HUE034237T2 - Alap, amely el van látva megfelelõ hõtani tulajdonságokkal bíró prizmával, elsõsorban hevített üveg gyártásához - Google Patents

Description

$U!ÜRÂÎ1 PROVIDED WITH PRDfOTfö M PARTICULAR FDR

FRÖ0UDI1DH M «TED DiMND IMT ümmmm

Tim Wimm r^m iö Än§paf^:su^ts/8^i&%:m^#fsuch as glass, seid äubätosts htortg coaWd with a thto-iüm multilayer comprises a plurality of functional films ihat can act on solar Nation arsd/or infrared radrtomn si hong wavelength,

Thö -Tsor© partieuishy relates: to a substrate, ©specially a transpsrgqt glass substrate, equipped vhth a vm&tto :wpiii| ·* iteration, ’ntometefite 1unsteg{8®rns, aspadgily tonclienal D®s based eft silver or a metal espy cpntsihtog sitvsp sad hin©/ antlreliecfa coatings, where m is as integer ä 3, sa that ascto funPiiorsal ΤΙΙϊώ is iecatem besten two sniirefieeiibft odatlngs, Seen coaling: comprises at least bhe:isnfirsileciisn:: ? lisp and: each costing pr«teraby eensssfeset & plurality st lltos stoeaslbadilliny er even .eaetoifn, οί which is Id abfirefteotlönlrm

Tbe toveritton ?sleies toáia pantoulsdy ío is Use of st/eh substrates io? manufacturing Ihew# Insulátiaháhd/ofsoisr protection ds|:i?ig urtls. Thseé $Sűɧ; uhlfs-máy'bitohtehded bath tot equipping buildings and lor equipping vehicles, espemaky mn mz purpdss of rsducihg airmshbtoontoq: load mêffî pfeversilng overheating testied "sotar condor' gia^ng) andio? reducing?·*# amount of energy dissipated to too outside (called low#· or Row-emiasivity" glaeihgt brought about by the ever increasing usé ptgtoyedsurfepas irt buiidlnpiand in vehicle passenger ccnmerimehlto

Inaso : substrates: may In paieuiar bs Incerpofiad in eiepttonib: doviees and the multilayer may inon serve as an electrode m order íö sófiiiuci ©ürrprlf display device, photovoltaic panel, electrochromio gls&ng uroh etc.) or they may be i=xorpo?atoö to gtatong units having a particular purpose such as, tor example, boated giadng units, and to prticuief heated vehicle «shields, yyphio toe context Of the present invention. a multilayer comprising s plurality of iunciiona! films is understood to mean a hlÍliípT:^P®^i-^a5l8*f08 ^nettónál films.

Film multilayers comprising a plurality of functional «ms ate to)p>yn: in this; type Of rgpfayer, each: tunotionai film is toctoeb between two sntifefl&amp;ciion coatings each in ggnerafcomprising: rtpluratify öhantlreíleotfen Dmsithaf are;each rnsdeçf tonifride and especially of silicon or aluminum nitride sndfOf of ton okidé. torom1 the npttoai point of vieto, dhe aim Of these ooafingS: that fisak the functional film is to make this functional film ‘tontptlsofive' These antirofeotlon Dme m -dfeMlric films’, to contrast with the metallic land tnemfore conduohye) nature € fhe functional ims< •!OAevr a v$ry thin h!o#ef layer is sometimes Interposed between one or each antirelieotion costing and sn pdjspeitf toncfionál: film:; a blocker layer located under the function# film, in the substrate direction, and/or a blocker layer located óh the functional flipp Opposite ifroito the substrata, protect this film item damage kabie to occur during deposition of the subsequent anttrefieOtion coat ng c, dur mi any nigh-tempersiens heat treatments carried out such as Pending and/or tempering heat treatments.

These blocker layers ate not mart of hte anarefiselos?: coatings because irr general They ate por tekert into epusidefaiigrt when rtefiiibg the pplpai properties of i® tM|iiay®r, aitototownferttehu pdprert. f ©05/051858 in the multilayers comprising Ihres or tour iunciiona! films presented sn that document, the antiretleciion 81ms ussd am customplycpnslderedi lebe whgteffcaiidd: toiadiunvOrbfîactlvedfîdfex fiilms^im. having a retractive indsxrthat is neithertoigh m: ICW: :;S«Siííit iSpéiiibâfiy, te itosÄ «silàpil nmto mma- «Motors<rÂx«Hi#ψ.Μ% fei %!Â#-réte8yè>î8â®x.ints te Ü # teifacttes ihÄ#; between * 1:JO and « a·. ·» an« îo· $φ mirsciivednaex Pirns te Ä tMÄMÄ 2,1 S or mss®. F.wlÄmMteà Ptet'iî dsfeofes teoaii refractive ί»Λ meat ai à: §*β mw&amp;tqÿn »át^a*pls. the imaginary part öf fee sx-íractiva teds* as a given wavelength mmmm trn'h the Ai®* »u^#is ssds esteteteery; lói thé saked simplicity fee ?#aáis#:fegleas are given te twodec-mál: places »tout naateg.5 u»; extinction caafegiMts k m ÉS|ií»fe»»*P of 55δ m f (appears feat feaicboifeuiwilon: of feeelfempies m applicahon fefö 200:5/051 Ä:fe entirety safedactery.

Far s hamber of epgiiesiibns I; is: desired for tee vgld äIÄ of the feuitifaysr (and mesetere of m glszmg: unm teeofporating fee rnuliilsyer} te be higher #ie fee sheet resistance of fee mdlhteyer iskent Ä ancmr ter fee ·$Μ Áiote fee mutipyer (arte therefore: of fee giazing unit ineerporabng M ^ tfMim&amp;M resisiáriestei fee mpiiayer is Kept tow and/or ter fee rteior In releribn to be less otenosnsepi wife valses measured ter example in see tab system: feat are olosgr fe mo, mm fee to* &amp; tew: sheet tesistenes: is mmtmmm of 1 0/a or less.

The prior art also comprises European patent application £fJ/2 Q30 914¾ 'to. aflfeÄte Ä$· miled "dielectric abssrttefe filmte which are ifeOte mpreover feeyfraP sbsorsem, is located under fee first meteillc functional |m. starting from fee substate, oi a muitilapr Uprising: ai least tee meialiic fenchoneilms, and fee other miaetric absorb#’film is: located on fee fest metaiite fenotteaai feet starting item tee substrat», of eted multilayer.

The dielectric ebsorbeef films of feat doounreht have a npn-'negligteie absorption goafmaeru k of at teast ö<á.

The dlslectnc absorbent films of feat document are : thus vguaiiiied ps: being: feletecfete sg as re aitew: teem te bo u>teingusahed tom: tee motsilio fenoftersaii iiimS: which. also absorb io ». certain degree. By way pr tetemtefeit fee coefficient a si a^hfeom which trie metallic functional iiims are made. Is about 3 34 at: 558 am, furthermore, teantraiT absorption: in fast corrseponss to balanced: absorption in the visibte wavetengfe: rapgpi wife to® ratio oi fee Efficient; k at short wavelengths pO <·ι·Λ «4S0 nrn): te tee visible to. fee coefficient fc at teng wavelengths f SO < k* W mn the vîstbte beirig beiarrcsdi i.e, about 1 and more precisely lying hafweandJE and 1 .§ I'hs aim of^ fee solution ef feat document is te increase fee-capacity of fee multilayer to absorb: soisr radiation :pn pattice^i fe· fe« infeetedf while teeing offcolor qaalified in feat document as 'feleasanf. by using neutral absorbent films and: by pnetfeteg said iiims in a particular way in tee multilayer.

The necessary consequence of fers solution is fem the rnuftilayer oanem: neve a high ignl: transmission m to§:-yisti#··^^^ >0$ dlsfectric absorbent films absorb not: orsiy ih the fehared: wavelength; rarsge; cm aiso, tora non-negiigtbte way, rn waveierspi range, figures 7 arte: 8 of Européen paient application EP 2 83(1» show, respecllvety, fee sxiiMise osetedent i?: and: the tefepotsve in'áá*:#-:#iMí.slltoon«fllaniuinrnifedecompoands, on#pmpd^-4Â-iriN.aas.»a^.sàfec^aÂi»id':ife»:0>ît«f· >·: ^ ^,Λ· and 28te:sIcon: nitride.

The coefedient kof TIN at §50 nnnis ebout IMand fee,csafecienf k si SiaNi at SSu nrn ss about 0 013$. itegiv-ffei %·-showsifeat fee h values tor tee, two compounds am between: these, two, values, teoresver, figure: / shews featfee k vafe'-e fep two compounds are relatively high: inserting SIÄ at JSfF end §5% isto liN feererore has Utile etteevon fee eoafeesente· -^v The refrediveIndex n ofoiN at 550 ran:is about Oferiand: the refractive index of SbNx at u5u nm::s about χ us wcu..* be expected: for the retractive: indices: of cempaunds censisting of a mixture or tnese rwo msienais ro iw deiWsd1 ^l·’ väögäiitaW: completely u naxpecisdiy; : % indicates il# : rëiâÂsndex of Mmr>pwwi*mm· mmt. sighs? mm between M anÄ Äsl/isiÄtsitoÄW. HurtÄö^.« regardé sößVMitfmfef'Sfite gMKfentforpt ay.Ä.:-shown in figure <^p$eteáiter figure 6 to s»Miire refractiveIndices átm.im. compounds to be iewmndbamiy affected % the teioftof'SiÄ at^t^Äg figure 8: ém\ nmre inconsistent, ta feet, 8:öompo«n£l:®ns;stihg of à mixture o? sllmon nitride arid ^fàrdtim :nitri# :neoessariiÿshas a fetradtiw iadfexl^aa batwgsa: the refractive index of Shhk and that of liN,

Priorért knows moreover from tue intemanonai p^rït;^ôiï^^®î:iH^ ü^ö·· with a plurality Of funcifonsvi layers comprising moreover layers in high mdex dtieciric material.

The aim of the invenÉaiÉ to provide a aiultileysr vyhirntSes a very iow sheef reMtahoein order, in particular, for the giaxiog unit incorporating this multilayer fes be sole to exhibit high energy reflectionmäiot· very m em-sstvity sndfer to he abiet? bë: heaisb by applying a current between two busbars electrically connected to the multilayer. and a high light transmission aod s relatively neffral: sólor, in parffeuipr when laminated; and for these properties to be prefersiy obtained ÄÜ (or mere) high* temperature oendsng and/or tempering and/or annealing heat treatmenpl: or indeed for is be obtained: betöre one or oiore high-temperature bending 3nd/or tempering and/or annealing heat treatments, and for these properties to he maintained within a limited fapp:s^#tfW:Ä i§ miispr$f rmréW- Sdif lheat treatmerdfef;: Theripi transmission p^MIbcd^f m> of csürse, ire fight tsipsmispfi and light Paction in the visible wavelength range,

One subject: ef the invention, In its widest sense, is thus a transparent gisse substrate, as claimed in ólaim 1. The dependent sisims define advastpeoueembodlmontsp^

The substrate: according to the invente Is thus pguipped with a; fin>im muflayer comptÄg;,· Iß: Äpfe. funoiionfaf films, in particular fungssnarfilms pasedpn sífw»a'«§tsí#öy:^Ml|R8 silver, where n is an Integer > 3, each antfreftection coating comprising at least one antlrefieotloo film, se that each functional tiim Is located: between : two antlmtiectlon costings f he present Invention Is in partrealar suitable for muff avers comprising n ~ 3 or n -4 fimctionsl fiims.

This substrate Is noteworthy in that said mufhiayer comprises at least tws:hfgh*retractivedndes antirefiectidn films: each having a rofractive Index >. 2.15. such that the snhrehsctiom costing located under the t-rst. starting from fhe substrate, hrnctionaf him and fee aohreflecttoo eoating: locafed an »re last starting; from lire substrate, functional 1m each comprise af least one high-reactive-index aotirsfiMlon him aadeaeh shttreilsetion coating located between two functional films does not comprise shigh-refractive-lndex im the. each antirefleelluh easting located between two functional lists comprises m hiih-refracfivedopex anbreffect-on flirn having a refractive -odex ä 2.15)

By its very nature, in the technical held ol the invention. an arrtireflecflon him cannot be art absorbent film because customarily tlte term ‘'ant-refieohorf denotes a nonabsorbenf film.

High-reiractive-lndex films according to the invsnftenrcan in ihfsirsspssf be .paiiHaf as. transparent films since they are non-absorbent; fhey each have amsgitf b!e absorption cosiciehI k below iTil. 4 >%%*. the higb-refractlve-index ims according its :flm Invention de M «xhi fasafef· :Λδ©φ®>8|. 'Ésf dehmsl exhibit baisnsed; absorption in ihe visible wavelength range, with The : ratio of the ooeffeient k at short wavelengths: í|8Öi d λ <MB nmf in the visible to the coeiheient k at long weveisngihs:|SSS €%.< rSSmm) in the visible being baianend, f,e;. about t, .and more precisely lying between ;pt and; 1.9., beesuse this ratio only has meaning;for nonmeglfgibteT values.

These ihlgh-refractive-lndex: films acbordlng to the Invention could siss be sailed llgb-reirasfivmindex dielestnc afitire^s^iisrî fiimsTtoeorifrasfivviihfhg metallic (anditherefore conduefivst natum rálhefenchopafllms. 1¼ antirefiecfioo coating located undor {he fest, starting tern lhe substrats·. funatorsai Him preismbif «lets, ín til Ψ$$> starting írom the pjptrafe. of one or more nigh<rsifæti*«4bdex antlreftoip ferns and fhars a sriedium-re^arivfelohes:: wetting antirefseetion fern having a refractwe index of between 160 and 2.15, excluding fease: values, wild bassdibhm crystalline oxide, MpacbKy based on sine oxide, optionally doped with at leas!: one other aiemptsuch as aluminum.

In. a particular variant the antireflection costing toted, on: the fast starting from the substrate, functions] film oobfefefepiqbsiy of one or mors hsgh -?îî f {-«oil var I r i déx an ti let tSi^f io?ï f ^ f : U therefore doss not comprise a medium- or iow-refractive'index him. Preferably at teast one, even each, hlgmraSmctive'fedsx anörefiafeíon lm Is based ou álicoa ^ifoersom niínde: Another gossihlg rhetsrlai tho high^acive^dex snilrofiecSon Aim may be diesen from: tPO (rehscfivs index of 2.IS at 550 nm}< WCb (refractive index of 2,15 si 650 nrn). Ibd3s:|raffac?ive index of 2.3 at 55ΰ nm), EfeOs (refractive index of 2.6 at 550 urn) and Zell (refractive index of 2.55 si §50 nm). it is Inown that thin bigh^^ctiveabdax ®ms have at most arsfractive index of 5.1 of 556 f» Each high-relfectivenndex ahtirefiecfion film according to the invention preferably has a refractive index of 2.6 er less er even 2.3 or less.

When a bigh-refraeSve-úndex int fessed m. sicoh ziftoiuro nitride is chosen, fee proportion ef: sinon: rwiatlve tofercomumis pseiefabiy bmm 40 and; §ÔI Si for 25 is ASliZr. m, dmm,. a tdfei. by weigh?.: in the fetget of m% so as to obtain the desirodiigh: fsirptlmlbdax: it pgpfiite^ Äfe § high labove dbi if weight inihe target), u w possfeie to use enether aiernenf. .sup as fed example Ai, to increase the eonducfivny of the terget. in this case, to Obtain the dosirad refractive index; ibis prfeeraois far fee eipmpfs Si, Zr and Ai to he present in a proportion by weight infee target in me foilowmg ranges, respectively:: - for SI: between 45% arid ?5%, including these values; - lor Zi between 20% and 50%. including these values; And * fer At: between i% and 15%, including these values; with, oi course, a total, by weight, in the target, of 100%. yereover, when fee one or more antifefiecion costini are one or Mrs nitride ferns, fee nntireleetion ooating located m fee lest, starting Pom the so as to make manufacturing the multilayer easier. yereover, at fees? one, even hot based Wz or ‘ΠΟ,·. fe a variant, the thickness e.,of each fundflenailifhnfthe multilayer (i.e. at least functional films In row 2 and fow fe starting ffem fee substrate) is smaller than the thickness of fee preceding fencfonai film, in fee direction of fee substrate, andlswueh tifet: et ® ,w e>.i, where; x Is the row, starting from: fee eudstfsfe, of fee functional film, x-1 is fee row. in the direction of the substrate., sf the. preceding functional film, and a is 8 feghfeef such the; 0.5 < a <· 1, and preferably 0 55 < a < G.95, or 0.6 < a < 0.35. in gncther venant, the thickness e* of each functional fern of the multilayer <;i e. si least functional ferns in mw 2 and few? 3. starting from the substrate) Is idenfcai to this thickness of the preceding functional film, in the direction of the substrate, and is such feat: e> ~ a e>-i, where: x is the row, starting from the substrate, of fee functional film;, x-·] ss the row, in the direction of the substrate, of the preceding functional fern; and a is a number such that 0.35 < a <' 1.15, and preferably 0.90 < a % 1:1, or 0.95 < ix < 1.05

The term "row': is, fe the present jiventiori understood to mean the integer number, starting: from the substrate, of east? feftcSonaifem' the fenctiohal film clops! fhô sühstrste is the functional fern of row:1). ifeviliwin|llfe·. on movlhiiferthsrawsy from hie substrate, is that of row % etc. file feir&amp;nass ;o? the fest, sferkng: tet fee seostrate, mstsifc functional film fis. ihat of row: 1): isfücb'ifesl lô &amp; ers, 18'M'Éft 3i-d preferably il «:®r * 1§ th«m.

Tife;whM δ,55 s< <ί s Oft the th'kjlßps of Ihs Urst, starling fmm asilsir#. mataiite fpdionsi im is such fei: ίδ sí ον« s I in nm pd greftebiy 11 &amp; ® -> iS fe um and: whop 0¾ s si 0,95, the feloimoss of fee tel Sfartfeis tom; fee substrate, ;iiuß#psi (stetesurfefet: 10 « IS in nrn arte pMHy 11 s? et« 15 in mn. |{ is morasven poesibfe fer M &amp; 0,9 and for fe of % first, §tgrfiag from the substrat«, mpfeliie itestisneS 51¾ îo ba ,m&amp; thai; 10 « t» «Änd preferably 11 « a « 15 mim.. m'M®M « « %M and tor fei thtehnoss ói: fe feli starting fen (he m^m,rostaiiic iuoohonai mio bs such:iSati 10 .temfte II írn om andpreferably 11 si **13 io nra. feorao^rrfeeopse P essential aim bf the invention; is: b provide a ntelayerihsvlng« lowshaet resistasfce,the total (hleknosS olfes mefetöp fenclionsfifes is, especially whan fi W·^ s is in am, pröíarabiy grsaior tbaoSO no; and ospooialiyiies Ootisson t| and 00 am, including those csinos, or ilfsMsi tbictínass (las böiwsah SS andífíönm (sr a feinte moliapr «mphsífm three iaoclfenal films. or (his totalthickness lies isstweeo: 40 and 60 nm fer fms, ^?S&amp;Sy>:Í8' value of et is at Sepsl0,92,e?en by at lasst 0,05} lor sitps (Ohctlpai ioss of ms? 2 or mom of (he ioslilfeyar fevfelch the formula e, ~ a eu is applied ill? Important ίο noie here that: theteecrease in me distribution of (he thicknesses is not 3 decrease in (he dtetribufion oi all the Sims of iim molteyo? (íakiog into account (he aniireifeoilon films), but only· 9 decrease in the distribution of the thicknesses of the fenotiensi 5ims, inside the multilayer comprising functions! films ót decreasing thickness, starting horn the substrate, alt (he tenctionsi (time have different thidmesses; however, the disiriteion in the feiakness of the ÂÉMÂS Insde the oioifisyer (hen allows, in a completely unexpected way, â ïMêt sheet resistance: iofee obtained »?r•psfedle fhâî achieves fer fee corfeguration comprising functional elms W constant feiokness or comprising1 fehelioteÄ starting fesmfea tetefete,:

Uhfess dihePise specified, the thicknesses; given i;t *y (p^nt^SÄpt m f®$ thidpessp (end nm optical feicknasses}

Steeaver, when iÄ is made of (ho vsiioairnasSoh of a film (e g. ofeender}, fee scaring substrate is always taken fe P positioned hositehidly, ai the bottom, with the multilayer on te, When (( ts speoiee thPm firn 0. deposited directly on Pofeh ihls feeaP that feerelsiafé} no other fimfet intermediate between Jiese fwo (ins. The row of fee hmohonai asms is here: mtäß :dofineS stahii^ teifi the edhsirate hearing fee multilayer (substreie on the tap e( Wiidh the muillayer is deposited}!: pÄrshjy lip between 8 pdÄnrn. irieludihg (hepyaSpes, oven petwsen 10 mê 13: nm, feeidding these vgfees. and more preferably leapen 11 end 15 nm, ineiodvig feosa vslues.

Too total thickness of hie metallic functiona! films is preferably greater ihass SO nm and especially ties between SO and 00 nm, Insleding these values, or (his total tblckrress lies between 35 ami 59 nm tor 3 thln-liim nuiiiaayer composing shree tuhctional ims, or (his total thickness lies between 40 anctfW nm jTbb rïtalf í layák acuöfd I a Q fo tf=a luvontion is a Icw^hdeffosistancsimyllayer such >hsi ds sheet resistance ft in Π/ = ;s prefer so!.»· i W/nroriess affef an 0p^s}.lül?Hgite^Ü of isMndiß^ fernpering or armabiiiici ffP®. of mm 1 Ω or isssi oefom fee aÄ keairrrent, because such a treatment In general reduces fee sheet resistance. in a specie variant of fee Inverfch, each c? said anflrÉieoSon oostfegs Ibosiad bafereen two iuncflohai films arid feat he «of comprise, ehighnmhpciiyedndexardiretiocilon Sörnpflss'-ÄsiStÄ §nÄ#ölpri»^d ^TO:.:bfffldP,:PP5dßS8yÄM wfei ai least one ofee; eiemont, such as alum-rfem. IK I rnmw mmm rnm mmm &amp;mm&amp;m síim «feçfonfilm beadón si#mÄ mem··»p«v^mrnmmtm. mw^ aluminum. m ptmmi Mm ^ömrntmm ÏV M &amp;æm «# ïnooîporating st kast m;*mm mwwwto m mrnmm m^rnmmm^mM least: one ether suNraieand «spscisiiy e multiple *v*-^*! imiter afaminafedgiasing unit and up**«»* initiated glazing unit co^pbs^g means; et eiecm^ mtiÄyar m&amp;tumm &amp; .teköMtirÄ ί#»59 «* lù ^ P*«*«*0·S8id substr^ fe0m?si 9**k Ât* boni andrer tempered depends on the ip coiônmstno aspoet required fer tiw faang yiIöbaemabMiiibred:·

The üm according &amp; ^ ïmrnm m &amp;*» » rnmm mm^ mmymmrn ® &amp;»«* ÿm substrates with at/lpst m î^lymer sfeeo ss as to provîds a gisss/tbínbíím may especially P Pasad on polyvinyl buiyr*.....(mim*™ vioyi -aoefefe W« polyethylene tereptdhsiate PBTy or poly vinyl ehioddo f^VC];.

Ttte glazing unit may itsad hava a; .glass/min'-tilm musbleyeugeiymerehseiiSf/giSSS abu-tuns,

Ihn gMing adits according többe invention ar»éié«tettá arheat treatment without damage seing done to M bíamtsm multilayer. They are iismíbre optionally bent and/or tomporod.

Tha glaring dnit may be hant and/or tempered whüe consisting of a single substrat pjvihad Mh 1ha moila^n file gisising: unit is than formed ««C in fsa case äo:tig giaííng um m fesni mmMx m B diaaing, the tblndin multiigpf is pfeibraetylöcaisd mméM8$lpiÉM? nonpíaner íap&amp; tno glaÉ/gMlt, esbseiaiiyé double glaring unit. 6^^^gf^g"m!öíPáy@Er· pssÉiy being bedtond/ßrtdmperad, in f:|öitl^lÄf;iöd'P|i!ÄQd. the rnuitstayer is pfofofSDiy arranged do as to be next Ίο: the iftüsÄ!## Ifcf -fsítSld^ii;§lds§^ ína sdlsdete bearing ins multilayer may make contact wif; the polymer sheet

Tbo glasig unit may aîso bo s triple glazing und consisting of throe glsss panes separated, two by two, by a gas-iled cavity. In a triple poing structure, the substrate bearing the multilayer may bo on face 2 and/or taco 5, it incident sunlight is taken to pass through the Icons in Inomosm! nurnedcaroraen

When the gisming end its a monolithic; multiple (doable .of^pl^röflÄätadl'^hl iA atiieast the substrate; bearing1 the multilayer may ho made of bant or tempered glass, the stlbsÄ:|bssiNV:fc#'ibftef mdltiiayer has bears deposited.

Tt-a iöveattsn also relates to: the use :^' .@li^^. tinit having high energy rensetien and/or aliasing unit a fleeted |tsin| unit with a transparent: costing heated by Jeuie heating,

The lnventidh; lieg reistes to the use of tho substsste accoming to the ioveolibo to produce a transparent oteeSrode fer an: oiscifoehromidigldKihg unit cr for a ipiinfi doyica: o: ter a display device or for a photovoltaic panel, the subsifste dbcerdidg to the |^8§b' ^)rtpÄferk pe used to pfOduee: a substrate haying; nlh eneiiy teiection snd/er s substrate heytng;very low emissivity esm/or a healed transparent coatmg for a heated glazing unit.

The substrate sosording to fre invenson; mev, inyparscuier, be used to prodace e transperent eiecfrddo for on eloctmehromic gissingehit (ffiia gtasmg unit peisrga monciimfe. multiple |ásuhie or trlpio} or iaminatsd gtaslno uriitfer % o ilghfingdeyloe, orfer a display demen: or for a photpyoiidic lc: here unserstopd 10^000: ^00^080001,

Th«- fnűíiápf fö'-fh«: invention Ä&amp; avery m-mm- Äte#: -ir&amp;gh Sgftti tesm»n:F?ô^':«ad' mm:>72% when íamináfadk a tow #% isMfe tháffe not tepswracíWia* and r cooídinafdá P m MÉ fÄ:W': Ä'MO; any: ^ ipwertban *2: far s% and wdish^ffemsns does not vary greedy as a tsnctían Ä Äbgüb#, i© da bbfsinem.

Spâiïifiqiydii seemslfai 0f*»ilr$*tfNtf«ft» aip>Maotívsándax ánfeftóan:ia>:ia ^ firsl asÄlfecfencsdüng: üäI® f§? lynefen#:1(nr and; ai tea^ sa© f«i the lant iubcitonaj aim, withöutsí«yli8g: a nach; ioeeied: between W$mv$w%\ fte :ir^s I fm$m. mMmmthetigmbeton that : fs W close * sem Äi viewingangle, wiihmtt öv^ify-^wlP^fÄ-ds^teúle.»iP<ör gisstsy increasing pcost (this jebeoayso, jn eaners; a hi§n»foftöcUv9^Rdex:':^Äte»:i^%ö^f#.#Äiö'MpSiit^«: nsadsii^rsfeaofsyanndgx sn|jrggao|oa fe, and öpsés more Inan anislleçiidn: din).

Thé aniNlisűiion: coalings si tf5©:muidiay©raneordmg lo th© invention comprise op absorbent films, küdhgmmre, smoloythg s #c?8así% stadlí^pteípr^u^tstSi bisibbt/tton al fonctiona)-·::;;© rr-icknassas^ aisows mmtmmm te U ebiÄed, 1er the mmtliayen wlhls bm color in fÄ m # ine acceptable, though; aämltiadfy not as good: as mat obtained; with an increasing cilstriballon of tbigKnassepandrwMie cist .obtaining nee acceptable vAte in the dolor

However, ü isi.Inon important fór the dlhersnce in thickness hom ona fanstional Him to another, in toe sebstrsre onecsore or in me dimdlon away tram the sobstrste, not to be too pat;. Ibis is the mason why a a ö.S. and praiersbiy a .¾ ¢0¾ syen c<: ~í) ö· Detslls: m seyeniaiebbS: leatcres oftlhe; mtM m mmdm tom mmtms;mm ih§ appended figeresshowingf fipero 1, **# provided: with err enderbioober layerfeci being provided with m overciocker -apr en© É» mmkiayer fhrihemsXv ***»>§ puwUvd .Wft m. çgllQftdl^sW^^Pi^ bduro; 2, a multilayer semo»g m Ä ****** to %e invention, each fundhoesr Mm\ oelng provided with on onderbipoker layer bet not being provided with ran overlooker layer and: the muhiiepr tormore being ptmfâeé wi'tfe m klgie: Æ iiiusirsles a meiiayer stfocture comprising; thrao idoekonai films 4Q: 88, Ä Ä atme» m§ mpmm. m a transoarentoioas sebetreie 1I> a*U m* A ® kMAM w ·**-» «>*«»« » « » »<* « *** .m**m m «k*ô Mk « iS MM 6««s« :«»*** «»9* » « » «*! fc “ * ^ wmm m mmm ®*9« «0, w »>« ite m *»' 1» fe W *« »>«*» m Î40 *,,,(,«* COÄP Î0. S9.1« m, mm mm»s> * &amp;* °«i ® «’ *** ®! i9% 105/10¾ 18t 14Sm4; «*»%, m»*»M fc: 40, ft ttû: n»?, «» »se ted. be 0« a WMMwr Wf W1 »*» M» «KÄwiiMAblM aMM ita meosnal««, or««b Mt« *« m<*e».«Mf w«i»*Pa*a bW| 3»»r «3v*Bi«* im> 55. », « wN «"«" «« 6®*η8' * "* »* “«**®*® mmmmmsrnmm him. hgare 1 söows a oipliayér ísraűíisiing ki ab optional protect! ste im 20Q ihat is bot passent in: táe esanipiaa Ä» in ganeral, ii protóativ« fiissi ip vary Ihin aad ss not fákén isin coasideestion wáen defines) me optical propprilos of the last aoi'ilesnon costing of ihebibiiayeo

Isi ali sí ine exastipies below, the iinilfs; biuliifaye? is deposited on s oiesr aodasinie glass sobsbsie 1.6 suai ln fhiofcieas, marketed by Salni-Gobsio. iß nach of lbs examples feelew. tne depositions conditions of the films, wtiioii wars deposited by spotfsdng: fmaenoiroo spattering·, wem bis following: írni

Afirstset öl four examples was prodaoed; these examples am rsoaibpsed 1 fa 4 below. Ali four worn inoorperstad Iwaisnilnated giaáog stmciofe: glass substrate 1:6 assn in thickness hsamig lbs multilayet'/pys lamination tetertayor 0:?6 mm. is: teiaimess/gisss substrate I.Smrs In ililetasess.

Tsbie 2 below collates the materials and thioknesses In nanometers of esett layer pnd tbe composition of thé layers: ihM form file multiiayer la their positional omar relative te bie fiialblayermssslag: sobsbafe {iasilioeat tee bottom of the table); the nuaibersia Ilia 1st and 2od columns correspond to tee referendes la figure 1,

Mi§J

Each eníirefeofen seating M 4$ IM subiac^tálnsIöasi im 40.. Bö, iSOcomprises s tesi*œ®r®:im Ä öS; 168 terns m crystalline aluminum-doped sine oxide sad t# maxes contact with the functiona! film 40,80.120 depcedted just above Ischfentirefeofen coating 20,60; 100,140 fenforises: , «t 4: medfom-reifaotwemrds* afen^iöö aim 24 §4, M 144ifessd on aiusdnam-döpád iileoh siiiSfclil daliad ííiAlN fertâk «Ä cf simplicity although she two hÄfö of v* film &amp; in foot $»1%:$, aii#ia»ied ahova; or: a: high4dií'seiíy®4ridex áh8íé»o8 Posting 2δ, 65.105,145 based on xireoniaia-dQped sééfe rsiiride, here caíied Slipfe?; the sake of simplicity although thÄo ϋβ· of are f«m is id feet as^iáÉi#abevm

These Sims am important for ohminlng the oxygen half 1er effect daring neat treatment, in addition, these four examples heve the advantage that they can he tampered and Porit.

The fotel thickness of the tunotfonai dime and és disfoouüon in the thickness of the functional films is the Mhb 111 these four examples: ths «Äiapi'-Moflii.ihaysittP «μ* sfeetraslstsnce; however, they do not nave the sadSddlphf iransmifekfe: t|Kl:refeofion or color in reflection.

Table 3 coiiafom for examples 1 to 4, the sheet resistance measured, aller a heal treatment (fending sí feöC), for each substrate bearing foe mulfifeypoana the main optical properties measured for foe complete laminated giamng unit incorporating the substrate nearing the multilayer, ll&amp;l

ffor these suhsttafos, •: T1, recmsdnts fhd Ight irperfsiesionin foe vielhie lrr li mfesured under liurnibant: A with $10» observer; -t% represents the light:refection in the visible in 1,: measured under:IIlymirfent A with a Ifedfeefyef; .*· R,, represents the sheet resiSfehce ih Ofq alter a host tfonfofont (bending); , sSiie and fe5s represeht feo hfe esordinetes a* end r ef foe color in mm » ΙΟ5 observer, end thus measured substantially normal to foe glfeSfe uni?; and ·· Oies'' and represenlfoe Lab coordinates a* and if of foe color In refection measured under DCS illuminM: With a I8®fesarvar at an artfis of #> fo the norma! to foe: giaxing unit, !t =2- fo example 1. that u«tng entirerlecison barrier films 25,15, 105. 145 made of

SiZÂiiâà barrier ΐρΜ, Ιί ÜM44 fromSlAlN S^y: Uîtit wm mmmti by mots ip 11 'v#i€"i#1pWÄ5t® §ams mém <»lorjn:iiitès&amp;fc·&amp;Φ and ai 60a remains acceplable.

Utmm< *?ΐΓΓ*?' % fesiiçyt-fe PÜiA iWfeeôPss the central aifieiibbhon bafrlêr films ÉS, i-DSmadeof S® le. those flanked by two functional films, are msek (68 m) tampering example 3 io. Kampfes 1 «ad %ê®m flit using only ^pM-PÄpÜös barfieriias :88,405 made : barder ί|τη64> 104 írem SiAlhl while: mafrinp; the Ural dlÄsf antirsiiectidb banw $ms. 24v 144 fmm um dosa net sliövi lim IpNt tmasfalssloa of iä giaeingjanillo he sigmfcanilv increased (only by about +ö.2%).

The SiAihl and fsfZrhl films al hayaaR:axigcflarsaoaSlöidprb yew 8,51: thé eoefcieni k oí $Ü.N at 558: hm is abpatiJxlO'5 and the ooeftósni k of SI2fN at 556ami atxatf 7> 4>k

Samparksg example 4 to samples 1 tot shows mai using o&amp;^·-fits^-^sd (bâiT^ Ί'^. 2^= 145 mais of SiZdd instead of first and f^tm^to^ftpfepriidXraRffföfteÄ tarifer Ima 24, 144: mads of SÊ1N while making sash centra! aotefecSom totter im 64, 104 of SIAIN slows, as In example % Ifs Ighl transmission cl the pissing unit Is be sipniléafàlylasmssed (by about +1%); however, mis example is simpler and: easier to implement mao example 2. and if is itäfthemmra less coaly. I« mis sat of examples, 1 to 4, only example 4 is ah axampia anrsstfing fs the invenlon bacause the anlmlectinn ooanng 20 located under me first, starting írom the substrate, taciiona! him 40, and iha anlirellecticri coating 140 located on the last, starting bom the substrate, futofeto tin 126 each sawpnss ai least one bigh-rafradivadttdex anfeefieeiion film 25,14| and each shtimiscfidh boating 00,100: Ideated: between: two fuÄPaf. Sims doss net comprise; a high-fsbaclxe-lödex móimfiecíiuh film.

Exampld t id ftPfmh example according to Ifte inyahfion haosuSs none of the anlireitectiofrcoatings 25,5¾185.148 oprspnsesa; I :igb#eifamtvsindsx eniirsíisciion film,

Example 2 ?$ nor an example a-mordlng to thalnveotief! because; ail me anlitelecfion coalbgs 28, 88, 181), Idöcompnse a h^h-s^sBpv^ihÄMWfecfen film.

Example 3 -s also not an exemple according to ihe invention because neither Ihe autkellection costing 20 located under Ire first, starting from thé: substrate, ioheilQnahfiifn 45 nor :i$8 located on the last, starting fiem mesubSMÄ functienal; ire 428 comprises at least; ene film : and; each arstlrefledion; coating 88, Ip: located between Wq functional films comprises: a him 85, tOil,

In this first set of examples. 1 to 4, the thicknesses of ihe three silver films of each example were; identical arm all 13 nm. A second set of four examples was produced usmg ihe sane? deposition conditions as for the first set (table 1); these example;; am numbemts δ to 8 below All fear wars incorporated In a laminated glaring structure: glees substrate 1.8 mm In thickness pearmphe multiiayei/PvS lamination interlays? 8 78 mfwlf1ÄhÄfiħÖb#^t4,l;rnm íhlhiokness.

In; its second set, thuletë thickness of the iundioníá 1ms was menhoa; from one example le another and was; identical :fo;4ha létal thickness of the funefionai Tims: Ip the first set of exemptes; however, unlike the h?s! set of examples, ihe three funsfionaf «ms were not all Ihe: same: fifekness: M film closes?: the substrate (Apt:; was thicker : than the: Mowing fi!m#g2) 'Âh 'WM.«l;É»r-i§h ihe following film, (Ag% in the set of examples 5 tu 8 there la therafcre a decreasing, starting front Ihe eupsffeté, dislrihiion of fhe thicknesses uf the functional filma, thereby following the teaching of the tritemahona: patent eppfication filed under number PCT/FR20lG/05f732 and published under the number WO 2011/020974.

Tab;« 4 below $Me$ tbs materials: and ihicknesses in nanometers of each layer and the composition of the savors that femvM multilayer ip their positional order relative to the multilayer-bearing substrate (last line at the bottom of the tablet for examples $ to 8, the numbers in ibe Is! and SM getarnt» correspond to the references in figura 1.,

Ilkitâ

The thickness e* or each functional ffirn δδ. 120 is smaller mart the thickness of the preceding imcfionai -rise, in the direction of toe substrate 18, end is sped that; &amp; a a ο,-η whore; * xis tno row, sterling front the substrate 1t5. of the functional id; » x-1 is the row, in the direction of the substrate 10. of the preceding iuneiionai in·; » a Is a number such that Oh a < 1, and preferably 0,§δ Ο u S 0.SÔ, er Ô.6 Su Odd; end * the thickness of the first «farting bom ibe substrate, mefallie funetlprsal film 40 is such that 10 $ en s 18 in nos and preferably 11 < e· < 1§ in nm.

The thickness es of the second fonelionai id 8b is e? ~ P.OTe;, where « thus «= 0 87; and the thickness os of the third funciionai im 120 Is 83 » O jSéï where a thus ~ QM. The voies of a is different (by 0.021 tor elkthe inctlonef ids of row 2 or more of the duitiiayer. Täfele 5 collates, lor examples 5 m tl Ste sheet resistance hfeadüfeci,: after a heat boatmens thanping at 840¾¾ %r each csibsttete beatlni the multilayer an$ the engin optical properties m$mnMfor lie complote tammated glss'sg; ueit incorporating ®s suMiwfa feear|fe|:tha:hH|tt|P|sr, ail these Sieasataipeat^peihl eateegbyi Ih ss tor examples 4 to 4:

Mai

14 wilt thus fes ofes&amp;rysáciiT thls second: set of Mampfes,, op comparing: example δ to texsmpte: 8s. that usihganiitisheotk® Mrrter tllms: 2&amp; §5,10S, 14| »# : or SiZtte instead m ?? ;afit| each: m teefieefted: banter Uni : H 64,104.144 bom: : Si&amp;tte ; allows : the light t^sîTiissioo of ^ ftssho: patt is be inefsass<:l by msfr». 1% while the tight mlleclteb Sixl the color la reiieciion at Q-> andatW remains acceptable.

However, mmpte &amp; äffe» implements!·: as industrial production lige bÄ low $$, t öö mtteeorSlZrhf, i.e. those flanked % » mngidnal fllrns: aratihksK <58 nm}:

Comparing: example ? to examples 5: and 8shows that using: ofily central anfimtiecloo bafriar fms Si, 10Ï made ofBsZrte instead Of making::sach central snhmtlseiisP: barrier Cm: §4,104 from M #lis: making the; first gno 111018124,144: fmmrSMIN to:net allow- %, iighH'ensmissioa te (onfy by: about *0:.2%}.

Ooaipsrirsg: example: 8 to exemples 5: to 7 shows that using: only M: and fast aotirahectieh: fearfeer films 2¾ 14;S made of: izmi i?^lMt#É.sf.ánö::!#t:anl}m}}ton:bgr«gr iœs-24:; 144 made, of StelN white 104 öt::IÉIN allows, es In example s, tie light tomiswR 4? i*r§js*i?if fe® sipiipÉ? ipto# (by #β*ί^)ι ítewsver,, this example.is simpler andmaster ts =mpf©msntihm extmpie 6, aaditla&amp;rthermcfe less costly,

In this set of examples, 5 to 8; only example 8 is an example according to the invention because trie aniireiseciion coating 2G located under tee first, starting fmm the substrate, functional Ä-4Q, and the a-itlrsfteptioo soattng 140 locatedi on tip lest, startiül from tfea sobstsMO. functional: film igg eachioorppnss st: flirrt: 25. 145 and each antlreiiection coating 60,100 locstsd between two functional:films does not compose:

Sim,

Exempts 5 is notn3^ oxarnpfe aoeording to ihs invention because, none of the anlireflection coatings 2¾ 50.400.140 dömprises a hlglwaf^

Exampfe δ 18 'hötiááí^tiípfe:·^^^^^® invention: because all the antireiteelou coatings 20, $0, 400,140conpiss a nlgte •eh active-index aiYtireftectton tilm.

Example 7 is ateonot ah exempte according to fftelnvention because neither fhaantea^scfiod goadhi SS located: pnder the test,, starting from the substrate, iarsciiöítel filing m the anflraisction coating, 440 located onIhe last, tearing, item the, substrate, functional: Him 420 comprises at tessi o% bfgh«fcÄ84Ä.i»iM«08 film and; each antee5ebtiorv:Cöäf;hg: 6ö, 1Ô0 iscated; between two:funclíonái;f4mscompnssss:h|gh.f8^5cvsgftegx anflrefibetlon film SI. 108.

BeSÄs of; the Í8fp M cf the: stiver ims (ptf fiesefom lm m mMmmmrn mmm m$ te |ood Optio#: mmmm-fc mmw mmi mmm$m·· MM*H# fp wmm p## **«* «Ad wii m·· mmm mmm ®e äPqo ίο

Tfíii; frgpSpäfSSt éieblfödb P)g¥ ÖS' stiifsfeio fői' so; OrgariiC iight-edtdlng device,; tU p;«fs’,-ls0: -il: jiä$ s« vie y#v.X··?! xteonium nitride ahbnsüeoiiou im 14$ -$ tüpfle 4 io replaced ilth s conçabilva fm (im paifi&amp;emr hawng a fsswhv-ty rower mao 1*fÖ? tof and especially m m qÄW*»# im, Thisimmay » ^ »Ä Ä^liP mm- mm> optionally doped ^ ai or m orissoaen &amp; ®m x>m ^ m$&amp;m. mm psi m opfienaflHoped: (for wampte with Sb and/or i£* Inm oxide p» Thte örpÄ «p4gÄft|«vfew m* be produce a lighting device or a dispíay device (screen). ftppfg .¾ illustrates a .muftüayer structure composing touf functions; films 48, Bö- 120,168, tins structura being deposited-on- » ifànspsrsfü glass substrate 1(1 ßscii function# im 40: SO, 120, 160, b located between two anPr^eobön ceaöngs 26; Bö, 100,148,1BQ, sums mal tbs lim, siariinilrPm thamubstrate, lubóilonai §m 48 1s locates between fbe Ätefe Mg» 26,, 68; (he second tataiürn m-b imtid bat mm ia aniireliccilon coatings 68, 1 SD; fclWfcifeá* *28is ta«st üelÄi mm* too, 140. and the fourth functional im 160 Is moated between ine amireitection coatings 146.180.

These a#e?teciion coatings 20, 60.186,149, ISO, bash comprise aS teasf one antirefieclon te 29/24,28; 62, 68(54, 98,102, iOS/104.10S; 149/144,148; 104/185, apfidnaiiy,: each funefionai im 40.89, m ISO, may. on is one band, m deposited on an encerbiccter layer 29, 7¾ 195,19$, moated between tbs subjacent antefieefion ccafin|;sn9 me kmetibpai Him, or each Imimnél tlim may, m the ober hand, ba deposited : directly under an sviÉtór sups^cent ahtirebeopob

Figure 2 shows e mehiiayer iemwiarmg io an opiiona! protective ifim 200, in parficuiar an owds-based film. especially an oxygen-substölohlofpeiric ibi.

Wi antlrelection pbaffng 20, $0:,196,148 sdb|xsmi::;3 (enmibn# im 4P, 00,128, ^comprises a filhtiSI, 58.108:,: 148 based on aryafaifibo: aidminummoped: sine oxide onsii ^nioh mop*mifvely msk«s not^tsot wtfH ihö m^otionot flint 48,80; 128; llOidepceited idstiabeve:, 88Cit:®oia8ecaco cpatlng 20, 80,18¾ 149; 180 oomph»: -either a flimlllff,1841 |44s. ^84 based onaiumintsnt-eopbd stiioonn-trids,: bfeie called SIAIN for the sehe of simpiibity although the true oefurs: of the flint is ;te;fect $Λ Ai. as espisined eboee; -· or a highnafraefiye-iodox apfirefleofioh coafihg jd, 89,106,145, 185 based on aifeobluai-doped 0m hieidc, bots called SiZrN for the sase of s-mpiioty eitnough hie Tue nature of the ISm w ip fact S.jM.r2··, as axplalned ahoys,

These films, are important for obtaining the oxygen barrier effect dunng heat trpaimeob a med set of focr exampies was produced os;ng the sante uepositmn conditions as for me first set and fm second set dabie 1·. msso examples are numbered $ to 12 |si»w; Alt lour were incorporated la s taminaisd giaxlng structura; gisas subsuam I 6 mm In iblohnesa beadhgihe: myltifayer/Ov^slamlnatior! intehayer 6.71 m® ib thickaessiitess eobstrate 1;0 mm In thickness, in this second set, the tot# thickness af the dtisetionas Io tbs fear funclions; immwers ail the same ifticknpss.

Table Sbsiow collates the materials and tbickhespaln nanometers Of eaohilayor and the composition of the layers that femt me multilayer in pnsltfdnal «tddd mlaflye to ilia mnllieysr-beahhg soOptmfe |asf ime at the bottom of the fabis; fcr examotes 8 to 12; the numbers in the 1st and 2nd columns correspond to me references in figure 2.

Mmt

Table 7 celiaies, for examples S io 12, te« onset resistance measured, oner a beat bemmem (bendmg s: SdieCÏjte each substrate bearing the multilayer sud ibe main opbaai properties measured ter the complete laminated gteping teli! irteorporaiina the substrate bearing tea multilayer, ail these measurements being: carded out m the samp wax as for examples 1 to 8,

Mi&amp;I

a m mm® fe10t&amp; «xempfe % .iát· dsing teás,#, ιββ(*1)&amp; ÄMtft4£98$rfe#^si^íöptó1Ä t$ löi -44, IP from !ÜM allows illő; fight ; tíOosmíssiófs; of the glazing uni;i&amp; be by almost 1 % wife fed öghirmftesiioí; mmäins $ÂÂÈ|:É$ SähWt sad fes ooler th reffecípl sl séd at 60° remaHy acceptable.

However, Kämpfe 1 δ fe iopsuii to Implement ,on an industrial produetibn %m mmm m centrai antóilaclön barNsr ima 61,; 186,iWSmadsprfÄ i«« by twö fengfebal i^ ofalbfestSbnmi.

Comparing; example 11. ^ examples &amp; and tó slmws ihat using only entras anhreiiecilon barber films S|. i;8f 14S made öf SiZrlll ipsfeed tfssii ceniml anie%olmri>arrler fm 64, 104, 144 from $jAjN while making the first sob fest snttrelieeiton barrier Ims M, 1i4:?rom SiAlhi dogs ndt ajiow thelghi trpsfoissirm r4 the glazing ynlitp he slgniiicaolfy increased (only by about +0.2Ά).

Comparingmxampte, 12 to examples*; to 11 shawsthaf usirrgmnly fire! and Iasi amirsflecilon barrier films 2|, í8f made, of §M Instead«! first ;and last soágfigoliDnbamarims :24,,184 msdssi §1*114 while makfeg each antral antirsheetieri barrier imM, 104,, 144 of mm aiiawSi as In example: 1¾ the light transmission of tbs. §1mm feme. slgmfisanfiy memsMdybewevor, this example 12 isstmpfer and easier toimplement than example IS, sod It is fyrfemsrmtess easily, in ibis set of examples, $ to 12, billy example It is art example according to maánvenSori bscsuss the shtlfsfieeiloft easting 20 ibeatsd under the M, sIStÉg from tbè Subsiisié, HSOSobdi lm 40s and 0¾ abhrefiastlan boating 180 located bn the last, starting from the substrate, fpnofiodai im 18Ö é8éb jtoföpfBáeát I§à#è8é .Ü^WsftMyêifeâsx .istiréÉ» fiira ts, ids sad escn ambefiaction oPating 80, 1θ|: 148: löosted bstwepn two inmm fi Ms. mm m comprise: a: bigh-refrasS*e-index arwmimilöp im.

Example: 8 is nef : an exemple according to the- Invéfjgômêécâuse cone of tire eht-mtesüen costings 28, 6¾ 18t), 14¾ 180 comprises aêijjpHÂe^ film. Semple 10 is oof art example, acscrding to the invsntiors because ail oi the antireripption, castings 28, 68,, 100,, 440,180 Mmphse a; bi^retSèSV^iHÂ. $$· 11 is also net an example g»dl%# Is invention because neliher the eoteffeciion coating ID iecatel tinder the firm, slatting from: the .Äl^ifebbtesi'Ä4t-öoffr&amp;180 located on ^lÉai-stâiÉl':^·^iötofepincööMlbs 180: emprises: si isast ι?ΐί©.:|pr and eacb antlrefecfleh poatiog :60:, 180,140 ipdated Salween two luocsooai dims comprises a higb-rolractive-indcx antimnection Him 86,108.146;

Generally, the transparent electrode substrate may be suitabie tor use as a heated substrate for a heated giaxing ait and in párficuíar a laminated heated windshield. It may also be suitable for use ss a transparent elecmxie SUPstrgte: for any electmchromic giaxing ,un| any ,display screen or even törést ^ a,frontside or bácKside substfptprlor a trastsparerrt::pböfövplfelcmeíi, Ére presbntllrwpptiôn besfeebn described apbvb by Way of example. &amp; course, s person sKüied a the srowar oe acre to produee variobs alternative fonsts: of tbelb wfeibut depaftiagshbrs 1rs scope öltre pdferit tlefrhed by hie claims.

Claims (5)

1. ÂUR «LY El VAN iSVlTETT Θ» SVÄHTlilHÖl SZABADALMI IGÉNYPONTOK

   1. Aisp IsübsÄi {1% Ässö 8¾ amely € van !» ypkopytess $Mn) többszörös réteggel (multilayer), amelyek tar talmsznak váíiakten „n‘: számú tea fcnKlaaâlis teip. 80i: ÎSS), a!sôai)rb8n: olyan funkcionális É?neléi, Mieipk szüsih vagy MftrittIgitte^liv^Ä SfepÉtel:. é§ Jt*1f saáaiaTukrtegáHö rétiét (anhreliection «Äg) 420, 60, IP 140); shó! &amp; érte te« s»<: Am# hilden íptegáílö Äg m&amp;mz íag^Sbé agy liKröPagilö épét úg% lágy aVaéégyi ljpciöéliis I8m (4(5. 64 128): két ikrlgésgátlö réteg : (20;: 60* 100: 140) kezd??: helyezkedik el, irnutkleyar) tartalmaz legaisbb két nagy törésre utte (hign- iiméüvé Index) iükrözésgáfíó Nmei (25.145), ptäyek rnindagyíke * 2.IS törésmutatóval bír Sió éra hiÉémhossxnst, es 0.01 Ä áhsgorpslös együUhaivsí bú 5S0 am huiiàmhôssznèi; agy. hogy a mkrópsgátló réteg <2ö>4 amely aï sise, az alapon! (subsfmie) »dúló fuassioaáiia Sgr (40) alatt helyezkedik el, és a túKfózésgatló hm. amely az utolsó, alapból kmte WteöfetöPiÄröz^liö tiaet (2¾ Ip, os dpk itegêsgâtiè réteg (60, lôô}, amely két funkcionális tip közöd heiyegkaöikei. som mßxm nsgy törésrnuteK# Nmet, 2 Ari Igénypont szedni! alap (10). ss&amp;i spiienmítvm hagy a tükrezésgátló réteg (20), amely az oiső, aa alapba ksnobie funkcionális Ilim (40) alatt helyezkedik el, abban a serrante ag alapból kiindulva a következőkből áll: egy vagy több nagy törésmutatójú iökrözósgátiö Ilim (25), maid agy közepes törésmutatóié nedvesítő Nveltíng) fükrozésgátló hím: (28); amelynek tömamutatójá a?: 1.80 és:í2,fS itett) tartományban van, kmarva ezeket a határértékeket sa soy kristályos ősidőm alapúk aisösóttíán cintedan, kíván?: ékéiben belakkozva (déped|; fegélább egy másik aleínmak amilyen például az alumínium. .3. Air 1, vágy 2. igénypont szerinti alap llOi.rsaátléilémsrfé, hogy a iúxrózésgéííó réteg, amely az ulnlsó, az aíspbblkteié lunkciobâlls filmen helyezkedik al. Nzarölag piatjéiylegy «agy Pbb nagy mmsmutatOlé tükröséegatlo ititePl.
2. 4, Ag.1-3, Igénypontok bármelyike ssebnti: alap (10), azzá! ijéitezve, hogy legalább égy, dé skér as összes nagy :temtíMóiú iiikrözésgátló Ilim (25, 145) szii!nium»ői$íum minden alapul, iíM "Í-4, .igényetek .bármelyiké .saróí! alap (¾¾ azzal jelismazeemhógy áz egyes: funkcionális álmák: pl, 120) % vá§te8^ál^áÁiárSgjö.fuak6iO«áhs Him vastagsága ág jläpp.OliÄpfesh, és ég á kövétkegö képlgt szerint:: e* ~ oes< uShof Φ ;< a itmkülonálls Ilim sara (row) az alapból (10) kiindulva; $ ;<-1 az alázd íunkoonáks Ilim sara az alap (10) Irányában: rpí ο {jqy szám úgy, hogy 0.5 s ü < 1, es elonyoaer: Ö.Sn ss η o,ep vagy óm 4 a &amp; n.s1': és Íí az első fémes nmkdonáiis fíkn vastagsága, az alapból kiindulva, olyan, hogy 10 ó e: 4 18 cm-ben.
3. 6, Az 5. igénypont saennti alap Hu), szítéi jelíemmtve, hogy az o értéke eltör ez Qá^M:ttíAyöwilte'Í»bsz::á;;2; sor vagy nagyobb sorok értekeitől i Az 1-6: igèoypootek bïrte#b várttá Jsiiémszvé, iogy é imsé tunkólonális Simák te|es vastagsága: éihy&amp;sen naayobb, mmt 30 nm, ésélsleorbáh á 39:htn ás Oónnt köÄIÄthäriVöih-.ftetSigik, ö határérmRsks? rs balesríva, vagy ez a teljes vastagság a 36 nm és ÖO bm kózöttl tartomá?>yban lakszik egy olyan vékouyhimas többszörös réteghez, amely bárom hMéíohiis Éráét tartalmaz, vagy éz á tállás vaáta|ssg a 40 nm és 60 nm közöli· lártománybáh lékszik egy olyan váknayimesstobbszöfés rltégbég, :amé!y négyAipkélönáksTItmet tartalmaz,

   5, Az 1-7. igénypontok bármelyike szerinti:tgiap érni JÄmsfv«, hogy ég emiltétt tük^zésgábó: réteaek (W, ISO), amelyek két elpn fuhkcicnllis Ilim sögött héiyezkedhék gl, ameiyek:nem tükmzésgstlp méi&amp;· 1δάΐ' sÄÄl{rte^4 éol:m Ä'ÄÄ»*®»1 looped) legalább egy mavis memmel. amilyen péloàüS es Stemmern·;·
4. 9. Ας 1'?. igénypontok o^mely*« «enni! alap {«0}, am! jeiiamssy«.mm m P|yes iMsgá« fétepek ieguto»»^ .Ιϋ|ΐ&amp;ϋ (sá!|acen| egy w®im m> m '(^ mwy: egy $jimm mkm előnyösen di^KÄ Ä *Μ*Ν0»β»» *r % #**&amp; eSsmsttei, amilyen psisáu! aá aiamigiMfn.
5. 10. Fényei# (gisaíng) apység, «mely magában ép!t legalább egy. az 1-8. igénypontok bfe^yiPa sattenii agyséû- P*^1 hevíteti (heated) többrétegű fénye# egység elkészitese, ahol az említeti alapot, amely hordozza (bean a löbbsacsfós rétég# (nteiülayer).. tehetséges hajlítani (bend) és hókezeíni (temper). 11. »aima#ss m 1-9 igénypontok bármelyike swnti atepnaíg hagy elSállítephk egy tepysKb egységhez vagy eioámtsunk agy áltetsaó elektródát egf agy vitegMdlghlteg) bem?teaaeihe2: vagy egy lejátszó (display) bsíegda#sbes vagy sgyjötevi:^