GB891769A - Carboxymethyl dextran-iron complexes - Google Patents
Carboxymethyl dextran-iron complexesInfo
- Publication number
- GB891769A GB891769A GB2898958A GB2898958A GB891769A GB 891769 A GB891769 A GB 891769A GB 2898958 A GB2898958 A GB 2898958A GB 2898958 A GB2898958 A GB 2898958A GB 891769 A GB891769 A GB 891769A
- Authority
- GB
- United Kingdom
- Prior art keywords
- complex
- ferric
- ferrous
- water
- carboxymethyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08B—POLYSACCHARIDES; DERIVATIVES THEREOF
- C08B37/00—Preparation of polysaccharides not provided for in groups C08B1/00 - C08B35/00; Derivatives thereof
- C08B37/0006—Homoglycans, i.e. polysaccharides having a main chain consisting of one single sugar, e.g. colominic acid
- C08B37/0009—Homoglycans, i.e. polysaccharides having a main chain consisting of one single sugar, e.g. colominic acid alpha-D-Glucans, e.g. polydextrose, alternan, glycogen; (alpha-1,4)(alpha-1,6)-D-Glucans; (alpha-1,3)(alpha-1,4)-D-Glucans, e.g. isolichenan or nigeran; (alpha-1,4)-D-Glucans; (alpha-1,3)-D-Glucans, e.g. pseudonigeran; Derivatives thereof
- C08B37/0021—Dextran, i.e. (alpha-1,4)-D-glucan; Derivatives thereof, e.g. Sephadex, i.e. crosslinked dextran
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Biochemistry (AREA)
- Molecular Biology (AREA)
- Engineering & Computer Science (AREA)
- General Health & Medical Sciences (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polysaccharides And Polysaccharide Derivatives (AREA)
Abstract
The invention comprises a complex of iron with a carboxymethyl ether of inherently water-dispersible dextran containing, per anhydroglucose unit, an average of about 1,0 to 3,0 carboxymethyl groups. The complexes may contain ferrous or ferric iron. The novel complexes may be made by adding an aqueous solution of a water-soluble iron salt to an aqueous solution of a carboxymethyl ether of inherently water-dispersible dextran containing an average of 1,0 to 3,0 carboxymethyl groups per anhydroglucose unit, holding the mixture at acid pH until the complex is formed, adding aqueous alkali to the mixture to adjust the pH thereof to a value at which the complex formed is stable, and precipitating and separating the complex. The ferrous complex may be formed using ferrous ammonium sulphate or ferrous chloride and is precipitated by adjusting the pH to between 6,2 and 10,2 by adding aqueous alkali such as aqueous sodium hydroxide solution, and adding the water-miscible non-solvent, such as isopropanol. When ferric chloride is used to form the ferric complex, the addition of sodium hydroxide solution to raise the pH to 1,3-1,4 results in a heavy precipitate of the ferric complex.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB2898958A GB891769A (en) | 1958-09-10 | 1958-09-10 | Carboxymethyl dextran-iron complexes |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB2898958A GB891769A (en) | 1958-09-10 | 1958-09-10 | Carboxymethyl dextran-iron complexes |
Publications (1)
Publication Number | Publication Date |
---|---|
GB891769A true GB891769A (en) | 1962-03-21 |
Family
ID=10284472
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB2898958A Expired GB891769A (en) | 1958-09-10 | 1958-09-10 | Carboxymethyl dextran-iron complexes |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB891769A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1668033A1 (en) * | 1966-10-22 | 1971-05-13 | Fisons Pharmaceuticals Ltd | New ferric hydroxide-carbohydrate complexes and processes for their production |
-
1958
- 1958-09-10 GB GB2898958A patent/GB891769A/en not_active Expired
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1668033A1 (en) * | 1966-10-22 | 1971-05-13 | Fisons Pharmaceuticals Ltd | New ferric hydroxide-carbohydrate complexes and processes for their production |
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