GB449060A - A process for the production of high molecular 1.2-glycols - Google Patents

A process for the production of high molecular 1.2-glycols

Info

Publication number
GB449060A
GB449060A GB25383/35A GB2538335A GB449060A GB 449060 A GB449060 A GB 449060A GB 25383/35 A GB25383/35 A GB 25383/35A GB 2538335 A GB2538335 A GB 2538335A GB 449060 A GB449060 A GB 449060A
Authority
GB
United Kingdom
Prior art keywords
glycols
carbon atoms
stated
hydrogen peroxide
olefines
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB25383/35A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Boehme Fettchemie GmbH
Original Assignee
Boehme Fettchemie GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Boehme Fettchemie GmbH filed Critical Boehme Fettchemie GmbH
Publication of GB449060A publication Critical patent/GB449060A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C31/00—Saturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
    • C07C31/18—Polyhydroxylic acyclic alcohols
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C31/00—Saturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
    • C07C31/18—Polyhydroxylic acyclic alcohols
    • C07C31/20—Dihydroxylic alcohols

Abstract

1 : 2-Olefines containing at least eight carbon atoms in the molecule are heated with hydrogen peroxide in the presence of an aliphatic acid having not less than two and not more than four carbon atoms whereby glycols are produced. In an example, 1 : 2-hexadecene dissolved in glacial acetic acid is treated with hydrogen peroxide to give the mono acetyl derivative of 1 : 2-hexadecanediol, which is saponified to obtain the corresponding glycol. A small quantity of a monobasic acid is also obtained. The a -oxysulphuric esters and a -oxysulphonic acids of the glycols are mentioned. The glycols are stated to be emulsifying-agents.ALSO:Higher glycols derived, by oxidation, from 1 : 2-olefines having at least eight carbon atoms are stated to have emulsifying properties.
GB25383/35A 1934-10-27 1935-09-12 A process for the production of high molecular 1.2-glycols Expired GB449060A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE449060X 1934-10-27

Publications (1)

Publication Number Publication Date
GB449060A true GB449060A (en) 1936-06-19

Family

ID=6538209

Family Applications (1)

Application Number Title Priority Date Filing Date
GB25383/35A Expired GB449060A (en) 1934-10-27 1935-09-12 A process for the production of high molecular 1.2-glycols

Country Status (1)

Country Link
GB (1) GB449060A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2500599A (en) * 1944-12-19 1950-03-14 Shell Dev Catalytic hydroxylation of olefinic compounds
US2701813A (en) * 1951-03-08 1955-02-08 Houdry Process Corp Process for the partial oxidation of olefins to form glycols and esters thereof
EP0010236A1 (en) * 1978-10-13 1980-04-30 Ruhrchemie Aktiengesellschaft Process for the synthesis of 2,3-dimethyl-2,3-butane diol

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2500599A (en) * 1944-12-19 1950-03-14 Shell Dev Catalytic hydroxylation of olefinic compounds
US2701813A (en) * 1951-03-08 1955-02-08 Houdry Process Corp Process for the partial oxidation of olefins to form glycols and esters thereof
EP0010236A1 (en) * 1978-10-13 1980-04-30 Ruhrchemie Aktiengesellschaft Process for the synthesis of 2,3-dimethyl-2,3-butane diol

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