GB438548A - Improvements in the manufacture and production of polymerisation products of acetylene - Google Patents
Improvements in the manufacture and production of polymerisation products of acetyleneInfo
- Publication number
- GB438548A GB438548A GB2718134A GB2718134A GB438548A GB 438548 A GB438548 A GB 438548A GB 2718134 A GB2718134 A GB 2718134A GB 2718134 A GB2718134 A GB 2718134A GB 438548 A GB438548 A GB 438548A
- Authority
- GB
- United Kingdom
- Prior art keywords
- acetylene
- copper
- chloride
- salt
- copper powder
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
- C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
- C07C2/38—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of dienes or alkynes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- C07C2527/06—Halogens; Compounds thereof
- C07C2527/08—Halides
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Polymerization Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
In the manufacture of monovinylacetylene and other acetylene polymerization products by treating acetylene with acid aqueous cuprous salt solutions, use is made of cuprous salt solutions not containing a nitrogenous base or a salt thereof, but containing a salt or salts of an alkali or alkaline-earth metal, including magnesium, or of a metal of the third periodic group, including the rare-earth metals; the halides of the specified metals are preferred. The acidity of the solution may be adjusted by addition of an inorganic or organic acid, and the oxidation of the cuprous salt may be restrained by addition of copper or by the use of apparatus made wholly or in part of copper. Concentrated or dilute acetylene may be used. Examples are given in which monovinylacetylene and other acetylene polymerization products are obtained with the aid of aqueous cuprous chloride solutions containing (1) sodium chloride and copper powder, (2) sodium silicate, (3) lithium chloride and copper powder, (4) barium chloride and copper powder, (5) aluminium chloride and copper. Specifications 384,654 and 390,179 are referred to.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB2718134A GB438548A (en) | 1934-09-21 | 1934-09-21 | Improvements in the manufacture and production of polymerisation products of acetylene |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB2718134A GB438548A (en) | 1934-09-21 | 1934-09-21 | Improvements in the manufacture and production of polymerisation products of acetylene |
Publications (1)
Publication Number | Publication Date |
---|---|
GB438548A true GB438548A (en) | 1935-11-19 |
Family
ID=10255503
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB2718134A Expired GB438548A (en) | 1934-09-21 | 1934-09-21 | Improvements in the manufacture and production of polymerisation products of acetylene |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB438548A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2743264A (en) * | 1953-01-21 | 1956-04-24 | Air Reduction | Catalytic polymerization of acetylene |
-
1934
- 1934-09-21 GB GB2718134A patent/GB438548A/en not_active Expired
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2743264A (en) * | 1953-01-21 | 1956-04-24 | Air Reduction | Catalytic polymerization of acetylene |
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