FR3018702B1 - Catalyseur fischer-tropsch a base d'un metal du groupe viiib et d'un support d'oxydes comprenant de l'alumine, de la silice, une spinelle et du phosphore - Google Patents

Catalyseur fischer-tropsch a base d'un metal du groupe viiib et d'un support d'oxydes comprenant de l'alumine, de la silice, une spinelle et du phosphore

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Publication number
FR3018702B1
FR3018702B1 FR1452311A FR1452311A FR3018702B1 FR 3018702 B1 FR3018702 B1 FR 3018702B1 FR 1452311 A FR1452311 A FR 1452311A FR 1452311 A FR1452311 A FR 1452311A FR 3018702 B1 FR3018702 B1 FR 3018702B1
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FR
France
Prior art keywords
fischer
alumina
phosphorus
silica
oxide support
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
FR1452311A
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English (en)
French (fr)
Other versions
FR3018702A1 (fr
Inventor
Dominique Decottignies
Fabrice Diehl
Vincent Lecocq
Marie Velly
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
IFP Energies Nouvelles IFPEN
Eni SpA
Original Assignee
IFP Energies Nouvelles IFPEN
Eni SpA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by IFP Energies Nouvelles IFPEN, Eni SpA filed Critical IFP Energies Nouvelles IFPEN
Priority to FR1452311A priority Critical patent/FR3018702B1/fr
Priority to DK15305245.1T priority patent/DK2921227T3/en
Priority to EP15305245.1A priority patent/EP2921227B1/fr
Priority to JP2015054085A priority patent/JP6511305B2/ja
Priority to CA2885633A priority patent/CA2885633C/fr
Priority to US14/663,731 priority patent/US9486789B2/en
Priority to CN201510124262.3A priority patent/CN104923270B/zh
Publication of FR3018702A1 publication Critical patent/FR3018702A1/fr
Application granted granted Critical
Publication of FR3018702B1 publication Critical patent/FR3018702B1/fr
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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/185—Phosphorus; Compounds thereof with iron group metals or platinum group metals
    • B01J27/1853—Phosphorus; Compounds thereof with iron group metals or platinum group metals with iron, cobalt or nickel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/12—Silica and alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/005—Spinels
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/75—Cobalt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/755—Nickel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/613—10-100 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/615—100-500 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/633—Pore volume less than 0.5 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/635—0.5-1.0 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0205—Impregnation in several steps
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0209—Impregnation involving a reaction between the support and a fluid
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B01J37/082—Decomposition and pyrolysis
    • B01J37/088—Decomposition of a metal salt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/28—Phosphorising
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
    • C10G2/33—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
    • C10G2/33—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used
    • C10G2/331—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals
    • C10G2/332—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals of the iron-group
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
    • C10G2/34—Apparatus, reactors
    • C10G2/342—Apparatus, reactors with moving solid catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
FR1452311A 2014-03-20 2014-03-20 Catalyseur fischer-tropsch a base d'un metal du groupe viiib et d'un support d'oxydes comprenant de l'alumine, de la silice, une spinelle et du phosphore Active FR3018702B1 (fr)

Priority Applications (7)

Application Number Priority Date Filing Date Title
FR1452311A FR3018702B1 (fr) 2014-03-20 2014-03-20 Catalyseur fischer-tropsch a base d'un metal du groupe viiib et d'un support d'oxydes comprenant de l'alumine, de la silice, une spinelle et du phosphore
DK15305245.1T DK2921227T3 (en) 2014-03-20 2015-02-19 FISCHER-TROPSCH CATALYST BASED ON A METAL OF GROUP VIIIB AND A CARRIER OF OXIDES INCLUDING ALUMINA, SILICA, A SPINEL AND PHOSPHOR
EP15305245.1A EP2921227B1 (fr) 2014-03-20 2015-02-19 Catalyseur fischer-tropsch à base d'un metal du groupe viiib et d'un support d'oxydes comprenant de l'alumine, de la silice, une spinelle et du phosphore
JP2015054085A JP6511305B2 (ja) 2014-03-20 2015-03-18 第ｖｉｉｉｂ族の金属と、アルミナ、シリカ、スピネルおよびリンを含む酸化物担体とをベースとするフィッシャー−トロプシュ触媒
CA2885633A CA2885633C (fr) 2014-03-20 2015-03-19 Catalyseur fischer-tropsch a base d'un metal du groupe viiib et d'un support d'oxydes comprenant de l'alumine, de la silice, une spinelle et du phosphore
US14/663,731 US9486789B2 (en) 2014-03-20 2015-03-20 Fischer-Tropsch catalyst based on a metal of group VIIIB and an oxides support comprising alumina, silica, a spinel and phosphorus
CN201510124262.3A CN104923270B (zh) 2014-03-20 2015-03-20 基于viiib族金属和包含氧化铝、二氧化硅、尖晶石和磷的氧化物载体的费托催化剂

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR1452311A FR3018702B1 (fr) 2014-03-20 2014-03-20 Catalyseur fischer-tropsch a base d'un metal du groupe viiib et d'un support d'oxydes comprenant de l'alumine, de la silice, une spinelle et du phosphore

Publications (2)

Publication Number Publication Date
FR3018702A1 FR3018702A1 (fr) 2015-09-25
FR3018702B1 true FR3018702B1 (fr) 2017-10-20

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FR1452311A Active FR3018702B1 (fr) 2014-03-20 2014-03-20 Catalyseur fischer-tropsch a base d'un metal du groupe viiib et d'un support d'oxydes comprenant de l'alumine, de la silice, une spinelle et du phosphore

Country Status (7)

Country Link
US (1) US9486789B2 (https=)
EP (1) EP2921227B1 (https=)
JP (1) JP6511305B2 (https=)
CN (1) CN104923270B (https=)
CA (1) CA2885633C (https=)
DK (1) DK2921227T3 (https=)
FR (1) FR3018702B1 (https=)

Cited By (1)

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US11208597B2 (en) 2016-10-17 2021-12-28 IFP Energies Nouvelles Cobalt catalyst comprising a support containing a mixed oxide phase including cobalt and/or nickel produced using a hydrocarbon compound

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FR3018702B1 (fr) * 2014-03-20 2017-10-20 Ifp Energies Now Catalyseur fischer-tropsch a base d'un metal du groupe viiib et d'un support d'oxydes comprenant de l'alumine, de la silice, une spinelle et du phosphore
FR3028770B1 (fr) * 2014-11-26 2016-12-02 Ifp Energies Now Procede de preparation d'un catalyseur fischer-tropsch avec traitement a la vapeur
FR3035007B1 (fr) * 2015-04-16 2019-04-19 IFP Energies Nouvelles Catalyseur comprenant une phase active dopee au bore
US10066169B2 (en) * 2015-07-14 2018-09-04 Research & Business Foundation Sungkyunkwan University Mesoporous cobalt-metal oxide catalyst for Fischer-Tropsch synthesis reactions and a preparing method thereof
FR3041270A1 (fr) * 2015-09-17 2017-03-24 Ifp Energies Now Catalyseur fischer-tropsch a base d'un metal du groupe viiib, de bore et d'un support contenant du phosphore introduit sous forme d'un sel
CN108884007A (zh) * 2016-04-04 2018-11-23 花王株式会社 醇的制造方法
FR3053260B1 (fr) * 2016-06-30 2020-12-11 Ifp Energies Now Masse de captation constitue d'une phase active sous forme cristalline
CN106268888B (zh) * 2016-07-21 2019-06-11 中国科学院广州能源研究所 一种水相催化糖醇原料制取c5、c6烷烃的催化剂及其应用
CN106268894A (zh) * 2016-07-28 2017-01-04 中国科学院广州能源研究所 一种用于低碳烷烃脱氢制乙烯和丙烯的催化剂、其制备方法及其应用
CN108144643B (zh) * 2016-12-05 2020-03-10 中国科学院大连化学物理研究所 一种催化剂及合成气直接转化制低碳烯烃的方法
CN108212162B (zh) * 2016-12-22 2021-03-16 成功大学 纳米镍触媒及碳氧化物的氢化方法
CN108654654B (zh) * 2017-04-01 2021-09-03 国家能源投资集团有限责任公司 沉淀铁费托催化剂及其制备方法和应用
KR102324239B1 (ko) * 2017-11-06 2021-11-08 한화솔루션 주식회사 방향족 화합물의 수소화 반응용 촉매 및 이의 제조방법
EP3801888A2 (en) * 2018-06-05 2021-04-14 SABIC Global Technologies B.V. Iron-magnesium silica supported catalysts, methods of making and uses thereof
WO2020028518A1 (en) * 2018-07-31 2020-02-06 Boards Of Regents Of The University Of Texas System Methods for preparation and use of liquid synthesis catalysts
CN110773189A (zh) * 2018-07-31 2020-02-11 中国石油化工股份有限公司 一种加氢活性保护催化剂及其制备与应用
CN110773182A (zh) * 2018-07-31 2020-02-11 中国石油化工股份有限公司 一种加氢活性保护催化剂及其制备与应用
FR3085284B1 (fr) 2018-09-04 2021-05-07 Ifp Energies Now Procede de preparation d'un catalyseur ou d'une masse de captation a partir de sels fondus
FR3085382B1 (fr) * 2018-09-04 2020-08-14 Ifp Energies Now Procede fischer-tropsch en presence d'un catalyseur prepare a partir d'un sel fondu
CN111318293B (zh) * 2018-12-13 2023-09-01 中国石油化工股份有限公司 一种快速提高单环芳烃含量的加氢处理催化剂及其制备方法
FR3104463B1 (fr) 2019-12-17 2021-12-17 Ifp Energies Now Catalyseur d’hydrogenolyse obtenu a partir de sels fondus et d’un additif organique
FR3104461B1 (fr) 2019-12-17 2022-06-17 Ifp Energies Now Catalyseur d’hydrogenation selective obtenu a partir de sels fondus et d’un additif organique
CN113117691A (zh) * 2020-01-16 2021-07-16 中国科学院大连化学物理研究所 一种钴基催化剂在费托合成反应中的应用
FR3112088B1 (fr) 2020-07-03 2022-09-30 Ifp Energies Now Procede de preparation d’un catalyseur d’hydrogenation selective obtenu a partir de sels fondus et un alliage nickel cuivre
FR3112087B1 (fr) 2020-07-03 2022-09-30 Ifp Energies Now Procede de preparation d’un catalyseur d’hydrogenation de composes aromatiques obtenu a partir de sels fondus et un alliage nickel cuivre
FR3125438A1 (fr) 2021-07-22 2023-01-27 IFP Energies Nouvelles Procede de preparation d’un catalyseur a partir de sels fondus et d’un support particulier
CN116020498B (zh) * 2021-10-27 2024-10-15 中国石油化工股份有限公司 加氢催化剂的制备方法、由该方法制备的催化剂及应用
CN116020497B (zh) * 2021-10-27 2024-07-12 中国石油化工股份有限公司 复合载体、加氢催化剂及其制备方法和应用
CN115555015A (zh) * 2022-09-16 2023-01-03 福州大学 一种负载型Ru和/或Ni催化剂及其制备方法
CN119034743B (zh) * 2024-08-21 2025-03-28 宁夏千锋科技有限公司 一种经济环保型氯酸盐分解工艺用添加剂

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FR2879478B1 (fr) * 2004-12-17 2007-10-26 Inst Francais Du Petrole Catalyseur a base de cobalt pour la synthese fisher-tropsch
KR100885310B1 (ko) * 2007-07-26 2009-02-24 한국화학연구원 피셔-트롭쉬 합성용 코발트／인―알루미나 촉매와 이의제조방법
KR100918105B1 (ko) 2008-03-27 2009-09-22 한국화학연구원 피셔-트롭쉬 합성용 코발트／지르코늄-인/실리카 촉매와이의 제조방법
US9242229B2 (en) 2010-08-09 2016-01-26 Gtl.F1 Ag Fischer-tropsch catalysts
FR2991199B1 (fr) * 2012-05-30 2015-05-15 IFP Energies Nouvelles Procede de preparation d'un catalyseur mettant en oeuvre une etape de sechage rapide et son utilisation pour la synthese fischer-tropsch
FR2991198B1 (fr) * 2012-05-30 2015-05-15 IFP Energies Nouvelles Procede de preparation d'un catalyseur mettant en oeuvre au moins une etape de sechage rapide et au moins une etape de sechage en lit fluidise et son utilisation pour la synthese fischer-tropsch
FR3018702B1 (fr) * 2014-03-20 2017-10-20 Ifp Energies Now Catalyseur fischer-tropsch a base d'un metal du groupe viiib et d'un support d'oxydes comprenant de l'alumine, de la silice, une spinelle et du phosphore
FR3018810B1 (fr) * 2014-03-20 2017-06-09 Ifp Energies Now Procede fischer-tropsch utilisant un catalyseur a base d'un metal du groupe viiib et d'un support d'oxydes comprenant de l'alumine, de la silice et du phosphore

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11208597B2 (en) 2016-10-17 2021-12-28 IFP Energies Nouvelles Cobalt catalyst comprising a support containing a mixed oxide phase including cobalt and/or nickel produced using a hydrocarbon compound

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CA2885633A1 (fr) 2015-09-20
CN104923270A (zh) 2015-09-23
CA2885633C (fr) 2021-10-26
US9486789B2 (en) 2016-11-08
EP2921227A1 (fr) 2015-09-23
JP6511305B2 (ja) 2019-05-15
DK2921227T3 (en) 2017-07-31
CN104923270B (zh) 2019-07-09
EP2921227B1 (fr) 2017-04-12
FR3018702A1 (fr) 2015-09-25
US20150266006A1 (en) 2015-09-24

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