GB1525381A - Process for the polymerization of conjugated dienes - Google Patents

Process for the polymerization of conjugated dienes

Info

Publication number
GB1525381A
GB1525381A GB579477A GB579477A GB1525381A GB 1525381 A GB1525381 A GB 1525381A GB 579477 A GB579477 A GB 579477A GB 579477 A GB579477 A GB 579477A GB 1525381 A GB1525381 A GB 1525381A
Authority
GB
United Kingdom
Prior art keywords
conjugated dienes
oli
oet
polymerization
compound
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB579477A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Compagnie Generale des Etablissements Michelin SCA
Original Assignee
Compagnie Generale des Etablissements Michelin SCA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from FR7419475A external-priority patent/FR2273822A1/en
Application filed by Compagnie Generale des Etablissements Michelin SCA filed Critical Compagnie Generale des Etablissements Michelin SCA
Publication of GB1525381A publication Critical patent/GB1525381A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerization Catalysts (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

1525381 Polymerization of conjugated dienes MICHELIN & CIE 11 Feb 1977 [12 Feb 1976] 05794/77 Addition to 1516861 Heading C3P Conjugated dienes are polymerized using a catalyst consisting of an organolithium compound, a compound of Ba, Ca or Sr, an organometallic compound of a metal of Group IIB or IIIB of Mendeleef's Periodic Table and to increase the trans content an amino- or etheralcoholate of an alkali metal. In the examples butadiene is homopolymerized or copolymerized with styrene to polymers of 80 to 90% trans content using nBuLi, Banonylphenate, AlEt 3 and one of Et(OEt) 2 OLi, Et(OEt) 2 ONa, Et(OEt) 3 OLi or Et 2 NCH 2 CH 2 OLi.
GB579477A 1974-06-05 1977-02-11 Process for the polymerization of conjugated dienes Expired GB1525381A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR7419475A FR2273822A1 (en) 1974-06-05 1974-06-05 POLYMERS OR COPOLYMERS WITH MODIFIED STERIC COMPOSITION OBTAINED BY IMPLEMENTATION OF A NEW CATALYTIC COMPOSITION
FR7604115A FR2340958A2 (en) 1974-06-05 1976-02-12 PROCESS FOR POLYMERIZATION OR COPOLYMERIZATION OF CONJUGATE AND POLYMERIC DIENES THUS OBTAINED

Publications (1)

Publication Number Publication Date
GB1525381A true GB1525381A (en) 1978-09-20

Family

ID=26218363

Family Applications (1)

Application Number Title Priority Date Filing Date
GB579477A Expired GB1525381A (en) 1974-06-05 1977-02-11 Process for the polymerization of conjugated dienes

Country Status (7)

Country Link
AT (1) AT351758B (en)
BE (1) BE882565Q (en)
DE (1) DE2704763A1 (en)
FR (1) FR2340958A2 (en)
GB (1) GB1525381A (en)
LU (1) LU76740A1 (en)
NL (1) NL167977C (en)

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4297240A (en) 1980-02-25 1981-10-27 The General Tire & Rubber Company Solution polymerization
US4413098A (en) 1978-08-18 1983-11-01 Asahi Kasei Kogyo Kabushiki Kaisha Isoprene-butadiene copolymer rubber having improved processing properties
US4933401A (en) * 1988-02-26 1990-06-12 Japan Synthetic Rubber Co., Ltd. Catalyst composition for polymerization of conjugated diene and process for producing conjugated diene polymer
US5100965A (en) * 1991-04-08 1992-03-31 The Goodyear Tire & Rubber Company Process for synthesizing high trans polymers
US6018007A (en) * 1997-09-22 2000-01-25 Bridgestone Corporation Synthesis of 1,4-trans-polybutadiene using a lanthanide organic acid salt catalyst
WO2003037946A2 (en) * 2001-10-31 2003-05-08 Societe De Technologie Michelin Method of preparing block copolymers for tyre tread compositions and the copolymers thus prepared
FR2854636A1 (en) * 2003-05-07 2004-11-12 Michelin Soc Tech PROCESS FOR THE PREPARATION OF BLOCK COPOLYMERS FOR TIRE TREAD COMPOSITIONS, AND COPOLYMERS THEREOF
FR2854635A1 (en) * 2003-05-07 2004-11-12 Michelin Soc Tech PROCESS FOR THE PREPARATION OF BLOCK COPOLYMERS FOR TIRE TREAD COMPOSITIONS, AND COPOLYMERS THEREOF

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4302568A (en) * 1980-02-25 1981-11-24 The General Tire & Rubber Co. Solution polymerization
FR2480291A1 (en) * 1980-04-09 1981-10-16 Michelin & Cie PROCESS FOR THE PREPARATION OF CONJUGATED DIENE POLYMERS OR CONJUGATED DIENE COPOLYMERS EITHER BETWEEN THEM, OR WITH A VINYLAROMATIC COMPOUND
FR2480288A1 (en) * 1980-04-09 1981-10-16 Michelin & Cie PROCESS FOR THE PREPARATION OF POLYMERS OF CONJUGATED DENES OR OF CONJUGATED COPOLYMERS EITHER BETWEEN THEM, OR WITH A VINYLAROMATIC COMPOUND
JPS57159807A (en) * 1981-03-27 1982-10-02 Asahi Chem Ind Co Ltd Production of conjugated diene polymer
FR2567135B1 (en) * 1984-07-03 1989-01-13 Asahi Chemical Ind POLYMER OR COPOLYMER OF BUTADIENE AND PROCESS FOR PREPARATION
FR2722503A1 (en) 1994-07-15 1996-01-19 Michelin & Cie FUNCTIONAL DIENE POLYMERS, PROCESS FOR THEIR PREPARATION AND THEIR USE IN ELASTOMERIC SILICA-FILLED COMPOSITIONS FOR USE IN TIRE ENVELOPES
FR2722505B1 (en) 1994-07-15 1996-09-27 Michelin & Cie SILICA-FILLED ELASTOMERIC COMPOSITIONS FOR USE IN TIRE TIRES
FR2744127A1 (en) 1996-01-26 1997-08-01 Michelin & Cie RUBBER COMPOSITION BASED ON A DIENE POLYMER HAVING A SILANOL FUNCTION AND COMPRISING AN ORGANOSILANE DERIVATIVE
DE19646066A1 (en) * 1996-11-08 1998-05-14 Basf Ag Initiator systems for the anionic polymerization of vinyl monomers with polar groups
FR2951186B1 (en) 2009-10-12 2012-01-06 Michelin Soc Tech RUBBER COMPOSITION BASED ON GLYCEROL AND A FUNCTIONALIZED ELASTOMER AND TIRE TREAD FOR PNEUMATIC
FR2992649B1 (en) 2012-07-02 2015-06-19 Michelin & Cie PROCESS FOR CONTINUOUS SYNTHESIS OF DIENE ELASTOMER

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL295376A (en) * 1962-12-19
FR2273822A1 (en) * 1974-06-05 1976-01-02 Michelin & Cie POLYMERS OR COPOLYMERS WITH MODIFIED STERIC COMPOSITION OBTAINED BY IMPLEMENTATION OF A NEW CATALYTIC COMPOSITION

Cited By (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4413098A (en) 1978-08-18 1983-11-01 Asahi Kasei Kogyo Kabushiki Kaisha Isoprene-butadiene copolymer rubber having improved processing properties
US4297240A (en) 1980-02-25 1981-10-27 The General Tire & Rubber Company Solution polymerization
US4933401A (en) * 1988-02-26 1990-06-12 Japan Synthetic Rubber Co., Ltd. Catalyst composition for polymerization of conjugated diene and process for producing conjugated diene polymer
US5100965A (en) * 1991-04-08 1992-03-31 The Goodyear Tire & Rubber Company Process for synthesizing high trans polymers
US6018007A (en) * 1997-09-22 2000-01-25 Bridgestone Corporation Synthesis of 1,4-trans-polybutadiene using a lanthanide organic acid salt catalyst
US6184168B1 (en) 1997-09-22 2001-02-06 Bridgestone Corporation Synthesis of 1,4-trans-polybutadiene using a lanthanide organic acid salt catalyst
WO2003037946A2 (en) * 2001-10-31 2003-05-08 Societe De Technologie Michelin Method of preparing block copolymers for tyre tread compositions and the copolymers thus prepared
WO2003037946A3 (en) * 2001-10-31 2003-09-25 Michelin Soc Tech Method of preparing block copolymers for tyre tread compositions and the copolymers thus prepared
US7205360B2 (en) 2001-10-31 2007-04-17 Michelin Recherche Et Technique S.A. Preparation process for block copolymers for tire tread compositions, and such copolymers
FR2854636A1 (en) * 2003-05-07 2004-11-12 Michelin Soc Tech PROCESS FOR THE PREPARATION OF BLOCK COPOLYMERS FOR TIRE TREAD COMPOSITIONS, AND COPOLYMERS THEREOF
FR2854635A1 (en) * 2003-05-07 2004-11-12 Michelin Soc Tech PROCESS FOR THE PREPARATION OF BLOCK COPOLYMERS FOR TIRE TREAD COMPOSITIONS, AND COPOLYMERS THEREOF
WO2004099277A1 (en) * 2003-05-07 2004-11-18 Societe De Technologie Michelin Method for producing block copolymers for tyre tread compositions, and corresponding copolymers
WO2004099278A1 (en) * 2003-05-07 2004-11-18 Societe De Technologie Michelin Method for producing block copolymers for tyre tread compositions, and corresponding copolymers
US7504454B2 (en) 2003-05-07 2009-03-17 Michelin Recherche Et Technique S.A. Process for the preparation of block copolymers for tire tread compositions, and these copolymers
US7625983B2 (en) 2003-05-07 2009-12-01 Michelin-Recherche et Technique S.A. Process for the preparation of block copolymers for tire tread compositions and these copolymers

Also Published As

Publication number Publication date
FR2340958A2 (en) 1977-09-09
LU76740A1 (en) 1977-08-19
DE2704763C2 (en) 1987-10-22
DE2704763A1 (en) 1977-08-18
FR2340958B2 (en) 1979-07-20
NL7701476A (en) 1977-08-16
NL167977C (en) 1982-02-16
NL167977B (en) 1981-09-16
ATA89377A (en) 1979-01-15
AT351758B (en) 1979-08-10
BE882565Q (en) 1980-07-31

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Legal Events

Date Code Title Description
PS Patent sealed
PE20 Patent expired after termination of 20 years

Effective date: 19950603