GB1431190A - Alkali metal desulphurization process for petroleum oil stocks - Google Patents

Alkali metal desulphurization process for petroleum oil stocks

Info

Publication number
GB1431190A
GB1431190A GB2261973A GB2261973A GB1431190A GB 1431190 A GB1431190 A GB 1431190A GB 2261973 A GB2261973 A GB 2261973A GB 2261973 A GB2261973 A GB 2261973A GB 1431190 A GB1431190 A GB 1431190A
Authority
GB
United Kingdom
Prior art keywords
alkali metal
sulphur
hydrogen
oil
contacted
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB2261973A
Other languages
English (en)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Technology and Engineering Co
Original Assignee
Exxon Research and Engineering Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Exxon Research and Engineering Co filed Critical Exxon Research and Engineering Co
Publication of GB1431190A publication Critical patent/GB1431190A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B17/00—Sulfur; Compounds thereof
    • C01B17/22—Alkali metal sulfides or polysulfides
    • C01B17/34—Polysulfides of sodium or potassium
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G29/00—Refining of hydrocarbon oils, in the absence of hydrogen, with other chemicals
    • C10G29/04—Metals, or metals deposited on a carrier
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G67/00—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one process for refining in the absence of hydrogen only
    • C10G67/02—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one process for refining in the absence of hydrogen only plural serial stages only
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/32—Thermal properties
    • C01P2006/33—Phase transition temperatures
    • C01P2006/34—Melting temperatures

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Electrolytic Production Of Metals (AREA)
GB2261973A 1972-06-01 1973-05-11 Alkali metal desulphurization process for petroleum oil stocks Expired GB1431190A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US25855572A 1972-06-01 1972-06-01

Publications (1)

Publication Number Publication Date
GB1431190A true GB1431190A (en) 1976-04-07

Family

ID=22981078

Family Applications (1)

Application Number Title Priority Date Filing Date
GB2261973A Expired GB1431190A (en) 1972-06-01 1973-05-11 Alkali metal desulphurization process for petroleum oil stocks

Country Status (8)

Country Link
US (1) US3787315A (enrdf_load_stackoverflow)
JP (1) JPS5515514B2 (enrdf_load_stackoverflow)
CA (1) CA1003353A (enrdf_load_stackoverflow)
DE (1) DE2326696A1 (enrdf_load_stackoverflow)
FR (1) FR2186522B1 (enrdf_load_stackoverflow)
GB (1) GB1431190A (enrdf_load_stackoverflow)
IT (1) IT988819B (enrdf_load_stackoverflow)
NL (1) NL7307457A (enrdf_load_stackoverflow)

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JPS51123160A (en) * 1975-04-21 1976-10-27 Hitachi Ltd Electronic photograph device
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US4003824A (en) * 1975-04-28 1977-01-18 Exxon Research And Engineering Company Desulfurization and hydroconversion of residua with sodium hydride and hydrogen
US4003823A (en) * 1975-04-28 1977-01-18 Exxon Research And Engineering Company Combined desulfurization and hydroconversion with alkali metal hydroxides
US4007109A (en) * 1975-04-28 1977-02-08 Exxon Research And Engineering Company Combined desulfurization and hydroconversion with alkali metal oxides
US4017381A (en) * 1975-04-28 1977-04-12 Exxon Research And Engineering Company Process for desulfurization of residua with sodamide-hydrogen and regeneration of sodamide
US4007111A (en) * 1975-04-28 1977-02-08 Exxon Research And Engineering Company Residua desulfurization and hydroconversion with sodamide and hydrogen
US4076613A (en) * 1975-04-28 1978-02-28 Exxon Research & Engineering Co. Combined disulfurization and conversion with alkali metals
US3976559A (en) * 1975-04-28 1976-08-24 Exxon Research And Engineering Company Combined catalytic and alkali metal hydrodesulfurization and conversion process
US4087348A (en) * 1975-06-02 1978-05-02 Exxon Research & Engineering Co. Desulfurization and hydroconversion of residua with alkaline earth metal compounds and hydrogen
US4018572A (en) * 1975-06-23 1977-04-19 Rollan Swanson Desulfurization of fossil fuels
JPS604464B2 (ja) * 1975-08-21 1985-02-04 キヤノン株式会社 画像形成装置
US4366045A (en) * 1980-01-22 1982-12-28 Rollan Swanson Process for conversion of coal to gaseous hydrocarbons
US4606812A (en) * 1980-04-15 1986-08-19 Chemroll Enterprises, Inc. Hydrotreating of carbonaceous materials
DE3114766A1 (de) * 1980-04-15 1982-06-16 Rollan Dr. 89316 Eureka Nev. Swanson Verfahren zum umwandeln von kohle oder torf in gasfoermige kohlenwasserstoffe oder fluechtige destillate oder gemische hiervon
ZA812483B (en) * 1980-04-15 1982-04-28 R Swanson Process for conversion of coal to hydrocarbons and other values
US4468316A (en) * 1983-03-03 1984-08-28 Chemroll Enterprises, Inc. Hydrogenation of asphaltenes and the like
JP2706994B2 (ja) * 1990-04-09 1998-01-28 行正 佐藤 オイルスラッジ及び含油廃水の処理方法とその装置
US5695632A (en) * 1995-05-02 1997-12-09 Exxon Research And Engineering Company Continuous in-situ combination process for upgrading heavy oil
US5935421A (en) * 1995-05-02 1999-08-10 Exxon Research And Engineering Company Continuous in-situ combination process for upgrading heavy oil
US5798394A (en) * 1995-10-27 1998-08-25 Exxon Research And Engineering Company Rubber devulcanization process
US5602186A (en) * 1995-10-27 1997-02-11 Exxon Research And Engineering Company Rubber devulcanization process
US6210564B1 (en) 1996-06-04 2001-04-03 Exxon Research And Engineering Company Process for desulfurization of petroleum feeds utilizing sodium metal
US20040206670A1 (en) * 2002-12-11 2004-10-21 Paul Baskis Carbon transforming process
US7192516B2 (en) * 2003-04-17 2007-03-20 Trans Ionics Corporation Desulfurization of petroleum streams using metallic sodium
US7897028B2 (en) * 2004-01-26 2011-03-01 Ceramatec, Inc. Process for the recovery of materials from a desulfurization reaction
US7507327B2 (en) * 2004-09-30 2009-03-24 Exxonmobil Research And Engineering Company Desulfurizing organosulfur heterocycles in feeds with supported sodium
CA2531262A1 (en) * 2005-12-21 2007-06-21 Imperial Oil Resources Limited Very low sulfur heavy crude oil and process for the production thereof
WO2007095501A2 (en) * 2006-02-10 2007-08-23 Parallel Synthesis Technologies, Inc. Authentication and anticounterfeiting methods and devices
WO2008133642A2 (en) * 2006-10-13 2008-11-06 Ceramatec, Inc. Advanced metal-air battery having a ceramic membrane electrolyte
US8771879B2 (en) * 2007-09-05 2014-07-08 Ceramatec, Inc. Lithium—sulfur battery with a substantially non-porous lisicon membrane and porous lisicon layer
US8012621B2 (en) * 2007-11-26 2011-09-06 Ceramatec, Inc. Nickel-metal hydride battery using alkali ion conducting separator
US9209445B2 (en) 2007-11-26 2015-12-08 Ceramatec, Inc. Nickel-metal hydride/hydrogen hybrid battery using alkali ion conducting separator
US8088270B2 (en) 2007-11-27 2012-01-03 Ceramatec, Inc. Process for recovering alkali metals and sulfur from alkali metal sulfides and polysulfides
WO2009070600A2 (en) 2007-11-27 2009-06-04 Ceramatec, Inc. Substantially solid, flexible electrolyte for alkili-metal-ion batteries
WO2009073436A2 (en) * 2007-11-28 2009-06-11 Saudi Arabian Oil Company Process for catalytic hydrotreating of sour crude oils
US20090189567A1 (en) * 2008-01-30 2009-07-30 Joshi Ashok V Zinc Anode Battery Using Alkali Ion Conducting Separator
US10320033B2 (en) 2008-01-30 2019-06-11 Enlighten Innovations Inc. Alkali metal ion battery using alkali metal conductive ceramic separator
EP2300566B1 (en) * 2008-07-14 2016-09-07 Saudi Arabian Oil Company Process for the treatment of heavy oils using light hydrocarbon components as a diluent
WO2010009082A1 (en) * 2008-07-14 2010-01-21 Saudi Arabian Oil Company A prerefining process for the hydrodesulfurization of heavy sour crude oils to produce sweeter lighter crudes using moving catalyst system
US8372267B2 (en) * 2008-07-14 2013-02-12 Saudi Arabian Oil Company Process for the sequential hydroconversion and hydrodesulfurization of whole crude oil
US8323817B2 (en) * 2008-09-12 2012-12-04 Ceramatec, Inc. Alkali metal seawater battery
US9475998B2 (en) 2008-10-09 2016-10-25 Ceramatec, Inc. Process for recovering alkali metals and sulfur from alkali metal sulfides and polysulfides
JP5670997B2 (ja) * 2009-03-16 2015-02-18 セラマテック・インク ナトリウム−硫黄電池および２００℃未満の温度での電池の操作方法
WO2011005476A2 (en) * 2009-06-22 2011-01-13 Saudi Arabian Oil Company Alternative process for the treatment of heavy crudes in a coking refinery
US9546325B2 (en) 2009-11-02 2017-01-17 Field Upgrading Limited Upgrading platform using alkali metals
US9688920B2 (en) * 2009-11-02 2017-06-27 Field Upgrading Limited Process to separate alkali metal salts from alkali metal reacted hydrocarbons
US9441170B2 (en) * 2012-11-16 2016-09-13 Field Upgrading Limited Device and method for upgrading petroleum feedstocks and petroleum refinery streams using an alkali metal conductive membrane
US9512368B2 (en) 2009-11-02 2016-12-06 Field Upgrading Limited Method of preventing corrosion of oil pipelines, storage structures and piping
KR101736753B1 (ko) * 2009-11-02 2017-05-17 필드 업그레이딩 리미티드 알칼리 금속과 탄화수소를 사용하여 석유 공급원료를 업그레이드시키는 방법
US8859141B2 (en) 2009-11-05 2014-10-14 Ceramatec, Inc. Solid-state sodium-based secondary cell having a sodium ion conductive ceramic separator
US8771855B2 (en) 2010-08-11 2014-07-08 Ceramatec, Inc. Alkali metal aqueous battery
KR101940337B1 (ko) 2010-12-01 2019-01-18 필드 업그레이딩 유에스에이, 인코포레이티드 중온 나트륨 배터리
CN103534337B (zh) * 2011-03-23 2016-08-31 埃迪亚贝拉科技有限公司 一种用于石油油料脱硫的方法
CA2840133C (en) 2011-07-15 2018-08-14 Ceramatec, Inc. Upgrading platform using alkali metals
RU2578692C2 (ru) 2011-10-24 2016-03-27 Адитиа Бирла Нуво Лимитед Усовершенствованный способ производства углеродной сажи
JP6099676B2 (ja) 2012-02-03 2017-03-22 フィールド アップグレーディング リミテッド 石油原料の脱硫プロセス
ES2733444T3 (es) * 2012-03-30 2019-11-29 Aditya Birla Science And Tech Company Private Limited Un procedimiento para obtener polvo de negro de carbón con contenido reducido de azufre
EP2986691A4 (en) * 2013-04-15 2017-03-29 Field Upgrading Limited Process to separate alkali metal salts from alkali metal reacted hydrocarbons
DE102014012110A1 (de) 2014-08-19 2016-02-25 Dr. Bilger Umweltconsulting Gmbh Verfahren zur Entfernung von unerwünschten Verbindungen aus Mineralöl und Vorrichtung zur Durchführung des Verfahres
US10519386B2 (en) 2015-05-25 2019-12-31 Technology Holding Llc Processing alkali metal-sulfide or alkali earth metal-sulfide to obtain the alkali metal or alkali earth metal
US10435631B2 (en) 2016-10-04 2019-10-08 Enlighten Innovations, Inc. Process for separating particles containing alkali metal salts from liquid hydrocarbons
CN113881454A (zh) * 2021-09-30 2022-01-04 中国石油化工股份有限公司 一种从渣油中分离硫化钠的方法

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US213661A (en) * 1879-03-25 Improvement in plows
US1729943A (en) * 1921-06-14 1929-10-01 Firm Of Internationale Bergin Treatment by pressure and heat of heavy mineral oils and carbon material
US2020661A (en) * 1923-06-20 1935-11-12 Phillips Petroleum Co Process for treating hydrocarbon oils
US3004912A (en) * 1959-04-13 1961-10-17 Nat Distillers Chem Corp Desulfurization process utilizing metallic sodium and recycling of sludge
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US3164545A (en) * 1962-12-26 1965-01-05 Exxon Research Engineering Co Desulfurization process
US3404036A (en) * 1965-10-22 1968-10-01 Ford Motor Co Energy conversion device comprising a solid crystalline electrolyte and a solid reaction zone separator
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US3565792A (en) * 1968-06-07 1971-02-23 Frank B Haskett Cyclic process for desulfurizing crude petroleum fractions with sodium

Also Published As

Publication number Publication date
US3787315A (en) 1974-01-22
FR2186522A1 (enrdf_load_stackoverflow) 1974-01-11
FR2186522B1 (enrdf_load_stackoverflow) 1978-09-29
DE2326696A1 (de) 1973-12-20
JPS4942703A (enrdf_load_stackoverflow) 1974-04-22
CA1003353A (en) 1977-01-11
NL7307457A (enrdf_load_stackoverflow) 1973-12-04
IT988819B (it) 1975-04-30
JPS5515514B2 (enrdf_load_stackoverflow) 1980-04-24

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Legal Events

Date Code Title Description
PS Patent sealed [section 19, patents act 1949]
PCNP Patent ceased through non-payment of renewal fee