GB984502A - Process for the production of adsorption agents - Google Patents

Process for the production of adsorption agents

Info

Publication number
GB984502A
GB984502A GB28262A GB28262A GB984502A GB 984502 A GB984502 A GB 984502A GB 28262 A GB28262 A GB 28262A GB 28262 A GB28262 A GB 28262A GB 984502 A GB984502 A GB 984502A
Authority
GB
United Kingdom
Prior art keywords
ions
sodium
alkali metal
added
soluble
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB28262A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
DAREX GmbH
Original Assignee
DAREX GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by DAREX GmbH filed Critical DAREX GmbH
Publication of GB984502A publication Critical patent/GB984502A/en
Expired legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
    • B01J20/16—Alumino-silicates
    • B01J20/18—Synthetic zeolitic molecular sieves
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B33/00—Silicon; Compounds thereof
    • C01B33/20—Silicates
    • C01B33/26—Aluminium-containing silicates, i.e. silico-aluminates
    • C01B33/28—Base exchange silicates, e.g. zeolites
    • C01B33/2807—Zeolitic silicoaluminates with a tridimensional crystalline structure possessing molecular sieve properties; Isomorphous compounds wherein a part of the aluminium ore of the silicon present may be replaced by other elements such as gallium, germanium, phosphorus; Preparation of zeolitic molecular sieves from molecular sieves of another type or from preformed reacting mixtures
    • C01B33/2884—Zeolitic silicoaluminates with a tridimensional crystalline structure possessing molecular sieve properties; Isomorphous compounds wherein a part of the aluminium ore of the silicon present may be replaced by other elements such as gallium, germanium, phosphorus; Preparation of zeolitic molecular sieves from molecular sieves of another type or from preformed reacting mixtures the aluminium or the silicon in the network being partly replaced

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Analytical Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)

Abstract

Synthetic zeolites of the general formulae 0.6-1.2 Me2O.Al2O3, 0-0.2 (Z2O3 or Z2O5), 1.22-4.5 SiO2, 0-7.2 H2O, where Me is an alkali metal and Z2O3 represents B2O3 or As2O3 and Z2O3 represents P2O3, As2O5\t or V2O5, are produced by adding to the reactent system borates, cosenites, arsenates, phosphates and/or vanadates. Sodium aluminite with an Al2O3 content of 54% by weight is preferably used as aluminium carrier and sodium metasilicate in anhydrous form or in the form of the hydrates Na2SiO3.SH2O or Na2SiO3.9H2O o a mixture of a silicic acid SO and the corresponding quantity of sodium hydroxide in the form of aqueous solutions are used as reactents for the formation of SiO2. The diaclochic ions are added as a solution of the corresponding alkali metal water-soluble salt of the meta form; in the case of P2O3 or As2O3, or as an aqueous solutio of the alkali metal water-soluble tertiary salt thereof. The sodium ions may be wholly or partially replaced by Pb++ or Zn++ions. Fluorine ions may be added to the reaction mixture. A water-soluble chlorinate and then a reducing agent such as sodium difluorite, which reduces the chromate ions to the trivalent state, may also be added to the reaction mixture. German Specification 1,174,149 is referred to.
GB28262A 1961-01-04 1962-01-03 Process for the production of adsorption agents Expired GB984502A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DES71945A DE1174749B (en) 1961-01-04 1961-01-04 Process for the production of modified synthetic molecular sieves

Publications (1)

Publication Number Publication Date
GB984502A true GB984502A (en) 1965-02-24

Family

ID=7502851

Family Applications (1)

Application Number Title Priority Date Filing Date
GB28262A Expired GB984502A (en) 1961-01-04 1962-01-03 Process for the production of adsorption agents

Country Status (2)

Country Link
DE (1) DE1174749B (en)
GB (1) GB984502A (en)

Cited By (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3622268A (en) * 1968-03-20 1971-11-23 Takeda Chemical Industries Ltd Method for recovery of metallic cations
US4091079A (en) * 1974-10-07 1978-05-23 W. R. Grace & Co. Zeolite VK-2
US4269813A (en) * 1977-09-26 1981-05-26 Standard Oil Company (Indiana) Crystalline borosilicate and process of preparation
US4285919A (en) * 1978-12-26 1981-08-25 Standard Oil Company (Indiana) Method of preparing a metal-cation-deficient crystalline borosilicate
US4440871A (en) * 1982-07-26 1984-04-03 Union Carbide Corporation Crystalline silicoaluminophosphates
US4456582A (en) * 1978-07-13 1984-06-26 Basf Aktiengesellschaft Manufacture of nitrogen-containing crystalline metal silicates having a zeolite structure
US4738837A (en) * 1984-04-13 1988-04-19 Union Carbide Corporation Chromium-aluminum-phosphorus-silicon-oxide molecular sieve compositions
US4744970A (en) * 1984-04-13 1988-05-17 Union Carbide Corporation Cobalt-aluminum-phosphorus-silicon-oxide molecular sieves
US4758419A (en) * 1984-04-13 1988-07-19 Union Carbide Corporation Magnesium-aluminum-phosphorus-silicon-oxide molecular sieve compositions
US4824554A (en) * 1984-04-13 1989-04-25 Uop Processes for the use of cobalt-aluminum-phosphorus-silicon-oxide molecular sieve compositions
US4882038A (en) * 1984-04-13 1989-11-21 Uop Process for the use of magnesium-aluminum-phosphorus-silicon-oxide molecular sieve compositions
US4894213A (en) * 1984-04-13 1990-01-16 Uop Arsenic-aluminum-phosphorus-silicon-oxide molecular sieve compositions
US4973460A (en) * 1984-04-13 1990-11-27 Uop Lithium-aluminum-phosphorus-silicon-oxide molecular sieve compositions
WO1991000845A1 (en) * 1989-07-13 1991-01-24 Mobil Oil Corporation Synthesis of zeolite zsm-35
WO1991000844A1 (en) * 1989-07-07 1991-01-24 Chevron Research And Technology Company Zeolite (b)ssz-24
US5057295A (en) * 1984-04-13 1991-10-15 Uop Boron-aluminum-phosphorus-silicon-oxide molecular sieve compositions

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB484549A (en) * 1936-09-30 1938-05-06 Burgess Zeolite Company Ltd Improvements in artificial zeolites and method of making the same

Cited By (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3622268A (en) * 1968-03-20 1971-11-23 Takeda Chemical Industries Ltd Method for recovery of metallic cations
US4091079A (en) * 1974-10-07 1978-05-23 W. R. Grace & Co. Zeolite VK-2
US4269813A (en) * 1977-09-26 1981-05-26 Standard Oil Company (Indiana) Crystalline borosilicate and process of preparation
US4456582A (en) * 1978-07-13 1984-06-26 Basf Aktiengesellschaft Manufacture of nitrogen-containing crystalline metal silicates having a zeolite structure
US4285919A (en) * 1978-12-26 1981-08-25 Standard Oil Company (Indiana) Method of preparing a metal-cation-deficient crystalline borosilicate
US4440871A (en) * 1982-07-26 1984-04-03 Union Carbide Corporation Crystalline silicoaluminophosphates
US4758419A (en) * 1984-04-13 1988-07-19 Union Carbide Corporation Magnesium-aluminum-phosphorus-silicon-oxide molecular sieve compositions
US4744970A (en) * 1984-04-13 1988-05-17 Union Carbide Corporation Cobalt-aluminum-phosphorus-silicon-oxide molecular sieves
US4738837A (en) * 1984-04-13 1988-04-19 Union Carbide Corporation Chromium-aluminum-phosphorus-silicon-oxide molecular sieve compositions
US4824554A (en) * 1984-04-13 1989-04-25 Uop Processes for the use of cobalt-aluminum-phosphorus-silicon-oxide molecular sieve compositions
US4882038A (en) * 1984-04-13 1989-11-21 Uop Process for the use of magnesium-aluminum-phosphorus-silicon-oxide molecular sieve compositions
US4894213A (en) * 1984-04-13 1990-01-16 Uop Arsenic-aluminum-phosphorus-silicon-oxide molecular sieve compositions
US4973460A (en) * 1984-04-13 1990-11-27 Uop Lithium-aluminum-phosphorus-silicon-oxide molecular sieve compositions
US5057295A (en) * 1984-04-13 1991-10-15 Uop Boron-aluminum-phosphorus-silicon-oxide molecular sieve compositions
WO1991000844A1 (en) * 1989-07-07 1991-01-24 Chevron Research And Technology Company Zeolite (b)ssz-24
WO1991000845A1 (en) * 1989-07-13 1991-01-24 Mobil Oil Corporation Synthesis of zeolite zsm-35

Also Published As

Publication number Publication date
DE1174749B (en) 1964-07-30

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