HUP9901352A2 - Prokatalizátorok, prokatalizátor prekurzorok és eljárás többmódusú etilén polimer előállítására - Google Patents
Prokatalizátorok, prokatalizátor prekurzorok és eljárás többmódusú etilén polimer előállításáraInfo
- Publication number
- HUP9901352A2 HUP9901352A2 HU9901352A HUP9901352A HUP9901352A2 HU P9901352 A2 HUP9901352 A2 HU P9901352A2 HU 9901352 A HU9901352 A HU 9901352A HU P9901352 A HUP9901352 A HU P9901352A HU P9901352 A2 HUP9901352 A2 HU P9901352A2
- Authority
- HU
- Hungary
- Prior art keywords
- procatalyst
- heated
- contact
- pressure catalyst
- preparation
- Prior art date
Links
- 238000000034 method Methods 0.000 title abstract 4
- 229920000573 polyethylene Polymers 0.000 title 1
- 239000002243 precursor Substances 0.000 title 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 2
- 239000012018 catalyst precursor Substances 0.000 abstract 2
- 239000007795 chemical reaction product Substances 0.000 abstract 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 abstract 1
- 239000005977 Ethylene Substances 0.000 abstract 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical group [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 abstract 1
- 229910003074 TiCl4 Inorganic materials 0.000 abstract 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- UAIZDWNSWGTKFZ-UHFFFAOYSA-L ethylaluminum(2+);dichloride Chemical compound CC[Al](Cl)Cl UAIZDWNSWGTKFZ-UHFFFAOYSA-L 0.000 abstract 1
- 238000012685 gas phase polymerization Methods 0.000 abstract 1
- 125000001183 hydrocarbyl group Chemical group 0.000 abstract 1
- 229910052749 magnesium Inorganic materials 0.000 abstract 1
- 239000011777 magnesium Substances 0.000 abstract 1
- -1 methoxy-methoxy groups Chemical group 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 239000007800 oxidant agent Substances 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 abstract 1
- 239000012041 precatalyst Substances 0.000 abstract 1
- 238000010517 secondary reaction Methods 0.000 abstract 1
- 235000012239 silicon dioxide Nutrition 0.000 abstract 1
- 239000000377 silicon dioxide Substances 0.000 abstract 1
- 239000004575 stone Substances 0.000 abstract 1
- 229920001187 thermosetting polymer Polymers 0.000 abstract 1
- 239000004634 thermosetting polymer Substances 0.000 abstract 1
- 150000003609 titanium compounds Chemical class 0.000 abstract 1
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
- C08F297/06—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type
- C08F297/08—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/901—Monomer polymerized in vapor state in presence of transition metal containing catalyst
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
A találmány tárgya prőkatalizátőr, prőkatalizátőr prekűrzőr és eljárásezek előállítására. Ugyancsak a találmány tárgya eljárás többmódűsúetilén hőmőpőlimer vagy kőpőlimer előállítására gázfázisúpőlimerizálással, előnyösen két lépésben. Az eljárásban alkalmazőttprőkatalizátőrt úgy állítják elő, hőgy i) a hőrdőzót, előnyösenszilíciűm-diőxidőt érintkezésbe hőzzák egy halőgénezőszerrel,előnyösen etil-alűmíniűm-diklőriddal; ii) az i) lépésben kapőtt elsőreakcióterméket érintkezésbe hőzzák egy vegyülettel vagy keverékkel,amely egy hidrőkarbil- és egy vagy több hidrőkarbil-őxi-, mőnőalkil-amidő-, dialkil-amidő-, karbőxilátő- vagy alkőxi-metőxicsőpőrtőttartalmaz magnéziűmhőz kötve; és iii) az ii) lépésben kapőtt másődikreakcióterméket (a prőkatalizátőr prekűrzőrt) érintkezésbe hőzzák egytitánvegyülettel, előnyösen TiCl4-gyel. ŕ
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
SE9504539A SE9504539D0 (sv) | 1995-12-19 | 1995-12-19 | Procatalyst and process for the preparation of a multimodal ethylene homopolymer and/or ethylene/ 1-olefin copolymer by gas-phase polymerisation |
Publications (2)
Publication Number | Publication Date |
---|---|
HUP9901352A2 true HUP9901352A2 (hu) | 1999-08-30 |
HUP9901352A3 HUP9901352A3 (en) | 2000-04-28 |
Family
ID=20400642
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
HU9901352A HUP9901352A3 (en) | 1995-12-19 | 1996-12-13 | Procatalyst, procatalyst precursor, and process for the preparation of a multimodal ethylene polymer |
Country Status (16)
Country | Link |
---|---|
US (1) | US6225420B1 (hu) |
EP (1) | EP0869978B1 (hu) |
JP (1) | JP2000502143A (hu) |
KR (1) | KR20000064475A (hu) |
AR (1) | AR005144A1 (hu) |
AT (1) | ATE195537T1 (hu) |
AU (1) | AU705479B2 (hu) |
BR (1) | BR9612067A (hu) |
CA (1) | CA2240170A1 (hu) |
CZ (1) | CZ191498A3 (hu) |
DE (1) | DE69609865T2 (hu) |
HU (1) | HUP9901352A3 (hu) |
SE (1) | SE9504539D0 (hu) |
TW (1) | TW418216B (hu) |
WO (1) | WO1997022633A1 (hu) |
ZA (1) | ZA9610637B (hu) |
Families Citing this family (33)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FI111372B (fi) | 1998-04-06 | 2003-07-15 | Borealis Polymers Oy | Olefiinien polymerointiin tarkoitettu katalyyttikomponentti, sen valmistus ja käyttö |
US6399531B1 (en) * | 1999-12-28 | 2002-06-04 | Union Carbide Chemicals & Plastics Technology Corporation | Hybrid ziegler-natta and cycloalkadienyl catalysts for the production of polyolefins |
US6444605B1 (en) * | 1999-12-28 | 2002-09-03 | Union Carbide Chemicals & Plastics Technology Corporation | Mixed metal alkoxide and cycloalkadienyl catalysts for the production of polyolefins |
US20010029286A1 (en) * | 2000-01-12 | 2001-10-11 | Williams Darryl Stephen | Procatalysts, catalyst systems, and use in OLEFIN polymerization |
ITMI20012710A1 (it) | 2001-12-20 | 2003-06-20 | Enichem Spa | Catalizzatore supportato contenente titanio attivo nella omo-,co-, e ter-polimerizzazione di composti olefinicamente insaturi |
TW200504093A (en) * | 2003-05-12 | 2005-02-01 | Dow Global Technologies Inc | Polymer composition and process to manufacture high molecular weight-high density polyethylene and film therefrom |
US7067451B1 (en) * | 2004-12-17 | 2006-06-27 | Fina Technology, Inc. | Soluble magnesium complexes useful for the production of polyolefin catalysts and catalysts prepared therewith |
ATE512996T1 (de) | 2005-01-12 | 2011-07-15 | Borealis Tech Oy | Polyethylen für die extrusionsbeschichtung |
EP1847551A1 (en) | 2006-04-18 | 2007-10-24 | Borealis Technology Oy | Process for the preparation of polypropylene |
DE602006004987D1 (de) | 2006-07-10 | 2009-03-12 | Borealis Tech Oy | Elektrischer Isolierfilm |
EP2208749B1 (en) | 2006-07-10 | 2015-12-16 | Borealis Technology Oy | Biaxially oriented polypropylene films |
ATE427330T1 (de) | 2006-08-25 | 2009-04-15 | Borealis Tech Oy | Polypropylenschaumstoff |
EP1903070B9 (en) | 2006-08-25 | 2009-12-23 | Borealis Technology Oy | Blown film of polypropylene |
EP1892264A1 (en) | 2006-08-25 | 2008-02-27 | Borealis Technology Oy | Extrusion coated substrate |
DE602006013137D1 (de) | 2006-09-25 | 2010-05-06 | Borealis Tech Oy | Koaxiales Kabel |
KR20090102802A (ko) * | 2006-12-20 | 2009-09-30 | 바셀 폴리올레핀 이탈리아 에스.알.엘 | 올레핀의 중합을 위한 촉매 성분 및 이로부터 수득된 촉매 |
US8071499B2 (en) | 2006-12-22 | 2011-12-06 | Basell Poliolefine Italia S.R.L. | Catalyst components for the polymerization of olefins and catalysts therefrom obtained |
ES2322186T3 (es) | 2006-12-28 | 2009-06-17 | Borealis Technology Oy | Proceso para la fabricacion de polipropileno ramificado. |
EP1990353B1 (en) | 2007-05-08 | 2009-08-05 | Borealis Technology Oy | Electrical insulation film |
US20090048402A1 (en) * | 2007-08-17 | 2009-02-19 | Lynch Michael W | Preparing multimodal polyethylene having controlled long chain branching distribution |
EP2113541A1 (en) | 2008-04-28 | 2009-11-04 | Borealis AG | Adhesive propylene polymer composition suitable for extrusion coating of paper substrates |
EP2133389A1 (en) | 2008-06-12 | 2009-12-16 | Borealis AG | Polypropylene composition |
EP2251361B1 (en) * | 2009-05-04 | 2013-10-02 | Borealis AG | Preparation of precipitated ZN PP catalysts with internal pore structure using nanoparticles |
EP2341088B1 (en) | 2009-12-30 | 2012-06-20 | Borealis AG | BOPP with homogeneous film morphology |
EP2341086A1 (en) | 2009-12-30 | 2011-07-06 | Borealis AG | Bopp-film |
US8921466B2 (en) | 2010-01-15 | 2014-12-30 | Reliance Industries Limited | Concurrent solid and melt state grafting of coagents for making long chain branched polypropylene via direct reactive extrusion process |
EP2418237A1 (en) | 2010-08-12 | 2012-02-15 | Borealis AG | Easy tear polypropylene film without notch |
EP2603548A1 (en) | 2010-08-12 | 2013-06-19 | Borealis AG | Easy tear polypropylene film without notch |
EP2520425B1 (en) | 2011-05-02 | 2017-11-08 | Borealis AG | Polypropylene for foam and polypropylene foam |
US9163098B2 (en) | 2014-01-10 | 2015-10-20 | Chevron Phillips Chemical Company Lp | Processes for preparing metallocene-based catalyst systems |
EP3303424B1 (en) * | 2015-05-28 | 2020-03-11 | SABIC Global Technologies B.V. | Multimodal high density polyethylene |
CN107849178B (zh) * | 2015-07-16 | 2020-11-10 | Sabic环球技术有限责任公司 | 双峰高密度聚乙烯 |
CN115710349B (zh) * | 2022-03-23 | 2024-02-20 | 聚碳氧联新材料科技(无锡)有限公司 | 一种脂肪-芳香族共聚酯及其应用 |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2312511A1 (fr) * | 1975-05-27 | 1976-12-24 | Naphtachimie Sa | Polymerisation a sec des olefines dans des reacteurs en serie |
US5047468A (en) | 1988-11-16 | 1991-09-10 | Union Carbide Chemicals And Plastics Technology Corporation | Process for the in situ blending of polymers |
ES2145357T3 (es) | 1991-03-06 | 2000-07-01 | Mobil Oil Corp | Polimeros de etileno bimodales producidos en reactores en tandem. |
EP0533452A1 (en) * | 1991-03-21 | 1993-03-24 | Mobil Oil Corporation | Production of bimodal ethylene polymers in tandem reactors |
DE69232109T2 (de) * | 1991-07-24 | 2002-03-14 | Mobil Oil Corp., Fairfax | Verbesserte Polyethylenharze für Filme |
US5332706A (en) * | 1992-12-28 | 1994-07-26 | Mobil Oil Corporation | Process and a catalyst for preventing reactor fouling |
FI96866C (fi) * | 1993-11-05 | 1996-09-10 | Borealis As | Tuettu olefiinipolymerointikatalyytti, sen valmistus ja käyttö |
-
1995
- 1995-12-19 SE SE9504539A patent/SE9504539D0/xx unknown
-
1996
- 1996-12-13 DE DE69609865T patent/DE69609865T2/de not_active Expired - Fee Related
- 1996-12-13 HU HU9901352A patent/HUP9901352A3/hu unknown
- 1996-12-13 BR BR9612067A patent/BR9612067A/pt not_active Application Discontinuation
- 1996-12-13 KR KR1019980704658A patent/KR20000064475A/ko not_active Application Discontinuation
- 1996-12-13 AU AU12166/97A patent/AU705479B2/en not_active Ceased
- 1996-12-13 CA CA002240170A patent/CA2240170A1/en not_active Abandoned
- 1996-12-13 CZ CZ981914A patent/CZ191498A3/cs unknown
- 1996-12-13 AT AT96943431T patent/ATE195537T1/de not_active IP Right Cessation
- 1996-12-13 JP JP09522704A patent/JP2000502143A/ja active Pending
- 1996-12-13 WO PCT/SE1996/001652 patent/WO1997022633A1/en not_active Application Discontinuation
- 1996-12-13 EP EP96943431A patent/EP0869978B1/en not_active Expired - Lifetime
- 1996-12-18 TW TW085115640A patent/TW418216B/zh not_active IP Right Cessation
- 1996-12-18 ZA ZA9610637A patent/ZA9610637B/xx unknown
- 1996-12-19 AR ARP960105771A patent/AR005144A1/es unknown
-
1998
- 1998-06-09 US US09/093,765 patent/US6225420B1/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
TW418216B (en) | 2001-01-11 |
CZ191498A3 (cs) | 1998-10-14 |
AR005144A1 (es) | 1999-04-14 |
US6225420B1 (en) | 2001-05-01 |
ZA9610637B (en) | 1997-06-24 |
DE69609865T2 (de) | 2001-01-04 |
AU705479B2 (en) | 1999-05-20 |
WO1997022633A1 (en) | 1997-06-26 |
JP2000502143A (ja) | 2000-02-22 |
EP0869978B1 (en) | 2000-08-16 |
EP0869978A1 (en) | 1998-10-14 |
AU1216697A (en) | 1997-07-14 |
BR9612067A (pt) | 1999-02-17 |
ATE195537T1 (de) | 2000-09-15 |
SE9504539D0 (sv) | 1995-12-19 |
HUP9901352A3 (en) | 2000-04-28 |
DE69609865D1 (de) | 2000-09-21 |
KR20000064475A (ko) | 2000-11-06 |
CA2240170A1 (en) | 1997-06-26 |
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