GB1438722A - Production of polyethylenes - Google Patents

Production of polyethylenes

Info

Publication number
GB1438722A
GB1438722A GB4206973A GB4206973A GB1438722A GB 1438722 A GB1438722 A GB 1438722A GB 4206973 A GB4206973 A GB 4206973A GB 4206973 A GB4206973 A GB 4206973A GB 1438722 A GB1438722 A GB 1438722A
Authority
GB
United Kingdom
Prior art keywords
polyethylene
hydrocarbyl
sept
halogen
values
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB4206973A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
SnamProgetti SpA
Original Assignee
SnamProgetti SpA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by SnamProgetti SpA filed Critical SnamProgetti SpA
Publication of GB1438722A publication Critical patent/GB1438722A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02Ethene

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

1438722 Polyethylene preparation SNAMPROGETTI SpA 6 Sept 1973 [26 Sept 1972] 42069/73 Heading C3P Polyethylene having a narrow molecular weight distribution is obtained by polymerizing ethylene in the presence of a catalyst constituted by (a) a vanadium compound of formula where R<SP>1</SP> is hydrocarbyl, X is halogen, and y is 0, 1, 2 or 3, and (b) an organoaluminium compound of formula where R is hydrocarbyl, X is halogen and x is 0, 1 or 2, or such an organoaluminium compound complexed with a Lewis base. Hydrogen may be present. The products have Mw/Mn values up to 3À6 and I 21À6 /I 2À16 values up to 30. In examples polyethylene is obtained using V(NEt 2 ) 4 -EtAlCl 2 or Et 2 AlCl.
GB4206973A 1972-09-26 1973-09-06 Production of polyethylenes Expired GB1438722A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
IT29663/72A IT967855B (en) 1972-09-26 1972-09-26 PROCESS FOR THE PRODUCTION OF POLYETHYLENE WITH RESTRICTED DISTRIBUTION OF MOLECULAR WEIGHTS

Publications (1)

Publication Number Publication Date
GB1438722A true GB1438722A (en) 1976-06-09

Family

ID=11228207

Family Applications (1)

Application Number Title Priority Date Filing Date
GB4206973A Expired GB1438722A (en) 1972-09-26 1973-09-06 Production of polyethylenes

Country Status (16)

Country Link
JP (1) JPS4971078A (en)
AU (1) AU476673B2 (en)
BE (1) BE805098A (en)
CA (1) CA1028448A (en)
CH (1) CH606143A5 (en)
CS (1) CS183716B2 (en)
DD (1) DD106657A5 (en)
DE (1) DE2348489A1 (en)
DK (1) DK139525B (en)
FR (1) FR2200289B1 (en)
GB (1) GB1438722A (en)
IT (1) IT967855B (en)
LU (1) LU68501A1 (en)
NL (1) NL7313285A (en)
SU (1) SU568373A3 (en)
ZA (1) ZA735544B (en)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IT987223B (en) * 1973-05-09 1975-02-20 Snam Progetti PROCEDURE FOR THE PRODUCTION OF FIBROUS POLYALFAO LEFINE GELI
FI66405C (en) * 1978-03-31 1984-10-10 Union Carbide Corp FOERFARANDE FOER FRAMSTAELLNING AV EN POLYMERISERINGSKATALYSATOR OCH DESS ANVAENDNING FOER HOMOPOLYMERISERING AV ETYLEN
US5086023A (en) * 1991-06-13 1992-02-04 Akzo N.V. Catalyst for EPDM polymerization
DE102004029273A1 (en) * 2004-06-17 2006-01-05 Bayer Aktiengesellschaft Vanadium amido complexes for olefin polymerization

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1369866A (en) * 1962-09-25 1964-08-14 Snam Spa Process for the catalytic polymerization of mono-olefins and di-olenes

Also Published As

Publication number Publication date
DK139525B (en) 1979-03-05
SU568373A3 (en) 1977-08-05
BE805098A (en) 1974-01-16
FR2200289A1 (en) 1974-04-19
CS183716B2 (en) 1978-07-31
LU68501A1 (en) 1973-12-07
FR2200289B1 (en) 1976-10-01
CH606143A5 (en) 1978-10-31
IT967855B (en) 1974-03-11
CA1028448A (en) 1978-03-21
AU476673B2 (en) 1976-09-30
AU5914973A (en) 1975-02-13
NL7313285A (en) 1974-03-28
DD106657A5 (en) 1974-06-20
DK139525C (en) 1979-09-24
DE2348489A1 (en) 1974-04-18
ZA735544B (en) 1974-11-27
JPS4971078A (en) 1974-07-09

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Legal Events

Date Code Title Description
PS Patent sealed
PCNP Patent ceased through non-payment of renewal fee