GB766672A - Improvements relating to the hydrocatalytic desulphurisation of hydrocarbons - Google Patents

Improvements relating to the hydrocatalytic desulphurisation of hydrocarbons

Info

Publication number
GB766672A
GB766672A GB1112054A GB1112054A GB766672A GB 766672 A GB766672 A GB 766672A GB 1112054 A GB1112054 A GB 1112054A GB 1112054 A GB1112054 A GB 1112054A GB 766672 A GB766672 A GB 766672A
Authority
GB
United Kingdom
Prior art keywords
hydrocarbons
catalyst
sulphur
scf
consisting essentially
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB1112054A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
FREDERICK WILLIAM BERTRAM PORT
BP PLC
Original Assignee
FREDERICK WILLIAM BERTRAM PORT
BP PLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by FREDERICK WILLIAM BERTRAM PORT, BP PLC filed Critical FREDERICK WILLIAM BERTRAM PORT
Priority to GB1112054A priority Critical patent/GB766672A/en
Publication of GB766672A publication Critical patent/GB766672A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/02Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
    • C10G45/04Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
    • C10G45/06Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof
    • C10G45/08Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof in combination with chromium, molybdenum, or tungsten metals, or compounds thereof
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/02Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

Hydrocarbons are hydrocatalytically desulphurized by contacting them at a space velocity within the range of 0.5 to 10.0 v/v/hr. of the liquid feedstock and in the presence of 1,000-10,000 SCF/B of hydrogen, with a catalyst consisting essentially of the oxides of cobalt and molybdenum on a support consisting essentially of alumina, the catalyst containing a small proportion of fluorine, at a temperature of 650-850 DEG F. and a pressure of 200-1000 p.s.i. gauge so that the organically combined sulphur contained in the hydrocarbon is converted into hydrogen sulphide, and then separating the hydrogen sulphide. The catalyst is preferably that described in Specification 719,627. In an example, a Kuwait gas oil of 248-359 DEG C. boiling range containing 1-26 per cent of sulphur was treated at 780 DEG C. and a pressure of 600 p.s.i.ga. at a space velocity of 4.0 v/v/hr. and 4,000 SCF-B gas recycle to give a product containing only 0.03-0.04 per cent of sulphur.
GB1112054A 1954-04-15 1954-04-15 Improvements relating to the hydrocatalytic desulphurisation of hydrocarbons Expired GB766672A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB1112054A GB766672A (en) 1954-04-15 1954-04-15 Improvements relating to the hydrocatalytic desulphurisation of hydrocarbons

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB1112054A GB766672A (en) 1954-04-15 1954-04-15 Improvements relating to the hydrocatalytic desulphurisation of hydrocarbons

Publications (1)

Publication Number Publication Date
GB766672A true GB766672A (en) 1957-01-23

Family

ID=9980404

Family Applications (1)

Application Number Title Priority Date Filing Date
GB1112054A Expired GB766672A (en) 1954-04-15 1954-04-15 Improvements relating to the hydrocatalytic desulphurisation of hydrocarbons

Country Status (1)

Country Link
GB (1) GB766672A (en)

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