25 | E. I. Du Pont De Nemours And Company | Substituted bromo- or chloroacetamide herbicides |
| IL53938A0 (en) * | 1977-02-02 | 1978-04-30 | Bayer Ag | Novel n-substituted halogenoacetanilides, their preparation and their use as herbicides |
-
1976
- 1976-10-23 DE DE2648008A patent/DE2648008C3/de not_active Expired
-
1977
- 1977-08-12 GR GR54158A patent/GR61166B/el unknown
- 1977-09-13 FI FI772698A patent/FI64355C/fi not_active IP Right Cessation
- 1977-09-28 IL IL53014A patent/IL53014A/xx unknown
- 1977-10-03 JP JP11796777A patent/JPS5353651A/ja active Granted
- 1977-10-06 AR AR269470A patent/AR226276A1/es active
- 1977-10-06 US US05/839,777 patent/US4593104A/en not_active Expired - Lifetime
- 1977-10-12 CA CA000288583A patent/CA1240682A/en not_active Expired
- 1977-10-17 GB GB43042/77A patent/GB1588874A/en not_active Expired
- 1977-10-18 NO NO773579A patent/NO146910C/no unknown
- 1977-10-19 BR BR7706995A patent/BR7706995A/pt unknown
- 1977-10-19 SE SE7711782A patent/SE442399B/xx not_active IP Right Cessation
- 1977-10-19 CS CS776802A patent/CS194818B2/cs unknown
- 1977-10-20 CH CH1280777A patent/CH629362A5/de not_active IP Right Cessation
- 1977-10-20 UA UA2534897A patent/UA7012A1/uk unknown
- 1977-10-20 NZ NZ185482A patent/NZ185482A/xx unknown
- 1977-10-20 AU AU29890/77A patent/AU513441B2/en not_active Expired
- 1977-10-20 SU SU772534897A patent/SU670197A3/ru active
- 1977-10-20 NL NLAANVRAGE7711543,A patent/NL189279C/xx not_active IP Right Cessation
- 1977-10-20 IE IE2140/77A patent/IE46260B1/en unknown
- 1977-10-20 LU LU78353A patent/LU78353A1/xx unknown
- 1977-10-21 ZA ZA00776278A patent/ZA776278B/xx unknown
- 1977-10-21 DK DK469177A patent/DK151011C/da not_active IP Right Cessation
- 1977-10-21 IT IT51518/77A patent/IT1091110B/it active
- 1977-10-21 DD DD77201649A patent/DD133392A5/xx not_active IP Right Cessation
- 1977-10-21 PL PL1977201648A patent/PL104859B1/pl unknown
- 1977-10-21 HU HU77BA3599A patent/HU177168B/hu unknown
- 1977-10-21 AT AT755477A patent/AT356965B/de not_active IP Right Cessation
- 1977-10-21 PH PH20355A patent/PH17884A/en unknown
- 1977-10-24 BE BE182001A patent/BE860043A/xx not_active IP Right Cessation
- 1977-10-24 FR FR7731917A patent/FR2368476A1/fr active Granted
-
1978
- 1978-02-16 IN IN177/CAL/78A patent/IN149141B/en unknown
-
1981
- 1981-09-24 KE KE3162A patent/KE3162A/xx unknown
-
1982
- 1982-12-30 MY MY148/82A patent/MY8200148A/xx unknown
Also Published As
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| TA | Fee payment date (situation as of event date), data collected since 19931001 |
Effective date: 19951031 |