GB1516861A - Catalyst composition for polymerization of conjugated dienes - Google Patents
Catalyst composition for polymerization of conjugated dienesInfo
- Publication number
- GB1516861A GB1516861A GB24148/75A GB2414875A GB1516861A GB 1516861 A GB1516861 A GB 1516861A GB 24148/75 A GB24148/75 A GB 24148/75A GB 2414875 A GB2414875 A GB 2414875A GB 1516861 A GB1516861 A GB 1516861A
- Authority
- GB
- United Kingdom
- Prior art keywords
- catalyst
- compound
- conjugated dienes
- barium
- lithium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000003054 catalyst Substances 0.000 title abstract 4
- 150000001993 dienes Chemical class 0.000 title abstract 3
- 238000006116 polymerization reaction Methods 0.000 title abstract 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 abstract 4
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 abstract 3
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 abstract 2
- MZRVEZGGRBJDDB-UHFFFAOYSA-N N-Butyllithium Chemical compound [Li]CCCC MZRVEZGGRBJDDB-UHFFFAOYSA-N 0.000 abstract 2
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 abstract 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 abstract 2
- DXIJHCSGLOHNES-UHFFFAOYSA-N 3,3-dimethylbut-1-enylbenzene Chemical compound CC(C)(C)C=CC1=CC=CC=C1 DXIJHCSGLOHNES-UHFFFAOYSA-N 0.000 abstract 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 abstract 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 abstract 1
- 239000004411 aluminium Substances 0.000 abstract 1
- 229910052782 aluminium Inorganic materials 0.000 abstract 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract 1
- -1 aromatic vinyl compound Chemical class 0.000 abstract 1
- 229910052788 barium Inorganic materials 0.000 abstract 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 abstract 1
- DJHZYHWLGNJISM-FDGPNNRMSA-L barium(2+);(z)-4-oxopent-2-en-2-olate Chemical compound [Ba+2].C\C([O-])=C\C(C)=O.C\C([O-])=C\C(C)=O DJHZYHWLGNJISM-FDGPNNRMSA-L 0.000 abstract 1
- OODSDKNMZMPBKJ-UHFFFAOYSA-N barium;1,3-diphenylpropane-1,3-dione Chemical compound [Ba].C=1C=CC=CC=1C(=O)CC(=O)C1=CC=CC=C1 OODSDKNMZMPBKJ-UHFFFAOYSA-N 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 238000007334 copolymerization reaction Methods 0.000 abstract 1
- HQWPLXHWEZZGKY-UHFFFAOYSA-N diethylzinc Chemical compound CC[Zn]CC HQWPLXHWEZZGKY-UHFFFAOYSA-N 0.000 abstract 1
- 150000004678 hydrides Chemical class 0.000 abstract 1
- 229910052744 lithium Inorganic materials 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 125000005609 naphthenate group Chemical group 0.000 abstract 1
- 125000001400 nonyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 abstract 1
- 150000002900 organolithium compounds Chemical class 0.000 abstract 1
- 150000002902 organometallic compounds Chemical class 0.000 abstract 1
- 230000000737 periodic effect Effects 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 abstract 1
- HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical compound C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 abstract 1
- 229910052712 strontium Inorganic materials 0.000 abstract 1
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 abstract 1
- 229920002554 vinyl polymer Polymers 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerization Catalysts (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR7419475A FR2273822A1 (fr) | 1974-06-05 | 1974-06-05 | Polymeres ou copolymeres a composition sterique modifiee, obtenus par mise en oeuvre d'une nouvelle composition catalytique |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1516861A true GB1516861A (en) | 1978-07-05 |
Family
ID=9139681
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB24148/75A Expired GB1516861A (en) | 1974-06-05 | 1975-06-04 | Catalyst composition for polymerization of conjugated dienes |
Country Status (21)
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3023785A1 (de) | 1980-02-25 | 1981-09-03 | The General Tire & Rubber Co., 44329 Akron, Ohio | Katalysatormasse und ihre verwendung bei einem polymerisationsverfahren |
US4297240A (en) | 1980-02-25 | 1981-10-27 | The General Tire & Rubber Company | Solution polymerization |
WO2003037946A3 (fr) * | 2001-10-31 | 2003-09-25 | Michelin Soc Tech | Procede de preparation de copolymeres a blocs pour compositions de bande de roulement de pneumatique |
FR2854635A1 (fr) * | 2003-05-07 | 2004-11-12 | Michelin Soc Tech | Procede de preparation de copolymeres a blocs pour compositions de bande de roulement de pneumatique, et ces copolymeres |
FR2854636A1 (fr) * | 2003-05-07 | 2004-11-12 | Michelin Soc Tech | Procede de preparation de copolymeres a blocs pour compositions de bande de roulement de pneumatique, et ces copolymeres |
Families Citing this family (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2340958A2 (fr) * | 1974-06-05 | 1977-09-09 | Michelin & Cie | Procede de polymerisation ou de copolymerisation de dienes conjugues et polymeres ainsi obtenus |
FR2480288A1 (fr) * | 1980-04-09 | 1981-10-16 | Michelin & Cie | Procede de preparation de polymeres de dienes conjugues ou de copolymeres conjugues soit entre eux, soit avec un compose vinylaromatique |
FR2480291A1 (fr) * | 1980-04-09 | 1981-10-16 | Michelin & Cie | Procede de preparation de polymeres de dienes conjugues ou de copolymeres de dienes conjugues soit entre eux, soit avec un compose vinylaromatique |
ES2020484A6 (es) * | 1990-06-29 | 1991-08-01 | Repsol Quimica Sa | Procedimiento de preparacion de homopolimeros de dienos conjugados y de copolimeros de dienos conjugados con otros dienos o compuestos vinil aromaticos. |
FR2722505B1 (fr) | 1994-07-15 | 1996-09-27 | Michelin & Cie | Compositions elastomeres chargees a la silice utilisables pour des enveloppes de pneumatiques |
FR2722503A1 (fr) | 1994-07-15 | 1996-01-19 | Michelin & Cie | Polymeres dieniques fonctionnels, leur procede de preparation et leur utilisation dans des compositions elastomeres chargees a la silice utilisables pour des enveloppes de pneumatiques |
FR2744127A1 (fr) | 1996-01-26 | 1997-08-01 | Michelin & Cie | Composition de caoutchouc a base d'un polymere dienique ayant une fonction silanol et comprenant un derive organosilane |
FR2951186B1 (fr) | 2009-10-12 | 2012-01-06 | Michelin Soc Tech | Composition de caoutchouc a base de glycerol et d'un elastomere fonctionnalise et bande de roulement pour pneumatique |
FR2992649B1 (fr) | 2012-07-02 | 2015-06-19 | Michelin & Cie | Procede de synthese en continu d'un elastomere dienique |
JP2014040554A (ja) * | 2012-08-23 | 2014-03-06 | Asahi Kasei Chemicals Corp | ブタジエン及びその製造方法 |
FR3149608B1 (fr) | 2023-06-08 | 2025-05-23 | Michelin & Cie | Elastomère diénique fonctionnel et composition de caoutchouc le contenant. |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR1476322A (fr) * | 1965-04-20 | 1967-04-07 | Shell Int Research | Procédé de polymérisation en solution de diènes avec des lithium-hydrocarbyles ou le lithium métallique comme catalyseurs |
GB1271265A (en) * | 1968-06-08 | 1972-04-19 | Bridgestone Tire Co Ltd | Method of preparing conjugated diene polymers using catalysts based on organolithium compounds |
US3664989A (en) * | 1969-10-27 | 1972-05-23 | Gennady Nikolaevich Petrov | Methods for the preparation of synthetic polymers |
US3808186A (en) * | 1972-05-09 | 1974-04-30 | V Shatalov | Method for preparing trans-1,4-polydienes |
-
1974
- 1974-06-05 FR FR7419475A patent/FR2273822A1/fr active Granted
-
1975
- 1975-06-03 ES ES438160A patent/ES438160A1/es not_active Expired
- 1975-06-03 BE BE156974A patent/BE829806A/xx not_active IP Right Cessation
- 1975-06-03 IT IT68409/75A patent/IT1041376B/it active
- 1975-06-03 BR BR4460/75D patent/BR7503483A/pt unknown
- 1975-06-03 LU LU72633A patent/LU72633A1/xx unknown
- 1975-06-03 RO RO7582416A patent/RO70318A/ro unknown
- 1975-06-04 SE SE7506393A patent/SE407068B/xx not_active IP Right Cessation
- 1975-06-04 DE DE2560562A patent/DE2560562C2/de not_active Expired
- 1975-06-04 DE DE2524849A patent/DE2524849C2/de not_active Expired
- 1975-06-04 FI FI751645A patent/FI59109C/fi not_active IP Right Cessation
- 1975-06-04 NO NO751968A patent/NO145341C/no unknown
- 1975-06-04 CA CA228,556A patent/CA1061314A/en not_active Expired
- 1975-06-04 GB GB24148/75A patent/GB1516861A/en not_active Expired
- 1975-06-04 EG EG320/75A patent/EG12270A/xx active
- 1975-06-05 NL NL757506686A patent/NL154525B/xx not_active IP Right Cessation
- 1975-06-05 IE IE1262/75A patent/IE41546B1/en unknown
- 1975-06-05 AR AR259090A patent/AR213389A1/es active
- 1975-06-05 AT AT428975A patent/AT341212B/de not_active IP Right Cessation
- 1975-06-05 ZA ZA00753634A patent/ZA753634B/xx unknown
- 1975-06-05 CH CH727775A patent/CH603706A5/xx not_active IP Right Cessation
- 1975-06-05 JP JP50068107A patent/JPS5123589A/ja active Granted
Cited By (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3023785A1 (de) | 1980-02-25 | 1981-09-03 | The General Tire & Rubber Co., 44329 Akron, Ohio | Katalysatormasse und ihre verwendung bei einem polymerisationsverfahren |
US4297240A (en) | 1980-02-25 | 1981-10-27 | The General Tire & Rubber Company | Solution polymerization |
DE3050303C2 (de) * | 1980-02-25 | 1986-08-07 | The General Tire & Rubber Co., Akron, Ohio | Aus Butadien-(1,3)- und Styroleinheiten aufgebautes kautschukartiges Copolymeres mit bis zu 30 Gewichtsprozent an Styroleinheiten und Verfahren zu dessen Herstellung |
US7205360B2 (en) | 2001-10-31 | 2007-04-17 | Michelin Recherche Et Technique S.A. | Preparation process for block copolymers for tire tread compositions, and such copolymers |
RU2289596C2 (ru) * | 2001-10-31 | 2006-12-20 | Сосьете Де Текнолоджи Мишлен | Способ получения блок-сополимеров для композиций протекторов шин и сополимеры |
WO2003037946A3 (fr) * | 2001-10-31 | 2003-09-25 | Michelin Soc Tech | Procede de preparation de copolymeres a blocs pour compositions de bande de roulement de pneumatique |
CN100516103C (zh) * | 2001-10-31 | 2009-07-22 | 米其林技术公司 | 轮胎胎面组合物用嵌段共聚物的制备方法,和这样的共聚物 |
FR2854635A1 (fr) * | 2003-05-07 | 2004-11-12 | Michelin Soc Tech | Procede de preparation de copolymeres a blocs pour compositions de bande de roulement de pneumatique, et ces copolymeres |
FR2854636A1 (fr) * | 2003-05-07 | 2004-11-12 | Michelin Soc Tech | Procede de preparation de copolymeres a blocs pour compositions de bande de roulement de pneumatique, et ces copolymeres |
WO2004099278A1 (fr) * | 2003-05-07 | 2004-11-18 | Societe De Technologie Michelin | Procede de preparation de copolymeres a blocs pour compositions de bande de roulement de pneumatique, et ces copolymeres |
WO2004099277A1 (fr) * | 2003-05-07 | 2004-11-18 | Societe De Technologie Michelin | Procede de preparation de copolymeres a blocs pour compositions de bande de roulement de pneumatique, et ces copolymeres |
US7504454B2 (en) | 2003-05-07 | 2009-03-17 | Michelin Recherche Et Technique S.A. | Process for the preparation of block copolymers for tire tread compositions, and these copolymers |
RU2366668C2 (ru) * | 2003-05-07 | 2009-09-10 | Сосьете Де Текноложи Мишлен | Способ получения блок-сополимеров для композиций для протектора пневматической шины и указанные сополимеры |
US7625983B2 (en) | 2003-05-07 | 2009-12-01 | Michelin-Recherche et Technique S.A. | Process for the preparation of block copolymers for tire tread compositions and these copolymers |
Also Published As
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PS | Patent sealed [section 19, patents act 1949] | ||
PE20 | Patent expired after termination of 20 years |
Effective date: 19950603 |