HU199230B - Emulsion of oil-in-water type comprising slightly water soluble agrochemical active ingredient - Google Patents
Emulsion of oil-in-water type comprising slightly water soluble agrochemical active ingredient Download PDFInfo
- Publication number
- HU199230B HU199230B HU82933A HU93382A HU199230B HU 199230 B HU199230 B HU 199230B HU 82933 A HU82933 A HU 82933A HU 93382 A HU93382 A HU 93382A HU 199230 B HU199230 B HU 199230B
- Authority
- HU
- Hungary
- Prior art keywords
- water
- weight
- formula
- oil
- optionally
- Prior art date
Links
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims description 53
- 239000000839 emulsion Substances 0.000 title claims description 41
- 239000012868 active agrochemical ingredient Substances 0.000 title description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 30
- 239000000203 mixture Substances 0.000 claims description 24
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims description 22
- 239000003995 emulsifying agent Substances 0.000 claims description 22
- 150000001875 compounds Chemical class 0.000 claims description 17
- 239000003960 organic solvent Substances 0.000 claims description 16
- 229920000151 polyglycol Polymers 0.000 claims description 15
- 239000010695 polyglycol Substances 0.000 claims description 15
- 239000002904 solvent Substances 0.000 claims description 15
- -1 alkylaryl sulfonic acid salt Chemical class 0.000 claims description 11
- 125000002877 alkyl aryl group Chemical group 0.000 claims description 9
- 239000007764 o/w emulsion Substances 0.000 claims description 7
- 238000003756 stirring Methods 0.000 claims description 7
- 239000002253 acid Substances 0.000 claims description 6
- 239000012456 homogeneous solution Substances 0.000 claims description 6
- 239000013543 active substance Substances 0.000 claims description 5
- 239000003755 preservative agent Substances 0.000 claims description 5
- 150000003839 salts Chemical class 0.000 claims description 5
- 239000012190 activator Substances 0.000 claims description 4
- 229910052791 calcium Inorganic materials 0.000 claims description 4
- 239000011575 calcium Substances 0.000 claims description 4
- 239000002917 insecticide Substances 0.000 claims description 4
- 239000008367 deionised water Substances 0.000 claims description 3
- 229910021641 deionized water Inorganic materials 0.000 claims description 3
- 125000002816 methylsulfanyl group Chemical group [H]C([H])([H])S[*] 0.000 claims description 3
- 230000002335 preservative effect Effects 0.000 claims description 3
- 238000002474 experimental method Methods 0.000 claims description 2
- 125000000217 alkyl group Chemical group 0.000 claims 1
- 239000004480 active ingredient Substances 0.000 description 12
- LLEMOWNGBBNAJR-UHFFFAOYSA-N biphenyl-2-ol Chemical group OC1=CC=CC=C1C1=CC=CC=C1 LLEMOWNGBBNAJR-UHFFFAOYSA-N 0.000 description 10
- 150000002148 esters Chemical class 0.000 description 10
- 239000012153 distilled water Substances 0.000 description 9
- 239000012074 organic phase Substances 0.000 description 9
- 239000000126 substance Substances 0.000 description 9
- 239000007787 solid Substances 0.000 description 7
- 239000000243 solution Substances 0.000 description 7
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical group C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 6
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 6
- 239000007788 liquid Substances 0.000 description 6
- 239000008096 xylene Substances 0.000 description 6
- 239000000945 filler Substances 0.000 description 5
- 235000010292 orthophenyl phenol Nutrition 0.000 description 5
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 5
- 238000003860 storage Methods 0.000 description 5
- 239000004094 surface-active agent Substances 0.000 description 5
- ZSIAUFGUXNUGDI-UHFFFAOYSA-N hexan-1-ol Chemical compound CCCCCCO ZSIAUFGUXNUGDI-UHFFFAOYSA-N 0.000 description 4
- 239000012071 phase Substances 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- WVDDGKGOMKODPV-UHFFFAOYSA-N Benzyl alcohol Chemical compound OCC1=CC=CC=C1 WVDDGKGOMKODPV-UHFFFAOYSA-N 0.000 description 3
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 3
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 239000008346 aqueous phase Substances 0.000 description 3
- 238000004945 emulsification Methods 0.000 description 3
- 150000002170 ethers Chemical class 0.000 description 3
- HJOVHMDZYOCNQW-UHFFFAOYSA-N isophorone Chemical compound CC1=CC(=O)CC(C)(C)C1 HJOVHMDZYOCNQW-UHFFFAOYSA-N 0.000 description 3
- 239000004530 micro-emulsion Substances 0.000 description 3
- IWDCLRJOBJJRNH-UHFFFAOYSA-N para-hydroxytoluene Natural products CC1=CC=C(O)C=C1 IWDCLRJOBJJRNH-UHFFFAOYSA-N 0.000 description 3
- QNLZIZAQLLYXTC-UHFFFAOYSA-N 1,2-dimethylnaphthalene Chemical compound C1=CC=CC2=C(C)C(C)=CC=C21 QNLZIZAQLLYXTC-UHFFFAOYSA-N 0.000 description 2
- XNWFRZJHXBZDAG-UHFFFAOYSA-N 2-METHOXYETHANOL Chemical compound COCCO XNWFRZJHXBZDAG-UHFFFAOYSA-N 0.000 description 2
- FIPWRIJSWJWJAI-UHFFFAOYSA-N Butyl carbitol 6-propylpiperonyl ether Chemical compound C1=C(CCC)C(COCCOCCOCCCC)=CC2=C1OCO2 FIPWRIJSWJWJAI-UHFFFAOYSA-N 0.000 description 2
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
- ISRUGXGCCGIOQO-UHFFFAOYSA-N Rhoden Chemical compound CNC(=O)OC1=CC=CC=C1OC(C)C ISRUGXGCCGIOQO-UHFFFAOYSA-N 0.000 description 2
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 2
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 2
- 159000000007 calcium salts Chemical class 0.000 description 2
- KBPLFHHGFOOTCA-UHFFFAOYSA-N caprylic alcohol Natural products CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 description 2
- MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 description 2
- ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 125000000636 p-nitrophenyl group Chemical group [H]C1=C([H])C(=C([H])C([H])=C1*)[N+]([O-])=O 0.000 description 2
- 229920002554 vinyl polymer Polymers 0.000 description 2
- VAMMAGDQKCJBDT-UHFFFAOYSA-N (2,2-dimethyl-3H-1-benzofuran-7-yl)methyl hydrogen carbonate Chemical compound CC1(CC2=C(O1)C(=CC=C2)COC(=O)O)C VAMMAGDQKCJBDT-UHFFFAOYSA-N 0.000 description 1
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 description 1
- LJWQETZTWPNCDZ-UHFFFAOYSA-N 1-(2-hydroxyethoxy)-2-[(6-propyl-1,3-benzodioxol-5-yl)methyl]hexan-2-ol Chemical compound C1=C(CCC)C(CC(O)(COCCO)CCCC)=CC2=C1OCO2 LJWQETZTWPNCDZ-UHFFFAOYSA-N 0.000 description 1
- WURBVZBTWMNKQT-UHFFFAOYSA-N 1-(4-chlorophenoxy)-3,3-dimethyl-1-(1,2,4-triazol-1-yl)butan-2-one Chemical compound C1=NC=NN1C(C(=O)C(C)(C)C)OC1=CC=C(Cl)C=C1 WURBVZBTWMNKQT-UHFFFAOYSA-N 0.000 description 1
- SNTWKPAKVQFCCF-UHFFFAOYSA-N 2,3-dihydro-1h-triazole Chemical compound N1NC=CN1 SNTWKPAKVQFCCF-UHFFFAOYSA-N 0.000 description 1
- JGSIAOZAXBWRFO-UHFFFAOYSA-N 3-methylsulfanyl-1-phenyl-4,5-dihydrobenzo[g]indazole Chemical compound C1CC2=CC=CC=C2C2=C1C(SC)=NN2C1=CC=CC=C1 JGSIAOZAXBWRFO-UHFFFAOYSA-N 0.000 description 1
- KWXICGTUELOLSQ-UHFFFAOYSA-N 4-dodecylbenzenesulfonic acid Chemical compound CCCCCCCCCCCCC1=CC=C(S(O)(=O)=O)C=C1 KWXICGTUELOLSQ-UHFFFAOYSA-N 0.000 description 1
- 125000006181 4-methyl benzyl group Chemical group [H]C1=C([H])C(=C([H])C([H])=C1C([H])([H])[H])C([H])([H])* 0.000 description 1
- PCWGTDULNUVNBN-UHFFFAOYSA-N 4-methylpentan-1-ol Chemical compound CC(C)CCCO PCWGTDULNUVNBN-UHFFFAOYSA-N 0.000 description 1
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 1
- ULSLJYXHZDTLQK-UHFFFAOYSA-N Coumatetralyl Chemical compound C1=CC=CC2=C1OC(=O)C(C1C3=CC=CC=C3CCC1)=C2O ULSLJYXHZDTLQK-UHFFFAOYSA-N 0.000 description 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 239000004907 Macro-emulsion Substances 0.000 description 1
- 241000244206 Nematoda Species 0.000 description 1
- 241001494479 Pecora Species 0.000 description 1
- 239000007983 Tris buffer Substances 0.000 description 1
- 230000000895 acaricidal effect Effects 0.000 description 1
- 239000000642 acaricide Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000003905 agrochemical Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- MXWJVTOOROXGIU-UHFFFAOYSA-N atrazine Chemical compound CCNC1=NC(Cl)=NC(NC(C)C)=N1 MXWJVTOOROXGIU-UHFFFAOYSA-N 0.000 description 1
- SRSXLGNVWSONIS-UHFFFAOYSA-M benzenesulfonate Chemical compound [O-]S(=O)(=O)C1=CC=CC=C1 SRSXLGNVWSONIS-UHFFFAOYSA-M 0.000 description 1
- 235000019445 benzyl alcohol Nutrition 0.000 description 1
- IQAXZJZTCMIPCX-UHFFFAOYSA-L calcium;4-dodecylbenzenesulfonate Chemical compound [Ca+2].CCCCCCCCCCCCC1=CC=C(S([O-])(=O)=O)C=C1.CCCCCCCCCCCCC1=CC=C(S([O-])(=O)=O)C=C1 IQAXZJZTCMIPCX-UHFFFAOYSA-L 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- HPXRVTGHNJAIIH-UHFFFAOYSA-N cyclohexanol Chemical compound OC1CCCCC1 HPXRVTGHNJAIIH-UHFFFAOYSA-N 0.000 description 1
- 125000004177 diethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- BEFDCLMNVWHSGT-UHFFFAOYSA-N ethenylcyclopentane Chemical compound C=CC1CCCC1 BEFDCLMNVWHSGT-UHFFFAOYSA-N 0.000 description 1
- 125000003754 ethoxycarbonyl group Chemical group C(=O)(OCC)* 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 239000003337 fertilizer Substances 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 238000011010 flushing procedure Methods 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- UYJUZNLFJAWNEZ-UHFFFAOYSA-N fuberidazole Chemical compound C1=COC(C=2NC3=CC=CC=C3N=2)=C1 UYJUZNLFJAWNEZ-UHFFFAOYSA-N 0.000 description 1
- 239000000417 fungicide Substances 0.000 description 1
- JLYXXMFPNIAWKQ-GNIYUCBRSA-N gamma-hexachlorocyclohexane Chemical compound Cl[C@H]1[C@H](Cl)[C@@H](Cl)[C@@H](Cl)[C@H](Cl)[C@H]1Cl JLYXXMFPNIAWKQ-GNIYUCBRSA-N 0.000 description 1
- 239000003630 growth substance Substances 0.000 description 1
- 239000004009 herbicide Substances 0.000 description 1
- 239000008240 homogeneous mixture Substances 0.000 description 1
- 238000003898 horticulture Methods 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 125000005928 isopropyloxycarbonyl group Chemical group [H]C([H])([H])C([H])(OC(*)=O)C([H])([H])[H] 0.000 description 1
- 239000003350 kerosene Substances 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 231100001231 less toxic Toxicity 0.000 description 1
- 229960002809 lindane Drugs 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- YFBPRJGDJKVWAH-UHFFFAOYSA-N methiocarb Chemical compound CNC(=O)OC1=CC(C)=C(SC)C(C)=C1 YFBPRJGDJKVWAH-UHFFFAOYSA-N 0.000 description 1
- FOXFZRUHNHCZPX-UHFFFAOYSA-N metribuzin Chemical compound CSC1=NN=C(C(C)(C)C)C(=O)N1N FOXFZRUHNHCZPX-UHFFFAOYSA-N 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- 150000002825 nitriles Chemical class 0.000 description 1
- WSGCRAOTEDLMFQ-UHFFFAOYSA-N nonan-5-one Chemical compound CCCCC(=O)CCCC WSGCRAOTEDLMFQ-UHFFFAOYSA-N 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 125000000552 p-cresyl group Chemical group [H]C1=C([H])C(=C([H])C([H])=C1O*)C([H])([H])[H] 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- WVDDGKGOMKODPV-ZQBYOMGUSA-N phenyl(114C)methanol Chemical compound O[14CH2]C1=CC=CC=C1 WVDDGKGOMKODPV-ZQBYOMGUSA-N 0.000 description 1
- LFGREXWGYUGZLY-UHFFFAOYSA-N phosphoryl Chemical group [P]=O LFGREXWGYUGZLY-UHFFFAOYSA-N 0.000 description 1
- 231100000208 phytotoxic Toxicity 0.000 description 1
- 230000000885 phytotoxic effect Effects 0.000 description 1
- 229960005235 piperonyl butoxide Drugs 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 235000010199 sorbic acid Nutrition 0.000 description 1
- 229940075582 sorbic acid Drugs 0.000 description 1
- 239000004334 sorbic acid Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 150000003460 sulfonic acids Chemical class 0.000 description 1
- 230000002459 sustained effect Effects 0.000 description 1
- RYYWUUFWQRZTIU-UHFFFAOYSA-K thiophosphate Chemical compound [O-]P([O-])([O-])=S RYYWUUFWQRZTIU-UHFFFAOYSA-K 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K47/00—Medicinal preparations characterised by the non-active ingredients used, e.g. carriers or inert additives; Targeting or modifying agents chemically bound to the active ingredient
- A61K47/06—Organic compounds, e.g. natural or synthetic hydrocarbons, polyolefins, mineral oil, petrolatum or ozokerite
- A61K47/20—Organic compounds, e.g. natural or synthetic hydrocarbons, polyolefins, mineral oil, petrolatum or ozokerite containing sulfur, e.g. dimethyl sulfoxide [DMSO], docusate, sodium lauryl sulfate or aminosulfonic acids
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
- A01N25/04—Dispersions, emulsions, suspoemulsions, suspension concentrates or gels
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/30—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests characterised by the surfactants
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K47/00—Medicinal preparations characterised by the non-active ingredients used, e.g. carriers or inert additives; Targeting or modifying agents chemically bound to the active ingredient
- A61K47/06—Organic compounds, e.g. natural or synthetic hydrocarbons, polyolefins, mineral oil, petrolatum or ozokerite
- A61K47/08—Organic compounds, e.g. natural or synthetic hydrocarbons, polyolefins, mineral oil, petrolatum or ozokerite containing oxygen, e.g. ethers, acetals, ketones, quinones, aldehydes, peroxides
- A61K47/10—Alcohols; Phenols; Salts thereof, e.g. glycerol; Polyethylene glycols [PEG]; Poloxamers; PEG/POE alkyl ethers
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Agronomy & Crop Science (AREA)
- Dentistry (AREA)
- Toxicology (AREA)
- Environmental Sciences (AREA)
- Plant Pathology (AREA)
- Pest Control & Pesticides (AREA)
- Medicinal Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Veterinary Medicine (AREA)
- Public Health (AREA)
- Animal Behavior & Ethology (AREA)
- Epidemiology (AREA)
- Pharmacology & Pharmacy (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Colloid Chemistry (AREA)
- Medicinal Preparation (AREA)
- Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19813111934 DE3111934A1 (de) | 1981-03-26 | 1981-03-26 | Oel-in-wasser-emulsionen, verfahren zu deren herstellung und deren verwendung |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| HU199230B true HU199230B (en) | 1990-02-28 |
Family
ID=6128349
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| HU82933A HU199230B (en) | 1981-03-26 | 1982-03-26 | Emulsion of oil-in-water type comprising slightly water soluble agrochemical active ingredient |
Country Status (18)
Families Citing this family (29)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IE54464B1 (en) * | 1981-09-09 | 1989-10-25 | Ciba Geigy Ag | Aqueous pesticide concentrates |
| DE3236240A1 (de) * | 1982-09-30 | 1984-04-05 | Bayer Ag, 5090 Leverkusen | Homogene waessrige formulierungen |
| JPS601101A (ja) * | 1983-06-15 | 1985-01-07 | Yuukou Yakuhin Kogyo Kk | 水性懸濁農薬製剤 |
| DE3343092A1 (de) * | 1983-11-29 | 1985-06-05 | Bayer Ag, 5090 Leverkusen | Wasserloesliche pestizide formulierung |
| DE3587125D1 (de) * | 1984-04-09 | 1993-04-08 | American Cyanamid Co | Insektizide waessrige mikroemulsionen. |
| DE3445853A1 (de) * | 1984-12-15 | 1986-06-19 | Bayer Ag, 5090 Leverkusen | Selektiv-fungizide mittel |
| ZW3486A1 (en) * | 1985-03-12 | 1986-10-01 | Bayer Ag | Macroemulsions |
| ZW3586A1 (en) * | 1985-03-12 | 1986-06-11 | Bayer Ag | Macroemulsions |
| US4744917A (en) * | 1985-07-31 | 1988-05-17 | Olin Corporation | Toxic chemical agent decontamination emulsions, their preparation and application |
| JP2559704B2 (ja) * | 1986-04-12 | 1996-12-04 | 有恒薬品工業 株式会社 | 農薬活性成分の水中油型組成物 |
| DE3707711A1 (de) * | 1987-03-11 | 1988-09-22 | Hoechst Ag | Oel-in-wasser-emulsionen, verfahren zu deren herstellung und deren verwendung |
| CA1301642C (en) * | 1987-03-30 | 1992-05-26 | Howard Bernard Dawson | Chemical formulations |
| GB8822937D0 (en) * | 1988-09-30 | 1988-11-09 | Nc Dev Inc | Chemical formulations |
| GB8822936D0 (en) * | 1988-09-30 | 1988-11-09 | Nc Dev Inc | Pesticidal control |
| WO1990003112A1 (en) * | 1987-03-30 | 1990-04-05 | Nc Development, Inc. | Pesticidal control |
| DE3806294A1 (de) * | 1988-02-27 | 1989-09-07 | Hoechst Ag | Herbizide mittel in form von waessrigen mikroemulsionen |
| JP2861076B2 (ja) * | 1988-08-05 | 1999-02-24 | 住友化学工業株式会社 | 殺虫性水性液剤 |
| FR2673075B1 (fr) * | 1991-02-22 | 1998-12-31 | Rhone Poulenc Chimie | Microemulsions de pyrethrouides et leur utilisation. |
| UA43329C2 (uk) * | 1992-11-18 | 2001-12-17 | Хехст АГ | Рідкий пестицидний засіб у вигляді емульсії "масло-у-воді" |
| EP1205108A3 (de) * | 2000-10-02 | 2002-06-12 | Bayer Ag | Wirkstoffhaltige Emulsionen |
| DE10048797A1 (de) * | 2000-10-02 | 2002-04-18 | Bayer Ag | Wirkstoffhaltige Emulsionen |
| US20090227460A1 (en) * | 2008-03-07 | 2009-09-10 | Dow Agrosciences Llc | Stabilized oil-in-water emulsions including meptyl dinocap |
| PL2278876T3 (pl) | 2008-03-25 | 2016-07-29 | Dow Agrosciences Llc | Stabilne emulsje typu olej w wodzie obejmujące aktywne rolniczo składniki |
| EP2305030A1 (de) * | 2009-09-14 | 2011-04-06 | Bayer CropScience AG | Alkylpolypropylenglycolpolyethylenglycol enthaltende agrochemische Zusammensetzungen |
| TWI565465B (zh) | 2010-08-27 | 2017-01-11 | 歌林達股份有限公司 | 作為ｋｃｎｑ２／３調節劑之被取代之喹啉－３－甲醯胺 |
| US8653101B2 (en) | 2010-08-27 | 2014-02-18 | Gruenenthal Gmbh | Substituted 2-oxy-quinoline-3-carboxamides as KCNQ2/3 modulators |
| TW201211007A (en) | 2010-08-27 | 2012-03-16 | Gruenenthal Gmbh | Substituted 2-amino-quinoline-3-carboxamides as KCNQ2/3 modulators |
| JP5837934B2 (ja) | 2010-08-27 | 2015-12-24 | グリュネンタール・ゲゼルシャフト・ミト・ベシュレンクテル・ハフツング | Ｋｃｎｑ２／３調節因子としての置換２−オキソ−および２−チオキソ−ジヒドロキノリン−３−カルボキサミド |
| BR112013005056A2 (pt) | 2010-09-01 | 2016-05-31 | Gruenenthal Gmbh | 1-oxo-di-hidroisoquinolina-3-carboxamidas substituídas como moduladores kcnq2/3 |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2552187A (en) * | 1946-12-28 | 1951-05-08 | Monsanto Chemicals | Emulsion concentrate of a biological toxicant |
| DE824949C (de) * | 1948-11-26 | 1951-12-17 | Bayer Ag | Emulgier- und Dispergiermittel |
| BE490257A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) * | 1949-04-27 | |||
| DE1121814B (de) * | 1956-11-03 | 1962-01-11 | Bayer Ag | Verfahren zur Herstellung von Polyglykolaethern |
| DE2041480C3 (de) * | 1970-08-20 | 1974-05-02 | Vyzkumny Ustav Agrochemickej Technologie, Pressburg (Tschechoslowakei) | Nichtionogene oberflächenaktive Verbindungen auf der Basis von PoIyglykoläthern benzylierter Phenole |
| IT989329B (it) * | 1973-06-20 | 1975-05-20 | Montedison Spa | Processo per la preparazione di acido 3 cheto glutarico per car bossilazione di acetone in glime |
| JPS55129201A (en) * | 1979-03-28 | 1980-10-06 | Kao Corp | Fluid pesticidal composition |
| DE3048021A1 (de) * | 1980-12-19 | 1982-07-15 | Bayer Ag, 5090 Leverkusen | Insektizide und akarizide mittel und ihre verwendung |
-
1981
- 1981-03-26 DE DE19813111934 patent/DE3111934A1/de not_active Withdrawn
-
1982
- 1982-03-05 US US06/355,076 patent/US4500348A/en not_active Expired - Fee Related
- 1982-03-15 AT AT82102073T patent/ATE13617T1/de not_active IP Right Cessation
- 1982-03-15 DE DE8282102073T patent/DE3263998D1/de not_active Expired
- 1982-03-15 EP EP82102073A patent/EP0062181B1/de not_active Expired
- 1982-03-16 PT PT74586A patent/PT74586B/pt not_active IP Right Cessation
- 1982-03-19 JP JP57043006A patent/JPS57165026A/ja active Granted
- 1982-03-22 TR TR21440A patent/TR21440A/xx unknown
- 1982-03-23 GR GR67711A patent/GR78358B/el unknown
- 1982-03-23 AU AU81808/82A patent/AU549148B2/en not_active Ceased
- 1982-03-23 IL IL65323A patent/IL65323A0/xx not_active IP Right Cessation
- 1982-03-25 ZA ZA822027A patent/ZA822027B/xx unknown
- 1982-03-25 DK DK137982A patent/DK158284C/da not_active IP Right Cessation
- 1982-03-25 BR BR8201716A patent/BR8201716A/pt not_active IP Right Cessation
- 1982-03-25 ES ES510817A patent/ES8400890A1/es not_active Expired
- 1982-03-25 AR AR288867A patent/AR229606A1/es active
- 1982-03-25 CA CA000399354A patent/CA1177723A/en not_active Expired
- 1982-03-26 KR KR8201300A patent/KR890002071B1/ko not_active Expired
- 1982-03-26 HU HU82933A patent/HU199230B/hu not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| ZA822027B (en) | 1983-03-30 |
| GR78358B (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1984-09-26 |
| CA1177723A (en) | 1984-11-13 |
| PT74586A (en) | 1982-04-01 |
| US4500348A (en) | 1985-02-19 |
| PT74586B (en) | 1983-11-07 |
| AU549148B2 (en) | 1986-01-16 |
| DK137982A (da) | 1982-09-27 |
| AU8180882A (en) | 1982-09-30 |
| ATE13617T1 (de) | 1985-06-15 |
| ES510817A0 (es) | 1983-11-16 |
| DK158284B (da) | 1990-04-30 |
| TR21440A (tr) | 1984-06-04 |
| AR229606A1 (es) | 1983-09-30 |
| IL65323A0 (en) | 1982-05-31 |
| JPS57165026A (en) | 1982-10-09 |
| KR830008488A (ko) | 1983-12-10 |
| EP0062181B1 (de) | 1985-06-05 |
| DE3263998D1 (en) | 1985-07-11 |
| DE3111934A1 (de) | 1982-10-07 |
| BR8201716A (pt) | 1983-02-22 |
| JPH0336568B2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1991-05-31 |
| ES8400890A1 (es) | 1983-11-16 |
| KR890002071B1 (ko) | 1989-06-16 |
| DK158284C (da) | 1990-10-01 |
| EP0062181A1 (de) | 1982-10-13 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| HU90 | Patent valid on 900628 | ||
| HMM4 | Cancellation of final prot. due to non-payment of fee |