HRP950206A2 - Polyurethanes reinforced with rigid rod micro fillers and process for making the same - Google Patents
Polyurethanes reinforced with rigid rod micro fillers and process for making the same Download PDFInfo
- Publication number
- HRP950206A2 HRP950206A2 HRP-1177/87A HRP950206A HRP950206A2 HR P950206 A2 HRP950206 A2 HR P950206A2 HR P950206 A HRP950206 A HR P950206A HR P950206 A2 HRP950206 A2 HR P950206A2
- Authority
- HR
- Croatia
- Prior art keywords
- polymer
- polyurethane
- active hydrogen
- solid polymer
- preparation
- Prior art date
Links
- 229920002635 polyurethane Polymers 0.000 title claims description 53
- 239000004814 polyurethane Substances 0.000 title claims description 53
- 238000000034 method Methods 0.000 title claims description 8
- 239000000945 filler Substances 0.000 title description 17
- 229920000642 polymer Polymers 0.000 claims description 101
- 239000007787 solid Substances 0.000 claims description 38
- 239000001257 hydrogen Substances 0.000 claims description 34
- 229910052739 hydrogen Inorganic materials 0.000 claims description 34
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 30
- 150000001875 compounds Chemical class 0.000 claims description 27
- 239000002245 particle Substances 0.000 claims description 20
- 239000006185 dispersion Substances 0.000 claims description 19
- 239000005056 polyisocyanate Substances 0.000 claims description 19
- 229920001228 polyisocyanate Polymers 0.000 claims description 19
- 238000002360 preparation method Methods 0.000 claims description 17
- 238000006243 chemical reaction Methods 0.000 claims description 12
- 230000001413 cellular effect Effects 0.000 claims description 10
- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 claims description 9
- 238000002844 melting Methods 0.000 claims description 8
- 230000008018 melting Effects 0.000 claims description 8
- 238000006116 polymerization reaction Methods 0.000 claims description 6
- YBRVSVVVWCFQMG-UHFFFAOYSA-N 4,4'-diaminodiphenylmethane Chemical compound C1=CC(N)=CC=C1CC1=CC=C(N)C=C1 YBRVSVVVWCFQMG-UHFFFAOYSA-N 0.000 claims description 5
- 238000011065 in-situ storage Methods 0.000 claims description 5
- 150000004984 aromatic diamines Chemical class 0.000 claims description 4
- 150000002431 hydrogen Chemical class 0.000 claims description 4
- 238000005728 strengthening Methods 0.000 claims description 2
- 239000000243 solution Substances 0.000 description 19
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical group CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 15
- 239000000203 mixture Substances 0.000 description 13
- 229920005862 polyol Polymers 0.000 description 13
- 150000003077 polyols Chemical class 0.000 description 13
- 239000002904 solvent Substances 0.000 description 11
- 239000003054 catalyst Substances 0.000 description 8
- 230000000052 comparative effect Effects 0.000 description 8
- -1 for example Substances 0.000 description 8
- 239000010408 film Substances 0.000 description 7
- 229920000570 polyether Polymers 0.000 description 7
- 229920003225 polyurethane elastomer Polymers 0.000 description 7
- 229920003252 rigid-rod polymer Polymers 0.000 description 7
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- 239000004721 Polyphenylene oxide Substances 0.000 description 6
- KWGKDLIKAYFUFQ-UHFFFAOYSA-M lithium chloride Chemical compound [Li+].[Cl-] KWGKDLIKAYFUFQ-UHFFFAOYSA-M 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- 229920006264 polyurethane film Polymers 0.000 description 6
- 230000002787 reinforcement Effects 0.000 description 6
- 229920002396 Polyurea Polymers 0.000 description 5
- 229920005830 Polyurethane Foam Polymers 0.000 description 5
- 125000003118 aryl group Chemical group 0.000 description 5
- 239000003795 chemical substances by application Substances 0.000 description 5
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 description 5
- 239000011496 polyurethane foam Substances 0.000 description 5
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 4
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 4
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 4
- 239000000835 fiber Substances 0.000 description 4
- 239000011521 glass Substances 0.000 description 4
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 239000000178 monomer Substances 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical class ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- 239000007795 chemical reaction product Substances 0.000 description 3
- 229920001971 elastomer Polymers 0.000 description 3
- 239000000806 elastomer Substances 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 238000000465 moulding Methods 0.000 description 3
- 125000002524 organometallic group Chemical group 0.000 description 3
- 230000000704 physical effect Effects 0.000 description 3
- 229920003226 polyurethane urea Polymers 0.000 description 3
- 239000002244 precipitate Substances 0.000 description 3
- 238000010107 reaction injection moulding Methods 0.000 description 3
- 239000012744 reinforcing agent Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- ALQLPWJFHRMHIU-UHFFFAOYSA-N 1,4-diisocyanatobenzene Chemical compound O=C=NC1=CC=C(N=C=O)C=C1 ALQLPWJFHRMHIU-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 239000004971 Cross linker Substances 0.000 description 2
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- 239000004952 Polyamide Substances 0.000 description 2
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 150000001335 aliphatic alkanes Chemical class 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 229910000019 calcium carbonate Inorganic materials 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000006260 foam Substances 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 239000003999 initiator Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000011159 matrix material Substances 0.000 description 2
- 238000003541 multi-stage reaction Methods 0.000 description 2
- 239000012299 nitrogen atmosphere Substances 0.000 description 2
- 229920002647 polyamide Polymers 0.000 description 2
- 229920005906 polyester polyol Polymers 0.000 description 2
- 229920000582 polyisocyanurate Polymers 0.000 description 2
- 230000003014 reinforcing effect Effects 0.000 description 2
- 150000003335 secondary amines Chemical class 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- CDMDQYCEEKCBGR-UHFFFAOYSA-N 1,4-diisocyanatocyclohexane Chemical compound O=C=NC1CCC(N=C=O)CC1 CDMDQYCEEKCBGR-UHFFFAOYSA-N 0.000 description 1
- CBCKQZAAMUWICA-UHFFFAOYSA-N 1,4-phenylenediamine Chemical compound NC1=CC=C(N)C=C1 CBCKQZAAMUWICA-UHFFFAOYSA-N 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- 229920002799 BoPET Polymers 0.000 description 1
- 239000004970 Chain extender Substances 0.000 description 1
- VOPWNXZWBYDODV-UHFFFAOYSA-N Chlorodifluoromethane Chemical class FC(F)Cl VOPWNXZWBYDODV-UHFFFAOYSA-N 0.000 description 1
- 239000004338 Dichlorodifluoromethane Chemical class 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical class S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- 239000005057 Hexamethylene diisocyanate Substances 0.000 description 1
- 239000005058 Isophorone diisocyanate Substances 0.000 description 1
- 239000005041 Mylar™ Substances 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 230000003321 amplification Effects 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- HIFVAOIJYDXIJG-UHFFFAOYSA-N benzylbenzene;isocyanic acid Chemical class N=C=O.N=C=O.C=1C=CC=CC=1CC1=CC=CC=C1 HIFVAOIJYDXIJG-UHFFFAOYSA-N 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 150000007942 carboxylates Chemical class 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- PXBRQCKWGAHEHS-UHFFFAOYSA-N dichlorodifluoromethane Chemical class FC(F)(Cl)Cl PXBRQCKWGAHEHS-UHFFFAOYSA-N 0.000 description 1
- 235000019404 dichlorodifluoromethane Nutrition 0.000 description 1
- UMNKXPULIDJLSU-UHFFFAOYSA-N dichlorofluoromethane Chemical class FC(Cl)Cl UMNKXPULIDJLSU-UHFFFAOYSA-N 0.000 description 1
- 229940099364 dichlorofluoromethane Drugs 0.000 description 1
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 1
- 238000000113 differential scanning calorimetry Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000005337 ground glass Substances 0.000 description 1
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 239000011256 inorganic filler Substances 0.000 description 1
- 229910003475 inorganic filler Inorganic materials 0.000 description 1
- 229910017053 inorganic salt Inorganic materials 0.000 description 1
- 239000012948 isocyanate Substances 0.000 description 1
- 150000002513 isocyanates Chemical class 0.000 description 1
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical compound OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 description 1
- NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical class C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 238000003199 nucleic acid amplification method Methods 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920006149 polyester-amide block copolymer Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920006254 polymer film Polymers 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 150000003141 primary amines Chemical class 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 125000000467 secondary amino group Chemical group [H]N([*:1])[*:2] 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 150000003512 tertiary amines Chemical class 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- RUELTTOHQODFPA-UHFFFAOYSA-N toluene 2,6-diisocyanate Chemical compound CC1=C(N=C=O)C=CC=C1N=C=O RUELTTOHQODFPA-UHFFFAOYSA-N 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
- 239000010456 wollastonite Substances 0.000 description 1
- 229910052882 wollastonite Inorganic materials 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/82—Post-polymerisation treatment
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/0838—Manufacture of polymers in the presence of non-reactive compounds
- C08G18/0842—Manufacture of polymers in the presence of non-reactive compounds in the presence of liquid diluents
- C08G18/0861—Manufacture of polymers in the presence of non-reactive compounds in the presence of liquid diluents in the presence of a dispersing phase for the polymers or a phase dispersed in the polymers
- C08G18/0871—Manufacture of polymers in the presence of non-reactive compounds in the presence of liquid diluents in the presence of a dispersing phase for the polymers or a phase dispersed in the polymers the dispersing or dispersed phase being organic
- C08G18/0876—Manufacture of polymers in the presence of non-reactive compounds in the presence of liquid diluents in the presence of a dispersing phase for the polymers or a phase dispersed in the polymers the dispersing or dispersed phase being organic the dispersing or dispersed phase being a polyol
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L75/00—Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
- C08L75/04—Polyurethanes
Landscapes
- Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Engineering & Computer Science (AREA)
- Polyurethanes Or Polyureas (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Springs (AREA)
- Laminated Bodies (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US06/878,451 US4701475A (en) | 1986-06-25 | 1986-06-25 | Polyurethanes reinforced with rigid rod micro fillers |
| YU117787A YU46797B (sh) | 1986-06-25 | 1987-06-24 | Postupak za dobijanje ojačanog poliuretanskog polimera |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| HRP950206A2 true HRP950206A2 (en) | 1997-08-31 |
Family
ID=25372063
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| HRP-1177/87A HRP950206A2 (en) | 1986-06-25 | 1995-03-31 | Polyurethanes reinforced with rigid rod micro fillers and process for making the same |
Country Status (19)
| Country | Link |
|---|---|
| US (2) | US4701475A (ja) |
| EP (1) | EP0250977B1 (ja) |
| JP (1) | JPS6322818A (ja) |
| KR (1) | KR900003466B1 (ja) |
| AR (1) | AR242971A1 (ja) |
| AT (1) | ATE87643T1 (ja) |
| AU (1) | AU609042B2 (ja) |
| BR (1) | BR8703197A (ja) |
| CA (1) | CA1310148C (ja) |
| DD (2) | DD280535A5 (ja) |
| DE (1) | DE3785091T2 (ja) |
| DK (1) | DK326087A (ja) |
| ES (1) | ES2039376T3 (ja) |
| FI (1) | FI872780A (ja) |
| HR (1) | HRP950206A2 (ja) |
| NO (1) | NO170288C (ja) |
| NZ (1) | NZ220794A (ja) |
| YU (1) | YU46797B (ja) |
| ZA (1) | ZA874249B (ja) |
Families Citing this family (31)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5110852A (en) * | 1982-07-16 | 1992-05-05 | Rijksuniversiteit Te Groningen | Filament material polylactide mixtures |
| JPS6321118A (ja) * | 1986-07-14 | 1988-01-28 | Toyota Motor Corp | 強化反応射出成形方法 |
| US4894403A (en) * | 1987-07-14 | 1990-01-16 | The Dow Chemical Company | Polyisocyanate compositions containing rigid compounds or polymers, and polyurethanes prepared therefrom |
| BR8807617A (pt) * | 1987-07-14 | 1990-06-12 | Dow Chemical Co | Pre-polimeros de poliisocianato preparados a partir de materiais precursores poliaromaticos rigidos e poliuretanos preparados a partir dos mesmos |
| US5024785A (en) * | 1989-01-17 | 1991-06-18 | The Dow Chemical Company | Liquid crystal/rigid rodlike polymer modified epoxy/vinyl ester resins |
| US4962163A (en) * | 1989-01-17 | 1990-10-09 | The Dow Chemical Company | Vinyl ester resins containing mesogenic/rigid rodlike moieties |
| US5164464A (en) * | 1989-01-17 | 1992-11-17 | The Dow Chemical Company | Vinyl ester resins containing mesogenic/rigid rodlike moieties |
| US5373043A (en) * | 1989-09-13 | 1994-12-13 | The Dow Chemical Company | Particulate polymers and stabilizer compounds and polymer compositions prepared therefrom |
| US5362822A (en) * | 1990-08-03 | 1994-11-08 | The Dow Chemical Company | Mesogenic adducts |
| US5276184A (en) * | 1990-08-03 | 1994-01-04 | The Dow Chemical Company | Sulfonamide compounds containing mesogenic moieties |
| CA2131048C (en) * | 1993-09-17 | 2006-01-31 | Michael F. Hurley | Process for the preparation of filled urethane-based reinforced moldings and the resultant products |
| DE4401217A1 (de) * | 1994-01-18 | 1995-07-20 | Bayer Ag | Polymerblends |
| US20020058774A1 (en) | 2000-09-06 | 2002-05-16 | Kurth Thomas M. | Transesterified polyol having selectable and increased functionality and urethane material products formed using the polyol |
| US6979477B2 (en) | 2000-09-06 | 2005-12-27 | Urethane Soy Systems Company | Vegetable oil-based coating and method for application |
| US20030191274A1 (en) | 2001-10-10 | 2003-10-09 | Kurth Thomas M. | Oxylated vegetable-based polyol having increased functionality and urethane material formed using the polyol |
| US7063877B2 (en) | 1998-09-17 | 2006-06-20 | Urethane Soy Systems Company, Inc. | Bio-based carpet material |
| US6180686B1 (en) | 1998-09-17 | 2001-01-30 | Thomas M. Kurth | Cellular plastic material |
| US6962636B2 (en) | 1998-09-17 | 2005-11-08 | Urethane Soy Systems Company, Inc. | Method of producing a bio-based carpet material |
| US8575226B2 (en) | 1998-09-17 | 2013-11-05 | Rhino Linings Corporation | Vegetable oil-based coating and method for application |
| US7182981B1 (en) * | 1999-07-06 | 2007-02-27 | Konica Corporation | Cellulose ester film and production method of the same |
| US7537143B1 (en) * | 2003-10-09 | 2009-05-26 | Nike, Inc. | Backpack with external frame |
| CA2599983A1 (en) | 2005-03-03 | 2006-09-08 | South Dakota Soybean Processors, Llc | Novel polyols derived from a vegetable oil using an oxidation process |
| US9518163B2 (en) * | 2008-05-26 | 2016-12-13 | Semmes, Inc. | Reinforced polymer foams, articles and coatings prepared therefrom and methods of making the same |
| US10808123B2 (en) * | 2014-09-23 | 2020-10-20 | The Boeing Company | Nanoparticles for improving the dimensional stability of resins |
| US9862828B2 (en) | 2014-09-23 | 2018-01-09 | The Boeing Company | Polymer nanoparticle additions for resin modification |
| US10160840B2 (en) | 2014-09-23 | 2018-12-25 | The Boeing Company | Polymer nanoparticles for controlling permeability and fiber volume fraction in composites |
| US9845556B2 (en) | 2014-09-23 | 2017-12-19 | The Boeing Company | Printing patterns onto composite laminates |
| US10072126B2 (en) | 2014-09-23 | 2018-09-11 | The Boeing Company | Soluble nanoparticles for composite performance enhancement |
| US10472472B2 (en) | 2014-09-23 | 2019-11-12 | The Boeing Company | Placement of modifier material in resin-rich pockets to mitigate microcracking in a composite structure |
| US9587076B2 (en) | 2014-09-23 | 2017-03-07 | The Boeing Company | Polymer nanoparticles for controlling resin reaction rates |
| US10662302B2 (en) | 2014-09-23 | 2020-05-26 | The Boeing Company | Polymer nanoparticles for improved distortion capability in composites |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3884989A (en) * | 1968-07-24 | 1975-05-20 | Du Pont | Composition, process and article |
| US3872050A (en) * | 1972-07-19 | 1975-03-18 | William J Benton | Polyurethane liquid crystal dispersion system and devices |
| JPS5033297A (ja) * | 1973-07-23 | 1975-03-31 | ||
| DE2513815C3 (de) * | 1975-03-27 | 1979-05-23 | Bayer Ag, 5090 Leverkusen | Verfahren zur Herstellung von stabilen Dispersionen |
| US4102831A (en) * | 1976-10-12 | 1978-07-25 | Osgood Alan A | Imparting anlsotropy to foams by orienting added fibers whereby said fibers become parallely aligned |
| LU76474A1 (ja) * | 1976-12-24 | 1978-07-10 | ||
| US4207407A (en) * | 1978-05-03 | 1980-06-10 | The United States Of America As Represented By The Secretary Of The Air Force | Aromatic heterocyclic polymer alloys and products produced therefrom |
| JPS5616516A (en) * | 1979-07-20 | 1981-02-17 | Mitui Toatsu Chem Inc | Production of polyurethane elastomer |
| JPS56152830A (en) * | 1980-04-28 | 1981-11-26 | Kazuyoshi Iimura | High-molecular liquid crystal |
| US4332716A (en) * | 1980-12-10 | 1982-06-01 | Union Carbide Corporation | Polymer/polyisocyanate compositions, processes for making same and processes for making polyurethane products therefrom |
| US4721735A (en) * | 1986-01-23 | 1988-01-26 | Dentsply Research And Development Corporation | Frangible light cured compositions |
-
1986
- 1986-06-25 US US06/878,451 patent/US4701475A/en not_active Expired - Fee Related
-
1987
- 1987-06-08 CA CA000539047A patent/CA1310148C/en not_active Expired - Fee Related
- 1987-06-12 DE DE8787108484T patent/DE3785091T2/de not_active Expired - Fee Related
- 1987-06-12 ES ES198787108484T patent/ES2039376T3/es not_active Expired - Lifetime
- 1987-06-12 AT AT87108484T patent/ATE87643T1/de not_active IP Right Cessation
- 1987-06-12 EP EP87108484A patent/EP0250977B1/en not_active Expired - Lifetime
- 1987-06-12 ZA ZA874249A patent/ZA874249B/xx unknown
- 1987-06-18 AU AU74449/87A patent/AU609042B2/en not_active Ceased
- 1987-06-22 NZ NZ220794A patent/NZ220794A/xx unknown
- 1987-06-23 DD DD87327855A patent/DD280535A5/de not_active IP Right Cessation
- 1987-06-23 DD DD30409487A patent/DD268959A5/de unknown
- 1987-06-23 FI FI872780A patent/FI872780A/fi not_active Application Discontinuation
- 1987-06-24 YU YU117787A patent/YU46797B/sh unknown
- 1987-06-24 BR BR8703197A patent/BR8703197A/pt not_active IP Right Cessation
- 1987-06-24 KR KR1019870006399A patent/KR900003466B1/ko not_active IP Right Cessation
- 1987-06-24 JP JP62155606A patent/JPS6322818A/ja active Granted
- 1987-06-24 NO NO872638A patent/NO170288C/no unknown
- 1987-06-25 DK DK326087A patent/DK326087A/da not_active Application Discontinuation
- 1987-06-25 AR AR87307960A patent/AR242971A1/es active
- 1987-10-16 US US07/109,548 patent/US4861803A/en not_active Expired - Fee Related
-
1995
- 1995-03-31 HR HRP-1177/87A patent/HRP950206A2/hr not_active Application Discontinuation
Also Published As
| Publication number | Publication date |
|---|---|
| ATE87643T1 (de) | 1993-04-15 |
| NO872638D0 (no) | 1987-06-24 |
| DD280535A5 (de) | 1990-07-11 |
| DE3785091T2 (de) | 1993-07-08 |
| DD268959A5 (de) | 1989-06-14 |
| KR900003466B1 (ko) | 1990-05-19 |
| FI872780A0 (fi) | 1987-06-23 |
| NO872638L (no) | 1987-12-28 |
| NO170288C (no) | 1992-09-30 |
| AR242971A1 (es) | 1993-06-30 |
| BR8703197A (pt) | 1988-03-08 |
| AU609042B2 (en) | 1991-04-26 |
| JPH0541648B2 (ja) | 1993-06-24 |
| ZA874249B (en) | 1989-02-22 |
| DK326087D0 (da) | 1987-06-25 |
| US4701475A (en) | 1987-10-20 |
| KR890000539A (ko) | 1989-03-14 |
| YU117787A (en) | 1988-06-30 |
| US4861803A (en) | 1989-08-29 |
| CA1310148C (en) | 1992-11-10 |
| ES2039376T3 (es) | 1993-10-01 |
| EP0250977A1 (en) | 1988-01-07 |
| NZ220794A (en) | 1990-09-26 |
| YU46797B (sh) | 1994-06-10 |
| DK326087A (da) | 1987-12-26 |
| JPS6322818A (ja) | 1988-01-30 |
| DE3785091D1 (de) | 1993-05-06 |
| AU7444987A (en) | 1988-01-07 |
| FI872780A (fi) | 1987-12-26 |
| NO170288B (no) | 1992-06-22 |
| EP0250977B1 (en) | 1993-03-31 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A1OB | Publication of a patent application | ||
| ODBC | Application rejected |