GB657252A - Improvements in or relating to the treatment of pyrolysis apparatus - Google Patents

Improvements in or relating to the treatment of pyrolysis apparatus

Info

Publication number
GB657252A
GB657252A GB1103/49A GB110349A GB657252A GB 657252 A GB657252 A GB 657252A GB 1103/49 A GB1103/49 A GB 1103/49A GB 110349 A GB110349 A GB 110349A GB 657252 A GB657252 A GB 657252A
Authority
GB
United Kingdom
Prior art keywords
per
coke
temperature
per cent
pyrolysis
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB1103/49A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Standard Oil Development Co
Original Assignee
Standard Oil Development Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Standard Oil Development Co filed Critical Standard Oil Development Co
Publication of GB657252A publication Critical patent/GB657252A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23GCLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
    • C23G5/00Cleaning or de-greasing metallic material by other methods; Apparatus for cleaning or de-greasing metallic material with organic solvents
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/0006Controlling or regulating processes
    • B01J19/002Avoiding undesirable reactions or side-effects, e.g. avoiding explosions, or improving the yield by suppressing side-reactions
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/0006Controlling or regulating processes
    • B01J19/002Avoiding undesirable reactions or side-effects, e.g. avoiding explosions, or improving the yield by suppressing side-reactions
    • B01J19/0026Avoiding carbon deposits
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/87Preparation of ketenes or dimeric ketenes
    • C07C45/88Preparation of ketenes or dimeric ketenes from ketones
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/87Preparation of ketenes or dimeric ketenes
    • C07C45/89Preparation of ketenes or dimeric ketenes from carboxylic acids, their anhydrides, esters or halides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049Controlling or regulating processes
    • B01J2219/00245Avoiding undesirable reactions or side-effects
    • B01J2219/00252Formation of deposits other than coke

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

The inner surface of cracking vessels made of high nickel high chromium steel is subjected to a pyrolysis reaction until a substantial amount of coke has been deposited thereon, then treated with steam and air at 1400-1800 DEG F. until the coke is removed, the process being repeated until deposition of coke ceases and the temperature during the last few regenerating stages being 1400-1500 DEG F. The vessel may be in the form of a long tube, which may be coiled, formed from an alloy comprising 23-27 per cent Cr., 12-20 per cent Ni, less than 0.2 per cent C, the balance being iron. The temperature may be reduced to 1100 DEG F. between each regeneration and pyrolysis stage and brought back to pyrolysis temperature at 10-50 DEG F. per hour, during which time the substance to be cracked, e.g. acetone, is passed through at a mass velocity of 10-50 lbs. per sq. ft. per second and with a contact time of 0.1 to 1.0 second.ALSO:The inner surface of cracking vessels made of high-nickel high-chromium steel is subjected to a pyrolysis reaction until a substantial amount of coke has been deposited thereon, then treated with steam and air at 1400-1800 DEG F until the coke is removed, the process being repeated until deposition of coke ceases and the temperature during the last few regenerating stages being 1400-1500 DEG F. The vessel may be in the form of a long tube, which may be coiled, formed from an alloy comprising 23-27 per cent Cr, 12-20 per cent Ni, less than 0.2 per cent C the balance being iron. The temperature may be reduced to below 1100 DEG F between each regeneration and pyrolysis stage and brought back to pyrolysis temperature at 10-50 DEG F per hour, during which time the substance to be cracked, e.g. acetone, is passed through at a mass velocity of 10-15 lbs. per sq. ft. per second and with a contact time of 0.1 to 1.0 second.
GB1103/49A 1948-06-04 1949-01-14 Improvements in or relating to the treatment of pyrolysis apparatus Expired GB657252A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US657252XA 1948-06-04 1948-06-04

Publications (1)

Publication Number Publication Date
GB657252A true GB657252A (en) 1951-09-12

Family

ID=22064670

Family Applications (1)

Application Number Title Priority Date Filing Date
GB1103/49A Expired GB657252A (en) 1948-06-04 1949-01-14 Improvements in or relating to the treatment of pyrolysis apparatus

Country Status (1)

Country Link
GB (1) GB657252A (en)

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