HRP20110628T1 - Proizvodi poliuretanskog elastomera iz niskih slobodnih difenilmetan diizocijanat predpolimera - Google Patents
Proizvodi poliuretanskog elastomera iz niskih slobodnih difenilmetan diizocijanat predpolimera Download PDFInfo
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- HRP20110628T1 HRP20110628T1 HR20110628T HRP20110628T HRP20110628T1 HR P20110628 T1 HRP20110628 T1 HR P20110628T1 HR 20110628 T HR20110628 T HR 20110628T HR P20110628 T HRP20110628 T HR P20110628T HR P20110628 T1 HRP20110628 T1 HR P20110628T1
- Authority
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- Croatia
- Prior art keywords
- polyurethane elastomer
- mixture
- elastomer product
- product according
- diphenylmethane diisocyanate
- Prior art date
Links
- 229920003225 polyurethane elastomer Polymers 0.000 title claims abstract 18
- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 title claims 7
- 238000000034 method Methods 0.000 claims abstract 13
- 238000005299 abrasion Methods 0.000 claims abstract 2
- 239000000203 mixture Substances 0.000 claims 18
- 229920001971 elastomer Polymers 0.000 claims 10
- 239000000806 elastomer Substances 0.000 claims 10
- 239000004970 Chain extender Substances 0.000 claims 5
- 229920001610 polycaprolactone Polymers 0.000 claims 4
- 239000004632 polycaprolactone Substances 0.000 claims 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims 3
- IBOFVQJTBBUKMU-UHFFFAOYSA-N 4,4'-methylene-bis-(2-chloroaniline) Chemical compound C1=C(Cl)C(N)=CC=C1CC1=CC=C(N)C(Cl)=C1 IBOFVQJTBBUKMU-UHFFFAOYSA-N 0.000 claims 2
- 229920001730 Moisture cure polyurethane Polymers 0.000 claims 2
- 125000001931 aliphatic group Chemical group 0.000 claims 2
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 claims 2
- 238000004519 manufacturing process Methods 0.000 claims 2
- 229920005862 polyol Polymers 0.000 claims 2
- 150000003077 polyols Chemical class 0.000 claims 2
- YPFDHNVEDLHUCE-UHFFFAOYSA-N propane-1,3-diol Chemical compound OCCCO YPFDHNVEDLHUCE-UHFFFAOYSA-N 0.000 claims 2
- RVEZNIXHGFAPNQ-UHFFFAOYSA-N 1-[3-(2-hydroxypropoxy)phenoxy]propan-2-ol Chemical compound CC(O)COC1=CC=CC(OCC(C)O)=C1 RVEZNIXHGFAPNQ-UHFFFAOYSA-N 0.000 claims 1
- KGRVJHAUYBGFFP-UHFFFAOYSA-N 2,2'-Methylenebis(4-methyl-6-tert-butylphenol) Chemical compound CC(C)(C)C1=CC(C)=CC(CC=2C(=C(C=C(C)C=2)C(C)(C)C)O)=C1O KGRVJHAUYBGFFP-UHFFFAOYSA-N 0.000 claims 1
- PISLZQACAJMAIO-UHFFFAOYSA-N 2,4-diethyl-6-methylbenzene-1,3-diamine Chemical compound CCC1=CC(C)=C(N)C(CC)=C1N PISLZQACAJMAIO-UHFFFAOYSA-N 0.000 claims 1
- CTNICFBTUIFPOE-UHFFFAOYSA-N 2-(4-hydroxyphenoxy)ethane-1,1-diol Chemical compound OC(O)COC1=CC=C(O)C=C1 CTNICFBTUIFPOE-UHFFFAOYSA-N 0.000 claims 1
- IAXFZZHBFXRZMT-UHFFFAOYSA-N 2-[3-(2-hydroxyethoxy)phenoxy]ethanol Chemical compound OCCOC1=CC=CC(OCCO)=C1 IAXFZZHBFXRZMT-UHFFFAOYSA-N 0.000 claims 1
- ZYCRBOCGBKATBL-UHFFFAOYSA-N 3-tert-butyl-6-methylbenzene-1,2-diamine Chemical compound CC1=CC=C(C(C)(C)C)C(N)=C1N ZYCRBOCGBKATBL-UHFFFAOYSA-N 0.000 claims 1
- YBRVSVVVWCFQMG-UHFFFAOYSA-N 4,4'-diaminodiphenylmethane Chemical compound C1=CC(N)=CC=C1CC1=CC=C(N)C=C1 YBRVSVVVWCFQMG-UHFFFAOYSA-N 0.000 claims 1
- VIOMIGLBMQVNLY-UHFFFAOYSA-N 4-[(4-amino-2-chloro-3,5-diethylphenyl)methyl]-3-chloro-2,6-diethylaniline Chemical compound CCC1=C(N)C(CC)=CC(CC=2C(=C(CC)C(N)=C(CC)C=2)Cl)=C1Cl VIOMIGLBMQVNLY-UHFFFAOYSA-N 0.000 claims 1
- AOFIWCXMXPVSAZ-UHFFFAOYSA-N 4-methyl-2,6-bis(methylsulfanyl)benzene-1,3-diamine Chemical compound CSC1=CC(C)=C(N)C(SC)=C1N AOFIWCXMXPVSAZ-UHFFFAOYSA-N 0.000 claims 1
- DJOWTWWHMWQATC-KYHIUUMWSA-N Karpoxanthin Natural products CC(=C/C=C/C=C(C)/C=C/C=C(C)/C=C/C1(O)C(C)(C)CC(O)CC1(C)O)C=CC=C(/C)C=CC2=C(C)CC(O)CC2(C)C DJOWTWWHMWQATC-KYHIUUMWSA-N 0.000 claims 1
- 239000004721 Polyphenylene oxide Substances 0.000 claims 1
- XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical compound ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 claims 1
- YIMQCDZDWXUDCA-UHFFFAOYSA-N [4-(hydroxymethyl)cyclohexyl]methanol Chemical compound OCC1CCC(CO)CC1 YIMQCDZDWXUDCA-UHFFFAOYSA-N 0.000 claims 1
- HIFVAOIJYDXIJG-UHFFFAOYSA-N benzylbenzene;isocyanic acid Chemical class N=C=O.N=C=O.C=1C=CC=CC=1CC1=CC=CC=C1 HIFVAOIJYDXIJG-UHFFFAOYSA-N 0.000 claims 1
- 230000006835 compression Effects 0.000 claims 1
- 238000007906 compression Methods 0.000 claims 1
- GGSUCNLOZRCGPQ-UHFFFAOYSA-N diethylaniline Chemical compound CCN(CC)C1=CC=CC=C1 GGSUCNLOZRCGPQ-UHFFFAOYSA-N 0.000 claims 1
- XXMIOPMDWAUFGU-UHFFFAOYSA-N hexane-1,6-diol Chemical compound OCCCCCCO XXMIOPMDWAUFGU-UHFFFAOYSA-N 0.000 claims 1
- OHQOKJPHNPUMLN-UHFFFAOYSA-N n,n'-diphenylmethanediamine Chemical class C=1C=CC=CC=1NCNC1=CC=CC=C1 OHQOKJPHNPUMLN-UHFFFAOYSA-N 0.000 claims 1
- 239000002245 particle Substances 0.000 claims 1
- 229920000728 polyester Polymers 0.000 claims 1
- 229920000570 polyether Polymers 0.000 claims 1
- 239000011541 reaction mixture Substances 0.000 claims 1
- 238000011084 recovery Methods 0.000 claims 1
- JTNAAZXBTSMBSQ-UHFFFAOYSA-M sodium;n,n'-diphenylmethanediamine;chloride Chemical compound [Na+].[Cl-].C=1C=CC=CC=1NCNC1=CC=CC=C1 JTNAAZXBTSMBSQ-UHFFFAOYSA-M 0.000 claims 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 claims 1
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
- B60C1/00—Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
- B60C1/0016—Compositions of the tread
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
- B60C7/00—Non-inflatable or solid tyres
- B60C7/10—Non-inflatable or solid tyres characterised by means for increasing resiliency
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
- C08G18/44—Polycarbonates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
- C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
- C08G18/7657—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Polyurethanes Or Polyureas (AREA)
Abstract
Proizvod poliuretanskog elastomera, naznačen time, da ima najmanje dva od sljedećih svojstava: vrijednost Texus Flex-a na 30% od više od 10.000 ciklusa prema ASTM postupku D-3629-99; minimalno tan δ na 30-160°C od oko 0,010 do 0,025; svojstvo jačine trganja od oko 26.3 do 78.8 N/mm u skladu s ASTM postupkom D-1938; i DIN abrazija od oko 5 do 31 mm3 u skladu s ASTM postupkom D-5963. Patent sadrži još 14 patentnih zahtjeva.
Claims (15)
1. Proizvod poliuretanskog elastomera, naznačen time, da ima najmanje dva od sljedećih svojstava:
vrijednost Texus Flex-a na 30% od više od 10.000 ciklusa prema ASTM postupku D-3629-99;
minimalno tan δ na 30-160°C od oko 0,010 do 0,025;
svojstvo jačine trganja od oko 26.3 do 78.8 N/mm u skladu s ASTM postupkom D-1938; i
DIN abrazija od oko 5 do 31 mm3 u skladu s ASTM postupkom D-5963.
2. Proizvod poliuretanskog elastomera prema zahtjevu 1, naznačen time, da je proizvod poliuretanskog elastomera oblikovan iz smjese predelastomera koja sadrži smjesu predpolimera i produživač lanca i gdje je po mogućnosti smjesa predpolimera reakcijska smjesa poliola i difenilmetan diizocijanata, gdje je poliol odabran iz skupine koja se sastoji od poliestera, polietera i polikaprolaktona, a produživač lanca je po mogućnosti odabran iz skupine koja se sastoji od 1,4-butandiola; 13-propandiola; etilen glikola; 1,6-heksandiola; hidrokvinon-bishidroksietil etera; resorcinol di(beta-hidroksietil) etera; resorcinol di(betahidroksipropil) etera; 1,4-cikloheksan dimetanola; alifatskog triola; alifatskog tetrola; 4,4’-metilen-bis(2-kloroanilina); 4,4’-metilen-bis(3-kloro-2,6-dietilanilina); dietil toluen diamina; t-butil toluen diamina; dimetiltio-toluen diamina; trimetilen glikol di-p-amino-benzoata; metilen bis ortokloroanilina, metilen bis dietilanilina; metilendianilina; i kompleksa soli metilendianilina, poželjnije je da produživač lanca sadrži kompleks metilendianilin natrij klorida.
3. Proizvod poliuretanskog elastomera prema zahtjevu 2, naznačen time, da smjesa predelastomera ima vrijeme trajanja od 1 do 35 dana na temperaturi od 70°C.
4. Proizvod poliuretanskog elastomera prema zahtjevu 2, naznačen time, da smjesa predpolimera sadrži od 2,0 masenih % do 5,0 masenih % slobodnog difenilmetan diizocijanata.
5. Proizvod poliuretanskog elastomera prema zahtjevu 1, naznačen time, da je težina čestice od 225 kg do 7.000 kg i ima troosovinsku debljinu od 10,2 cm do 493 cm.
6. Proizvod poliuretanskog elastomera prema zahtjevu 1, naznačen time, da je proizvod ne-pneumatska guma koja je po mogućnosti sposobna nositi 9.000 kg do 91.000 kg.
7. Proizvod elastomera prema zahtjevu 1, naznačen time, da proizvod poliuretanskog elastomera ima kompresiju postavljenu na postotak od 10% do 32%.
8. Proizvod elastomera prema zahtjevu 1, naznačen time, da proizvod poliuretanskog elastomera ima vrijednost dijeljenja veću od 20,1 N/mm u skladu s ASTM postupkom D-470.
9. Proizvod elastomera prema zahtjevu 1, naznačen time, da proizvod poliuretanskog elastomera ima vrijednost Texus Flex-a na 45% višu od 1.500 ciklusa u skladu s ASTM postupkom D-339-99.
10. Proizvod elastomera prema zahtjevu 1, naznačen time, da proizvod poliuretanskog elastomera ima povratnu vrijednost od 52 to 99,9 u skladu s ASTM postupkom D-2632.
11. Proizvod elastomera prema zahtjevu 1, naznačen time, da proizvod poliuretanskog elastomera ima tvrdoću prema Shore-u u vrijednosti od 85A do 96A u skladu s ASTM postupkom 2240-00.
12. Proizvod elastomera prema zahtjevu 1, koji ima dinamična svojstva, naznačen time, da ima G’-30°C do G’30°C omjer u rasponu od 1,0 do 2,5.
13. Postupak za izradu poliuretanskog elastomera prema zahtjevima 1-12, naznačen time, da se sastoji od:
dobivanja smjese predpolimera koja sadrži polikaprolakton predpolimer, i difenilmetan diizocijanat, gdje smjesa predpolimera sadrži difenilmetan diizocijanat u količini od 2,0 masenih % do 5,0 masenih %;
miješanja smjese predpolimera sa produživačem lanca da oblikuje smjesu predelastomera; i stvrdnjavanja smjese predelastomera da se stvori poliuretanski elastomer;
po izboru podvrgavanja stvrdnute smjese predelastomera zagrijavanju na od 135°C do 16°C nakon stvrdnjavanja.
14. Postupak prema zahtjevu 13, naznačen time, da se nadalje sastoji od uklanjanja najmanje nekih od slobodnih difenilmetan diizocijanata iz smjese predpolimera stvarajući smjesu predelastomera.
15. Postupak za izradu poliuretanskog elastomera, naznačen time, da se sastoji od:
miješanja prve smjese predpolimera mase A i druge smjese predpolimera mase B, dok navedena prva smjesa predpolimera sadrži prvi polikaprolakton koji po mogućnosti ima molekularnu masu od 200 do 6000, i X masenih % slobodnog difenilmetan diizocijanata, a navedena druga smjesa predpolimera sadrži drugi polikaprolakton koji po mogućnosti ima molekularnu masu od 200 do 6000, i Y masenih % slobodnog difenilmetan diizocijanata, i gdje su A, B, X i Y odabrani tako da (AX+BY)/(A+B) je od 2,0 do 5,0; i
stvrdnjavanja miješanih prvih i drugih smjesa predpolimera sa produživačem lanca da oblikuju navedeni poliuretanski elastomer.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US12/036,939 US8056593B2 (en) | 2007-10-26 | 2008-02-25 | Non-pneumatic tire |
| US12/206,534 US20090110894A1 (en) | 2007-10-26 | 2008-09-08 | Polyurethane elastomer articles from low free diphenylmethane diisocyanate prepolymers |
| PCT/US2009/033983 WO2009108510A1 (en) | 2008-02-25 | 2009-02-13 | Polyurethane elastomer articles from low free diphenylmethane diisocyanate prepolymers |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| HRP20110628T1 true HRP20110628T1 (hr) | 2011-09-30 |
Family
ID=40560268
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| HR20110628T HRP20110628T1 (hr) | 2008-02-25 | 2011-09-01 | Proizvodi poliuretanskog elastomera iz niskih slobodnih difenilmetan diizocijanat predpolimera |
Country Status (18)
| Country | Link |
|---|---|
| US (1) | US20090110894A1 (hr) |
| EP (1) | EP2247452B1 (hr) |
| CN (1) | CN101959699B (hr) |
| AR (1) | AR070471A1 (hr) |
| AT (1) | ATE514571T1 (hr) |
| AU (1) | AU2009217554B2 (hr) |
| CA (1) | CA2713875A1 (hr) |
| CL (1) | CL2009000413A1 (hr) |
| DK (1) | DK2247452T3 (hr) |
| HR (1) | HRP20110628T1 (hr) |
| MX (1) | MX2010009320A (hr) |
| PE (1) | PE20091868A1 (hr) |
| PL (1) | PL2247452T3 (hr) |
| PT (1) | PT2247452E (hr) |
| RU (1) | RU2489461C2 (hr) |
| SI (1) | SI2247452T1 (hr) |
| WO (1) | WO2009108510A1 (hr) |
| ZA (1) | ZA201005698B (hr) |
Families Citing this family (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8586682B2 (en) * | 2009-04-07 | 2013-11-19 | Chemtura Corporation | Curing compositions having low-free amounts of methylenedianiline |
| FR2952118B1 (fr) * | 2009-11-03 | 2012-04-06 | Technip France | Raidisseur pour une conduite flexible |
| CN102432818A (zh) * | 2011-11-18 | 2012-05-02 | 上海珀理玫化学科技有限公司 | 1,5-萘二异氰酸酯基聚氨酯微孔弹性体的制备方法 |
| CN102604028B (zh) * | 2012-02-08 | 2015-04-01 | 苏州市湘园特种精细化工有限公司 | 热固化单组分液体型聚氨酯浇注材料及其制备方法 |
| WO2014039814A1 (en) * | 2012-09-07 | 2014-03-13 | Caterpillar Inc. | Systems and methods for forming non-pneumatic tires |
| US8720921B1 (en) * | 2012-10-30 | 2014-05-13 | SuperSprings International, Inc. | Vehicular suspension enhancement |
| US20160288569A1 (en) * | 2013-11-22 | 2016-10-06 | Alain Parfondry | Polyurethane support for non-pneumatic tire |
| CN106188479A (zh) * | 2016-07-28 | 2016-12-07 | 东莞市雄林新材料科技股份有限公司 | 一种高性能tpu微孔弹性体材料及其制备方法 |
| EP3638515B1 (en) | 2017-06-15 | 2023-04-05 | Camso Inc. | Wheel comprising a non-pneumatic tire |
| CN111989226B (zh) * | 2018-04-20 | 2024-03-29 | 米其林集团总公司 | 具有可模制的加强型热塑性聚氨酯轮辐的非充气车轮及其制备方法 |
| USD1009724S1 (en) | 2018-08-23 | 2024-01-02 | Jelly Products Limited | Wheel side |
| US20220088966A1 (en) | 2019-01-21 | 2022-03-24 | Covestro Intellectual Property Gmbh & Co. Kg | Non-pneumatic tire and preparation process and use thereof |
| EP3722345A1 (en) | 2019-04-09 | 2020-10-14 | Covestro Deutschland AG | Non-pneumatic tire and preparation process and use thereof |
| CN111454418A (zh) * | 2019-01-21 | 2020-07-28 | 科思创德国股份有限公司 | 无充气轮胎及其制备方法和应用 |
| CN112175161B (zh) * | 2019-07-03 | 2022-05-20 | 北京化工大学 | 一种生物基热塑性介电弹性体材料及其制备方法 |
| USD917891S1 (en) | 2019-07-26 | 2021-05-04 | Lilly Brush Co., LLC | Detailing tool |
| US11517171B2 (en) | 2019-07-26 | 2022-12-06 | Lilly Brush Co., LLC | Detailing tool |
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| US1299205A (en) * | 1916-06-03 | 1919-04-01 | Ralph L Morgan | Demountable rim for vehicle-tires. |
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-
2008
- 2008-09-08 US US12/206,534 patent/US20090110894A1/en not_active Abandoned
-
2009
- 2009-02-13 AT AT09715744T patent/ATE514571T1/de active
- 2009-02-13 MX MX2010009320A patent/MX2010009320A/es active IP Right Grant
- 2009-02-13 AU AU2009217554A patent/AU2009217554B2/en not_active Ceased
- 2009-02-13 SI SI200930044T patent/SI2247452T1/sl unknown
- 2009-02-13 CA CA2713875A patent/CA2713875A1/en not_active Abandoned
- 2009-02-13 WO PCT/US2009/033983 patent/WO2009108510A1/en active Application Filing
- 2009-02-13 EP EP09715744A patent/EP2247452B1/en not_active Not-in-force
- 2009-02-13 PT PT09715744T patent/PT2247452E/pt unknown
- 2009-02-13 PL PL09715744T patent/PL2247452T3/pl unknown
- 2009-02-13 RU RU2010139480/05A patent/RU2489461C2/ru not_active IP Right Cessation
- 2009-02-13 DK DK09715744.0T patent/DK2247452T3/da active
- 2009-02-13 CN CN2009801063791A patent/CN101959699B/zh not_active Expired - Fee Related
- 2009-02-24 CL CL2009000413A patent/CL2009000413A1/es unknown
- 2009-02-24 AR ARP090100632A patent/AR070471A1/es active IP Right Grant
- 2009-02-24 PE PE2009000271A patent/PE20091868A1/es not_active Application Discontinuation
-
2010
- 2010-08-10 ZA ZA2010/05698A patent/ZA201005698B/en unknown
-
2011
- 2011-09-01 HR HR20110628T patent/HRP20110628T1/hr unknown
Also Published As
| Publication number | Publication date |
|---|---|
| EP2247452A1 (en) | 2010-11-10 |
| SI2247452T1 (sl) | 2011-09-30 |
| PE20091868A1 (es) | 2009-12-16 |
| PT2247452E (pt) | 2011-10-03 |
| EP2247452B1 (en) | 2011-06-29 |
| WO2009108510A1 (en) | 2009-09-03 |
| AU2009217554A1 (en) | 2009-09-03 |
| CL2009000413A1 (es) | 2010-07-19 |
| MX2010009320A (es) | 2010-09-24 |
| CA2713875A1 (en) | 2009-09-03 |
| ATE514571T1 (de) | 2011-07-15 |
| CN101959699A (zh) | 2011-01-26 |
| AR070471A1 (es) | 2010-04-07 |
| DK2247452T3 (da) | 2011-10-17 |
| CN101959699B (zh) | 2013-07-10 |
| RU2489461C2 (ru) | 2013-08-10 |
| RU2010139480A (ru) | 2012-04-10 |
| AU2009217554B2 (en) | 2013-07-11 |
| ZA201005698B (en) | 2011-04-28 |
| PL2247452T3 (pl) | 2011-12-30 |
| US20090110894A1 (en) | 2009-04-30 |
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