GB273743A - Improvements in or relating to the manufacture or treatment of cellulose esters - Google Patents

Improvements in or relating to the manufacture or treatment of cellulose esters

Info

Publication number
GB273743A
GB273743A GB17523/27A GB1752327A GB273743A GB 273743 A GB273743 A GB 273743A GB 17523/27 A GB17523/27 A GB 17523/27A GB 1752327 A GB1752327 A GB 1752327A GB 273743 A GB273743 A GB 273743A
Authority
GB
United Kingdom
Prior art keywords
cellulose
treatment
hydrogen peroxide
acetylation
iron
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB17523/27A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Acordis UK Ltd
Original Assignee
British Celanese Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by British Celanese Ltd filed Critical British Celanese Ltd
Publication of GB273743A publication Critical patent/GB273743A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08BPOLYSACCHARIDES; DERIVATIVES THEREOF
    • C08B3/00Preparation of cellulose esters of organic acids
    • C08B3/22Post-esterification treatments, including purification
    • C08B3/24Hydrolysis or ripening

Abstract

273,743. British Celanese, Ltd., (Assignees of Schneider, G., and Dreyfus, C.). July 2, 1926, [Convention date]. Cellulose acetates and other carboxylates; cellulose nitrates.-The viscosity characteristics of cellulose esters, particularly cellulose acetates, are lowered by treatment with hydrogen peroxide in the presence of an irou salt preferably a ferrous salt. The treatment may he carried out with the ester in suspension or in solution as in the original acetylation mixture. In examples, a solution of cellulose acetate in acetic acid as obtained on the completion of the acetylation process, is treated with hydrogen peroxide solution and ferrous acetate, and then allowed to stand; alternatively, if the acetylation is carried out in an iron vessel, the addition of the iron salt may be omitted; cellulose is acetylated by means of a mixture of acetic anhydride, acetic acid, and sulphuric acid containing a small proportion of ferrous acetate, and after completion of the acetylation, hydrogen peroxide solution is added; cellulose butyrate dissolved in acetic or butyric acid as obtained by carrying out the esterification in an iron vessel, is treated with hydrogen peroxide solution. The treatment may also be applied to nitrocellulose in the form of a neutral solid. The Specification, as open to inspection under Sect. 91 (3) (a), refers to the treatment of cellulose esters with hydrogen peroxide in the presence of iron. This subject-matter does not appear in the Specification as accepted.
GB17523/27A 1926-07-02 1927-07-01 Improvements in or relating to the manufacture or treatment of cellulose esters Expired GB273743A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US273743XA 1926-07-02 1926-07-02

Publications (1)

Publication Number Publication Date
GB273743A true GB273743A (en) 1928-05-10

Family

ID=21837363

Family Applications (1)

Application Number Title Priority Date Filing Date
GB17523/27A Expired GB273743A (en) 1926-07-02 1927-07-01 Improvements in or relating to the manufacture or treatment of cellulose esters

Country Status (1)

Country Link
GB (1) GB273743A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1141448B (en) * 1957-01-09 1962-12-20 Hoechst Ag Process for lowering the viscosity of aqueous polyvinyl ester or vinyl ester copolymer dispersions with high solids contents

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1141448B (en) * 1957-01-09 1962-12-20 Hoechst Ag Process for lowering the viscosity of aqueous polyvinyl ester or vinyl ester copolymer dispersions with high solids contents

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