GB800445A - Improved fuel for use in gas turbine plants - Google Patents

Improved fuel for use in gas turbine plants

Info

Publication number
GB800445A
GB800445A GB2520156A GB2520156A GB800445A GB 800445 A GB800445 A GB 800445A GB 2520156 A GB2520156 A GB 2520156A GB 2520156 A GB2520156 A GB 2520156A GB 800445 A GB800445 A GB 800445A
Authority
GB
United Kingdom
Prior art keywords
metal
group
proportion
gas turbine
vanadium
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB2520156A
Inventor
Antony Winward
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Technology and Engineering Co
Original Assignee
Exxon Research and Engineering Co
Esso Research and Engineering Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Exxon Research and Engineering Co, Esso Research and Engineering Co filed Critical Exxon Research and Engineering Co
Priority to GB2520156A priority Critical patent/GB800445A/en
Publication of GB800445A publication Critical patent/GB800445A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/12—Inorganic compounds
    • C10L1/1233—Inorganic compounds oxygen containing compounds, e.g. oxides, hydroxides, acids and salts thereof
    • C10L1/1241—Inorganic compounds oxygen containing compounds, e.g. oxides, hydroxides, acids and salts thereof metal carbonyls
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/12—Inorganic compounds
    • C10L1/1291—Silicon and boron containing compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/1805—Organic compounds containing oxygen oxidised hydrocarbon fractions
    • C10L1/1808—Organic compounds containing oxygen oxidised hydrocarbon fractions oxidised mineral waxes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/188—Carboxylic acids; metal salts thereof
    • C10L1/1881—Carboxylic acids; metal salts thereof carboxylic group attached to an aliphatic carbon atom
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/188—Carboxylic acids; metal salts thereof
    • C10L1/1886—Carboxylic acids; metal salts thereof naphthenic acid

Abstract

A fuel composition to reduce corrosion in gas turbines attributable to vanadium comprises (i) a major proportion of a fuel oil containing a vanadium compound; (ii) a minor proportion of a Group II metal, for example magnesium, a Group II metal oxide, or a compound of a Group II metal which will give rise to the oxide under working conditions in a gas turbine, e.g. naphthenates, palmitates, stearates or salts obtained from the acids formed during the oxidation of petroleum waxes or from the acids contained in tall oil; and (iii) a minor proportion of an inert refractory substance with a particle size not greater than 30 microns. The refractory substance must be inert under the conditions existing in the combustion chamber of a gas turbine burning fuel oil and can be silica, magnesia, silica-magnesia, silica alumina, montmorillonite or bentonite clays preferably with a particle size between 5 to 15 microns and in the proportion of 1 to 12 times the weight of ash produced by the fuel oil on combustion. A preferred refractory substance is a cracking catalyst such as magnesium or aluminium silicate. The proportion of Group II metal present should be not less than that stoichiometrically necessary to form the metal orthovanadate and is preferably 2 to 8 atoms of the metal to one atom of vanadium.
GB2520156A 1956-08-17 1956-08-17 Improved fuel for use in gas turbine plants Expired GB800445A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB2520156A GB800445A (en) 1956-08-17 1956-08-17 Improved fuel for use in gas turbine plants

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB2520156A GB800445A (en) 1956-08-17 1956-08-17 Improved fuel for use in gas turbine plants

Publications (1)

Publication Number Publication Date
GB800445A true GB800445A (en) 1958-08-27

Family

ID=10223864

Family Applications (1)

Application Number Title Priority Date Filing Date
GB2520156A Expired GB800445A (en) 1956-08-17 1956-08-17 Improved fuel for use in gas turbine plants

Country Status (1)

Country Link
GB (1) GB800445A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0078249A1 (en) * 1981-10-12 1983-05-04 Lang & Co., chemisch-technische Produkte Kommanditgesellschaft Additive with a combustion promoting and soot inhibiting activity for furnace oils, diesel fuels and other liquid combustion and fuel substances, as well as the aforesaid liquid combustion and fuel substances
WO1998003616A1 (en) * 1996-07-18 1998-01-29 Ica Innoconsult Ag Additive to be sprayed into the combustion chambers of heating plants and process for preventing high temperature corrosion

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0078249A1 (en) * 1981-10-12 1983-05-04 Lang & Co., chemisch-technische Produkte Kommanditgesellschaft Additive with a combustion promoting and soot inhibiting activity for furnace oils, diesel fuels and other liquid combustion and fuel substances, as well as the aforesaid liquid combustion and fuel substances
WO1998003616A1 (en) * 1996-07-18 1998-01-29 Ica Innoconsult Ag Additive to be sprayed into the combustion chambers of heating plants and process for preventing high temperature corrosion

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