GB2365215A - Composite diffusion barrier for protecting copper interconnects in low dielectric constant materials from oxidation - Google Patents
Composite diffusion barrier for protecting copper interconnects in low dielectric constant materials from oxidation Download PDFInfo
- Publication number
- GB2365215A GB2365215A GB0101254A GB0101254A GB2365215A GB 2365215 A GB2365215 A GB 2365215A GB 0101254 A GB0101254 A GB 0101254A GB 0101254 A GB0101254 A GB 0101254A GB 2365215 A GB2365215 A GB 2365215A
- Authority
- GB
- United Kingdom
- Prior art keywords
- copper
- insulator
- forming
- recited
- diffusion barrier
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 230000004888 barrier function Effects 0.000 title claims abstract description 55
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 title claims abstract description 54
- 238000009792 diffusion process Methods 0.000 title claims abstract description 33
- 239000010949 copper Substances 0.000 title claims abstract description 29
- 239000002131 composite material Substances 0.000 title claims abstract description 16
- 239000000463 material Substances 0.000 title claims description 52
- 229910052802 copper Inorganic materials 0.000 title claims description 28
- 230000003647 oxidation Effects 0.000 title abstract description 20
- 238000007254 oxidation reaction Methods 0.000 title abstract description 20
- 239000012212 insulator Substances 0.000 claims abstract description 37
- 239000004020 conductor Substances 0.000 claims abstract description 36
- 230000001681 protective effect Effects 0.000 claims abstract description 24
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 21
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 21
- 239000001301 oxygen Substances 0.000 claims abstract description 21
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 20
- 239000004065 semiconductor Substances 0.000 claims abstract description 14
- 150000004767 nitrides Chemical class 0.000 claims abstract description 9
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 7
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000010703 silicon Substances 0.000 claims abstract description 6
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 6
- 238000011065 in-situ storage Methods 0.000 claims abstract description 5
- 230000008439 repair process Effects 0.000 claims abstract description 5
- 238000000034 method Methods 0.000 claims description 28
- 238000004519 manufacturing process Methods 0.000 claims description 7
- 230000001590 oxidative effect Effects 0.000 claims description 3
- 206010011416 Croup infectious Diseases 0.000 claims 1
- 201000010549 croup Diseases 0.000 claims 1
- 230000007547 defect Effects 0.000 abstract description 10
- 229910052715 tantalum Inorganic materials 0.000 abstract description 5
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 abstract description 5
- MZLGASXMSKOWSE-UHFFFAOYSA-N tantalum nitride Chemical compound [Ta]#N MZLGASXMSKOWSE-UHFFFAOYSA-N 0.000 abstract description 5
- 239000004411 aluminium Substances 0.000 abstract description 3
- 230000009977 dual effect Effects 0.000 abstract 1
- 230000035699 permeability Effects 0.000 abstract 1
- 230000008569 process Effects 0.000 description 15
- 229910052751 metal Inorganic materials 0.000 description 6
- 239000002184 metal Substances 0.000 description 6
- 230000008901 benefit Effects 0.000 description 4
- 230000010354 integration Effects 0.000 description 4
- 239000003989 dielectric material Substances 0.000 description 3
- 238000005530 etching Methods 0.000 description 3
- 238000007789 sealing Methods 0.000 description 3
- 229910052581 Si3N4 Inorganic materials 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000005229 chemical vapour deposition Methods 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000000151 deposition Methods 0.000 description 2
- 230000006866 deterioration Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 2
- 229910052737 gold Inorganic materials 0.000 description 2
- 239000010931 gold Substances 0.000 description 2
- 230000036039 immunity Effects 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 description 2
- 230000007704 transition Effects 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 229910000577 Silicon-germanium Inorganic materials 0.000 description 1
- LEVVHYCKPQWKOP-UHFFFAOYSA-N [Si].[Ge] Chemical compound [Si].[Ge] LEVVHYCKPQWKOP-UHFFFAOYSA-N 0.000 description 1
- 230000003466 anti-cipated effect Effects 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 229910052732 germanium Inorganic materials 0.000 description 1
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 description 1
- 238000002513 implantation Methods 0.000 description 1
- 238000001459 lithography Methods 0.000 description 1
- 230000000873 masking effect Effects 0.000 description 1
- 238000001465 metallisation Methods 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 230000005012 migration Effects 0.000 description 1
- 238000013508 migration Methods 0.000 description 1
- 229920000620 organic polymer Polymers 0.000 description 1
- 238000002161 passivation Methods 0.000 description 1
- 238000000059 patterning Methods 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 239000003870 refractory metal Substances 0.000 description 1
- 229910052814 silicon oxide Inorganic materials 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 238000004544 sputter deposition Methods 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/70—Manufacture or treatment of devices consisting of a plurality of solid state components formed in or on a common substrate or of parts thereof; Manufacture of integrated circuit devices or of parts thereof
- H01L21/71—Manufacture of specific parts of devices defined in group H01L21/70
- H01L21/768—Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics
- H01L21/76838—Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics characterised by the formation and the after-treatment of the conductors
- H01L21/76841—Barrier, adhesion or liner layers
- H01L21/76843—Barrier, adhesion or liner layers formed in openings in a dielectric
- H01L21/76846—Layer combinations
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/28—Manufacture of electrodes on semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/268
- H01L21/283—Deposition of conductive or insulating materials for electrodes conducting electric current
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/70—Manufacture or treatment of devices consisting of a plurality of solid state components formed in or on a common substrate or of parts thereof; Manufacture of integrated circuit devices or of parts thereof
- H01L21/71—Manufacture of specific parts of devices defined in group H01L21/70
- H01L21/768—Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics
- H01L21/76838—Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics characterised by the formation and the after-treatment of the conductors
- H01L21/76841—Barrier, adhesion or liner layers
- H01L21/76843—Barrier, adhesion or liner layers formed in openings in a dielectric
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/70—Manufacture or treatment of devices consisting of a plurality of solid state components formed in or on a common substrate or of parts thereof; Manufacture of integrated circuit devices or of parts thereof
- H01L21/71—Manufacture of specific parts of devices defined in group H01L21/70
- H01L21/768—Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics
- H01L21/76838—Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics characterised by the formation and the after-treatment of the conductors
- H01L21/76841—Barrier, adhesion or liner layers
- H01L21/76853—Barrier, adhesion or liner layers characterized by particular after-treatment steps
- H01L21/76855—After-treatment introducing at least one additional element into the layer
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L23/00—Details of semiconductor or other solid state devices
- H01L23/52—Arrangements for conducting electric current within the device in operation from one component to another, i.e. interconnections, e.g. wires, lead frames
- H01L23/522—Arrangements for conducting electric current within the device in operation from one component to another, i.e. interconnections, e.g. wires, lead frames including external interconnections consisting of a multilayer structure of conductive and insulating layers inseparably formed on the semiconductor body
- H01L23/532—Arrangements for conducting electric current within the device in operation from one component to another, i.e. interconnections, e.g. wires, lead frames including external interconnections consisting of a multilayer structure of conductive and insulating layers inseparably formed on the semiconductor body characterised by the materials
- H01L23/53204—Conductive materials
- H01L23/53209—Conductive materials based on metals, e.g. alloys, metal silicides
- H01L23/53228—Conductive materials based on metals, e.g. alloys, metal silicides the principal metal being copper
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L23/00—Details of semiconductor or other solid state devices
- H01L23/52—Arrangements for conducting electric current within the device in operation from one component to another, i.e. interconnections, e.g. wires, lead frames
- H01L23/522—Arrangements for conducting electric current within the device in operation from one component to another, i.e. interconnections, e.g. wires, lead frames including external interconnections consisting of a multilayer structure of conductive and insulating layers inseparably formed on the semiconductor body
- H01L23/532—Arrangements for conducting electric current within the device in operation from one component to another, i.e. interconnections, e.g. wires, lead frames including external interconnections consisting of a multilayer structure of conductive and insulating layers inseparably formed on the semiconductor body characterised by the materials
- H01L23/53204—Conductive materials
- H01L23/53209—Conductive materials based on metals, e.g. alloys, metal silicides
- H01L23/53228—Conductive materials based on metals, e.g. alloys, metal silicides the principal metal being copper
- H01L23/53238—Additional layers associated with copper layers, e.g. adhesion, barrier, cladding layers
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L2924/00—Indexing scheme for arrangements or methods for connecting or disconnecting semiconductor or solid-state bodies as covered by H01L24/00
- H01L2924/0001—Technical content checked by a classifier
- H01L2924/0002—Not covered by any one of groups H01L24/00, H01L24/00 and H01L2224/00
Landscapes
- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- General Physics & Mathematics (AREA)
- Computer Hardware Design (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Power Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Internal Circuitry In Semiconductor Integrated Circuit Devices (AREA)
- Formation Of Insulating Films (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US53385100A | 2000-03-23 | 2000-03-23 |
Publications (2)
Publication Number | Publication Date |
---|---|
GB0101254D0 GB0101254D0 (en) | 2001-02-28 |
GB2365215A true GB2365215A (en) | 2002-02-13 |
Family
ID=24127691
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB0101254A Withdrawn GB2365215A (en) | 2000-03-23 | 2001-01-18 | Composite diffusion barrier for protecting copper interconnects in low dielectric constant materials from oxidation |
Country Status (5)
Country | Link |
---|---|
JP (1) | JP2001313296A (ko) |
KR (1) | KR20010092679A (ko) |
CN (1) | CN1319891A (ko) |
GB (1) | GB2365215A (ko) |
TW (1) | TW478101B (ko) |
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2387027A (en) * | 2002-01-02 | 2003-10-01 | Agere Systems Inc | Split barrier layer including nitrogen-containing portion and oxygen-containing portion |
WO2006048823A1 (en) * | 2004-11-08 | 2006-05-11 | Koninklijke Philips Electronics N.V. | Planarising damascene structures |
US7335990B2 (en) | 2004-04-27 | 2008-02-26 | Agency For Science, Technology And Research | Process of forming a composite diffusion barrier in copper/organic low-k damascene technology |
US7698012B2 (en) | 2001-06-19 | 2010-04-13 | Applied Materials, Inc. | Dynamic metrology schemes and sampling schemes for advanced process control in semiconductor processing |
US7966087B2 (en) | 2002-11-15 | 2011-06-21 | Applied Materials, Inc. | Method, system and medium for controlling manufacture process having multivariate input parameters |
US8070909B2 (en) | 2001-06-19 | 2011-12-06 | Applied Materials, Inc. | Feedback control of chemical mechanical polishing device providing manipulation of removal rate profiles |
US8504620B2 (en) | 2000-11-30 | 2013-08-06 | Applied Materials, Inc. | Dynamic subject information generation in message services of distributed object systems |
US8884441B2 (en) | 2013-02-18 | 2014-11-11 | Taiwan Semiconductor Manufacturing Co., Ltd. | Process of ultra thick trench etch with multi-slope profile |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP3648480B2 (ja) * | 2001-12-26 | 2005-05-18 | 株式会社東芝 | 半導体装置およびその製造方法 |
JP4266901B2 (ja) * | 2003-09-30 | 2009-05-27 | 三洋電機株式会社 | 半導体装置およびその製造方法 |
US9368448B2 (en) * | 2013-12-20 | 2016-06-14 | Applied Materials, Inc. | Metal-containing films as dielectric capping barrier for advanced interconnects |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0472804A2 (en) * | 1990-08-01 | 1992-03-04 | International Business Machines Corporation | Copper-semiconductor compounds capable of being produced at room temperature |
WO1998032175A1 (en) * | 1997-01-16 | 1998-07-23 | Koninklijke Philips Electronics N.V. | Semiconductor device provided with a metallization with a barrier layer comprising at least titanium, tungsten, or nitrogen, and method of manufacturing same |
US5913147A (en) * | 1997-01-21 | 1999-06-15 | Advanced Micro Devices, Inc. | Method for fabricating copper-aluminum metallization |
US6015749A (en) * | 1998-05-04 | 2000-01-18 | Taiwan Semiconductor Manufacturing Company | Method to improve adhesion between copper and titanium nitride, for copper interconnect structures, via the use of an ion implantation procedure |
-
2000
- 2000-12-29 TW TW089128210A patent/TW478101B/zh not_active IP Right Cessation
-
2001
- 2001-01-18 GB GB0101254A patent/GB2365215A/en not_active Withdrawn
- 2001-03-02 KR KR1020010010781A patent/KR20010092679A/ko not_active Application Discontinuation
- 2001-03-21 JP JP2001081508A patent/JP2001313296A/ja active Pending
- 2001-03-22 CN CN01111894A patent/CN1319891A/zh active Pending
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0472804A2 (en) * | 1990-08-01 | 1992-03-04 | International Business Machines Corporation | Copper-semiconductor compounds capable of being produced at room temperature |
WO1998032175A1 (en) * | 1997-01-16 | 1998-07-23 | Koninklijke Philips Electronics N.V. | Semiconductor device provided with a metallization with a barrier layer comprising at least titanium, tungsten, or nitrogen, and method of manufacturing same |
US5913147A (en) * | 1997-01-21 | 1999-06-15 | Advanced Micro Devices, Inc. | Method for fabricating copper-aluminum metallization |
US6015749A (en) * | 1998-05-04 | 2000-01-18 | Taiwan Semiconductor Manufacturing Company | Method to improve adhesion between copper and titanium nitride, for copper interconnect structures, via the use of an ion implantation procedure |
Cited By (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8504620B2 (en) | 2000-11-30 | 2013-08-06 | Applied Materials, Inc. | Dynamic subject information generation in message services of distributed object systems |
US7783375B2 (en) | 2001-06-19 | 2010-08-24 | Applied Materials, Inc. | Dynamic metrology schemes and sampling schemes for advanced process control in semiconductor processing |
US8694145B2 (en) | 2001-06-19 | 2014-04-08 | Applied Materials, Inc. | Feedback control of a chemical mechanical polishing device providing manipulation of removal rate profiles |
US8070909B2 (en) | 2001-06-19 | 2011-12-06 | Applied Materials, Inc. | Feedback control of chemical mechanical polishing device providing manipulation of removal rate profiles |
US7698012B2 (en) | 2001-06-19 | 2010-04-13 | Applied Materials, Inc. | Dynamic metrology schemes and sampling schemes for advanced process control in semiconductor processing |
US7725208B2 (en) | 2001-06-19 | 2010-05-25 | Applied Materials, Inc. | Dynamic metrology schemes and sampling schemes for advanced process control in semiconductor processing |
US6879046B2 (en) | 2001-06-28 | 2005-04-12 | Agere Systems Inc. | Split barrier layer including nitrogen-containing portion and oxygen-containing portion |
GB2387027B (en) * | 2002-01-02 | 2006-07-12 | Agere Systems Inc | Split barrier layer including nitrogen-containing portion and oxygen-containing portion |
GB2387027A (en) * | 2002-01-02 | 2003-10-01 | Agere Systems Inc | Split barrier layer including nitrogen-containing portion and oxygen-containing portion |
US7966087B2 (en) | 2002-11-15 | 2011-06-21 | Applied Materials, Inc. | Method, system and medium for controlling manufacture process having multivariate input parameters |
US7335990B2 (en) | 2004-04-27 | 2008-02-26 | Agency For Science, Technology And Research | Process of forming a composite diffusion barrier in copper/organic low-k damascene technology |
US8012872B2 (en) | 2004-11-08 | 2011-09-06 | Nxp B.V. | Planarising damascene structures |
WO2006048823A1 (en) * | 2004-11-08 | 2006-05-11 | Koninklijke Philips Electronics N.V. | Planarising damascene structures |
US8884441B2 (en) | 2013-02-18 | 2014-11-11 | Taiwan Semiconductor Manufacturing Co., Ltd. | Process of ultra thick trench etch with multi-slope profile |
Also Published As
Publication number | Publication date |
---|---|
TW478101B (en) | 2002-03-01 |
KR20010092679A (ko) | 2001-10-26 |
GB0101254D0 (en) | 2001-02-28 |
JP2001313296A (ja) | 2001-11-09 |
CN1319891A (zh) | 2001-10-31 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
WAP | Application withdrawn, taken to be withdrawn or refused ** after publication under section 16(1) |