HUP9901352A2 - Prokatalizátorok, prokatalizátor prekurzorok és eljárás többmódusú etilén polimer előállítására - Google Patents

Prokatalizátorok, prokatalizátor prekurzorok és eljárás többmódusú etilén polimer előállítására

Info

Publication number
HUP9901352A2
HUP9901352A2 HU9901352A HUP9901352A HUP9901352A2 HU P9901352 A2 HUP9901352 A2 HU P9901352A2 HU 9901352 A HU9901352 A HU 9901352A HU P9901352 A HUP9901352 A HU P9901352A HU P9901352 A2 HUP9901352 A2 HU P9901352A2
Authority
HU
Hungary
Prior art keywords
procatalyst
heated
contact
pressure catalyst
preparation
Prior art date
Application number
HU9901352A
Other languages
English (en)
Inventor
Peter Idelmann
Solveig Johansson
Daniel Lindgren
Ulf Palmqvist
Lars Thorn
Anders Wahlström
Original Assignee
Borealis A/S
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Borealis A/S filed Critical Borealis A/S
Publication of HUP9901352A2 publication Critical patent/HUP9901352A2/hu
Publication of HUP9901352A3 publication Critical patent/HUP9901352A3/hu

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F297/00Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
    • C08F297/06Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type
    • C08F297/08Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/901Monomer polymerized in vapor state in presence of transition metal containing catalyst

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

A találmány tárgya prőkatalizátőr, prőkatalizátőr prekűrzőr és eljárásezek előállítására. Ugyancsak a találmány tárgya eljárás többmódűsúetilén hőmőpőlimer vagy kőpőlimer előállítására gázfázisúpőlimerizálással, előnyösen két lépésben. Az eljárásban alkalmazőttprőkatalizátőrt úgy állítják elő, hőgy i) a hőrdőzót, előnyösenszilíciűm-diőxidőt érintkezésbe hőzzák egy halőgénezőszerrel,előnyösen etil-alűmíniűm-diklőriddal; ii) az i) lépésben kapőtt elsőreakcióterméket érintkezésbe hőzzák egy vegyülettel vagy keverékkel,amely egy hidrőkarbil- és egy vagy több hidrőkarbil-őxi-, mőnőalkil-amidő-, dialkil-amidő-, karbőxilátő- vagy alkőxi-metőxicsőpőrtőttartalmaz magnéziűmhőz kötve; és iii) az ii) lépésben kapőtt másődikreakcióterméket (a prőkatalizátőr prekűrzőrt) érintkezésbe hőzzák egytitánvegyülettel, előnyösen TiCl4-gyel. ŕ
HU9901352A 1995-12-19 1996-12-13 Procatalyst, procatalyst precursor, and process for the preparation of a multimodal ethylene polymer HUP9901352A3 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
SE9504539A SE9504539D0 (sv) 1995-12-19 1995-12-19 Procatalyst and process for the preparation of a multimodal ethylene homopolymer and/or ethylene/ 1-olefin copolymer by gas-phase polymerisation

Publications (2)

Publication Number Publication Date
HUP9901352A2 true HUP9901352A2 (hu) 1999-08-30
HUP9901352A3 HUP9901352A3 (en) 2000-04-28

Family

ID=20400642

Family Applications (1)

Application Number Title Priority Date Filing Date
HU9901352A HUP9901352A3 (en) 1995-12-19 1996-12-13 Procatalyst, procatalyst precursor, and process for the preparation of a multimodal ethylene polymer

Country Status (16)

Country Link
US (1) US6225420B1 (hu)
EP (1) EP0869978B1 (hu)
JP (1) JP2000502143A (hu)
KR (1) KR20000064475A (hu)
AR (1) AR005144A1 (hu)
AT (1) ATE195537T1 (hu)
AU (1) AU705479B2 (hu)
BR (1) BR9612067A (hu)
CA (1) CA2240170A1 (hu)
CZ (1) CZ191498A3 (hu)
DE (1) DE69609865T2 (hu)
HU (1) HUP9901352A3 (hu)
SE (1) SE9504539D0 (hu)
TW (1) TW418216B (hu)
WO (1) WO1997022633A1 (hu)
ZA (1) ZA9610637B (hu)

Families Citing this family (33)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FI111372B (fi) 1998-04-06 2003-07-15 Borealis Polymers Oy Olefiinien polymerointiin tarkoitettu katalyyttikomponentti, sen valmistus ja käyttö
US6399531B1 (en) * 1999-12-28 2002-06-04 Union Carbide Chemicals & Plastics Technology Corporation Hybrid ziegler-natta and cycloalkadienyl catalysts for the production of polyolefins
US6444605B1 (en) * 1999-12-28 2002-09-03 Union Carbide Chemicals & Plastics Technology Corporation Mixed metal alkoxide and cycloalkadienyl catalysts for the production of polyolefins
US20010029286A1 (en) * 2000-01-12 2001-10-11 Williams Darryl Stephen Procatalysts, catalyst systems, and use in OLEFIN polymerization
ITMI20012710A1 (it) 2001-12-20 2003-06-20 Enichem Spa Catalizzatore supportato contenente titanio attivo nella omo-,co-, e ter-polimerizzazione di composti olefinicamente insaturi
TW200504093A (en) * 2003-05-12 2005-02-01 Dow Global Technologies Inc Polymer composition and process to manufacture high molecular weight-high density polyethylene and film therefrom
US7067451B1 (en) * 2004-12-17 2006-06-27 Fina Technology, Inc. Soluble magnesium complexes useful for the production of polyolefin catalysts and catalysts prepared therewith
ATE512996T1 (de) 2005-01-12 2011-07-15 Borealis Tech Oy Polyethylen für die extrusionsbeschichtung
EP1847551A1 (en) 2006-04-18 2007-10-24 Borealis Technology Oy Process for the preparation of polypropylene
DE602006004987D1 (de) 2006-07-10 2009-03-12 Borealis Tech Oy Elektrischer Isolierfilm
EP2208749B1 (en) 2006-07-10 2015-12-16 Borealis Technology Oy Biaxially oriented polypropylene films
ATE427330T1 (de) 2006-08-25 2009-04-15 Borealis Tech Oy Polypropylenschaumstoff
EP1903070B9 (en) 2006-08-25 2009-12-23 Borealis Technology Oy Blown film of polypropylene
EP1892264A1 (en) 2006-08-25 2008-02-27 Borealis Technology Oy Extrusion coated substrate
DE602006013137D1 (de) 2006-09-25 2010-05-06 Borealis Tech Oy Koaxiales Kabel
KR20090102802A (ko) * 2006-12-20 2009-09-30 바셀 폴리올레핀 이탈리아 에스.알.엘 올레핀의 중합을 위한 촉매 성분 및 이로부터 수득된 촉매
US8071499B2 (en) 2006-12-22 2011-12-06 Basell Poliolefine Italia S.R.L. Catalyst components for the polymerization of olefins and catalysts therefrom obtained
ES2322186T3 (es) 2006-12-28 2009-06-17 Borealis Technology Oy Proceso para la fabricacion de polipropileno ramificado.
EP1990353B1 (en) 2007-05-08 2009-08-05 Borealis Technology Oy Electrical insulation film
US20090048402A1 (en) * 2007-08-17 2009-02-19 Lynch Michael W Preparing multimodal polyethylene having controlled long chain branching distribution
EP2113541A1 (en) 2008-04-28 2009-11-04 Borealis AG Adhesive propylene polymer composition suitable for extrusion coating of paper substrates
EP2133389A1 (en) 2008-06-12 2009-12-16 Borealis AG Polypropylene composition
EP2251361B1 (en) * 2009-05-04 2013-10-02 Borealis AG Preparation of precipitated ZN PP catalysts with internal pore structure using nanoparticles
EP2341088B1 (en) 2009-12-30 2012-06-20 Borealis AG BOPP with homogeneous film morphology
EP2341086A1 (en) 2009-12-30 2011-07-06 Borealis AG Bopp-film
US8921466B2 (en) 2010-01-15 2014-12-30 Reliance Industries Limited Concurrent solid and melt state grafting of coagents for making long chain branched polypropylene via direct reactive extrusion process
EP2418237A1 (en) 2010-08-12 2012-02-15 Borealis AG Easy tear polypropylene film without notch
EP2603548A1 (en) 2010-08-12 2013-06-19 Borealis AG Easy tear polypropylene film without notch
EP2520425B1 (en) 2011-05-02 2017-11-08 Borealis AG Polypropylene for foam and polypropylene foam
US9163098B2 (en) 2014-01-10 2015-10-20 Chevron Phillips Chemical Company Lp Processes for preparing metallocene-based catalyst systems
EP3303424B1 (en) * 2015-05-28 2020-03-11 SABIC Global Technologies B.V. Multimodal high density polyethylene
CN107849178B (zh) * 2015-07-16 2020-11-10 Sabic环球技术有限责任公司 双峰高密度聚乙烯
CN115710349B (zh) * 2022-03-23 2024-02-20 聚碳氧联新材料科技(无锡)有限公司 一种脂肪-芳香族共聚酯及其应用

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2312511A1 (fr) * 1975-05-27 1976-12-24 Naphtachimie Sa Polymerisation a sec des olefines dans des reacteurs en serie
US5047468A (en) 1988-11-16 1991-09-10 Union Carbide Chemicals And Plastics Technology Corporation Process for the in situ blending of polymers
ES2145357T3 (es) 1991-03-06 2000-07-01 Mobil Oil Corp Polimeros de etileno bimodales producidos en reactores en tandem.
EP0533452A1 (en) * 1991-03-21 1993-03-24 Mobil Oil Corporation Production of bimodal ethylene polymers in tandem reactors
DE69232109T2 (de) * 1991-07-24 2002-03-14 Mobil Oil Corp., Fairfax Verbesserte Polyethylenharze für Filme
US5332706A (en) * 1992-12-28 1994-07-26 Mobil Oil Corporation Process and a catalyst for preventing reactor fouling
FI96866C (fi) * 1993-11-05 1996-09-10 Borealis As Tuettu olefiinipolymerointikatalyytti, sen valmistus ja käyttö

Also Published As

Publication number Publication date
TW418216B (en) 2001-01-11
CZ191498A3 (cs) 1998-10-14
AR005144A1 (es) 1999-04-14
US6225420B1 (en) 2001-05-01
ZA9610637B (en) 1997-06-24
DE69609865T2 (de) 2001-01-04
AU705479B2 (en) 1999-05-20
WO1997022633A1 (en) 1997-06-26
JP2000502143A (ja) 2000-02-22
EP0869978B1 (en) 2000-08-16
EP0869978A1 (en) 1998-10-14
AU1216697A (en) 1997-07-14
BR9612067A (pt) 1999-02-17
ATE195537T1 (de) 2000-09-15
SE9504539D0 (sv) 1995-12-19
HUP9901352A3 (en) 2000-04-28
DE69609865D1 (de) 2000-09-21
KR20000064475A (ko) 2000-11-06
CA2240170A1 (en) 1997-06-26

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