GB705719A - Complex metal tetra-phenyl boron salts - Google Patents
Complex metal tetra-phenyl boron saltsInfo
- Publication number
- GB705719A GB705719A GB23634/51A GB2363451A GB705719A GB 705719 A GB705719 A GB 705719A GB 23634/51 A GB23634/51 A GB 23634/51A GB 2363451 A GB2363451 A GB 2363451A GB 705719 A GB705719 A GB 705719A
- Authority
- GB
- United Kingdom
- Prior art keywords
- sodium
- reacting
- tetraphenylboron
- complex metal
- phenyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000002184 metal Substances 0.000 title 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 abstract 4
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 abstract 4
- 229910052708 sodium Inorganic materials 0.000 abstract 4
- 239000011734 sodium Substances 0.000 abstract 4
- 229910015900 BF3 Inorganic materials 0.000 abstract 3
- WTEOIRVLGSZEPR-UHFFFAOYSA-N boron trifluoride Chemical compound FB(F)F WTEOIRVLGSZEPR-UHFFFAOYSA-N 0.000 abstract 3
- 239000011541 reaction mixture Substances 0.000 abstract 2
- 239000011780 sodium chloride Substances 0.000 abstract 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 abstract 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 abstract 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 abstract 1
- CIUQDSCDWFSTQR-UHFFFAOYSA-N [C]1=CC=CC=C1 Chemical compound [C]1=CC=CC=C1 CIUQDSCDWFSTQR-UHFFFAOYSA-N 0.000 abstract 1
- 229910052796 boron Inorganic materials 0.000 abstract 1
- 229910052792 caesium Inorganic materials 0.000 abstract 1
- TVFDJXOCXUVLDH-UHFFFAOYSA-N caesium atom Chemical compound [Cs] TVFDJXOCXUVLDH-UHFFFAOYSA-N 0.000 abstract 1
- 150000001768 cations Chemical class 0.000 abstract 1
- 229910052744 lithium Inorganic materials 0.000 abstract 1
- -1 phenyl magnesium halide Chemical class 0.000 abstract 1
- ANRQGKOBLBYXFM-UHFFFAOYSA-M phenylmagnesium bromide Chemical compound Br[Mg]C1=CC=CC=C1 ANRQGKOBLBYXFM-UHFFFAOYSA-M 0.000 abstract 1
- 229910052700 potassium Inorganic materials 0.000 abstract 1
- 239000011591 potassium Substances 0.000 abstract 1
- 229910052701 rubidium Inorganic materials 0.000 abstract 1
- IGLNJRXAVVLDKE-UHFFFAOYSA-N rubidium atom Chemical compound [Rb] IGLNJRXAVVLDKE-UHFFFAOYSA-N 0.000 abstract 1
- 238000005185 salting out Methods 0.000 abstract 1
- KSMWLICLECSXMI-UHFFFAOYSA-N sodium;benzene Chemical compound [Na+].C1=CC=[C-]C=C1 KSMWLICLECSXMI-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
- C07F5/02—Boron compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
Abstract
Sodium tetraphenyl-boron, in which the phenyl radical may be substituted, is prepared by reacting the required phenyl magnesium halide with boron fluoride, and salting out the reaction mixture with sodium chloride, or by reacting the required phenyl sodium with boron fluoride. The sodium in the sodium tetraphenylboron obtained may be replaced in known manner by other monovalent cations, e.g. by potassium, ammonium, rubidium or caesium. In an example, sodium tetraphenylboron is prepared by reacting boron fluoride and phenylmagnesium bromide and adding sodium chloride to an ethereal solution of the reaction mixture. Lithium tetraphenylboron is also referred to.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE705719X | 1950-10-11 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB705719A true GB705719A (en) | 1954-03-17 |
Family
ID=6616974
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB23634/51A Expired GB705719A (en) | 1950-10-11 | 1951-10-10 | Complex metal tetra-phenyl boron salts |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB705719A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2982785A (en) * | 1959-01-07 | 1961-05-02 | Theodore R Mckenzie | Cesium recovery |
| US3119857A (en) * | 1955-05-09 | 1964-01-28 | Shell Oil Co | Process for the manufacture of organoboron halides and esters |
| US3187054A (en) * | 1957-04-12 | 1965-06-01 | United States Borax Chem | Production of organic compounds containing boron-carbon bonds |
| EP0913400A1 (en) * | 1997-03-10 | 1999-05-06 | Nippon Shokubai Co., Ltd. | Method for purifying tetrakis(fluoroaryl) borate/magnesium halide, tetrakis(fluoroaryl) borate/ether complex and process for preparing the same, and process for preparing tetrakis(fluoroaryl) borate derivative |
| US6248265B1 (en) | 1998-12-18 | 2001-06-19 | Albemarle Corporation | Clean generation of a fluoroaryl grignard reagent |
-
1951
- 1951-10-10 GB GB23634/51A patent/GB705719A/en not_active Expired
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3119857A (en) * | 1955-05-09 | 1964-01-28 | Shell Oil Co | Process for the manufacture of organoboron halides and esters |
| US3187054A (en) * | 1957-04-12 | 1965-06-01 | United States Borax Chem | Production of organic compounds containing boron-carbon bonds |
| US2982785A (en) * | 1959-01-07 | 1961-05-02 | Theodore R Mckenzie | Cesium recovery |
| EP0913400A1 (en) * | 1997-03-10 | 1999-05-06 | Nippon Shokubai Co., Ltd. | Method for purifying tetrakis(fluoroaryl) borate/magnesium halide, tetrakis(fluoroaryl) borate/ether complex and process for preparing the same, and process for preparing tetrakis(fluoroaryl) borate derivative |
| EP0913400A4 (en) * | 1997-03-10 | 2000-10-04 | Nippon Catalytic Chem Ind | Method for purifying tetrakis(fluoroaryl) borate/magnesium halide, tetrakis(fluoroaryl) borate/ether complex and process for preparing the same, and process for preparing tetrakis(fluoroaryl) borate derivative |
| US6215025B1 (en) | 1997-03-10 | 2001-04-10 | Nippon Shokubai Co., Ltd. | Method for purifying tetrakis (fluoroaryl) borate/magnesium halide, tetrakis (fluoroaryl) borate/ether complex and process for preparing the same, and process for preparing tetrakis (fluoroaryl) borate derivative |
| US6380435B2 (en) | 1997-03-10 | 2002-04-30 | Nippon Shokubai Co., Ltd. | Purifying process of tetrakis(fluoroaryl)borate.magnesium halide, tetrakis(fluoroaryl)borate·ether complex and producing process of the same, and producing process of tetrakis(fluoroaryl)borate derivative |
| US6624329B2 (en) | 1997-03-10 | 2003-09-23 | Nippon Shokubai Co., Ltd. | Purifying process of tetrakis (fluoroaryl) borate·magnesium halide, tetrakis (fluoroaryl) borate·ether complex and producing process of the same, and producing process of tetrakis (fluoroaryl) borate derivative |
| US6248265B1 (en) | 1998-12-18 | 2001-06-19 | Albemarle Corporation | Clean generation of a fluoroaryl grignard reagent |
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