GB697977A - Process for the manufacture of hydroxy-indazoles - Google Patents

Process for the manufacture of hydroxy-indazoles

Info

Publication number
GB697977A
GB697977A GB25479/50A GB2547950A GB697977A GB 697977 A GB697977 A GB 697977A GB 25479/50 A GB25479/50 A GB 25479/50A GB 2547950 A GB2547950 A GB 2547950A GB 697977 A GB697977 A GB 697977A
Authority
GB
United Kingdom
Prior art keywords
hydroxy
indazoles
indazole
hydroxyindazole
separates
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB25479/50A
Inventor
Dennis Arthur William Adams
Robert Ronald Davies
Robert Hugh Wilson
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Imperial Chemical Industries Ltd
Original Assignee
Imperial Chemical Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Imperial Chemical Industries Ltd filed Critical Imperial Chemical Industries Ltd
Priority to GB25479/50A priority Critical patent/GB697977A/en
Publication of GB697977A publication Critical patent/GB697977A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D231/00Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
    • C07D231/54Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings condensed with carbocyclic rings or ring systems
    • C07D231/56Benzopyrazoles; Hydrogenated benzopyrazoles

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Hydroxy-indazoles, particularly 6-hydroxyindazole, are prepared by heating the corresponding amino-indazole with dilute sulphuric acid under pressure at a temperature between 150 DEG and 210 DEG C. Novel hydroxy-indazoles mentioned include 4-, 5-, and 7-hydroxyindazoles, and 4-, 5-, 6-and 7-hydroxy-indazoles, when further substituted by methyl groups. In examples: (1) 6-amino-indazole is heated at 175 DEG C. with 10 per cent sulphuric acid in an autoclave, neutralized with caustic soda, when 6-hydroxy-indazole separates; (2) 5-aminoindazole is treated as in (1), and 5-hydroxyindazole separates upon the addition of salt to the neutralized solution.
GB25479/50A 1950-10-19 1950-10-19 Process for the manufacture of hydroxy-indazoles Expired GB697977A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB25479/50A GB697977A (en) 1950-10-19 1950-10-19 Process for the manufacture of hydroxy-indazoles

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB25479/50A GB697977A (en) 1950-10-19 1950-10-19 Process for the manufacture of hydroxy-indazoles

Publications (1)

Publication Number Publication Date
GB697977A true GB697977A (en) 1953-10-07

Family

ID=10228370

Family Applications (1)

Application Number Title Priority Date Filing Date
GB25479/50A Expired GB697977A (en) 1950-10-19 1950-10-19 Process for the manufacture of hydroxy-indazoles

Country Status (1)

Country Link
GB (1) GB697977A (en)

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