HRP20170871T1 - Pripravak za omekšavanje tekstila - Google Patents

Pripravak za omekšavanje tekstila Download PDF

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Publication number
HRP20170871T1
HRP20170871T1 HRP20170871TT HRP20170871T HRP20170871T1 HR P20170871 T1 HRP20170871 T1 HR P20170871T1 HR P20170871T T HRP20170871T T HR P20170871TT HR P20170871 T HRP20170871 T HR P20170871T HR P20170871 T1 HRP20170871 T1 HR P20170871T1
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Croatia
Prior art keywords
preparation
methyl
fabric
fabric softening
component
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HRP20170871TT
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English (en)
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Hans-Jürgen Köhle
Ulrike Kottke
Hans Henning Wenk
Harald Jakob
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Evonik Degussa Gmbh
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Publication of HRP20170871T1 publication Critical patent/HRP20170871T1/hr

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    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/835Mixtures of non-ionic with cationic compounds
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C213/00Preparation of compounds containing amino and hydroxy, amino and etherified hydroxy or amino and esterified hydroxy groups bound to the same carbon skeleton
    • C07C213/06Preparation of compounds containing amino and hydroxy, amino and etherified hydroxy or amino and esterified hydroxy groups bound to the same carbon skeleton from hydroxy amines by reactions involving the etherification or esterification of hydroxy groups
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C219/00Compounds containing amino and esterified hydroxy groups bound to the same carbon skeleton
    • C07C219/02Compounds containing amino and esterified hydroxy groups bound to the same carbon skeleton having esterified hydroxy groups and amino groups bound to acyclic carbon atoms of the same carbon skeleton
    • C07C219/04Compounds containing amino and esterified hydroxy groups bound to the same carbon skeleton having esterified hydroxy groups and amino groups bound to acyclic carbon atoms of the same carbon skeleton the carbon skeleton being acyclic and saturated
    • C07C219/06Compounds containing amino and esterified hydroxy groups bound to the same carbon skeleton having esterified hydroxy groups and amino groups bound to acyclic carbon atoms of the same carbon skeleton the carbon skeleton being acyclic and saturated having the hydroxy groups esterified by carboxylic acids having the esterifying carboxyl groups bound to hydrogen atoms or to acyclic carbon atoms of an acyclic saturated carbon skeleton
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38Cationic compounds
    • C11D1/62Quaternary ammonium compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005Other compounding ingredients characterised by their effect
    • C11D3/001Softening compositions
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005Other compounding ingredients characterised by their effect
    • C11D3/001Softening compositions
    • C11D3/0015Softening compositions liquid
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/2003Alcohols; Phenols
    • C11D3/2006Monohydric alcohols
    • C11D3/201Monohydric alcohols linear
    • C11D3/2013Monohydric alcohols linear fatty or with at least 8 carbon atoms in the alkyl chain
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/2075Carboxylic acids-salts thereof
    • C11D3/2079Monocarboxylic acids-salts thereof
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/667Neutral esters, e.g. sorbitan esters

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Claims (16)

1. Pripravak za omekšavanje tkanine naznačen time da sadrži a) kao komponentu A barem jednu tercijarnu ili kvarternarnu amonijevu sol, koja je odabrana od spojeva s formulama (I) i (II): R1R2R3N+CH2CHR4OC(=O) R5 X-(I) R1R2R3N+(CH2)3NHC(=O)R5 X- (II) u kojima R1 je vodik, metil ili etil, R2 i R3, međusobno neovisno, su C1-4 alkil ili C2-4 hidroksialkil, R4 je vodik ili metil, R5 je ravni C15-21 alkil ili alkenil radikal i X- je jednovalentni anion, i b) kao komponentu B barem jedan neionski omekšivač koji ima samo jedan dugo-lančani radikal ugljikovodika koji ima 15 do 21 ugljikovih atoma vezan na polarni radikal, gdje polarni radikal sadrži najviše 9 ugljikovih atoma i nosi barem jednu slobodnu hidroksi skupinu, koja sadrži alkoholne hidroksi skupine vezane na zasićeni ugljikov atom i karboksilne hidroksi skupine vezane na karbonil ugljikov atom, te gdje neionski omekšivač nije alkoksilat masnog alkohola ili alkoksilat masne kiseline, gdje i) molarni omjer ukupne količine komponente A prema ukupnoj količini komponente B je u rasponu od 2:1 do 1:3, ii) razlika između prosječne duljine lanca dugo-lančanih radikala ugljikovodika komponenata A i B je najviše 2 ugljikova atoma, iii) radikali ugljikovodika komponenata A i B imaju u prosjeku u svakom slučaju najviše 0.5 dvostruke veze po radikalu ugljikovodika, iv) ukupna količina tercijarnih i kvaternarnih amonijevih soli, koje nose dva dugo-lančana radikala ugljikovodika od 15 do 21 ugljikovih atoma, u pripravku je najviše 80 mol% i poželjno najviše 50 mol% ukupne količine komponenata A i v) ukupan udio komponenata A i komponenata B u pripravku je barem 50% težinski.
2. Pripravak za omekšavanje tkanine prema zahtjevu 1, naznačen time da je ukupan udio komponenata A i komponenata B u pripravku barem 80% težinski.
3. Pripravak za omekšavanje tkanine prema zahtjevu 1 ili 2, naznačen time da pripravak sadrži najviše 10% težinski vode.
4. Pripravak za omekšavanje tkanine prema bilo kojem od zahtjeva 1 do 3, naznačen time da je komponenta B odabrana iz skupine koju čine masne kiseline, monoesteri masnih kiselina s C2-6 diolom ili C3-9 poliolom, te monoesteri masnih alkohola s C2-6 hidroksikarboksilnom kiselinom.
5. Pripravak za omekšavanje tkanine prema zahtjevu 4, naznačen time da je komponenta B odabrana iz skupine koju čine masne kiseline i monoesteri masnih kiselina, monoesteri glicerola, diglicerola, triglicerola, sorbitola i sorbitana.
6. Pripravak za omekšavanje tkanine prema bilo kojem od zahtjeva 1 do 5, naznačen time da u formulama (I) i (II) R2 je C1-4 alkilni radikal i poželjno metilni radikal.
7. Pripravak za omekšavanje tkanine prema bilo kojem od zahtjeva 1 do 6, naznačen time da u formulama (I) i (II) R2 i R3, međusobno neovisno, su C1-4 alkilni radikali i poželjno metilni radikali.
8. Pripravak za omekšavanje tkanine prema bilo kojem od zahtjeva 1 do 7, naznačen time da R1 je metil, u formuli (I) R2 i R3, međusobno neovisno, su metil, 2-hidroksietil ili 2-hidroksipropil, u formuli (II) R2 i R3 su metil, i X- je klorid ili metilsulfat.
9. Pripravak za omekšavanje tkanine prema bilo kojem od zahtjeva 1 do 8, naznačen time da komponenta A i komponenta B sadrže isti dugolančani radikal ugljikovodika.
10. Postupak za proizvodnju pripravka za omekšavanje tkanine, naznačen time da sadrži a) reakciju smjese koja sadrži n mola C16-22 masne kiseline s jodnim brojem od najviše 45, m mola C2-6 diola ili C3-9 poliola i p mola alkanolamina s formulom R2R3NCH2CHR4OH, u kojoj R2 i R3, međusobno neovisno, su metil, 2-hidroksietil ili 2-hidroksipropil i R4 je vodik ili metil, gdje je omjer p:m u rasponu od 2:1 do 1:3 i n:(p+m) je u rasponu od 0.75 do 1.4, kod temperature u rasponu od 140 do 210°C uz uklanjanje vode i b) reakciju smjese dobivene u koraku a) sa sredstvom za alkiliranje kod temperature u rasponu od 50 do 100°C sve dok se ne kvaternizira barem 90% tercijarnih amino skupina, ili s kiselinom sve dok se ne protonira barem 98% tercijarnih amino skupina.
11. Postupak za proizvodnju pripravka za omekšavanje tkanine, naznačen time da sadrži a) reakciju smjese koja sadrži n mola C16-22 masne kiseline s jodnim brojem od najviše 45, m mola C2-6 diola ili C3-9 poliola i p mola N,N-dimetil-1,3-propanediamina, gdje je omjer p:m u rasponu od 2:1 do 1:3 i n je u rasponu od 0.75*m+p do 1.4*m+p, kod temperature u rasponu od 140 do 210°C uz uklanjanje vode i b) reakciju smjese dobivene u koraku a) sa sredstvom za alkiliranje kod temperature u rasponu od 50 do 100°C sve dok se ne kvaternizira barem 90% tercijarnih amino skupina, ili s kiselinom sve dok se ne protonira barem 98% tercijarnih amino skupina.
12. Postupak prema zahtjevu 10 ili 11, naznačen time da sredstvo za alkiliranje je dimetil sulfat ili metil klorid.
13. Postupak prema zahtjevu 10 ili 11, naznačen time da kiselina je karboksilna kiselina koja ima 1 do 3 ugljikovih atoma.
14. Pripravak za omekšavanje tkanine, naznačen time da se može dobiti postupkom prema bilo kojem od zahtjeva 10 do 13.
15. Omekšivač tkanine za vodeno pranje, naznačen time da sadrži 2 do 25% težinski pripravka za omekšavanje tkanine prema bilo kojem od zahtjeva 1 do 9 ili prema zahtjevu 14 i 70 do 98% težinski vode.
16. Uporaba pripravka za omekšavanje tkanine prema bilo kojem od zahtjeva 1 do 9 ili prema zahtjevu 14, naznačen time da je za proizvodnju omekšivača tkanine za vodeno pranje.
HRP20170871TT 2010-04-28 2017-06-07 Pripravak za omekšavanje tekstila HRP20170871T1 (hr)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP10161296 2010-04-28
EP11721249.8A EP2563889B1 (de) 2010-04-28 2011-04-19 Textilweichmachende zusammensetzung
PCT/EP2011/056185 WO2011134835A1 (de) 2010-04-28 2011-04-19 Textilweichmachende zusammensetzung

Publications (1)

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HRP20170871T1 true HRP20170871T1 (hr) 2017-09-08

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US (1) US8883712B2 (hr)
EP (1) EP2563889B1 (hr)
CN (1) CN102869757B (hr)
BR (1) BR112012027530B1 (hr)
ES (1) ES2627705T3 (hr)
HR (1) HRP20170871T1 (hr)
HU (1) HUE033227T2 (hr)
MX (1) MX2012012340A (hr)
PL (1) PL2563889T3 (hr)
WO (1) WO2011134835A1 (hr)

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CN102869757B (zh) 2015-12-02
EP2563889B1 (de) 2017-03-15
MX2012012340A (es) 2012-11-21
WO2011134835A1 (de) 2011-11-03
BR112012027530B1 (pt) 2020-12-01
ES2627705T3 (es) 2017-07-31
US20130053299A1 (en) 2013-02-28
PL2563889T3 (pl) 2017-08-31
US8883712B2 (en) 2014-11-11
HUE033227T2 (en) 2017-11-28
EP2563889A1 (de) 2013-03-06
CN102869757A (zh) 2013-01-09

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