CA2885633C - Catalyseur fischer-tropsch a base d'un metal du groupe viiib et d'un support d'oxydes comprenant de l'alumine, de la silice, une spinelle et du phosphore - Google Patents

Catalyseur fischer-tropsch a base d'un metal du groupe viiib et d'un support d'oxydes comprenant de l'alumine, de la silice, une spinelle et du phosphore Download PDF

Info

Publication number
CA2885633C
CA2885633C CA2885633A CA2885633A CA2885633C CA 2885633 C CA2885633 C CA 2885633C CA 2885633 A CA2885633 A CA 2885633A CA 2885633 A CA2885633 A CA 2885633A CA 2885633 C CA2885633 C CA 2885633C
Authority
CA
Canada
Prior art keywords
spinel
phosphorus
silica
oxyde
fischer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CA2885633A
Other languages
English (en)
French (fr)
Other versions
CA2885633A1 (fr
Inventor
Dominique DECOTTIGNIES
Fabrice Diehl
Vincent Lecocq
Marie Velly
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
IFP Energies Nouvelles IFPEN
Eni SpA
Original Assignee
IFP Energies Nouvelles IFPEN
Eni SpA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by IFP Energies Nouvelles IFPEN, Eni SpA filed Critical IFP Energies Nouvelles IFPEN
Publication of CA2885633A1 publication Critical patent/CA2885633A1/fr
Application granted granted Critical
Publication of CA2885633C publication Critical patent/CA2885633C/fr
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/185—Phosphorus; Compounds thereof with iron group metals or platinum group metals
    • B01J27/1853—Phosphorus; Compounds thereof with iron group metals or platinum group metals with iron, cobalt or nickel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/12—Silica and alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/005—Spinels
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/75—Cobalt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/755—Nickel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/613—10-100 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/615—100-500 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/633—Pore volume less than 0.5 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/635—0.5-1.0 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0205—Impregnation in several steps
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0209—Impregnation involving a reaction between the support and a fluid
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B01J37/082—Decomposition and pyrolysis
    • B01J37/088—Decomposition of a metal salt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/28—Phosphorising
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
    • C10G2/33—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
    • C10G2/33—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used
    • C10G2/331—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals
    • C10G2/332—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals of the iron-group
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
    • C10G2/34—Apparatus, reactors
    • C10G2/342—Apparatus, reactors with moving solid catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
CA2885633A 2014-03-20 2015-03-19 Catalyseur fischer-tropsch a base d'un metal du groupe viiib et d'un support d'oxydes comprenant de l'alumine, de la silice, une spinelle et du phosphore Active CA2885633C (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR1452311A FR3018702B1 (fr) 2014-03-20 2014-03-20 Catalyseur fischer-tropsch a base d'un metal du groupe viiib et d'un support d'oxydes comprenant de l'alumine, de la silice, une spinelle et du phosphore
FR1452311 2014-03-20

Publications (2)

Publication Number Publication Date
CA2885633A1 CA2885633A1 (fr) 2015-09-20
CA2885633C true CA2885633C (fr) 2021-10-26

Family

ID=50933354

Family Applications (1)

Application Number Title Priority Date Filing Date
CA2885633A Active CA2885633C (fr) 2014-03-20 2015-03-19 Catalyseur fischer-tropsch a base d'un metal du groupe viiib et d'un support d'oxydes comprenant de l'alumine, de la silice, une spinelle et du phosphore

Country Status (7)

Country Link
US (1) US9486789B2 (https=)
EP (1) EP2921227B1 (https=)
JP (1) JP6511305B2 (https=)
CN (1) CN104923270B (https=)
CA (1) CA2885633C (https=)
DK (1) DK2921227T3 (https=)
FR (1) FR3018702B1 (https=)

Families Citing this family (31)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR3018702B1 (fr) * 2014-03-20 2017-10-20 Ifp Energies Now Catalyseur fischer-tropsch a base d'un metal du groupe viiib et d'un support d'oxydes comprenant de l'alumine, de la silice, une spinelle et du phosphore
FR3028770B1 (fr) * 2014-11-26 2016-12-02 Ifp Energies Now Procede de preparation d'un catalyseur fischer-tropsch avec traitement a la vapeur
FR3035007B1 (fr) * 2015-04-16 2019-04-19 IFP Energies Nouvelles Catalyseur comprenant une phase active dopee au bore
US10066169B2 (en) * 2015-07-14 2018-09-04 Research & Business Foundation Sungkyunkwan University Mesoporous cobalt-metal oxide catalyst for Fischer-Tropsch synthesis reactions and a preparing method thereof
FR3041270A1 (fr) * 2015-09-17 2017-03-24 Ifp Energies Now Catalyseur fischer-tropsch a base d'un metal du groupe viiib, de bore et d'un support contenant du phosphore introduit sous forme d'un sel
CN108884007A (zh) * 2016-04-04 2018-11-23 花王株式会社 醇的制造方法
FR3053260B1 (fr) * 2016-06-30 2020-12-11 Ifp Energies Now Masse de captation constitue d'une phase active sous forme cristalline
CN106268888B (zh) * 2016-07-21 2019-06-11 中国科学院广州能源研究所 一种水相催化糖醇原料制取c5、c6烷烃的催化剂及其应用
CN106268894A (zh) * 2016-07-28 2017-01-04 中国科学院广州能源研究所 一种用于低碳烷烃脱氢制乙烯和丙烯的催化剂、其制备方法及其应用
FR3057472B1 (fr) 2016-10-17 2018-11-16 IFP Energies Nouvelles Catalyseur de cobalt a base d'un support contenant une phase d'oxyde mixte contenant du cobalt et/ou du nickel prepare par l'utilisation d'un compose hydrogenocarbone.
CN108144643B (zh) * 2016-12-05 2020-03-10 中国科学院大连化学物理研究所 一种催化剂及合成气直接转化制低碳烯烃的方法
CN108212162B (zh) * 2016-12-22 2021-03-16 成功大学 纳米镍触媒及碳氧化物的氢化方法
CN108654654B (zh) * 2017-04-01 2021-09-03 国家能源投资集团有限责任公司 沉淀铁费托催化剂及其制备方法和应用
KR102324239B1 (ko) * 2017-11-06 2021-11-08 한화솔루션 주식회사 방향족 화합물의 수소화 반응용 촉매 및 이의 제조방법
EP3801888A2 (en) * 2018-06-05 2021-04-14 SABIC Global Technologies B.V. Iron-magnesium silica supported catalysts, methods of making and uses thereof
WO2020028518A1 (en) * 2018-07-31 2020-02-06 Boards Of Regents Of The University Of Texas System Methods for preparation and use of liquid synthesis catalysts
CN110773189A (zh) * 2018-07-31 2020-02-11 中国石油化工股份有限公司 一种加氢活性保护催化剂及其制备与应用
CN110773182A (zh) * 2018-07-31 2020-02-11 中国石油化工股份有限公司 一种加氢活性保护催化剂及其制备与应用
FR3085284B1 (fr) 2018-09-04 2021-05-07 Ifp Energies Now Procede de preparation d'un catalyseur ou d'une masse de captation a partir de sels fondus
FR3085382B1 (fr) * 2018-09-04 2020-08-14 Ifp Energies Now Procede fischer-tropsch en presence d'un catalyseur prepare a partir d'un sel fondu
CN111318293B (zh) * 2018-12-13 2023-09-01 中国石油化工股份有限公司 一种快速提高单环芳烃含量的加氢处理催化剂及其制备方法
FR3104463B1 (fr) 2019-12-17 2021-12-17 Ifp Energies Now Catalyseur d’hydrogenolyse obtenu a partir de sels fondus et d’un additif organique
FR3104461B1 (fr) 2019-12-17 2022-06-17 Ifp Energies Now Catalyseur d’hydrogenation selective obtenu a partir de sels fondus et d’un additif organique
CN113117691A (zh) * 2020-01-16 2021-07-16 中国科学院大连化学物理研究所 一种钴基催化剂在费托合成反应中的应用
FR3112088B1 (fr) 2020-07-03 2022-09-30 Ifp Energies Now Procede de preparation d’un catalyseur d’hydrogenation selective obtenu a partir de sels fondus et un alliage nickel cuivre
FR3112087B1 (fr) 2020-07-03 2022-09-30 Ifp Energies Now Procede de preparation d’un catalyseur d’hydrogenation de composes aromatiques obtenu a partir de sels fondus et un alliage nickel cuivre
FR3125438A1 (fr) 2021-07-22 2023-01-27 IFP Energies Nouvelles Procede de preparation d’un catalyseur a partir de sels fondus et d’un support particulier
CN116020498B (zh) * 2021-10-27 2024-10-15 中国石油化工股份有限公司 加氢催化剂的制备方法、由该方法制备的催化剂及应用
CN116020497B (zh) * 2021-10-27 2024-07-12 中国石油化工股份有限公司 复合载体、加氢催化剂及其制备方法和应用
CN115555015A (zh) * 2022-09-16 2023-01-03 福州大学 一种负载型Ru和/或Ni催化剂及其制备方法
CN119034743B (zh) * 2024-08-21 2025-03-28 宁夏千锋科技有限公司 一种经济环保型氯酸盐分解工艺用添加剂

Family Cites Families (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS4931433B1 (https=) * 1970-02-25 1974-08-21
US4172810A (en) * 1978-05-08 1979-10-30 Exxon Research & Engineering Co. Catalysts for the conversion of relatively low molecular weight hydrocarbons to high molecular weight hydrocarbons and the regeneration of the catalysts
CN1103631C (zh) * 1994-11-02 2003-03-26 安格罗美国研究实验室(私营)有限公司 催化剂
US6333294B1 (en) * 1998-05-22 2001-12-25 Conoco Inc. Fischer-tropsch processes and catalysts with promoters
JP5072136B2 (ja) * 1998-07-24 2012-11-14 千代田化工建設株式会社 多孔性スピネル型複合酸化物の製造方法
GB2410449B (en) 2004-01-28 2008-05-21 Statoil Asa Fischer-Tropsch catalysts
JP4472556B2 (ja) * 2004-03-26 2010-06-02 コスモ石油株式会社 炭化水素油の水素化処理触媒及びその製造方法並びに炭化水素油の水素化処理方法
RU2389548C2 (ru) * 2004-09-23 2010-05-20 Статоил Аса Промотированный катализатор синтеза фишера-тропша, способ его получения и способ синтеза углеводородов фишера-тропша
FR2879478B1 (fr) * 2004-12-17 2007-10-26 Inst Francais Du Petrole Catalyseur a base de cobalt pour la synthese fisher-tropsch
KR100885310B1 (ko) * 2007-07-26 2009-02-24 한국화학연구원 피셔-트롭쉬 합성용 코발트／인―알루미나 촉매와 이의제조방법
KR100918105B1 (ko) 2008-03-27 2009-09-22 한국화학연구원 피셔-트롭쉬 합성용 코발트／지르코늄-인/실리카 촉매와이의 제조방법
US9242229B2 (en) 2010-08-09 2016-01-26 Gtl.F1 Ag Fischer-tropsch catalysts
FR2991199B1 (fr) * 2012-05-30 2015-05-15 IFP Energies Nouvelles Procede de preparation d'un catalyseur mettant en oeuvre une etape de sechage rapide et son utilisation pour la synthese fischer-tropsch
FR2991198B1 (fr) * 2012-05-30 2015-05-15 IFP Energies Nouvelles Procede de preparation d'un catalyseur mettant en oeuvre au moins une etape de sechage rapide et au moins une etape de sechage en lit fluidise et son utilisation pour la synthese fischer-tropsch
FR3018702B1 (fr) * 2014-03-20 2017-10-20 Ifp Energies Now Catalyseur fischer-tropsch a base d'un metal du groupe viiib et d'un support d'oxydes comprenant de l'alumine, de la silice, une spinelle et du phosphore
FR3018810B1 (fr) * 2014-03-20 2017-06-09 Ifp Energies Now Procede fischer-tropsch utilisant un catalyseur a base d'un metal du groupe viiib et d'un support d'oxydes comprenant de l'alumine, de la silice et du phosphore

Also Published As

Publication number Publication date
JP2015182077A (ja) 2015-10-22
CA2885633A1 (fr) 2015-09-20
CN104923270A (zh) 2015-09-23
FR3018702B1 (fr) 2017-10-20
US9486789B2 (en) 2016-11-08
EP2921227A1 (fr) 2015-09-23
JP6511305B2 (ja) 2019-05-15
DK2921227T3 (en) 2017-07-31
CN104923270B (zh) 2019-07-09
EP2921227B1 (fr) 2017-04-12
FR3018702A1 (fr) 2015-09-25
US20150266006A1 (en) 2015-09-24

Similar Documents

Publication Publication Date Title
CA2885633C (fr) Catalyseur fischer-tropsch a base d'un metal du groupe viiib et d'un support d'oxydes comprenant de l'alumine, de la silice, une spinelle et du phosphore
ZA201901026B (en) Dry reforming catalyst using metal oxide support, and method for preparing synthetic gas by using same
ZA201806817B (en) Platinum group metal catalysts supported on large pore alumina support
SG11201504141VA (en) HIGH PERFORMANCE ZIEGLER-NATTA CATALYST SYSTEMS, PROCESS FOR PRODUCING SUCH MgCl<sb>2</sb> BASED CATALYSTS AND USE THEREOF
ZA201806194B (en) Cobalt catalyst based on a support containing a mixed oxide phase containing cobalt and/or nickel prepared by the use of a dicarboxylic acid comprising at least three carbon atoms
WO2011113611A3 (en) Reforming catalyst
ZA201802178B (en) Processes for producing low nitrogen, essentially nitride-free chromium and chromium plus niobium-containing nickel-based alloys and the resulting chromium and nickel-based alloys
WO2016063043A3 (en) Process of removing heat
WO2012096744A3 (en) Rare earth-containing attrition resistant vanadium trap for catalytic cracking catalyst
ZA201503633B (en) High performance ziegler-natta catalyst systems, process for producing such supported catalysts and use thereof
WO2017017028A8 (en) Catalytically active protein aggregates and methods for producing the same
EP3152475A4 (en) Metal hydride bed, metal hydride container, and method for the making thereof
WO2016104883A8 (ko) 연성이 우수한 페라이트계 스테인리스 강재 및 그 제조방법
Giné et al. Limit cycles bifurcating from planar polynomial quasi-homogeneous centers
ZA201807579B (en) Catalyst for the hydroformylation of olefins, and use thereof
Смирнова et al. English for computer science students
WO2018125560A3 (en) Catalyst carrier and methods of forming thereof
Дроздова et al. The Keys. English Grammar
SG11202101016QA (en) Nanocage-confined catalyst, preparation process and use thereof
WO2012035004A3 (en) Hydrocracking catalyst composition
Алексеева Tourismus
Картер et al. Grammar in Use. For the 1st year students
Дзюбенко et al. SOME TIPS FOR THOSE INTERPRETING THE MODERN FICTIONAL DISCOURSE
Sergeev et al. Deutsche Obungsgrammatik. Die Syntax des Nebensatzes
Дон-Мишель Kind regards

Legal Events

Date Code Title Description
EEER Examination request

Effective date: 20200127

MPN Maintenance fee for patent paid

Free format text: FEE DESCRIPTION TEXT: MF (PATENT, 10TH ANNIV.) - STANDARD

Year of fee payment: 10

U00 Fee paid

Free format text: ST27 STATUS EVENT CODE: A-4-4-U10-U00-U101 (AS PROVIDED BY THE NATIONAL OFFICE); EVENT TEXT: MAINTENANCE REQUEST RECEIVED

Effective date: 20250311

U11 Full renewal or maintenance fee paid

Free format text: ST27 STATUS EVENT CODE: A-4-4-U10-U11-U102 (AS PROVIDED BY THE NATIONAL OFFICE); EVENT TEXT: MAINTENANCE FEE PAYMENT DETERMINED COMPLIANT

Effective date: 20250311

Free format text: ST27 STATUS EVENT CODE: A-4-4-U10-U11-U102 (AS PROVIDED BY THE NATIONAL OFFICE); EVENT TEXT: MAINTENANCE FEE PAYMENT PAID IN FULL

Effective date: 20250311

MPN Maintenance fee for patent paid

Free format text: FEE DESCRIPTION TEXT: MF (PATENT, 11TH ANNIV.) - STANDARD

Year of fee payment: 11

U00 Fee paid

Free format text: ST27 STATUS EVENT CODE: A-4-4-U10-U00-U101 (AS PROVIDED BY THE NATIONAL OFFICE); EVENT TEXT: MAINTENANCE REQUEST RECEIVED

Effective date: 20260310

U11 Full renewal or maintenance fee paid

Free format text: ST27 STATUS EVENT CODE: A-4-4-U10-U11-U102 (AS PROVIDED BY THE NATIONAL OFFICE); EVENT TEXT: MAINTENANCE FEE PAYMENT PAID IN FULL

Effective date: 20260310