HRP20170449T1 - Termoizolacijski ekspandirani artikli i smjese za njihovu pripravu - Google Patents
Termoizolacijski ekspandirani artikli i smjese za njihovu pripravu Download PDFInfo
- Publication number
- HRP20170449T1 HRP20170449T1 HRP20170449TT HRP20170449T HRP20170449T1 HR P20170449 T1 HRP20170449 T1 HR P20170449T1 HR P20170449T T HRP20170449T T HR P20170449TT HR P20170449 T HRP20170449 T HR P20170449T HR P20170449 T1 HRP20170449 T1 HR P20170449T1
- Authority
- HR
- Croatia
- Prior art keywords
- weight
- granules
- grains
- expandable
- polymer
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title claims 10
- 238000002360 preparation method Methods 0.000 title claims 2
- 229920000642 polymer Polymers 0.000 claims 16
- 239000008187 granular material Substances 0.000 claims 13
- 125000003118 aryl group Chemical group 0.000 claims 7
- 239000002245 particle Substances 0.000 claims 7
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims 4
- 239000003063 flame retardant Substances 0.000 claims 4
- 239000012764 mineral filler Substances 0.000 claims 3
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims 2
- 239000000654 additive Substances 0.000 claims 2
- 230000000996 additive effect Effects 0.000 claims 2
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims 2
- 229910052794 bromium Inorganic materials 0.000 claims 2
- 239000000571 coke Substances 0.000 claims 2
- 239000000463 material Substances 0.000 claims 2
- 229920001577 copolymer Polymers 0.000 claims 1
- 238000001125 extrusion Methods 0.000 claims 1
- 239000000945 filler Substances 0.000 claims 1
- 239000000725 suspension Substances 0.000 claims 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/0014—Use of organic additives
- C08J9/0019—Use of organic additives halogenated
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/0066—Use of inorganic compounding ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/16—Making expandable particles
- C08J9/20—Making expandable particles by suspension polymerisation in the presence of the blowing agent
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2203/00—Foams characterized by the expanding agent
- C08J2203/14—Saturated hydrocarbons, e.g. butane; Unspecified hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2325/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Derivatives of such polymers
- C08J2325/02—Homopolymers or copolymers of hydrocarbons
- C08J2325/04—Homopolymers or copolymers of styrene
- C08J2325/06—Polystyrene
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Claims (11)
1. Termoizolacijski ekspandirani artikli, s gustoćom u rasponu od 5 do 50 g/l, koje se može načiniti iz smjesa čestica ekspandibilnih viniliranih aromatskih polimera, naznačeni time što sadrže:
a) 10-90%, težinski, zrna/granula ekspandibilnog viniliranog aromatskog polimera, pigmentiranog atermalnim materijalom koji sadrži 0,05 do 25%, težinski, koksa u obliku čestica prosječne veličine čestica (dimenzijski) u rasponu od 0,5 do 100 µm i specifične površine, izmjerene u skladu s ASTM D-3037-89 (BET), u rasponu od 5 do 50 m2/g;
b) 90-10%, težinski, zrna/granula uglavnom bijelog ekspandibilnog viniliranog aromatskog polimera.
2. Ekspandirani artikli u skladu s patentnim zahtjevom 1, gdje uglavnom bijela granula (b) sadrži od 0,05 do 25%, težinski, mineralnog punila, naznačenog time što ima indeks bjeline manji od 22 i veličinu čestica od 0,1 do 50 µm.
3. Ekspandirani artikli u skladu s patentnim zahtjevom 1 ili 2, naznačeni time što sadrže sustav za usporavanje gorenja koji sadrži 0,1 do 8%, težinski, s obzirom na polimer (a) i/ili (b), bromiranog samougasivog aditiva koji sadrži najmanje 30%, težinski, broma i od 0,02 do 2%, težinski, s obzirom na polimer (a) i/ili (b) sinergističkog sredstva koje sadrži najmanje jednu slabu vezu C-C ili O-O.
4. Smjese zrna/granula viniliranog aromatskog polimera, pogodnog za upotrebu u pripravi termoizolacijskih ekspandiranih artikala, naznačene time što sadrže:
a) 10-90%, težinski, zrna/granula ekspandibilnog/ekspandiranog viniliranog aromatskog polimera, pigmentiranog atermalnim materijalom koji sadrži 0,05 do 25%, težinski, koksa u obliku čestica prosječne veličine čestica (dimenzijski) u rasponu od 0,5 do 100 µm i specifične površine, izmjerene u skladu s ASTM D-3037-89 (BET), od 5 do 50 m2/g;
b) 90-10%, težinski, zrna/granula uglavnom bijelog ekspandibilnog/ekspandiranog viniliranog aromatskog polimera.
5. Smjese u skladu s patentnim zahtjevom 4, gdje uglavnom bijelo zrno/granula (b) sadrži od 0,05 do 25%, težinski, mineralnog punila, naznačenog time što ima indeks bjeline manji od 22 i veličinu čestica (dimenzijski) od 0,1 do 50 µm.
6. Smjese u skladu s patentnim zahtjevom 4 ili 5, naznačene time što sadrže sustav za usporavanje gorenja koji uključuje od 0,1 do 8%, težinski, s obzirom na polimer (a) i/ili (b), bromiranog samougasivog aditiva koji sadrži najmanje 30%, težinski, broma i od 0,02 do 2%, težinski, s obzirom na polimer (a) i/ili (b), sinergističkog sredstva koje sadrži najmanje jednu slabu vezu C-C ili O-O.
7. Smjese u skladu s patentnim zahtjevom 4, 5 ili 6, naznačene time što se ekspandibilna zrna/granule, oba tipa (a) i (b), sastoje od viniliranih aromatskih polimera i/ili kopolimera prosječne molekulske težine MW u rasponu od 50.000 do 300.000.
8. Smjese u skladu s bilo kojim od patentnih zahtjeva od 4 do 7, naznačene time što su ekspandibilna zrna/granule uglavnom sferične, s prosječnim promjerom u rasponu od 0,2 do 2 mm, unutar kojih su atermalno punilo, polimeri (a) i moguće mineralno punilo, te polimeri (b) homogeno dispergirani.
9. Artikli i smjese u skladu s bilo kojim od prethodnih patentnih zahtjeva, naznačeni time što se ekspandibilni polimer u zrnima/granulama (a) i onaj u zrnima/granulama (b) pripravlja u suspenziji, ekstruzijom ili masovno.
10. Artikli i smjese u skladu s bilo kojim od prethodnih patentnih zahtjeva, naznačeni time što samo ekspandibilni polimer u zrnima/granulama (a) sadrži sustav za usporavanje gorenja.
11. Smjesa u skladu s bilo kojim od prethodnih patentnih zahtjeva, naznačena time što samo ekspandibilni polimer u zrnima/granulama (b) sadrži sustav za usporavanje gorenja.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| ITMI2009A001267A IT1394749B1 (it) | 2009-07-16 | 2009-07-16 | Articoli espansi termoisolanti e composizioni per la loro preparazione |
| PCT/IB2010/001630 WO2011007228A2 (en) | 2009-07-16 | 2010-07-01 | Thermo-insulating expanded articles and compositions for the preparation thereof |
| EP10742871.6A EP2454313B2 (en) | 2009-07-16 | 2010-07-01 | Thermo-insulating expanded articles and compositions for the preparation thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| HRP20170449T1 true HRP20170449T1 (hr) | 2017-05-19 |
| HRP20170449T4 HRP20170449T4 (hr) | 2024-04-26 |
Family
ID=41665145
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| HRP20170449TT HRP20170449T4 (hr) | 2009-07-16 | 2010-07-01 | Termoizolacijski ekspandirani artikli i smjese za njihovu pripravu |
Country Status (17)
| Country | Link |
|---|---|
| US (1) | US20120168668A1 (hr) |
| EP (1) | EP2454313B2 (hr) |
| JP (1) | JP5798554B2 (hr) |
| CN (1) | CN102612533A (hr) |
| BR (1) | BR112012001064B1 (hr) |
| DK (1) | DK2454313T3 (hr) |
| ES (1) | ES2619358T5 (hr) |
| FI (1) | FI2454313T4 (hr) |
| HR (1) | HRP20170449T4 (hr) |
| HU (1) | HUE031862T2 (hr) |
| IT (1) | IT1394749B1 (hr) |
| MX (1) | MX2012000742A (hr) |
| PL (1) | PL2454313T5 (hr) |
| PT (1) | PT2454313T (hr) |
| RU (1) | RU2543899C2 (hr) |
| SI (1) | SI2454313T2 (hr) |
| WO (1) | WO2011007228A2 (hr) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8535449B2 (en) * | 2011-06-22 | 2013-09-17 | Envirochem Solutions Llc | Use of coke compositions for on-line gas turbine cleaning |
| US9452550B2 (en) | 2012-12-28 | 2016-09-27 | Total Research & Technology Feluy | Expandable vinyl aromatic polymers comprising platelet needle coke particles |
| WO2018069178A1 (en) | 2016-10-10 | 2018-04-19 | Total Research & Technology Feluy | Improved expandable vinyl aromatic polymers |
| KR20190068532A (ko) | 2016-10-10 | 2019-06-18 | 토탈 리서치 앤드 테크놀로지 펠루이 | 개선된 팽창성 비닐 방향족 중합체 |
| CN109804005B (zh) | 2016-10-10 | 2022-08-19 | 道达尔研究技术弗吕公司 | 改进的能膨胀的乙烯基芳族聚合物 |
| IT201800020404A1 (it) * | 2018-12-20 | 2020-06-20 | Versalis Spa | Composizione polimerica espandibile e procedimento per la sua produzione |
| CN114341256A (zh) | 2019-09-04 | 2022-04-12 | 道达尔能源一技术比利时公司 | 具有改进的阻燃性的可膨胀乙烯基芳族聚合物 |
Family Cites Families (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AU4754090A (en) | 1988-11-25 | 1990-06-26 | Dow Chemical Company, The | Polystyrene foam containing carbon black |
| DE9305431U1 (de) * | 1993-04-13 | 1994-08-11 | AlgoStat GmbH & Co. KG, 29227 Celle | Formkörper aus Polystyrol-Hartschaum |
| EP0981574B1 (de) | 1997-05-14 | 2000-09-06 | Basf Aktiengesellschaft | Graphitpartikel enthaltende expandierbare styrolpolymerisate |
| EP0987292A1 (en) | 1998-09-16 | 2000-03-22 | Shell Internationale Researchmaatschappij B.V. | Process for the preparation of expanded polyvinylarene particles |
| ITMI20012168A1 (it) * | 2001-10-18 | 2003-04-18 | Enichem Spa | Polimeri vinilaromatici espandibili e procedimento per la loro preparazione |
| ITMI20012708A1 (it) | 2001-12-20 | 2003-06-20 | Enichem Spa | Dispositivo per la granulazione a caldo di polimeri termolastici |
| ITMI20012706A1 (it) | 2001-12-20 | 2003-06-20 | Enichem Spa | Procedimento per la produzione di granuli di polimeri termoplastici espandibili ed apparecchiatura adatta allo scopo |
| JP3714905B2 (ja) * | 2001-12-28 | 2005-11-09 | ダウ化工株式会社 | ポリスチレン系樹脂発泡粒子成型体からなる建築用断熱材 |
| DE20307608U1 (de) * | 2003-01-20 | 2003-08-28 | Deutsche Amphibolin-Werke von Robert Murjahn Stiftung & Co KG, 64372 Ober-Ramstadt | Dämmender geschäumter Werkstoff |
| WO2005021624A1 (ja) * | 2003-08-29 | 2005-03-10 | Sekisui Plastics Co., Ltd. | オレフィン改質ポリスチレン系樹脂予備発泡粒子、その製造方法及び発泡成形体 |
| GR1004968B (el) * | 2004-09-23 | 2005-09-08 | Weply Limited | Διογκωμενο πολυστυρενιο με δυνατοτητα απορροφησης υγρασιας στο εσωτερικο του, μονοστρωματικο, χωρις επιφανειακη επικαλυψη με μεμβρανες (μη λαμιναρισμενο). παραγομενα προϊοντα και μεθοδος |
| DE102005039976A1 (de) * | 2005-08-23 | 2007-03-08 | Basf Ag | Partikel aus expandierbarem Polystyrol und daraus erhältliche Formteile mit verbessertem Brandverhalten |
| US20070105967A1 (en) | 2005-11-08 | 2007-05-10 | Govind Rauniyar | Thermoplastic material |
| DE102006018528A1 (de) | 2006-04-21 | 2007-11-08 | Deutsche Amphibolin-Werke Von Robert Murjahn Stiftung & Co Kg | Dämmender geschäumter Werkstoff |
| US20080300328A1 (en) * | 2007-04-25 | 2008-12-04 | Dow Global Technologies Inc. | Process for the Preparation of Expandable Polystyrene Beads |
| EP1988119A1 (en) * | 2007-05-01 | 2008-11-05 | Nova Innovene International S.A. | Expandable polystyrene composition |
| ITMI20071003A1 (it) * | 2007-05-18 | 2008-11-19 | Polimeri Europa Spa | Compositi a base di polimeri vinilaromatici aventi migliorate proprieta' di isolamento termico e procedimento per la loro preparazione |
| EP2025700A1 (en) * | 2007-08-01 | 2009-02-18 | Ineos Europe Limited | process for the production of expandable polystyrene (eps) comprising flame retardant additives |
-
2009
- 2009-07-16 IT ITMI2009A001267A patent/IT1394749B1/it active
-
2010
- 2010-07-01 JP JP2012520114A patent/JP5798554B2/ja not_active Expired - Fee Related
- 2010-07-01 RU RU2012103462/05A patent/RU2543899C2/ru active
- 2010-07-01 WO PCT/IB2010/001630 patent/WO2011007228A2/en active Application Filing
- 2010-07-01 CN CN2010800367063A patent/CN102612533A/zh active Pending
- 2010-07-01 PT PT107428716T patent/PT2454313T/pt unknown
- 2010-07-01 EP EP10742871.6A patent/EP2454313B2/en active Active
- 2010-07-01 HR HRP20170449TT patent/HRP20170449T4/hr unknown
- 2010-07-01 SI SI201031423T patent/SI2454313T2/sl unknown
- 2010-07-01 US US13/383,968 patent/US20120168668A1/en not_active Abandoned
- 2010-07-01 PL PL10742871.6T patent/PL2454313T5/pl unknown
- 2010-07-01 DK DK10742871.6T patent/DK2454313T3/en active
- 2010-07-01 MX MX2012000742A patent/MX2012000742A/es not_active Application Discontinuation
- 2010-07-01 BR BR112012001064-6A patent/BR112012001064B1/pt active IP Right Grant
- 2010-07-01 HU HUE10742871A patent/HUE031862T2/hu unknown
- 2010-07-01 ES ES10742871T patent/ES2619358T5/es active Active
- 2010-07-01 FI FIEP10742871.6T patent/FI2454313T4/fi active
Also Published As
| Publication number | Publication date |
|---|---|
| EP2454313B1 (en) | 2016-12-21 |
| WO2011007228A3 (en) | 2011-08-04 |
| BR112012001064A2 (pt) | 2016-03-29 |
| HRP20170449T4 (hr) | 2024-04-26 |
| PT2454313T (pt) | 2017-03-22 |
| MX2012000742A (es) | 2012-05-08 |
| PL2454313T5 (pl) | 2024-04-08 |
| DK2454313T3 (en) | 2017-03-20 |
| EP2454313A2 (en) | 2012-05-23 |
| JP2012532978A (ja) | 2012-12-20 |
| ITMI20091267A1 (it) | 2011-01-17 |
| RU2012103462A (ru) | 2013-08-27 |
| CN102612533A (zh) | 2012-07-25 |
| SI2454313T2 (sl) | 2024-06-28 |
| PL2454313T3 (pl) | 2017-06-30 |
| IT1394749B1 (it) | 2012-07-13 |
| ES2619358T3 (es) | 2017-06-26 |
| US20120168668A1 (en) | 2012-07-05 |
| BR112012001064B1 (pt) | 2019-11-05 |
| RU2543899C2 (ru) | 2015-03-10 |
| HUE031862T2 (hu) | 2017-08-28 |
| EP2454313B2 (en) | 2024-02-21 |
| SI2454313T1 (sl) | 2017-04-26 |
| JP5798554B2 (ja) | 2015-10-21 |
| ES2619358T5 (es) | 2024-06-28 |
| FI2454313T4 (fi) | 2024-03-20 |
| WO2011007228A2 (en) | 2011-01-20 |
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