HRP20191309T1 - Vatrostalna mješavina polimera - Google Patents
Vatrostalna mješavina polimera Download PDFInfo
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- HRP20191309T1 HRP20191309T1 HRP20191309TT HRP20191309T HRP20191309T1 HR P20191309 T1 HRP20191309 T1 HR P20191309T1 HR P20191309T T HRP20191309T T HR P20191309TT HR P20191309 T HRP20191309 T HR P20191309T HR P20191309 T1 HRP20191309 T1 HR P20191309T1
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- Prior art keywords
- mixture
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- ethylene
- propylene
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- 239000000203 mixture Substances 0.000 title claims 43
- 229920000642 polymer Polymers 0.000 title claims 25
- 229920002943 EPDM rubber Polymers 0.000 claims 16
- 229920000181 Ethylene propylene rubber Polymers 0.000 claims 12
- 238000004073 vulcanization Methods 0.000 claims 11
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims 8
- 229920002959 polymer blend Polymers 0.000 claims 8
- 229940117958 vinyl acetate Drugs 0.000 claims 8
- 229920001971 elastomer Polymers 0.000 claims 6
- 229940075065 polyvinyl acetate Drugs 0.000 claims 6
- 229920002689 polyvinyl acetate Polymers 0.000 claims 6
- 239000011118 polyvinyl acetate Substances 0.000 claims 6
- 239000003063 flame retardant Substances 0.000 claims 5
- 238000000034 method Methods 0.000 claims 5
- 229920002725 thermoplastic elastomer Polymers 0.000 claims 5
- OJOWICOBYCXEKR-APPZFPTMSA-N (1S,4R)-5-ethylidenebicyclo[2.2.1]hept-2-ene Chemical compound CC=C1C[C@@H]2C[C@@H]1C=C2 OJOWICOBYCXEKR-APPZFPTMSA-N 0.000 claims 4
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 claims 4
- 150000001336 alkenes Chemical class 0.000 claims 4
- 238000004132 cross linking Methods 0.000 claims 4
- 239000005038 ethylene vinyl acetate Substances 0.000 claims 4
- 239000002480 mineral oil Substances 0.000 claims 4
- 235000010446 mineral oil Nutrition 0.000 claims 4
- 238000000465 moulding Methods 0.000 claims 4
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims 4
- 229920006285 olefinic elastomer Polymers 0.000 claims 4
- 229920001897 terpolymer Polymers 0.000 claims 4
- 229920001169 thermoplastic Polymers 0.000 claims 4
- HECLRDQVFMWTQS-RGOKHQFPSA-N 1755-01-7 Chemical compound C1[C@H]2[C@@H]3CC=C[C@@H]3[C@@H]1C=C2 HECLRDQVFMWTQS-RGOKHQFPSA-N 0.000 claims 3
- 239000000654 additive Substances 0.000 claims 3
- 239000002131 composite material Substances 0.000 claims 3
- 150000001993 dienes Chemical class 0.000 claims 3
- 239000000806 elastomer Substances 0.000 claims 3
- 239000008240 homogeneous mixture Substances 0.000 claims 3
- 238000002844 melting Methods 0.000 claims 3
- 230000008018 melting Effects 0.000 claims 3
- 238000002156 mixing Methods 0.000 claims 3
- 238000007493 shaping process Methods 0.000 claims 3
- 239000000126 substance Substances 0.000 claims 3
- SDJHPPZKZZWAKF-UHFFFAOYSA-N 2,3-dimethylbuta-1,3-diene Chemical compound CC(=C)C(C)=C SDJHPPZKZZWAKF-UHFFFAOYSA-N 0.000 claims 2
- RCJMVGJKROQDCB-UHFFFAOYSA-N 2-methylpenta-1,3-diene Chemical compound CC=CC(C)=C RCJMVGJKROQDCB-UHFFFAOYSA-N 0.000 claims 2
- FUDNBFMOXDUIIE-UHFFFAOYSA-N 3,7-dimethylocta-1,6-diene Chemical compound C=CC(C)CCC=C(C)C FUDNBFMOXDUIIE-UHFFFAOYSA-N 0.000 claims 2
- INYHZQLKOKTDAI-UHFFFAOYSA-N 5-ethenylbicyclo[2.2.1]hept-2-ene Chemical compound C1C2C(C=C)CC1C=C2 INYHZQLKOKTDAI-UHFFFAOYSA-N 0.000 claims 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims 2
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims 2
- 229920001577 copolymer Polymers 0.000 claims 2
- 239000003431 cross linking reagent Substances 0.000 claims 2
- -1 ethylene, propylene Chemical group 0.000 claims 2
- 229920001519 homopolymer Polymers 0.000 claims 2
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 claims 2
- 239000011159 matrix material Substances 0.000 claims 2
- 239000000178 monomer Substances 0.000 claims 2
- 239000002245 particle Substances 0.000 claims 2
- 238000005191 phase separation Methods 0.000 claims 2
- 230000002028 premature Effects 0.000 claims 2
- 230000003068 static effect Effects 0.000 claims 2
- 229910052717 sulfur Inorganic materials 0.000 claims 2
- 239000011593 sulfur Substances 0.000 claims 2
- 239000004416 thermosoftening plastic Substances 0.000 claims 2
- AHAREKHAZNPPMI-AATRIKPKSA-N (3e)-hexa-1,3-diene Chemical compound CC\C=C\C=C AHAREKHAZNPPMI-AATRIKPKSA-N 0.000 claims 1
- PRBHEGAFLDMLAL-GQCTYLIASA-N (4e)-hexa-1,4-diene Chemical compound C\C=C\CC=C PRBHEGAFLDMLAL-GQCTYLIASA-N 0.000 claims 1
- OJOWICOBYCXEKR-KRXBUXKQSA-N (5e)-5-ethylidenebicyclo[2.2.1]hept-2-ene Chemical compound C1C2C(=C/C)/CC1C=C2 OJOWICOBYCXEKR-KRXBUXKQSA-N 0.000 claims 1
- RJUCIROUEDJQIB-GQCTYLIASA-N (6e)-octa-1,6-diene Chemical compound C\C=C\CCCC=C RJUCIROUEDJQIB-GQCTYLIASA-N 0.000 claims 1
- PMJHHCWVYXUKFD-SNAWJCMRSA-N (E)-1,3-pentadiene Chemical compound C\C=C\C=C PMJHHCWVYXUKFD-SNAWJCMRSA-N 0.000 claims 1
- PPWUTZVGSFPZOC-UHFFFAOYSA-N 1-methyl-2,3,3a,4-tetrahydro-1h-indene Chemical compound C1C=CC=C2C(C)CCC21 PPWUTZVGSFPZOC-UHFFFAOYSA-N 0.000 claims 1
- UFERIGCCDYCZLN-UHFFFAOYSA-N 3a,4,7,7a-tetrahydro-1h-indene Chemical compound C1C=CCC2CC=CC21 UFERIGCCDYCZLN-UHFFFAOYSA-N 0.000 claims 1
- VSQLAQKFRFTMNS-UHFFFAOYSA-N 5-methylhexa-1,4-diene Chemical compound CC(C)=CCC=C VSQLAQKFRFTMNS-UHFFFAOYSA-N 0.000 claims 1
- WTQBISBWKRKLIJ-UHFFFAOYSA-N 5-methylidenebicyclo[2.2.1]hept-2-ene Chemical compound C1C2C(=C)CC1C=C2 WTQBISBWKRKLIJ-UHFFFAOYSA-N 0.000 claims 1
- UGJBFMMPNVKBPX-UHFFFAOYSA-N 5-propan-2-ylidenebicyclo[2.2.1]hept-2-ene Chemical compound C1C2C(=C(C)C)CC1C=C2 UGJBFMMPNVKBPX-UHFFFAOYSA-N 0.000 claims 1
- 238000005299 abrasion Methods 0.000 claims 1
- 239000003795 chemical substances by application Substances 0.000 claims 1
- 239000011248 coating agent Substances 0.000 claims 1
- 238000000576 coating method Methods 0.000 claims 1
- 150000001875 compounds Chemical class 0.000 claims 1
- UVJHQYIOXKWHFD-UHFFFAOYSA-N cyclohexa-1,4-diene Chemical compound C1C=CCC=C1 UVJHQYIOXKWHFD-UHFFFAOYSA-N 0.000 claims 1
- ZSWFCLXCOIISFI-UHFFFAOYSA-N cyclopentadiene Chemical compound C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 claims 1
- 238000004079 fireproofing Methods 0.000 claims 1
- 229910052736 halogen Inorganic materials 0.000 claims 1
- 150000002367 halogens Chemical class 0.000 claims 1
- 150000004677 hydrates Chemical class 0.000 claims 1
- 239000004615 ingredient Substances 0.000 claims 1
- 239000000347 magnesium hydroxide Substances 0.000 claims 1
- 229910001862 magnesium hydroxide Inorganic materials 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 claims 1
- 229910052751 metal Inorganic materials 0.000 claims 1
- 239000002184 metal Substances 0.000 claims 1
- 239000012466 permeate Substances 0.000 claims 1
- PMJHHCWVYXUKFD-UHFFFAOYSA-N piperylene Natural products CC=CC=C PMJHHCWVYXUKFD-UHFFFAOYSA-N 0.000 claims 1
- 229920001296 polysiloxane Polymers 0.000 claims 1
- 239000000843 powder Substances 0.000 claims 1
- 238000002360 preparation method Methods 0.000 claims 1
- 239000011253 protective coating Substances 0.000 claims 1
- 229920006395 saturated elastomer Polymers 0.000 claims 1
- 238000012216 screening Methods 0.000 claims 1
- 239000007787 solid Substances 0.000 claims 1
- 239000004071 soot Substances 0.000 claims 1
- 238000003860 storage Methods 0.000 claims 1
- 239000000725 suspension Substances 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/24—Crosslinking, e.g. vulcanising, of macromolecules
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/01—Use of inorganic substances as compounding ingredients characterized by their specific function
- C08K3/016—Flame-proofing or flame-retarding additives
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/04—Carbon
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/38—Boron-containing compounds
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
- C08K5/0016—Plasticisers
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
- C08K5/0066—Flame-proofing or flame-retarding additives
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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- C08K5/00—Use of organic ingredients
- C08K5/01—Hydrocarbons
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing more than three carbon atoms
- C08L23/0815—Copolymers of ethene with aliphatic 1-olefins
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- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/16—Elastomeric ethene-propene or ethene-propene-diene copolymers, e.g. EPR and EPDM rubbers
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- C08L31/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid; Compositions of derivatives of such polymers
- C08L31/02—Homopolymers or copolymers of esters of monocarboxylic acids
- C08L31/04—Homopolymers or copolymers of vinyl acetate
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- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2217—Oxides; Hydroxides of metals of magnesium
- C08K2003/2224—Magnesium hydroxide
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- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
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- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
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Claims (28)
1. Vatrostalna, vulkanizirana mješavina polimera koja kao polimernu komponentu sadrži najmanje jedan olefinski elastomer bez halogena iz skupine M sa zasićenim glavnim lancem uz udio veći od 70 phr u odnosu na polimerne sastojke, gdje je udio omekšivača mineralnog ulja u mješavini manji od ili jednak 50 phr, te gdje su polimerna komponenta ili polimerne komponente mješavine jednofazne i homogene, naznačen time
što kao sredstva za vatrostalnost sadrži najmanje jedan ili kombinaciju različitih metalnih hidrata bez halogena koji otpuštaju vodu uz udio od ukupno 60 do 100 phr,
što je vulkanizirani matriks načinjen uz pomoć sumpora ili sustava za umrežavanje koji sadrži sumpor, gdje se sustav za umrežavanje pruža po cijelom matriksu i posve ga prožima,
te što cijela mješavina ne sadrži halogene.
2. Mješavina u skladu s patentnim zahtjevom 1, naznačena time što sadrži omekšivač mineralnog ulja uz maksimalan udio manji od ili jednak 20 phr, po mogućnosti manji od ili jednak 10 phr, i/ili što mješavina ne sadrži omekšivače mineralnog ulja.
3. Mješavina u skladu s bilo kojim od prethodnih patentnih zahtjeva, naznačena time što sadrži olefinski elastomer bez halogena uz udio od 100 phr kao jedinu polimernu komponentu.
4. Mješavina u skladu s bilo kojim od prethodnih patentnih zahtjeva, naznačena time što kao sredstva za vatrostalnost sadrži magnezijev hidroksid (MDH) i/ili aluminijev hidroksid (ATH), po mogućnosti njihovu smjesu, i/ili što su sredstva za vatrostalnost čvrsta i u obliku praha ili u kristalnom obliku.
5. Mješavina u skladu s bilo kojim od prethodnih patentnih zahtjeva, naznačena time što je olefinski elastomer homopolimer ili kopolimer ili terpolimer načinjen od ili ima dienske monomerne jedinice, osobito terpolimer koji se sastoji od etilena, propilena i dien koji sadrži termonomer, po mogućnosti uz udio termonomera od najmanje 0 %, težinski, do 12 %, težinski, u odnosu na olefinski elastomer.
6. Mješavina u skladu s bilo kojim od prethodnih patentnih zahtjeva, naznačena time što olefinski elastomer se bira iz skupine koju čine etilen-propilen-dienska guma (EPDM) i etilen-propilenska guma (EPM) i/ili što mješavina etilen-propilen-dienske gume (EPDM) i etilen-propilenske gume (EPM) postoji kao jednopolimerne komponente.
7. Mješavina u skladu s bilo kojim od prethodnih patentnih zahtjeva, naznačena time što je olefinski elastomer guma s bočnom nezasićenom skupinom, osobito etilen-propilen-dienska guma (EPDM), koja po mogućnosti ima nekonjugirane dienske monomerne jedinice, koje se bira iz skupine koju čine 1,3-butadien, 2-metil-1,3-butadien (izopren), 2,3-dimetil-1,3-butadien, 1,3-pentadien, 1,3-ciklopentadien, diciklopentadien, 2-metil-1,3-pentadien, 1,3-heksadien, 1,4-heksadien, 1,4-cikloheksadien, tetrahidroinden, metiltetrahidroinden, etilidennorbornen ili 5-etiliden-2-norbornen (ENB), 5-metilen-2-norbornen (MNB), 1,6-oktadien, 5-metil-1,4-heksadien, 3,7-dimetil-1,6-oktadien, 5-izopropiliden-2-norbornen, 5-vinil-2-norbornen (VNB), gdje je etilen-propilen-dienska guma (EPDM) po mogućnosti terpolimer načinjen od etilena, propilena i 5-etiliden-2-norbornena (ENB) ili diciklopentadiena (DCPD).
8. Mješavina u skladu s bilo kojim od prethodnih patentnih zahtjeva, naznačena time što sadrži najmanje jednu dodatnu polimernu komponentu, osobito elastomer iz skupine R ili iz skupine Q (silikon) ili termoplastični polimer, gdje su osobito polimerne komponente mješavine prisutne kao homogena polimerna smjesa odn. mješavina.
9. Mješavina u skladu s bilo kojim od prethodnih patentnih zahtjeva, naznačena time što kao dodatnu polimernu komponentu sadrži termoplastični polimer koji sadrži vinil-acetat, osobito homopolimer, kopolimer ili terpolimer vinil-acetata i po mogućnosti se bira iz skupine koju čine polivinil-acetat (PVAc) ili etilen-vinil-acetat (EVA).
10. Mješavina u skladu s bilo kojim od prethodnih patentnih zahtjeva, naznačena time što polimer koji sadrži vinil-acetat ima talište ili početak raspona taljenja manji od 150 °C, po mogućnosti manji od 100 °C, te što polimer koji sadrži vinil-acetat ima udio vinil-acetata od 40 do 75 %, težinski, i/ili što je, po potrebi neumreženi, polimer koji sadrži vinil-acetat sadržan u udjelu od 0 do 50 phr.
11. Mješavina u skladu s bilo kojim od prethodnih patentnih zahtjeva, naznačena time što sadrži sljedeće polimerne komponente:
– etilen-propilen-diensku gumu (EPDM) ili
– etilen-propilensku gumu (EPM) ili
– etilen-propilen-diensku gumu (EPDM) i etilen-vinil-acetat (EVA) kao homogenu polimernu smjesu, ili
– etilen-propilensku gumu (EPM) i etilen-vinil-acetat (EVA) kao homogenu polimernu smjesu, ili
– etilen-propilen-diensku gumu (EPDM) i polivinil-acetat (PVAc) kao homogenu polimernu smjesu, ili
– etilen-propilensku gumu (EPM) i polivinil-acetat (PVAc) kao homogenu polimernu smjesu.
12. Mješavina u skladu s bilo kojim od prethodnih patentnih zahtjeva, naznačena time što je polimerna smjesa dizajnirana kao međusobno prožimajuća smjesa lanaca polimera koji sadrži vinil-acetat s, primjerice sumporom umreženih, elastomernim lancima i/ili što su polimerne komponente prisutne kao kemijski u grubu mrežu umrežene trodimenzijski umrežene molekule.
13. Mješavina u skladu s bilo kojim od prethodnih patentnih zahtjeva, naznačena time što su polimerna komponenta ili polimerne komponente mješavine jednofazne i homogene, bez makroskopskog ili pod svjetlosnim mikroskopom vidljivog razdvajanja faza, te što su polimerne komponente prisutne jedna u odnosu na drugu kao uglavnom jednofazna i homogena smjesa, osobito bez makroskopskog ili pod svjetlosnim mikroskopom vidljivog razdvajanja faza, i/ili što mješavina, polimerne komponente ili polimerna smjesa ne sadrži dispergirane vulkanizirane elastomerne čestice, a osobito ne sadrži elastomerne čestice ili domene gume srednjeg promjera većeg od 0,5 µm, osobito većeg od 0,1 µm, po mogućnosti većeg od 0,01 µm.
14. Mješavina u skladu s bilo kojim od prethodnih patentnih zahtjeva, naznačena time što mješavina i u rasponu temperatura upotrebe i u rasponu povišenih temperatura, osobito privremeno također na 150 do 200 °C, ima elastomerna svojstva ili isključivo elastomerna no ne i termoplastična svojstva, a termoplastična svojstva se povuku u pozadinu ili uopće nisu prisutna, ili što mješavina nije dizajnirana kao termoplastični elastomer (TPE), osobito ne kao termoplastični elastomer na bazi olefina (TPE-O) ili kao umreženi termoplastični elastomer na bazi olefina (TPE-V).
15. Mješavina u skladu s bilo kojim od prethodnih patentnih zahtjeva, naznačena time što mješavina u rasponu temperatura do 200 °C nema maksimum taljenja, što je izmjereno dinamičnom diferencijalnom pretražnom klalorimetrijom.
16. Mješavina u skladu s bilo kojim od prethodnih patentnih zahtjeva, naznačena time što mješavina u rasponu temperatura od sobne temperature do otprilike 200 °C ima faktor gubitka (odnos između modula gubitka i modula spremanja uz naprezanje dinamičnog smicanja) od tan δ < 0,3.
17. Mješavina u skladu s bilo kojim od prethodnih patentnih zahtjeva, naznačena time što je se proizvodi ili je se može dobiti proizvodnjom polimernih komponenata miješanjem polimernih komponenata do homogene smjese i, osobito nakon toga, uključivanjem sredstva za umrežavanje, sredstava za vatrostalnost i dodatnih aditiva i/ili pomoćnih tvari, uz izbjegavanje umrežavanja i/ili vulkaniziranja, po mogućnosti na temperaturi od najviše 110 °C, uz naknadno oblikovanje i vulkaniziranje, osobito na povišenoj temperaturi i po potrebi pod tlakom, gdje se vulkaniziranje ne provodi uz naprezanje smicanja.
18. Mješavina u skladu s bilo kojim od prethodnih patentnih zahtjeva, naznačena time što je se može dobiti statičnim vulkaniziranjem uz izbjegavanje naprezanja smicanja ili uz izbjegavanje dinamičnog vulkaniziranja, osobito nakon što je gotovo oblikovanje.
19. Mješavina u skladu s bilo kojim od prethodnih patentnih zahtjeva, naznačena time što sljedeća mješavina sadrži:
– etilen-propilen-diensku gumu (EPDM) ili etilen-propilensku gumu (EPM): 70-100 phr,
– polimer koji sadrži vinil-acetat, osobito etilen-vinil-acetat (EVA): 0-30 phr,
– omekšivač mineralnog ulja: 0-10 phr,
– sredstvo za vatrostalnost, osobito aluminijev hidroksid (ATH): 60 do 100 phr,
– čađa: 0-80 phr,
– preostale pomoćne tvari, aditivi itd.
20. Mješavina u skladu s bilo kojim od prethodnih patentnih zahtjeva, naznačena time što ima tvrdoću od 40 do 90 Shore A, po mogućnosti 55 do 85, Shore A i/ili vlačnu čvrstoću > 5 MPa, po mogućnosti > 7 MPa, i/ili abraziju < 400 mm3, po mogućnosti < 300 mm3, i/ili gustoću < 1,4 g/cm3, po mogućnosti < 1,3 g/cm3, i/ili MARHE vrijednost (ISO 5660-1) < 90 kw/m2, osobito < 60 kW/m2, te ispunjava normu EN 45545-2.
21. Postupak proizvodnje mješavine u skladu s bilo kojim od prethodnih patentnih zahtjeva, naznačen time što
– najprije se jednu ili više polimernih komponenata, sredstvo za umrežavanje, jedno ili više sredstava za vatrostalnost i po potrebi dodatne aditive i pomoćne tvari miješa uz izbjegavanje umrežavanja i/ili vulkaniziranja kako bi se dobilo homogenu smjesu,
– zatim slijedi korak oblikovanja,
– te se zatim, najranije tijekom ili na kraju oblikovanja, osobito nakon što je oblikovanje gotovo, vulkaniziranje provodi kao statično, nedinamično vulkaniziranje uz izbjegavanje naprezanja smicanja.
22. Postupak u skladu s patentnim zahtjevom 21, naznačen time što se pravljenje smjese prije oblikovanja provodi na temperaturi i u vremenskom periodu koji nisu kritični za prerano vulkaniziranje, osobito na temperaturi od najviše 125 °C, po mogućnosti u rasponu od 50 °C do najviše 110 °C, i/ili što su smjesa odn. jedna ili više polimernih komponenata prisutne tijekom miješanja u omekšanom stanju.
23. Postupak u skladu s patentnim zahtjevom 21 ili 22, naznačen time što se oblikovanje provodi na temperaturi i u vremenskom periodu koji nisu kritični za prerano vulkaniziranje, osobito na temperaturi od najviše 130 °C, osobito u rasponu od 70 °C do 100 °C.
24. Postupak u skladu s bilo kojim od prethodnih patentnih zahtjeva 21 do 23, naznačen time što se vulkaniziranje provodi na temperaturi od najviše 240 °C, osobito u rasponu od 160 °C do 180 °C, po mogućnosti na višoj temperaturi nego miješanje i/ili oblikovanje, osobito pod tlakom od 100 do 200 bara.
25. Mješavina osobito u skladu s bilo kojim od patentnih zahtjeva 1 do 20, naznačena time što je se može dobiti postupkom u skladu s bilo kojim od patentnih zahtjeva 21 do 24.
26. Vatrostalni artikl, naznačen time što sadrži/ili se sastoji od mješavine u skladu s bilo kojim od prethodnih patentnih zahtjeva.
27. Elastični vatrostalni kompozitni element, pogodan za prigušivanje vibracija i za ovjes opruge, naznačen time što ima osnovno tijelo, osobito načinjeno od gume, koje u najmanju ruku djelomično ili po odjeljcima, na svojoj vanjskoj površini, po potrebi na svojoj cijeloj vanjskoj površini, ima najmanje jednu oblogu načinjenu od mješavine u skladu s bilo kojim od prethodnih patentnih zahtjeva.
28. Upotreba mješavine, artikla ili kompozitnog elementa u skladu s bilo kojim od prethodnih patentnih zahtjeva, naznačena time što se mješavinu, artikl ili kompozitni element upotrebljava kao element opruge, amortizirajući element, brtvu, cijev, strunjaču, oblikovni element, zaštitnu oblogu, kao elastomerni profil.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| ATA50240/2015A AT517060B1 (de) | 2015-03-25 | 2015-03-25 | Flammgeschützte polymere Zusammensetzung |
| PCT/AT2016/050078 WO2016149729A1 (de) | 2015-03-25 | 2016-03-24 | Flammgeschützte polymere zusammensetzung |
| EP16719002.4A EP3274402B1 (de) | 2015-03-25 | 2016-03-24 | Flammgeschützte polymere zusammensetzung |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| HRP20191309T1 true HRP20191309T1 (hr) | 2019-10-18 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| HRP20191309TT HRP20191309T1 (hr) | 2015-03-25 | 2019-07-19 | Vatrostalna mješavina polimera |
Country Status (14)
| Country | Link |
|---|---|
| US (2) | US10472489B2 (hr) |
| EP (2) | EP3274402B1 (hr) |
| JP (1) | JP2018509521A (hr) |
| CN (2) | CN109354781A (hr) |
| AT (1) | AT517060B1 (hr) |
| AU (1) | AU2016236815B2 (hr) |
| ES (1) | ES2737407T3 (hr) |
| HR (1) | HRP20191309T1 (hr) |
| HU (1) | HUE044955T2 (hr) |
| PL (1) | PL3274402T3 (hr) |
| RU (1) | RU2686903C2 (hr) |
| SI (1) | SI3274402T1 (hr) |
| TR (1) | TR201910672T4 (hr) |
| WO (1) | WO2016149729A1 (hr) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR3049029B1 (fr) | 2016-03-18 | 2018-03-09 | Hutchinson | Dispositif antivibratoire tenant au feu destine a une application ferroviaire |
| CN107513200A (zh) * | 2017-09-07 | 2017-12-26 | 浙江大学宁波理工学院 | 聚乙烯/金属氢氧化物/纳米炭黑阻燃材料及其制备方法 |
| DE102017223545A1 (de) * | 2017-12-21 | 2019-06-27 | Contitech Luftfedersysteme Gmbh | Artikel, insbesondere ein Luftfederbalg, ein Metall-Gummi-Element oder ein Schwingungsdämpfer |
| GB2571701A (en) * | 2017-12-22 | 2019-09-11 | Eaton Intelligent Power Ltd | Rubber composition for a cover layer of a hydraulic hose, hydraulic hose, and method for producing the hydraulic hose |
| CN111171437B (zh) * | 2020-01-21 | 2023-10-20 | 苏州希普拉斯新材料有限公司 | 耐曲挠柔软热塑性低烟无卤阻燃聚烯烃护套料及其制备方法 |
| KR20230050415A (ko) * | 2020-08-13 | 2023-04-14 | 다우 글로벌 테크놀로지스 엘엘씨 | 할로겐 비함유 난연성 엘라스토머 조성물, 이로부터 제조된 물품 및 이의 제조 방법 |
| US11691576B2 (en) | 2021-07-28 | 2023-07-04 | Ford Global Technologies, Llc | High thermal tolerance shield |
| DE102021130725A1 (de) * | 2021-11-24 | 2023-05-25 | Phoenix Compounding Technology GmbH | Flammgeschützte elastomerzusammensetzung, verfahren zur herstellung derselben und verwendung in brandschutzanwendungen |
| EP4230685A1 (de) * | 2022-02-18 | 2023-08-23 | Salamander SPS GmbH & Co. KG | Flammschutz-verbundmaterial |
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| US4373048A (en) * | 1980-04-21 | 1983-02-08 | Amp Incorporated | High voltage flame retardant EPOM insulating compositions |
| JPS60179436A (ja) * | 1984-02-27 | 1985-09-13 | Shin Etsu Chem Co Ltd | 難燃性ポリオレフイン系ゴム組成物 |
| CN1009275B (zh) * | 1984-08-14 | 1990-08-22 | 藤电线株式会社 | 阻燃性组合物以及使用该组合物制成的阻燃性电缆 |
| US4671896A (en) | 1984-08-14 | 1987-06-09 | Fujikura Ltd. | Flame-retardant composition and flame-retardant cable using same |
| EP0280761B1 (en) * | 1987-03-02 | 1993-03-03 | Sumitomo Bakelite Company Limited | Flame-retardant olefinic resin composition |
| US4851463A (en) * | 1988-02-19 | 1989-07-25 | E. I. Du Pont De Nemours And Company | Ethylene copolymer compositions having improved fire retardancy |
| JPH01217050A (ja) * | 1988-02-26 | 1989-08-30 | Tonen Sekiyukagaku Kk | 難燃性熱可塑性エラストマー組成物 |
| DE3831894A1 (de) | 1988-09-20 | 1990-05-17 | Continental Ag | Schwerentflammbare elastische dichtung |
| US7378463B2 (en) * | 2004-02-04 | 2008-05-27 | Enerdel, Inc. | Halogen-free fire retardant system for low heat release polymers |
| DE10248174C1 (de) * | 2002-10-16 | 2003-11-13 | Nabaltec Gmbh | Flammgeschützte Polymerzusammensetzung und deren Verwendung sowie Verfahren zur Herstellung eines Flammschutzmittels |
| DE10348479A1 (de) * | 2003-10-14 | 2005-06-02 | Tesa Ag | Wickelfolie aus Polypropylencopolymer und einem mit Polypropylen unverträglichen Polymer |
| JP2005272581A (ja) * | 2004-03-24 | 2005-10-06 | Yazaki Corp | 難燃樹脂組成物 |
| DK1862496T3 (da) * | 2006-05-31 | 2013-02-11 | Borealis Tech Oy | Flammehæmmende polyethylensammensætning, omfattende polypropylen |
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| CN101921436A (zh) * | 2010-09-19 | 2010-12-22 | 无锡宝通带业股份有限公司 | 一种耐高温阻燃输送带表面覆盖胶及其制备方法 |
| JP6171666B2 (ja) * | 2012-08-01 | 2017-08-02 | 住友化学株式会社 | 難燃性熱可塑性エラストマー組成物の製造方法 |
| AT512907B1 (de) | 2012-08-02 | 2013-12-15 | Bategu Gummitechnologie Gmbh & Co Kg | Flammgeschützte polymere Zusammensetzung |
| CN103146081B (zh) * | 2013-03-01 | 2015-07-29 | 江阴海达橡塑股份有限公司 | 一种可挤出成型的高阻燃橡胶材料及其制备方法 |
| JP5590177B1 (ja) * | 2013-03-29 | 2014-09-17 | 日立金属株式会社 | 無リン系ノンハロゲン難燃絶縁電線および無リン系ノンハロゲン難燃絶縁ケーブル |
| CN103554686A (zh) * | 2013-10-31 | 2014-02-05 | 扬州大学 | 一种辐射硫化三元乙丙橡胶阻燃汽车胶管的生产方法 |
| CN105400086B (zh) * | 2015-12-21 | 2018-01-16 | 潍坊市宏源防水材料有限公司 | 一种阻燃型epdm防水卷材及其生产工艺 |
-
2015
- 2015-03-25 AT ATA50240/2015A patent/AT517060B1/de active
-
2016
- 2016-03-24 AU AU2016236815A patent/AU2016236815B2/en not_active Ceased
- 2016-03-24 CN CN201811172127.6A patent/CN109354781A/zh active Pending
- 2016-03-24 EP EP16719002.4A patent/EP3274402B1/de active Active
- 2016-03-24 HU HUE16719002A patent/HUE044955T2/hu unknown
- 2016-03-24 WO PCT/AT2016/050078 patent/WO2016149729A1/de active Application Filing
- 2016-03-24 PL PL16719002T patent/PL3274402T3/pl unknown
- 2016-03-24 JP JP2018500824A patent/JP2018509521A/ja not_active Withdrawn
- 2016-03-24 SI SI201630325T patent/SI3274402T1/sl unknown
- 2016-03-24 RU RU2017135120A patent/RU2686903C2/ru active
- 2016-03-24 ES ES16719002T patent/ES2737407T3/es active Active
- 2016-03-24 US US15/560,925 patent/US10472489B2/en active Active
- 2016-03-24 TR TR2019/10672T patent/TR201910672T4/tr unknown
- 2016-03-24 CN CN201680018175.2A patent/CN107735447A/zh active Pending
- 2016-03-24 EP EP19158664.3A patent/EP3524636A1/de not_active Withdrawn
-
2019
- 2019-07-19 HR HRP20191309TT patent/HRP20191309T1/hr unknown
- 2019-10-01 US US16/589,577 patent/US20200032030A1/en not_active Abandoned
Also Published As
| Publication number | Publication date |
|---|---|
| PL3274402T3 (pl) | 2019-10-31 |
| AT517060B1 (de) | 2017-03-15 |
| EP3274402A1 (de) | 2018-01-31 |
| AU2016236815A1 (en) | 2017-10-12 |
| HUE044955T2 (hu) | 2019-12-30 |
| SI3274402T1 (sl) | 2019-09-30 |
| AU2016236815B2 (en) | 2019-12-19 |
| RU2017135120A3 (hr) | 2019-04-08 |
| TR201910672T4 (tr) | 2019-08-21 |
| AT517060A1 (de) | 2016-10-15 |
| CN107735447A (zh) | 2018-02-23 |
| WO2016149729A1 (de) | 2016-09-29 |
| RU2686903C2 (ru) | 2019-05-06 |
| US20180051157A1 (en) | 2018-02-22 |
| EP3274402B1 (de) | 2019-04-24 |
| JP2018509521A (ja) | 2018-04-05 |
| ES2737407T3 (es) | 2020-01-14 |
| CN109354781A (zh) | 2019-02-19 |
| EP3524636A1 (de) | 2019-08-14 |
| US10472489B2 (en) | 2019-11-12 |
| US20200032030A1 (en) | 2020-01-30 |
| RU2017135120A (ru) | 2019-04-08 |
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